CU24672B1 - METHOD FOR THE SEPARATION BY HOMOGENEOUS PRECIPITATION OF NICKEL, COBALT AND MANGANESE FROM AN ACID LEACH SOLUTION OF LATERITE-NICKEL ORE - Google Patents
METHOD FOR THE SEPARATION BY HOMOGENEOUS PRECIPITATION OF NICKEL, COBALT AND MANGANESE FROM AN ACID LEACH SOLUTION OF LATERITE-NICKEL OREInfo
- Publication number
- CU24672B1 CU24672B1 CU2020000059A CU20200059A CU24672B1 CU 24672 B1 CU24672 B1 CU 24672B1 CU 2020000059 A CU2020000059 A CU 2020000059A CU 20200059 A CU20200059 A CU 20200059A CU 24672 B1 CU24672 B1 CU 24672B1
- Authority
- CU
- Cuba
- Prior art keywords
- nickel
- cobalt
- manganese
- solution
- precipitant
- Prior art date
Links
- 239000002253 acid Substances 0.000 title abstract 6
- 238000000034 method Methods 0.000 title abstract 6
- 229910017052 cobalt Inorganic materials 0.000 title abstract 5
- 239000010941 cobalt Substances 0.000 title abstract 5
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 title abstract 5
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 title abstract 4
- 229910052748 manganese Inorganic materials 0.000 title abstract 4
- 239000011572 manganese Substances 0.000 title abstract 4
- 238000000926 separation method Methods 0.000 title abstract 3
- 238000001556 precipitation Methods 0.000 title abstract 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 11
- 229910052759 nickel Inorganic materials 0.000 abstract 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 3
- KFDQGLPGKXUTMZ-UHFFFAOYSA-N [Mn].[Co].[Ni] Chemical compound [Mn].[Co].[Ni] KFDQGLPGKXUTMZ-UHFFFAOYSA-N 0.000 abstract 2
- 238000007670 refining Methods 0.000 abstract 2
- 239000000725 suspension Substances 0.000 abstract 2
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 abstract 1
- 239000000292 calcium oxide Substances 0.000 abstract 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000000839 emulsion Substances 0.000 abstract 1
- 238000001914 filtration Methods 0.000 abstract 1
- 238000009776 industrial production Methods 0.000 abstract 1
- 229910001710 laterite Inorganic materials 0.000 abstract 1
- 239000011504 laterite Substances 0.000 abstract 1
- 238000002386 leaching Methods 0.000 abstract 1
- 239000000395 magnesium oxide Substances 0.000 abstract 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 abstract 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 abstract 1
- 239000012066 reaction slurry Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B23/00—Obtaining nickel or cobalt
- C22B23/04—Obtaining nickel or cobalt by wet processes
- C22B23/0453—Treatment or purification of solutions, e.g. obtained by leaching
- C22B23/0461—Treatment or purification of solutions, e.g. obtained by leaching by chemical methods
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B47/00—Obtaining manganese
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
<p>La presente invención describe un método para la separación por precipitación homogénea de níquel, cobalto y manganeso de una solución de lixiviación de ácido de mineral de laterita-níquel, y se relaciona con el campo técnico de la utilización integral de recursos polimetálicos complejos. El método comprende: usar una solución de hidróxido de sodio o una suspensión de emulsión formulada con óxido de calcio u óxido de magnesio finamente molido como precipitante; administrar el precipitante a un reactor homogéneo a través de una tubería que tiene un dispositivo de control de velocidad, con un dispositivo de refinación montado en un extremo de salida para refinar el precipitante; administrar la solución ácida que contiene níquel, cobalto y manganeso al reactor homogéneo a través de una tubería con un dispositivo de control de velocidad, con un atomizador montado en un extremo de salida para atomizar la solución ácida; hacer reaccionar homogéneamente la solución ácida que contiene níquel, cobalto y manganeso atomizada a una velocidad controlada y el precipitante refinado a una velocidad controlada en el reactor homogéneo para obtener una suspensión posterior a la reacción; y filtrar la suspensión posterior a la reacción para obtener una solución con níquel y cobalto precipitados y un residuo de níquel-cobalto-manganeso similar a la arena. El método tiene como ventajas que es un proceso simple, de alta operabilidad, bajo costo y producción industrial conveniente, y puede lograr una separación eficiente de níquel, cobalto y manganeso de una solución de lixiviación de ácido de mineral de níquel de laterita, por lo que el método tiene una amplia posibilidad de aplicación.</p><p>The present invention describes a method for the separation by homogeneous precipitation of nickel, cobalt and manganese from an acid leach solution of laterite-nickel ore, and relates to the technical field of comprehensive utilization of complex polymetallic resources. . The method comprises: using a sodium hydroxide solution or an emulsion suspension formulated with finely ground calcium oxide or magnesium oxide as a precipitant; administering the precipitant to a homogeneous reactor through a pipeline having a speed control device, with a refining device mounted at an outlet end for refining the precipitant; administering the acid solution containing nickel, cobalt and manganese to the homogeneous reactor through a pipeline with a speed control device, with an atomizer mounted at an outlet end for atomizing the acid solution; homogeneously reacting the atomized nickel-cobalt-manganese-containing acid solution at a controlled rate and the refined precipitant at a controlled rate in the homogeneous reactor to obtain a post-reaction slurry; and filtering the post-reaction suspension to obtain a solution with precipitated nickel and cobalt and a sand-like nickel-cobalt-manganese residue. The method has the advantages of simple process, high operability, low cost and convenient industrial production, and can achieve efficient separation of nickel, cobalt and manganese from laterite nickel ore acid leaching solution, thus that the method has a wide application possibility.</p>
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810816383.8A CN109022823B (en) | 2018-07-24 | 2018-07-24 | A method for homogeneous precipitation and separation of nickel, cobalt and manganese from laterite nickel ore acid leaching solution |
| PCT/CN2019/092496 WO2020019918A1 (en) | 2018-07-24 | 2019-06-24 | Method for homogeneous precipitation separation of nickel, cobalt and manganese from laterite nickel ore acid leaching solution |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CU20200059A7 CU20200059A7 (en) | 2021-04-07 |
| CU24672B1 true CU24672B1 (en) | 2023-08-08 |
Family
ID=64644502
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CU2020000059A CU24672B1 (en) | 2018-07-24 | 2019-06-24 | METHOD FOR THE SEPARATION BY HOMOGENEOUS PRECIPITATION OF NICKEL, COBALT AND MANGANESE FROM AN ACID LEACH SOLUTION OF LATERITE-NICKEL ORE |
Country Status (5)
| Country | Link |
|---|---|
| CN (1) | CN109022823B (en) |
| AU (1) | AU2019310838B2 (en) |
| CU (1) | CU24672B1 (en) |
| PH (1) | PH12020551383A1 (en) |
| WO (1) | WO2020019918A1 (en) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109022823B (en) * | 2018-07-24 | 2020-10-02 | 眉山顺应动力电池材料有限公司 | A method for homogeneous precipitation and separation of nickel, cobalt and manganese from laterite nickel ore acid leaching solution |
| CN111549238A (en) * | 2020-04-15 | 2020-08-18 | 广西赛可昱新材料科技有限公司 | Method for producing high-grade nickel hydroxide from laterite-nickel ore leaching solution |
| CN115109927B (en) * | 2021-03-17 | 2024-08-16 | 中国科学院过程工程研究所 | A method for removing manganese and magnesium from laterite nickel ore hydrochloric acid leaching solution |
| CN115491518B (en) * | 2022-09-16 | 2023-09-22 | 内蒙古蒙能环保科技有限公司 | Method for producing nickel sulfate and cobalt sulfate by chlorination process |
| CN115818732B (en) * | 2022-10-28 | 2024-08-20 | 中南大学 | Method for directly preparing ternary precursor by co-extraction of nickel, cobalt and manganese in laterite-nickel ore high-pressure leaching solution |
| CN116162785B (en) * | 2023-02-03 | 2024-10-15 | 广东邦普循环科技有限公司 | High nickel matte full-chain integrated leaching method, ternary positive electrode material precursor, preparation method and application thereof |
| CN116497219A (en) * | 2023-04-17 | 2023-07-28 | 浙江华友钴业股份有限公司 | Method for recovering manganese from residual liquid of laterite nickel ore hydrometallurgy |
| EP4516950A4 (en) * | 2023-06-30 | 2025-08-27 | Pt Qmb New Energy Mat | Short-process nickel-cobalt-manganese co-extraction process for hydrometallurgical treatment of lateritic nickel ore |
| AU2023446718A1 (en) | 2023-07-03 | 2025-02-06 | Gem Co., Ltd. | System for preparing new energy ni-co-mn raw material from laterite nickel ore |
| EP4527959A4 (en) * | 2023-07-31 | 2025-08-27 | Pt Esg New Energy Mat | Process and system for the recovery of manganese in a high-pressure nickel laterite leaching system |
| CN119571061B (en) * | 2025-02-10 | 2025-04-29 | 中国恩菲工程技术有限公司 | Precipitation method of heavy metal solution |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1151075C (en) * | 2002-08-16 | 2004-05-26 | 中国科学院理化技术研究所 | A method for preparing spherical nickel hydroxide |
| WO2009114903A1 (en) * | 2008-03-20 | 2009-09-24 | Bhp Billiton Ssm Development Pty Ltd | Process for the recovery of nickel and/or cobalt from high ferrous content laterite ores |
| CN102876887B (en) * | 2012-09-28 | 2014-11-05 | 广西银亿科技矿冶有限公司 | Method for comprehensively recycling metal from laterite-nickel ore leaching agent |
| CN103545504B (en) * | 2013-10-17 | 2016-01-20 | 江西赣锋锂业股份有限公司 | A kind of preparation method of ternary anode material precursor |
| CN104743616A (en) * | 2013-12-30 | 2015-07-01 | 江阴市镍网厂有限公司 | Preparation device for spherical nickel hydroxide powder |
| CN105731553A (en) * | 2016-02-03 | 2016-07-06 | 广东佳纳能源科技有限公司 | Drusy ternary anode material precursor and preparation method thereof |
| CN106673025A (en) * | 2016-11-18 | 2017-05-17 | 江苏仁欣环保科技有限公司 | Technological method for producing magnesium hydroxide by utilization of magnesium-containing wastewater generated by laterite nickel ore wet-process |
| CN109022823B (en) * | 2018-07-24 | 2020-10-02 | 眉山顺应动力电池材料有限公司 | A method for homogeneous precipitation and separation of nickel, cobalt and manganese from laterite nickel ore acid leaching solution |
-
2018
- 2018-07-24 CN CN201810816383.8A patent/CN109022823B/en active Active
-
2019
- 2019-06-24 WO PCT/CN2019/092496 patent/WO2020019918A1/en not_active Ceased
- 2019-06-24 AU AU2019310838A patent/AU2019310838B2/en active Active
- 2019-06-24 CU CU2020000059A patent/CU24672B1/en unknown
-
2020
- 2020-09-04 PH PH12020551383A patent/PH12020551383A1/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| AU2019310838A1 (en) | 2020-08-13 |
| CU20200059A7 (en) | 2021-04-07 |
| WO2020019918A1 (en) | 2020-01-30 |
| CN109022823A (en) | 2018-12-18 |
| CN109022823B (en) | 2020-10-02 |
| PH12020551383A1 (en) | 2021-07-26 |
| AU2019310838B2 (en) | 2022-03-10 |
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