CZ20003241A3 - A fragrance-enhancing composition for cosmetic products - Google Patents

Abstract

The invention relates to fragrance-enhancing compositions capable of significantly controlling human body odor, while allowing the total amount of fragrance ingredient necessary to achieve a satisfactory cosmetic product, in particular a product intended for application in the armpit. The fragrance-enhancing compositions according to the invention are obtained by mixing at least three substances selected from the group of non-nitrophenyl substances.

Description

Fragrance enhancing composition for cosmetic products

Technical field

The invention relates to fragrance-enhancing compositions which can be used in antiperspirants, various products, in particular underarm products, such as deodorants, in order to achieve a deodorant effect against the odor produced by underarm sweating and to improve the effectiveness of the fragrance components of said products.

State of the art

Various mechanisms have been and are being implemented to achieve the reduction or complete elimination of human body odor, especially odor originating from underarm sweating. These mechanisms include the reduction or elimination of sweating itself, the reduction or elimination of the cause of the odor itself (for example, by interfering with the mechanism of sweat degradation caused by the action of bacteria), or finally, masking the odor itself.

US Patent 5,540,853 describes personal care and cosmetic compositions containing long-lasting perfume, in which long-lasting perfume is evaluated by the parameter of calculated log P. PCT Application WO 97/30689 describes personal care compositions which can be used as persistent application products and which are evaluated using the same criteria.

• ·· · • ·

Patent document EP 0 7 60 243 A1 describes the use of allyl perfumes as odor control agents.

Patent document EP 0 545 556 A2 describes a perfume composition containing at least 50 wt.

specific components (in a minimum percentage of each component) selected from the group consisting of ethers, salicylates, alcohols, acetate/propionate esters and methyl ethyl ketones, whereby the composition must contain at least representatives of four groups from the above-mentioned list of groups.

US Patent No. 5,601,809 describes neutralization of promoter odor.

Various references to publications that describe the evaluation of underarm deodorants or methods for evaluating products used as deodorants are given in: P.M. Baxter et al., International Journal of Cosmetic Science, Vol. 5, 85-95 (1983); Chemical Senses, Vol. 13, No. 3, 463-471 (1988); J.A. Killian, J.Soc.Cosmetic Chemists, Vol. 3, 30-76 (1952).

Specific studies of selected fragrances are given in: A. Baydar et al., Chemical Senses, vol. 18, no. 6, 661-668 (1993) (olfactory threshold for androstenone and galaxolide); Chemical Senses, vol. 18, no. 3, 245-256 (1993)(mutual cross adaptation of the volatile steroid androstenone and a non-steroid perceptual analog); L.J. Flett, J.Soc.Cosmetic Chemists, vol.l, 304-310 (1949) (deodorant properties of nacconol).

US Patent No. 5,354,737 describes fragrance compositions, such as Tonalide, for deodorant products.

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However, there is a continuing need to improve the method of perfuming cosmetic compositions. It is therefore an object of the invention to provide fragrance compositions which are useful for odor control, particularly for the control of underarm odor. Another object of the invention is to provide fragrance enhancing components of a fragrance system for cosmetic products with the aim of reducing the overall amount of fragrance components. Yet another object of the invention is to provide fragrance enhancing components which improve the effectiveness of conventional fragrance products. Another object of the invention is to reduce the overall irritant potential of cosmetic products by reducing the amount of fragrance component necessary to obtain a satisfactory product. It is also an object of the invention to provide fragrance compositions which have improved ability to mask underarm odor. Finally, a final object of the invention is to provide improved underarm products such as deodorants and antiperspirants comprising said fragrance compositions. These and other objects are achieved by the invention.

The essence of the invention

The invention relates to fragrance-enhancing compositions capable of significantly controlling human body odor, while allowing a reduction in the total amount of fragrance ingredient necessary to achieve a satisfactory cosmetic product, in particular a cosmetic product intended for application to the armpit. The fragrance-enhancing compositions of the invention are formulated using selected ingredients having a high olfactory value and good persistence (for example, having a duration of action equal to up to 24 hours), said ingredients being combined to achieve control of human odor, in particular the odor of underarm sweat. The fragrance achieved by the fragrance-enhancing compositions of the invention is long-lasting when evaluated by accepted evaluation methods

processes. By using the compositions according to the invention, it is also possible to achieve a reduction in the amount of fragrance component used in said cosmetic products (this amount is usually 0.1 to 10% by weight, based on the total weight of the cosmetic composition), to a certain lower value.

The fragrance-enhancing compositions of the invention are obtained by combining at least three components selected from the group consisting of the following non-nitrophilic substances:

1) Cinnamon Leaf Oil (Ceylon Cinnamon Leaf Oil, a natural essential oil consisting mainly of

2-methoxy-4-allylphenol),

2) Java vetiver oil (Vetiver Oíl Java, natural essential oil from couscous, mainly composed of vetiverol alcohol),

3) Moroccan orange oil (Orange Oil Morocco, natural essential oil from orange peels or from the orange plant, consisting mainly of d-limonene,

4) Patchouli Oil (natural essential oil from patchouli, consisting mainly of patchouli alcohol and patchoulen),

5) Iso Methyl Cedryl Ketone A (multi-component proprietary formulation available from Fragrance Resources, Keyport, New, New Jersey [this material contains predominantly esters and additional minor amounts of alcohols, essential oils, terpenes and other substances]),

6) Pelargonyl (multi-component proprietary formulation available from Synarome, Bois Colombes, France; this material contains mainly ethers with small amounts of esters, alcohols and terpenes), ·· · φ φ ·· φ · • · φφφφ φφφ· φ Φ·

7) Cassis 345 Β (multi-component proprietary formulation available from Firmenich SA, Geneva, Switzerland; this material is mainly composed of alcohols and esters and also contains minor amounts of natural extracts from essential oils),

8) nonylaldehyde,

9) decylaldehyde,

10) Ambroxan (8-alpha,12-oxido-13,14,15,16-tetranorlabdan or 3aR-(3a,alpha,5a,alpha,9a,beta,9b,beta))-dodecahydro3a,6,6,9a-tetramethylnaphtho(2,1-b)furan),

11) Alpha-Iso-Amyl-Cinnamic (amylcinnamylaldehyde),

12) benzyl propionate,

13) Carvone Laevo (L-1-methyl-4-isopropenyl-6-cyclohexen-2one),

14) Beta-Gamma-Hexenyl-Salicylate (cis-3-hexenyl salicylate),

15) Citral (3,7-dimethyl-2,6-octadienal),

16) Citronellol Dextro (3,7-dimethyl-6-octen-1-ol),

17) Cyclamen Aldehyde (2-methyl-3-(para-isopropylphenyl)propionaldehyde),

18) Damascone Alpha (1-(2,6,6-trimethyl-2-cyclohexen-1-yl)2-buten-1-one)

19) Decyl Aldehyde Natural (natural decanal),

20) Ethyl Vanillin (3-ethoxy-4-hydrobenzaldehyde),

21) Eugenol (2-methoxy-4-allylphenol),

22) Florazon (4-ethyl-alpha,alpha-dimethylbenzenepropanal),

23) Geraniol (2-trans-3,7-dimethyl-2,6-octadien-8-ol),

24) Herbanate (3-(1-methylethyl)bicyclo(2,2,1)hept-5-ene-2-carboxylic acid ethyl ester)

25) Iso Butyl Quinoleine (6-sec. butyl quinoline),

26) Menthol Laevo (5-methyl-2-isopropylcyclohexanol),

27) Menthone Laevo (4-isopropyl-1-menthylcyclohexan-3-one),

28) Iralia Total (methyl ionone (mixture of isomers)),

29) Methyl Ionone Garnma Coeur (3-methyl-4-(2,6,6-trimethyl-2-cyclohex-1-yl-3-buten-2-one),

30) Para Hydroxy Phenyl Butanone Crystals (4-(4-hydroxyphenyl)-2-butanone),

31) 4-methyl-2-phenyl-3,6-dihydropyran,

32) Rootanol 100 (2-(1,1-dimethylethyl)-4-methylcyclohexanol),

33) Terpineol Alpha (1-methyl-4-isopropyl-1-cyclohexen-8ol),

34) Vanillin (4-hydroxy-3-methoxybenzaldehyde) a

35) 2,4-diethoxy-5-methylpyrimidine.

The term Deo-Key herein refers to fragrance enhancing compositions that provide an improved method of controlling ·· ·· · ·· 4« «· ··· 4 4 4 φ ···· * ··· 444 4444

4 4 · 4 · · · « · · · • ·· 4·» 444·

44·4 44 ··· ·· ·· ·· odor, especially underarm odor, either alone or in combination with other fragrance ingredients conventionally used in cosmetic compositions, especially in compositions intended for application to the underarm. These fragrance-enhancing compositions (also referred to herein as fragrance-enhancing ingredients) are prepared by combining at least three (and in particular at least five) members of the group comprising the above thirty-five ingredients in the amounts indicated below, these amounts being based on the total amount of fragrance ingredient in the cosmetic product:

a) 0.5 to 1.0% Ceylon cinnamon leaf oil,

b) 0.01 until 0.3 % Javanese vetiver oils, c) 0.5 , until 6.0 % Moroccan orange oils, d) 0.05 until 6.0 patchouli oil, e) 0.05 until 4.0 % of product Iso Methyl Cedryl Ketone A, f) 0.05 until 6.0 % of product Pelargonium, g) 0.05 until 0.9 % of product Cassis 345 B,

h) 0.005 to 0.05% nonylaldehyde,

i) 0.005 to 0.05% decylaldehyde,

j) 0.05 to 0.30% 3aR-(3a,alpha,5a,alpha,9a,beta,9b,beta)dodecahydro-3a,6,6,9a-tetramethylnaphtho(2,1-b)furan,

k) 0.05 to 10.0% amylcinnamylaldehyde,

1) 0.05 to 0.9% benzyl propionate, • ·

m) 0.05 to 0.30% L-1-methyl-4-isopropenyl-6-cyclohexen-2-one,

n) 0.05 to 0.30% cis-3-hexenyl salicylate,

o) 0.05 to 0.70% 3,7-dimethyl-2,6-octadienal,

p) 0.05 to 2.00% of 3,7-dimethyl-6-octen-1-ol,

q) 0.05 to 0.9% 2-methyl-3-(para-isopropylphenyl)propionaldehyde,

r) 0.05 to 0.9% 1-(2,6,6-trimethyl-2-cyclohexen-1-yl)-2-buten-1-one,

s) 0.005 to 0.05% of the product Decyl Aldehyd Natural,

t) 0.05 to 0.3% of 3-ethoxy-4-hydrobenzaldehyde,

u) 0.05 to 1.00% 2-methoxy-4-allylphenol,

(v) 0.05 to 0.30 % 4-ethyl-alpha,alpha-dimethylbenzenepropanol,

w) 0.05 to 6.0% 2-trans-3,7-diraethyl-2,6-octadien-8-ol,

x) 0.05 to 4.0% ethyl ester of 3-(1-methylethyl)bicyclo(2,2,1)hept-5-ene-2-carboxylic acid,

y) 0.05 to 0.30% of 6-sec.butylquinoline,

z) 0.05 to 2.0% 5-methyl-2-isopropylcyclohexanol, aa) 0.05 to 0.3% 4-isopropyl-1-methylcyclohexan-3-one, bb) 0.05 to 2.0% methyl ionone (mixture of isomers),

44 · »4 44 44 • 4 · 4 4 4 4 4 4 4 4 4 ··♦· 4 4 4 4 4 4 4 • · · · ·· 4 4 4 4 4 4 · ••4 444 4444 ···· 44 444 44 44 4· cc) 0.05 to 2.0% 3-methyl-4-(2,6,6-trimethyl-2-cyclohex-lyl-3-buten-2-one, dd) 0.05 to 0.90% 4-(4-hydroxyphenyl)-2-butanone, ee) 0.05 to 4.0% 4-methyl-2-phenyl-3,6-dihydropyran, ff) 0.05 to 0.30% 2-(1,1-dimethyl)-4-methylcyclohexanol, gg) 0.05 to 6.0% 1-methyl-4-isopropyl-1-cyclohexen-8-ol, hh) 0.05 to 0.3% 4-hydroxy-3-methoxybenzaldehyde and ii) 0.05 to 0.3% 2,4-diethoxy-5-methylpyrimidine.

To achieve the desired effect in cosmetic compositions, an amount of 1.8 to 100%, in particular 1.8 to 60%, in particular 1.8 to 35%, specifically 1.8 to 32.5% and more specifically 2.5 to 30%, 25 to 27% and in particular 20% by weight, based on the total weight of the fragrance component added to the cosmetic composition, can be added to the cosmetic composition. It is also possible that the main proportion of the fragrance component, for example 60 to 90% of the fragrance component and even up to 100% of the fragrance component, can be formed by the fragrance-enhancing composition according to the invention.

The use of these fragrance enhancing compositions makes the use of conventional perfumes more effective in controlling underarm odor and may even result in the use of smaller amounts of fragrance ingredients while achieving efficacy that is equivalent to that of compositions not containing the fragrance enhancing compositions of the invention.

Although it is possible to use the fragrance-enhancing compositions of the invention as the sole fragrance ingredient in cosmetic products,

ΦΦΦ Φ • Φ Φ • Φ φ ί t 9 ·

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Φ Φ Φ Φ Φ ΦΦ ΦΦ products such as deodorants and/or antiperspirants, it has proven advantageous (for aesthetic reasons to achieve a more sophisticated scent) to use at least partially conventional fragrance ingredients in said cosmetic compositions.

Such conventional fragrance ingredients that may be combined with the fragrance enhancing compositions of the invention include the fragrance ingredients described in PCT patent application WO 97/30689. Such specific non-limiting examples of suitable fragrance ingredients are fragrance ingredients from the following groups including:

a) salicylic acid esters, such as hexyl salicylate, hexenyl salicylate, isoamyl salicylate, benzyl salicylate and cyclohexyl salicylate,

b) cinnamic acid esters, such as amyl cinnamate, cinnamyl cinnamate and methyl cinnamate,

c) various esters, allylcyclohexanepropionate, para-tert-butylcyclohexyl acetate, cedryl formate, ethyl undecylenate, linalyl benzoate, vetiveryl acetate, dihydroisoj asmonate, geranylathranilate, benzyl acetate, such as amyl benzoate, cedryl acetate, ethylene brassylate, geranyl phenyl acetate, linalyl acetate, such as amyl cinnamylaldehyde, lillial, benzaldehyde, citronellal,

d) aldehydes, cyclamenaldehyde, hydroxycitronellal,

e) alcohols, such as geraniol, linalool, nerol, phenylethyl alcohol, alpha-terpineol, eugenol, isoeugenol, alpha-citronellol, dihydromyrcenol, aurantiol, cedrol, phenylheptanol, phenolhexanol, alpha-santalol, undecavertol (4-methyl-3-decen-5-ol), benzyl alcohol,

• · · • · ·

f) ketones, such as benzophenone, dodecalactone, gamma-n-methylionone, delta-undecalactone, gamma-undecalactone, levo-carvone, beta-methylnaphthyl ketone,

g) nitro derivatives of substituted benzenes (nitro-musks), such as ketone musk, tibetine musk and indanone musk.

The individual components listed above and used to form the fragrance enhancing compositions of the invention are commercially available and can be obtained from suppliers of fragrance ingredients and chemicals known to those skilled in the art.

The ability of the fragrance-enhancing ingredients of the invention to improve the effectiveness of conventional fragrance ingredients may in some cases be due to synergy between the individual ingredients contained in the overall fragrance component (the sum of all fragrance ingredients used in a cosmetic product) of the cosmetic product.

Each of the thirty-five ingredients listed above has a sensory olfactory score obtained by evaluation in the prescribed tests. Such tests are described in the literature and are accepted as a suitable method for evaluating the fragrance efficacy of each given fragrance ingredient. An example of one such test is described in the International Journal of Cosmetic Science, vol. 5, pp. 85-95 (1983). In these tests, numerical scales are used to evaluate the efficacy of each fragrance ingredient. One such scale is, for example, a scale from 0 to 5 (0 indicating high efficacy, while 5 indicating low efficacy). On such a scale, the individual fragrance ingredients listed above as a group of fragrance ingredients from which fragrance improving compositions would be prepared according to « ·

* 12 • · · • · 44 4 4 4 • ·· · ·* 4 4 4 4 4 · · · • · · · · · · 4 4 4 4 4 4 4 4 • · · 4 4 44 44 invention, had a moving mark between 0 and 2. Such fragrant raw materials improve deodorant ability and durability of cosmetic products (for example deodorant

stick) and also the aesthetic effect of the fragrance. Since fragrance ingredients are sometimes responsible for skin irritation, it is advantageous in the case of the invention that by using the fragrance enhancing compositions according to the invention a reduction in the total amount of fragrance ingredient in cosmetic products can be achieved.

Cosmetic compositions may contain one or more active ingredients selected, for example, from the group consisting of antiperspirant active ingredients, deodorant active ingredients, sunscreen active ingredients, insect repellents, antifungal agents, and antimicrobial agents (also referred to as bacteriostatics or antibacterial agents), and additional fragrance ingredients.

In the case where the composition contains an antiperspirant active agent, the composition may contain any of the known antiperspirant active agents. These agents may be added as solutions, suspensions or as such during mixing. These agents include, but are not limited to, aluminum hydrochloride, aluminum chloride, aluminum sesquihydrochloride, zirconyl hydroxychloride, aluminum zirconium glycine complex (e.g., aluminum zirconium trichlorohydrex gly, aluminum zirconium pentachlorohydrex gly, aluminum tetrachlorohydrex gly, and aluminum zirconium octachlorohydrex gly).

aluminumchlorohydrex PG, aluminumchlorohydrex PEG, aluminumdichlorohydrex PG and aluminumdichlorohydrex PEG. These aluminum-containing materials are generally referred to as antiperspirant-effective aluminum salts. Generally, the above antiperspirant-effective materials are referred to as antiperspirant-effective metal salts. In the context of the embodiments of the antiperspirant compositions of the invention, these may not be

B B « B

The compositions may necessarily contain aluminum-containing metal salts and may contain other antiperspirant active substances, including other antiperspirant active metal salts.

In general, Category I antiperspirant active ingredients, listed in the Food and Drug Administration's Monograph on antiperspirant drugs for over-the counter use, may be used. In addition, novel active ingredients not described in the monograph may be incorporated as antiperspirant active ingredients in the antiperspirant compositions of the invention, such as aluminum nitrate hydrate and its combinations with zirconyl hydroxychlorides and nitrides or aluminum tin hydrochlorides.

Antiperspirant active materials may be incorporated into the composition of the invention in an amount of 0.1 to 30% by weight, preferably in an amount of 15 to 25% by weight, based on the total weight of the composition. The amount so employed will depend on the formulation of the composition. For example, at an amount near the lower end of the general range mentioned above (for example, an amount of 0.1 to 10%), the antiperspirant active material will not substantially reduce the rate of sweating, but will suppress odor, for example by acting as an antimicrobial active material.

In embodiments of the compositions of the invention which contain an antiperspirant (either at a level referred to as a deodorant or at a level referred to as an antiperspirant), it will be advantageous for such compositions to also contain a stabilizing agent. Examples of suitable stabilizing agents include cosmetically acceptable alkali metal salts, bases, amines and other nitrogen-containing compounds, particularly guanidine carbonate (which is described in US Patent 5,490,979).

In the event that a bacteriostatic composition is included in the cosmetic product according to the invention, such bacteriostatically active substances may include bacteriostatically active quaternary ammonium compounds (such as cetyl trimethylammonium bromide),

2-amino-2-methyl-1-propanol (AMP), cetylpyridinium chloride, 2,4,4-trichloro-2'-hydroxydiphenyl ether (Triclosan), N-(4-chlorophenyl)-N-(3,4-dichlorophenyl)urea (Triclocarban) and various zinc salts (e.g. zinc ricinoleate). The bacteriostatically active substance may, for example, be incorporated into the composition in an amount of 0.01 to 1.0% by weight, based on the total weight of the composition. For example, Triclosan may be included in the composition in an amount of 0.05 to about 0.5% by weight, based on the total weight of the composition.

If a sunscreen is used in the composition of the invention, any conventional sunscreen may be used.

The basis of cosmetic compositions prepared using the fragrance materials according to the invention includes soap-based deodorants, in particular deodorants prepared using one or more glycols (propylene glycol, dipropylene glycol, tripropylene glycol, tetrapropylene glycol and/or other propylene glycols), silicone-based deodorants and antiperspirants, in particular antiperspirants prepared using fatty alcohols.

Products formulated as cosmetic compositions may include antiperspirants and/or deodorants, deodorant soaps, lotions, creams, lotions, scented cosmetic products such as colognes and perfumes.

In the embodiment of the composition in the form of a deodorant stick, the fragrance raw materials can be used in an amount of 0.001 to 25.00% by weight, based on the weight of the total fragrance

Φ · · · · · ·'» · · • · · · · · · · · ··· • · φφ · · · φ · · a ·· · · · · · · · · · · · Β • · · ······· ···· φ· ΦΦΦ «φ φφ φφ of the proportion used in the composition, in particular in an amount of 0.001 to 20.00% by weight, more preferably in an amount of 0.05 to 15.00% by weight and even in an amount of 0.50 to 10.00% by weight, based on the weight of the total fragrant proportion used in the composition.

Deo-Key compositions combine fragrance ingredients such as those listed below. The example compositions listed below describe compositions used in amounts of 1.8 to 32.6% by weight, based on the total weight of the fragrance used in the composition. For example, a 30% fragrance ingredient used at a 10% level would mean a maximum level for a Deo-Key composition of 3.00% by weight, based on the total fragrance ingredient of the cosmetic product. The following embodiments show how ranges of individual fragrance ingredients can be combined, with the percentages of fragrance ingredients listed being based on the weight of the total fragrance ingredients used in the composition (unless another weight basis is used, such as a basis based on the total weight of the composition).

Scent enhancing composition Green Deo Key Folder Range A B range

Cassis 345 B 0.20-1, 50 oh, 40-0.90 Damascone Alpha 0.20-1, 50 oh, 40-0.90 Para Hydroxy Phenyl Butanone Crystal 0.20-1, 50 oh, 40-0.90 Herbanate 1.00-5, 00 2, 00-4.00 Rosyran 1.00-5, 00 2, 00-4.00 Total 2.60-14 , 50 5, 2-10.7

• · «I • · · • · ·· • · ♦ • ·· · ·· * ·· 9 9 · · »· 4 9 · · · · • · · · · · · • · · 4 · ·« « • · · · · « 9 • · · * · ·· · ·

In another embodiment, the Green Deo-Key fragrance enhancing composition may be used in an amount of 25-27%, based on the weight of the total fragrance component of the composition (which is more than the specifically described amount of 2.60-14.50), provided that the ratios of the individual ingredients are maintained as described for the composition with total fragrance composition contents of the invention 2.60-14.50).

Woo Deo-Key fragrance enhancing composition

Folder Range A B range Vanillin 0.02-0.50 0.05-0.30 Vethymine 0.02-0.50 0.05-0.30 Ambroxan 0.02-0.50 0.05-0.30 4-Ethyl-apfa,alpha-dimethylbenzenepropanal (Florazon 3/034395) 0.02-0.50 0.05-0.30 Javanese vetiver oil 0.02-0.50 0.05-0.30 Iso Methyl Cedryl Ketone A 1.00-5.00 2.00-4.00 Terpineol Alpha 1.00-5.00 2.00-4.00 Patchouli oil 2.00-8.00 3.00-6.00 Amylcinnamylaldehyde 4.00-12.00 6.00-10.00 Total 8.10-32.50 13.3-25.5

Fragrance enhancing composition Floral Wood Deo-Key Ingredient_Range A Range B

Damascone Alpha 0.02-0.50 0.05-0.30

Rootanol 100

0.02-0.50 0.05-0.30 • 4 · 4 9 4 · 4 4 4 · ··· · · * · · · · » • · · · · · 4 · 4 4 ♦ • · · 4·· ···« • ··· · · · · · · ·» ··

Carvone Laevo 0.02-0.50 0.05-0.30 Benzyl propionate 0.20-1.20 0.40-0.90 Cyclamen Aldehyde 0.50-2.50 1.00-2.00 Moroccan orange oil 2.00-8.00 3.00-6.00 Citronellol Dextro 2.00-8.00 3.00-6.00 Pelargonium 2.00-8.00 3.00-6.00 Total 6.76-29.20 10.6-21.8 Composition improving smell Citrus Wood Deo-Key Folder Range A B range Nonylaldehyde 0.02-0.1 0.005-0.05 Decylaldehyde 0.002-0.1 0.005-0.05 Cis-3-hexenyl salicylate 0.02-0.4 0.05-0.30 Citral Lemarome 0.02-0.4 0.05-0.30 Cyclamen Aldehyde 0.20-1.20 0.40-0.90 Citronellol Dextro 0.8-2.40 1.00-2.00 Iralia Total 0.8-2.40 1.00-2.00 Total 1.84-7.00 2.5-5.6 Composition improving smell Amber Wood Deo -Key Folder Range A Range B Isobutyl Quinolein 0.02-0.4 0.05-0, 30

Abroxan

0.02-0.4

0.05-0.30 • · · • » 9 9 · · V • · « · · · • 9 99 9 9

Ceylon tea tree leaf oil

cinnamon tree 0.4-1.20 0.60-1.00 Eugenol 0.4-1.20 0.60-1.00 Iso Methyl Cedryl Ketone A 1.00-5.00 2.00-4.00. Patchouli oil 2.00-7.00 3.00-6.00 Total 3.84-15.2 6.3-12.6

Mint Deo-Key Fragrance Enhancer Folder Range A B range 4-Isopropyl-1-methylcyclo- hexan-3-one (Methone Laevo) 0.02-0.40 0.05-0.30 Ethyl Vanillin 0.02-0.40 0.05-0.30 Decyl Aldehyde Natural decanal 951512) 0.1-0.5 0.15-0.40

5-Methyl-2-isopropylcyclo-

hexanol (Menthol Laevo) 0.8-2.40 1.00-2.00 Methyl Ionone Gamma Coeur 0.8-2.40 1.00-2.00 Geraniol 2.00-7.00 3.00-6.00 Total 3.74-13.10 5.3-11.0

It should be noted that other embodiments may contain greater total amounts of the fragrance enhancing composition than those listed for the above-mentioned compositions, provided that the same ingredient ratios are maintained for each composition and that a multiple of these ratios is used to obtain a greater total amount of composition than that listed in the specific cases listed above. This is particularly

9 described above Deo-Key.

in the case of a fragrance-enhancing composition

Green

Cosmetic compositions in which the invention may be used take a variety of forms, including sticks, gels, creams and liquids (e.g., roll-on formulations) and aerosols.

Solid compositions

Ingredients

Solid rod A

Aluminum zirconium tetrachlorohydrex-gly

Volatile silicone (e.g. cyclomethicone) Stearyl alcohol

Talc

Hydrogenated castor oil

PPG-14-butyl ether

A fragrance component of which 2.5-30% is made up of the Deo-Key composition (for example 2%, based on the total weight of the stick

Allantoin

Glyceryl stearate

PEG 100-stearate

Content_Beneficial content

15-25 18-22 30-60 45-55 5-15 8-12 5-15 8-12 0-5 1-3 0-3 1-2

0.1-10 1-3 0.01-1 0.05-0.5 0.01-1 0.05-0.5 0.01-1 0.05-0.5

• · · * » · · • 4 44

4«

4444 44

Dye (optional) 0.001-0.1 0.005

Solid stick B) (deodorant)

SD-alcohol 40

Propylene glycol

Sodium stearate

Water

Fragrance ingredient, of which 2.5-30% is made up of the Deo-Key composition

Trisodium EDTA

Dye (optional)

Solid bar C

Solvent (chosen from glycols as in the case of stick D)

Water

Compatible gelling agent

Calming agent

Antibacterial agent

Anti-irritant

Fragrance component, of which 2.5-30% is made up of the Deo-Key composition (for example 2%, based on the total weight of the stick)

Solid stick

5-20 10-15 5-20 10-15 2-10 6-8 0-20 10-15

0.1-10 1-3 0.05-0.5 0.1-0 0.001-0.01 0.005

5-88 60-75 1-50 10-20 1-10 4-8 0-5 1-2 0.01-2.0 0.05- 0.1-10 1-3

0.1-10 0.5-3

D(deodorant)

• · • 9 9 9 9 99 99 • · • 9 9 9 9 9 9 9 9 • • ·♦ 9 9 • 9 • 9 9 9 • • 9 9 9 • 9 9 9 9 9 9 9 9 • · 9 9 9 9 9 9 9 9 9

Glycol component (one or more glycols such as propylene glycol, di-, tri-, tetra- and

higher propylene glycols) 60-98 65-75 Sodium stearate 0-10 6-8 Water 0-40 10-25 Fragrance component, of which 2.5-30% is made up of the Deo-Key composition (for example 2%, based on the total weight of the stick) 0.1-10 0.5-3 Gels Ingredients Range Beneficial range Gel A Cyclomethicone and dimethicone polyol 5-30 8-10 Cyclomethicone 60-90 70-80 ^: Aluminum hydrochloride 10-25 Propylene glycol 10-20 12-18 Water 10-30 15-25 A fragrance component, of which 2.5-30% is made up of the Deo-Key composition (for example, 2 0, based on the total weight of the product 0.5-10 1-3

« · · · • · · • · ·· • 99 99 99 • · · · 9 9 9 ·

9 9 9 9 9 9

9 9 9 9 9 9 9

9 9 9 9 9 9

999 9 9 9 9 9 9 9

Creams

Cream A

Aluminum hydrochloride 10-25 15-22 Aluminum chloride 5-15 6-12 Water 40-70 50-65 Glyceryl stearate 1-20 5-15 PEG-4 0-stearate 1-20 5-15 Cetyl palmitate or synthetic spermaceti 1-10 3-7 Glycerin 1-10 2-8 Dimethicone 1-10 2-8 Isopropyl palmitate 1-10 2-5 Petrolatum and Lanolin- alcohol 1-10 2-6 Lanoline wax 1-10 2-8 Hydroxypropylmethyl- cellulose 0.5-1.5 0.8-1.2

The fragrant ingredient from which

2.5-30% is made up of the Deo-Key composition (for example 1%, based on the total

metal weight of the product 0.1-10 1-3 Titanium dioxide 0.1-1 0.2-0.8 Lanolin 0.5-1 0.6-0.8 Propylparaben 0.05- 0.1-0.2 Mineral oil 0.5-1 0.6-1

• · ·♦ · ·· • · · · · · ·

9 99 99 9

9 9 9 9 9

9999 99 999 9 9

99 • 9 9 9

9 9 9

9 9 9

9 9 9

99

Liquids

Roll-on A (antiperspirant)

Aluminum hydrochloride (for example 21%) 10-21 Water (for example 67%) 50-80 PPG-ll-stearyl ether (e.g. 7%) 5-10 Steareth-2 (for example 5%) 2-10 Steareth-20 (for example 5%) 2-10

18-22

65-75

6-8

4-8

4-8

The fragrant ingredient from which

2.5-30% is made up of Deo-Key composition (for example 1%, based on the total weight of the product) 0.1-10 1-3

Roll-on product (antiperspirant)

Zirconium-aluminum glycine hydrochloride complex 10-25 18-22 (e.g. 20%)

Water

20-40

24-30 (for example 24.3%)

PEG-4 0-stearate

5-15 8-12 for example 10%)

Glyceryl stearate

Glycerine

5-15 8-12

5-10 6-8 (for example 6.8%) • Β ·· Β Β Β BB ·Β • · · ·· · · · · · «

BBBBB BBBBB

Β Β ΒΒ ΒΒ Β · · Β Β Β

B · · BBB BBB

BBBB BB BB·BB BB «*

Refined paraffin

Isopropyl palmitate

4- 10 5-9 (for example 6.2 /)

5- 10 6-9 (for example 7.3%)

Magnesium aluminosilicate 10-20 12-18 (e.g. 15.2%)

The fragrant ingredient from which

2.5-30% is made up of the Deo-Key composition (for example

1.5%, based on the total weight of the bar 0.1-10 1-3

Roll-on C

Aluminum hydrochloride 10-25 15-22 (e.g. 21%)

Cyclomethicone 40-80 60-70 (preferably e.g. 70%)

Quaternium-18-hectorite 0-6 3-5 (e.g. 4%)

SD-alcohol 40 (3.1% vol.) 1-4 2.5-3.5 e.g. 2%)

Steareth-2 0

0-4

1-3

Fragrance component, of which 2.5-30% is made up of the Deo-Key composition (for example, %, based on the total weight of the product 0.5-10 1-3

Roll-on D

10-80 35-55

Cyclomethicone

9

9999 99

Cyclomethicone and dimethicone polyol

5-20

10-15

Aluminum zirconium tetrachlorohydrex-gly

10-25

15-22

Propylene glycol

5-15

7-12

Water

0.5

2-4

The fragrant ingredient from which

2.5-30% is made up of Deo-Key composition

0.5-10

1-3

Aerosols

Aerosol ” A

An aerosol formulation is prepared using the following ingredients, the amounts of which are based on the total weight of the composition: aluminum hydrochloride (e.g. 10-22%), isobutane (e.g. 30-45%), cyclomethicone (e.g. 10-20%), isopropyl myristate (e.g. 2-5%), dimethicone (e.g. 2-4%), quaternium-18-hectorite (e.g. 1-2%), propylene carbonate (e.g. 0.5-1%), an effective amount of a fragrance component, of which

2.5-30% is made up of the Deo-Key composition (for example 1%, based on the total weight of the product).

Aerosol B

An aerosol composition is prepared containing the following ingredients, the amounts of which are based on the total

B · B B

Β Β Β Β Β • Β · Β • Β Β Β Β • Β Β Β Β mass composition: SD-alcohol 40 (for example 10-30%), isobutane (for example 10-30%), propane (for example 10-20%), propylene glycol (for example 5-20%), butane (for example 5-10

%), an effective amount of a fragrance component, of which 2.5-30% is formed by the Deo-Key composition (for example 1%, based on the total weight of the product), an effective amount of the product Triclosan.

Pump spray A

A pump spray formulation is prepared containing the following ingredients, the amounts of which are based on the total weight of the composition: cyclomethicone (e.g. 40-60%), SD-alcohol 4B (anhydrous alcohol) (e.g. 20-40%), PEG-3-myristyl ether (e.g. 2-10%), C12-15-alcohol benzoate (e.g. 2-10%), water (e.g.

2-10%), an effective amount of a fragrance component, of which 2.30% is formed by the Deo-Key composition, dimethicone (e.g. 0.5-5%), zinc phenosulfonate (e.g. 0.1-1.0%).

Pump spray B (amounts of ingredients are based on the total weight of the composition)

Ingredients Range Example Cyclomethicone 30-50% 33% Mineral oil 1-10% 2.0% Phenyltrimethicone 1-10% 5.0% Cyclomethicone and dimethicone polyol 0.5-10% 10% Polysorbate 20 0.5-5% 1.0% Aluminum hydrochloride 5-25% 10-25%

·· ·· · ·· ·· ·· ·· · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · ·· ·· ·» ·<

The fragrant ingredient from which

2.5-30% is made up of the composition Deo-Key 0.1-10

10-25%

Examples of embodiments of the invention

The following examples are for illustrative purposes only and are not intended to limit the scope of the invention. In these examples and elsewhere in the description of the invention, chemical symbols and chemical nomenclature have their usual meanings. Temperatures are given in degrees Celsius unless otherwise specified. The amounts of components are given in weight percent based on the weight basis indicated; if no weight basis is indicated, then the percentage is based on the total weight of the composition.

the names of chemical ingredients match those listed in the CTFA International Cosmetic

Dictionary (Cosmetics, Toiletry and Fragrance Association, Inc., ^4th ed.1991). It should be noted that the antiperspirant active ingredients described in the following examples and elsewhere in the specification are usually added in solution form, for example in the form of a 50% solution. Effective amounts of the fragrance ingredient range from 0.1 to 10% by weight, based on the total weight of the cosmetic composition, part of which is listed as the Deo-Key composition.

Individual designations

Ingredients

Example 1

General method A

The Deo-Key fragrance-enhancing composition according to the invention can be prepared by conventional mixing techniques known per se. These techniques take into account the solid or liquid nature of the products used and the fact that it may be necessary to pre-dissolve or melt said products before mixing them. First, the solid ingredients are added and these are dissolved or melted until a liquid is obtained by heating in a sand bath (for example at a temperature in the range of 40 to 60 ° C). In a subsequent step, the liquid ingredients can then be added and the final mixture is obtained at room temperature and with mixing (for example at 500 rpm in an AM 3000 D mixer commercially available from Heidolph).

For example, in one method, ingredients are weighed into a beaker that has been tared (Mettler PJ3600 Delta Range balance). The total amount of Deo-Key material should be calculated so that the minimum amount of individual material is greater than 1 gram (minimum weighable amount). In the event of an error, this error should be corrected by repeating the entire weighing process; this sequential weighing methodology eliminates loss of ingredients during transport from one beaker to another.

Example 2

Test samples can be prepared using ten Webril disc pads to which the selected test product is applied by rubbing or smearing one side of the pad. Each treated pad is then placed in a disposable plastic Petri dish, which is appropriately labeled. Each pad is then allowed to dry for 24 hours at room temperature, with the Petri dishes uncovered during drying.

Φ· »* » » v • φφφ • ·· «φ Μ φφφφ φφφ φφφ» φφφφ φφ • φ ♦ φφφφ φφφ φφφ φφφ lids. After 24 hours, a solution of synthetic odorant material is applied to each pad in an amount that represents about a nine-fold excess of the amount of test sample that was previously applied to the pad. The said solution is applied dropwise to the pad so that the solution covers the entire surface of the pad. The pad is then allowed to dry for 2 hours, after which the Petri dishes are closed with lids. The dishes are then stored at room temperature for 48 hours, after which the odor evaluation is carried out. The odor evaluation is carried out by a certain number of trained persons, the results of the odor evaluation being carried out using a predetermined numerical scale.

Example 3

Test method for determining the effectiveness of a fragrance ingredient against odor

The Green Deo-Key and Woody Deo-Key compositions prepared as described in Example 1 were tested against traditional 2.5% fragrance formulations. The efficacy of each test sample was evaluated using a 0 to 7 rating system, assessing the efficacy of the samples in odor control. The results below show that the 0.4% concentration of the Deo-Key compositions was as effective as the 2.5% concentration of the traditional fragrance compositions. These results show that the Deo-Key compositions can be used at much lower concentrations.

Type and concentration of Deo-Key Brand

Comparative experiment

0.4% Green Deo-Key

0.3

0.4

I ►· 4 • 4 4 * · 4 4 • · 4 4 ♦ «4 ·

4« 4 4 4 4 «4 44φ · 4 4

444 4 4 44 44

0.4% Woody Deo-Key

0.6

0.6

Example 4

The evaluation was performed using a group of five trained individuals. The three samples tested were: sample A1 - commercial product A, which is assumed to contain about 2.5% of a conventional fragrance ingredient; sample B1 = a cosmetic stick formulated using 0.4% of the Green Deo-Key composition described above; and sample C1 = the same cosmetic stick as sample B1, but which does not contain the Deo-Key composition of the invention, but contains

1.1% conventional fragrance component. The evaluation results represent the average of the marks given to the samples by the evaluators, with the following rule: the higher the mark, the worse the performance. The following results were achieved during the evaluation: sample Al - 0.45, sample Bl - 0.33, sample Cl - 0.58.

Example 5

The procedure described in Example 4 is repeated, with sample A2 = sample A1, sample B2 = sample B1, and sample C2 is the same cosmetic formulation as sample B1 except that 0.6% of the Deo-Key composition is used. The following results were obtained when evaluating: sample A2 - 0.45, sample B2 - 0.33, sample C2 - 0.19.

Claims (3)

PATENT CLAIMS 1.00 2.00 and methyl ionone (mixture of isomers), based on the total weight of the fragrance component of the cosmetic composition, wherein the total amount of added fragrance improving composition is 2.5 to 5.6%, based on the total weight of the fragrance component of the cosmetic composition. 26. A cosmetic composition according to claim 3 obtained using a fragrance-enhancing composition comprising 0.02 to 0.4% isobutylquinoline, 0.02 to 0.40% 3aR-(3a, alpha,5a, alpha,9a, beta,9b, beta)-dodecahydro-3a,6,69a-tetramethylnaphtho(2,1-b)furan, 0.4 to 1.20% Ceylon cinnamon leaf oil, 0.4 to 1.20% 1-(2,6,6-trimethyl-2-cyclohexen-1-yl)-2-buten-1-one, 0.05 to 0.30% 2-(11-dimethylethyl)-4-methylcyclohexanol, 0.05 to 0.30% L-1-methyl-4-isopropenyl-6-cyclohexen-2-one, 0.40 to 0.90% benzyl propionate, 1.00 to 2.00% 1-(2,6,6-trimethyl-2-cyclohexen-1-yl)-2-buten-1-one, up to 0.5 1-(2,6,6-trimethyl-2-cyclohexen-1-yl)-2-buten-1-one, 0.40 to 0.90% para-hydroxyphenylbutanone, crystalline, 2.00-4.00% ethyl ester of the acid 3-(1-methylethyl)bicyclo (2,2,1)hept-5-ene-2-carboxylic acid, 1-(2,6,6-trimethyl-2-cyclohexen-1-yl)-2-buten-1-one, 0.20 to 1.50% para-hydroxyphenylbutanone, crystalline, 1.00 to 5.00% ethyl ester of the acid 3-(1-methylethyl)bicyclo (2,2,1)hept-5-ene-2-carboxylic acid and 1.00 to 5.00 4-methyl-2-phenyl-3,6-dihydropyran, based on the total weight of the fragrance component of the cosmetic composition, wherein the total added amount of the fragrance improving composition is 2.60 to 14.50%, based on the total weight of the fragrance component of the cosmetic composition. 19. A cosmetic composition according to claim 4 obtained using a fragrance enhancing composition comprising 0.40 to 0.90% of Cassis 345 B, 0.40-0.90% 1. 4. A cosmetic composition characterized in that it is obtained using a fragrance-enhancing composition according to claim 1-(2,6,6-trimethyl-2-cyclohexen-1-yl-2-buten-1-one), 0.05 to 0.9%, decylaldehyde natural, 0.005 to 0.05%, 3- ethoxy-4-hydrobenzaldehyde, 0.05 to 0.3%, 1. A fragrance-enhancing composition for a cosmetic composition, obtained by adding, as part of the total fragrance component of the cosmetic composition, at least three substances selected from the group consisting of the following non-nitrophilic substances: a) Ceylon cinnamon leaf oil, b) Javanese vetiver oil, c) Moroccan orange oil, d) patchouli oil, e) Iso Methyl Cedryl Ketone A, f) Pelargonium, g) Cassis 345 B, h) nonylaldehyde, (i) decylaldehyde j) 3aR-(3a,alpha,5a,alpha9a,beta,9b,beta)dodecahydro3a, 6,6, 9a-tetramethylnaphtho(2,1-b)furan, k) amylcinnamylaldehyde, (i) benzyl propionate, m) L-1-methyl-4-isopropenyl-6-cyclohexen-2-one n) cis-3-hexenyl salicylate, o) 3,7-dimethyl-2,6-octadienal, p) 3,7-dimethyl-6-octen-1-ol, q) 2-methyl-3-(para-isopropylphenyl)propionaldehyde, r) 1-(2,6,6-trimethyl-2-cyclohexen-1-yl-2-buten-1-one), s) natural decylaldehyde, t) 3-eth,hoxy-4-hydrobenzaldehyde, u) 2-methoxy-4-allylphenol, v) 4-ethyl-alpha,alpha-dimethylbenzenepropanal, w) 2-trans-3,7-dimethyl-2,6-octadien-8-ol, x) 3-(1-methylethyl)bicyclo(2,2,1)hept-5-ene-2-carboxylic acid ethyl ester, (y) isobutylquinoline, z) 5-methyl-2-isopropylcyclohexanol, aa) 4-isopropyl-1-methylcyclohexan-3-one, bb) methyl ionone (mixture of isomers), cc) 3-methyl-4-(2,6,6-trimethyl-2-cyclohex-1-yl-3-buten-2one, dd) para-hydroxyphenylbutanone crystalline, ee) 4-methyl-2-phenyl-3,6-dihydropyran, ff) 2-(1,1-dimethylethyl)-4-methyl-cyclohexanol, gg) 1-methyl-4-isopropyl-1-cyclohexen-8-ol, hh) 4-hydroxy-3-methoxybenzaldehyde and ii) 2,4-diethoxy-5-methylpyrimidine. 2-methoxy-4-allylphenol, 2.00 to 4.00 of Iso Methyl Cedryl Ketone A and 3.00 to 6.00% of patchouli oil, based on the total weight of the fragrance component of the cosmetic composition, wherein the total amount of added fragrance improving composition is 6.3 to 12.6%, based on the total weight of the fragrance component of the cosmetic composition. 28. A cosmetic composition according to claim 3 obtained using a fragrance enhancing composition containing 0.02 to 0.40% 4-isopropyl-1-methylcyclohexan-3-one, 0.02 to 0.40% 3-ethoxy-4-hydrobenzaldehyde, 0.1 to 0.5% natural decylaldehyde, 0.8 to 2.4% 5-methyl-2-isopropylcyclohexanol, 0.8 to 2.4% 3-methyl-4-(2,6,6-trimethyl-2-cyclohex-1-yl)-3-buten-2-one and 2.00 to 7.00% of 2-trans-3,7-dimethyl-2,6-octadien-8-ol, based on the total amount of the fragrance component of the cosmetic composition, wherein the total amount of the added fragrance improving composition is 3.74 to 13.10%, based on the total weight of the fragrance component of the cosmetic composition. 4· ·· * ·· 44 44 •44 4444 4 4 4 4 • ··· 4 4 · 4 4 4 4 44 44 44 444 44 4 4 44 444 444· 44· 4 44 444 44 44 44 29. The cosmetic composition according to claim 4 obtained using a fragrance-enhancing composition containing 0.05 to 0.30% 4-isopropyl-1-methylcyclohexan-3-one, 0.05 to 0.30% 3-ethoxy-4-hydrobenzaldehyde, 0.15 to 0.40% natural decylaldehyde, 1.00 to 2.00% 5-methyl-2-isopropylcyclohexanol, 1.00 to 2.00% 2-methoxy-4-allylphenol, 1.00 to 5.00 of Iso Methyl Cedryl Ketone A and 2.00 to 7.00% of patchouli oil, based on the total weight of the fragrance component of the cosmetic composition, wherein the total amount of the added fragrance-enhancing composition is 3.84 to 15.20%, based on the total weight of the fragrance component of the cosmetic composition. 27. A cosmetic composition according to claim 4 obtained using a fragrance-enhancing composition comprising 0.05 to 0.30% isobutylquinoline, 0.05 to 0.30% 3aR-(3a,alpha,5a,alpha,9a,beta,9b,beta)-dodecahydro-3a,6,69a-tetramethylnaphtho (2,1-b)furan, 0.6 to 1.00% Ceylon cinnamon leaf oil, 0.6 to 1.00% 2.00% 3,7-dimethyl-6-octen-1-ol and 1.00 to decylaldehyde, 0.05 to 0.40 to 0.05% 0.05 to 0.30 0.30% 0.90% 2-methyl-3-(para-isopropylphenyl)propionaldehyde, 2-methyl-3-(para-isopropylphenyl)propionaldehyde, 3.00 to 6.00 Moroccan orange oil, 3.00 to 6.00 3,7-dimethyl-6-octen-1-ol, 3.00 to 6.00% of the product Peralgyl, based on the total weight of the fragrance component of the cosmetic composition, wherein the total amount of the added fragrance improving composition is 10.6 to 21.8%, based on the total weight of the fragrance component of the cosmetic composition. 24. A cosmetic composition according to claim 3 obtained using a fragrance-improving composition comprising 0.002 to 0.1% nonylaldehyde, 0.002 to 0.1% decylaldehyde, 0.02 to 0.4% cis-3-hexenyl salicylate, 0.02 to 0.4% 3,7-dimethyl-2,6-octadienal, 0.90 to 1.20% 2-methyl-3-(para-isopropylphenyl)propionaldehyde, 0.8 to 2.40% 3,7-dimethyl-6-octen-1-ol and 0.8 to 2.40% methyl ionone (mixture of isomers), based on the total weight of the fragrance component of the cosmetic composition, wherein the total amount of added fragrance-improving composition is 1.84 to 7.00%, based on on compositions. total weight of the cosmetic fragrance ingredient 25. A cosmetic composition according to claim 4 obtained using a fragrance-enhancing composition comprising 0.005 to 0.05% of nonylaldehyde, 0.005 to 0.05% of cis-3-hexenyl salicylate, 3,7-dimethyl-2,6-octadienal, 2-methyl-3-(para-isopropylphenyl)propionaldehyde, 8.00 Moroccan orange oil, 2.00 3,7-dimethyl-6-octen-1-ol, 2.00 to 8.00% Peralgyl, based on the total weight of the fragrance component of the cosmetic composition, wherein the total amount of the added fragrance-improving composition is 6.76 to 29.20%, based on the total weight of the fragrance component of the cosmetic composition. 23. The cosmetic composition according to claim 4 obtained using a fragrance-enhancing composition containing 0.05 to 0.30% 2.00 to 8.00 of the product up to 1.20% benzyl propionate, 0.50 to 2.5% 2-(11-dimethylethyl)-4-methylcyclohexanol, up to 0.5% L-1-methyl-4-isopropenyl-6-cyclohexen-2-one, 0.02 0.02 0.20 2.00 to 4.00% of 4-methyl-2-phenyl-3,6-dihydropyran, based on the total weight of the fragrance component of the cosmetic composition, wherein the total amount of added fragrance improving composition is 5.2 to 10.7%, based on the total weight of the fragrance component of the cosmetic composition. 44 44 » 4 4 4 4 4 4 4444 44 20. A cosmetic composition according to claim 3 obtained using scent enhancing compositions contain ing 0.02 until 0.50 4-hydroxy-3-methoxybenzaldehyde, 0, 02 until 0.50 o 0 of 2,4-diethoxy-5-methylpyrimidine, 0, 02 until 0.50 o 0 3aR-(3a,alpha, 5a,alpha,9a,beta,9b,beta)-dodecahydro-3a,6, 6, 9a-tetramethylnaphtho (2,1-b)furan, 0.02 to 0.5% 4-ethylalpha,alpha-dimethylbenzenepropanal, 0.02 to 0.5% Javanese vetiver oil, 1.00 to 5.00% Iso Methyl Cedryl Ketone A, 1.00 to 5.00% . 1-methyl-4-isopropyl-1-cyclohexen-8-ol, 2.00 to 8.00% patchouli oil and 4.00 to 12% amylcinnamylaldehyde, 4 based on the total weight of the fragrance component of the cosmetic composition, wherein the total amount of added fragrance improving composition is 8.10 to 32.50%, based on the total weight of the fragrance component of the cosmetic composition. 21. A cosmetic composition according to claim 4 obtained using a fragrance enhancing composition containing 0.05 until 0.30 4-hydroxy-3-methoxybenzaldehyde, 0.05 until 0.30 c O 2,4-diethoxy-5-methylpyrimidine, 0.05 until 0.30 o O 3aR-(3a,alpha, 5a,alpha,9a,beta,9b,beta)-dodecahydro-3a,6, 6, 9a-tetramethylnaphtho (2,1-b)furan, 0.05 to 0.30% 4-ethylalpha,alpha-dimethylbenzenepropanal, 0.05 to 0.30% Javanese vetiver oil, 2.00 to 4.00% Iso Methyl Cedryl Ketone A, 2.00 to 4.00% l-methyl-4-isopropyl-l-cyclohexen-8-ol, 3.00 to 6.00% patchouli oil and 6.00 to 10% amylcinnamylaldehyde, < based on the total weight of the fragrance component of the cosmetic composition, wherein the total amount of added fragrance improving composition is 13.2 to 25.5%, based on the total weight of the fragrance component of the cosmetic composition. B· BB » B B «BBBB 22. A cosmetic composition according to claim 3 obtained using a fragrance-enhancing composition containing 0.02 to 0.5% 2,4,4'-trichloro-2'-hydroxydiphenyl ether (Triclosan), N-(4-chlorophenyl)-N'-(3,4-dichlorophenyl)urea (Triclocarban) and bacteriostatic zinc salts. 18. A cosmetic composition according to claim 3 obtained using a fragrance enhancing composition comprising 0.20 to 1.50% of Cassis 345 B, 0.20 to 1.50% of 2 . » ♦ 4 4 4 4 4 · « · » • 44* · · Λ · · « y • 4 4· 44 4 4 4 4 · · • · · · · 4 ·»·· ···· »· ·4· ·· ·· · 5. The cosmetic composition according to claim 3, characterized in that the total amount of the fragrance-enhancing composition added to the cosmetic composition is 1.8 to 100% by weight, based on the total weight of the fragrance component in the cosmetic composition. 6. The cosmetic composition according to claim 4, characterized in that the total amount of the fragrance-enhancing composition added to the cosmetic composition is 1.8 to 100% by weight, based on the total weight of the fragrance component in the cosmetic composition. 7. The cosmetic composition according to claim 3, characterized in that the total amount of the fragrance-enhancing composition added to the cosmetic composition is 1.8 to 60% by weight, based on the total weight of the fragrance component in the cosmetic composition. 8. The cosmetic composition according to claim 4, characterized in that the total amount of the fragrance-enhancing composition added to the cosmetic composition is 1.8 to 60% by weight, based on the total weight of the fragrance component in the cosmetic composition. 9. The cosmetic composition of claim 3, wherein the total amount of the fragrance-enhancing composition 4 4 4 4 4 4 4 ·«·· 4 4 4 4 4« 4 · 44 · 44 4· 44 444 44 4 4 44 444 · · 4 · 4444 44 «44 44 4 4 « · added to the cosmetic composition is 1.8 to 35% by weight, based on the total weight of the fragrance component in the cosmetic composition. 10. The cosmetic composition according to claim 4, characterized in that the total amount of the fragrance-enhancing composition added to the cosmetic composition is 1.8 to 35% by weight, based on the total weight of the fragrance component in the cosmetic composition. 11. A cosmetic composition that provides a deodorant effect, characterized in that the deodorant is formed by a fragrance-enhancing composition itself obtained by mixing at least three substances selected from the group consisting of: a) Ceylon cinnamon leaf oil, b) Javanese vetiver oil, c) Moroccan orange oil, d) patchouli oil, e) Iso Methyl Cedryl Ketone A, f) Pelargonium, g) Cassis 345 B, h) nonylaldehyde, i) decylaldehyde j ) 3aR-(3a,alpha,5a,alpha9a,beta,9b,beta) dodecahydro3a, 6, 6, 9a-tetramethylnaphtho(2,1-b)furan, k) amylcinnamylaldehyde, • Β Β · ♦ · Β BBB BBB BBBBBB B B B BBBBB BBB BBBBB BB BBBBB BB (i) benzyl propionate, m) L-1-methyl-4-isopropenyl-6-cyclohexen-2-one η) cis-3-hexenyl salicylate, ο) 3,7-dimethyl-2,6-octadienal, ρ) 3,7-dimethyl-6-octen-1-ol·, q) 2-methyl-3-(para-isopropylphenyl)propionaldehyde, r) 1-(2,6,6-trimethyl-2-cyclohexen-1-yl-2-buten-1-one), s) natural decylaldehyde, t) 3-ethoxy-4-hydrobenzaldehyde, u) 2-methoxy-4-allylphenol, v) 4-ethyl-alpha,alpha-dimethylbenzenepropanal, w) 2-trans-3,7-dimethyl-2,6-octadien-8-ol, x) 3-(1-methylethyl)bicyclo(2,2,1)hept-5-ene-2-carboxylic acid ethyl ester, (y) isobutylquinoline, z) 5-methyl-2-isopropylcyclohexanol, aa) 4-isopropyl-1-methylcyclohexan-3-one, bb) methyl ionone (mixture of isomers), cc) 3-methyl-4-(2,6,6-trimethyl-2-cyclohex-1-yl-3-buten-2 one, dd) para-hydroxyphenylbutanone crystalline, ee) 4-methyl-2-phenyl-3,6-dihydropyran, ff) 2-(1, 1-dimethylethyl)-4-methyl-cyclohexanol, gg) 1-methyl-4-isopropyl-1-cyclohexen-8-ol, hh) 4-hydroxy-3-methoxybenzaldehyde and 9 9 9 9 *9 9 9 9 · 9 · ίί) 2,4-diethoxy-5-methylpyrimidine. 12. A cosmetic composition that provides a deodorant effect, characterized in that the deodorant is formed by a fragrance-enhancing composition itself obtained by mixing at least three of the following substances in the indicated amounts, based on the total amount of fragrance component in the final cosmetic composition: a) Ceylon cinnamon leaf oil, 0.5 to 1.0%, b) Javanese vetiver oil, 0.01 to 0.3%, c) Moroccan orange oil, 0.5-6.0%, d) patchouli oil, 0.05 to 6.0%, e) Iso Methyl Cedryl Ketone A, 0.05 to 4.0%, f) Pelargonium, 0.05 to 6.0%, g) Cassis 345 B, 0.05 to 0.9%, h) nonylaldehyde, 0.005 to 0.05%, i) decylaldehyde 0.005 to 0.05%, j ) 3aR-(3a,alpha,5a,alpha9a,beta,9b,beta)dodecahydro3a,6,6,9a-tetramethylnaphtho(2,1-b)furan, 0.05 to 0.30%, k) amylcinnamylaldehyde, 0.05 to 10.0%, (i) benzyl propionate, 0.05 to 0.9%, m) L-1-methyl-4-isopropenyl-6-cyclohexen-2-one 0.05 to 0.30%, n) cis-3-hexenyl salicylate, 0.05 to 0.30%, o) 3,7-dimethyl-2,6-octadienal, 0.05 to 0.70%, p) 3,7-dimethyl-6-octen-1-ol, 0.05 to 2.00%, q) 2-methyl-3-(para-isopropylphenyl)propionaldehyde, 0.05 to 0.9%, r) 1-(2, 6, 6-trimethyl-2-cyclohexen-1-yl-2-buten-1-one), 0.05 to 0.9%, s) natural decylaldehyde, 0.005 to 0.05%, t) 3-eth.hoxy-4-hydrobenzaldehyde, 0.05 to 0.3%, u) 2-methoxy-4-allylphenol, 0.05 to 1.00%, v) 4-ethyl-alpha,alpha-dimethylbenzenepropanal, 0.05 to 0.30%, w) 2-trans-3,7-dimethyl-2,6-octadien-8-ol, 0.05 to 6.0%, x) 3-(1-methylethyl)bicyclo(2,2,1)hept-5-ene-2-carboxylic acid ethyl ester, 0.05 to 4.0%, • * · · ♦ 9 9 · (y) isobutylquinoline, 0.05 to 0.30%, z) 5-methyl-2-isopropylcyclohexanol, 0.05 to 2.0%, aa) 4-isopropyl-1-methylcyclohexan-3-one, 0.05 to 0.3%, bb) methyl ionone (mixture of isomers), 0.05 to 2.0%, cc) 3-methyl-4-(2,6,6-trimethyl-2-cyclohex-1-yl-3-buten-2one, 0.05 to 2.0%, dd) crystalline para-hydroxyphenylbutanone, 0.05 to 0.90%, ee) 4-methyl-2-phenyl-3,6-dihydropyran, 0.05 to 4.0%, ff) 2-(1,1-dimethylethyl)-4-methylcyclohexanol, 0.05 to 0.30%, gg) 1-methyl-4-isopropyl-1-cyclohexen-8-ol, 0.05 to 6.0%, hh) 4-hydroxy-3-methoxybenzaldehyde, 0.05 to 0.3% and ii) 2,4-diethoxy-5-methylpyrimidine, 0.05 to 0.3%. 13. Cosmetic composition according to any one of claims 3, 4, 5, 6, 7, 8, 9, 10, 11 or 12, characterized in that the total fragrance component further comprises at least one substance selected from the group consisting of: 4 4 4444 44 a) salicylic acid esters, hexyl salicylate, hexenyl salicylate, benzyl salicylate and cyclohexyl salicylate, such as isoamyl salicylate, b) cinnamic acid esters, such as amyl cinnamate, cinnamyl cinnamate and methyl cinnamate, c) various esters, j allylcyclohexanepropionate, para-tert-butylcyclohexyl acetate, cedryl formate, ethyl undecylenate, linalyl benzoate, vetiveryl acetate, dihydroisoj asmonate, geranylathranilate, benzyl acetate, such as amyl benzoate, cedryl acetate, ethylene brassylate, geranyl phenyl acetate, linalyl acetate, such as amyl cinnamyl aldehyde, lillial, benzaldehyde, citronellal, d) aldehydes, cyclamenaldehyde, hydroxycitronellal, e) alcohols, such as geraniol, linalool, nerol, phenylethyl alcohol, alpha-terpineol, eugenol, isoeugenol, alpha-citronellol, dihydromyrcenol, aurantiol, cedrol, phenylheptanol, phenolhexanol, alpha-santalol, undecavertol (4-methyl-3-decen-5-ol), benzyl alcohol, f) ketones, such as benzophenone, dodecalactone, gamma-n-methylionone, delta-undecalatone, gamma-undecalatone, levo-carvone, beta-methylnaphthyl ketone, g) nitro derivatives of substituted benzenes (nitro-musks), such as ketone musk, tibetine musk and indanone musk. ·· ·· ♦ ·· «· ·· • » · · 9 · · · · * · • · ·· · · · · · · · · · · · · · · · » · *·· ··· ···« ♦· 99 99 14. A cosmetic composition according to any one of claims 3, 4, 5, 6, 7, 8, 9, 10, 11 or 12, characterized in that it further comprises an antiperspirant active substance added in an amount of 0.1 to 30% by weight, based on the total weight of the composition. 15. A cosmetic composition according to any one of claims 3, 4, 5, 6, 7, 8, 9, 10, 11 or 12, characterized in that it further comprises an antiperspirant active substance selected from the group consisting of aluminum hydrochloride, aluminum chloride, aluminum sesquihydrochloride, zirconyl hydroxychloride, aluminum zirconium glycine complex (for example aluminum zirconium trichlorohydrex gly, aluminum zirconium pentachlorohydrex gly, aluminum zirconium tetrachlorohydrex gly and aluminum zirconium octochlorohydrex gly)< aluminum chlorohydrex PG, aluminum chlorohydrex PEG, aluminum dichlorohydrex PG and aluminum dichlorohydrex PEG. 16. A cosmetic composition according to any one of claims 3, 4, 5, 6, 7, 8, 9, 10, 11 or 12, characterized in that it further comprises a bacteriostatic composition. 17. The cosmetic composition according to any one of claims 3, 4, 5, 6, 7, 8, 9, 10, 11 or 12, characterized in that it further comprises a bacteriostatic composition selected from the group consisting of bacteriostatic quaternary ammonium compounds, 2-amino-2-methyl-1-propanol, cetylpyridinium chloride, ... 9 9 9 99 9 9 9 9 9 9 9999 99 9 9 99 · • · · 9 · · 9 9 9 · 9999 99 999 99 99 99 2-trans-3,7-dimethyl-2,6-octadien-8-ol, 0.05 to 6.0%, ethyl ester of 3-(1-methylethyl)bicyclo(2,2,1)hept-5-ene-2-carboxylic acid, 0.05 to 4.0%, isobutylquinoline, 0.05 to 0.30%, 5-methyl-2-isopropylcyclohexanol, 0.05 to 2.0%, aa) 4-isopropyl-1-methylcyclohexan-3-one, 0.05 to 0.3%, bb) methyl ionone (mixture of isomers), 0.05 to 2.0%, cc) 3-methyl-4-(2,6,6-trimethyl-2-cyclohex-1-yl-3-buten-2one, 0.05 to 2.0%, dd) crystalline para-hydroxyphenylbutanone, 0.05 to 0.90%, ee) 4-methyl-2-phenyl-3,6-dihydropyran, 0.05 to 4.0%, ff) 2-(1,1-dimethylethyl)-4-methylcyclohexanol, 0.05 to 0.30%, gg) 1-methyl-4-isopropyl-1-cyclohexen-8-ol, 0.05 to 6.0%, hh) 4-hydroxy-3-methoxybenzaldehyde, 0.05 to 0.3% and ii) 2,4-diethoxy-5-methylpyrimidine, 0.05 to 0.3%. 3. A cosmetic composition characterized in that it is obtained using a fragrance-enhancing composition according to claim 2- methoxy-4-allylphenol, 0.05 to 1.00%, 4- ethyl-alpha,alpha-dimethylbenzenepropanal, 0.05 to 0.30%, 2- methyl-3-(para-isopropylphenyl)propionaldehyde, 0.05 to 0.9%, 2. A fragrance-enhancing composition according to claim 1 obtained by mixing at least three of the following non-nitrophenyl substances in the amounts indicated, based on the total weight of the fragrance component in the final cosmetic composition: a) Ceylon cinnamon leaf oil, 0.5 to 1.0%, b) Javanese vetiver oil, 0.01 to 0.3%, c) Moroccan orange oil, 0.5-6.0%, d) patchouli oil, 0.05 to 6.0%, e) Iso Methyl Cedryl Ketone A, 0.05 to 4.0%, f) Pelargonium, 0.05 to 6.0%, g) Cassis 345 B, 0.05 to 0.9%, h) nonylaldehyde, 0.005 to 0.05%, i) decylaldehyde 0.005 to 0.05%, j ) 3aR-(3a,alpha,5a,alpha9a,beta,9b,beta)dodecahydro3a, 6, 6, 9a-tetramethylnaphtho(2,1-b)furan, 0.05 to 0.30%, k) amylcinnamylaldehyde, 0.05 to 10.0%, (i) benzyl propionate, 0.05 to 0.9%, m) L-1-methyl-4-isopropenyl-6-cyclohexen-2-one 0.05 to 0.30%, (η) P) q) r) t) at) IN) w) x) Y) cis-3-hexenyl salicylate, 0.05 to 0.30%, 3.7-dimethyl-2,6-octadienal, 0.05 to 0.70%, 3.7-dimethyl-6-octen-1-ol, 0.05 to 2.00%, 3-methyl-4-(2,6,6-trimethyl-2-cyclohex-1-yl)-3-buten-2-one and 3.00 to 6.00% of 2-trans-3,7-dimethyl-2,6-octadien-8-ol, based on the total amount of the fragrance component of the cosmetic composition, wherein the total amount of the added fragrance improving composition is 5.30 to 11.00%, based on the total mass of fragrant cosmetic ingredients composition. 30. Composition improving smell according to claim 1 acquired combination of five of the above substances. 31. Composition improving smell according to claim 2 acquired combination of five of the above substances. Represented by: