CZ2002255A3 - Způsob výroby amonium glyfosatu ve formě práąku - Google Patents

Způsob výroby amonium glyfosatu ve formě práąku Download PDF

Info

Publication number: CZ2002255A3
Authority: CZ; Czechia
Prior art keywords: glyphosate; ammonium; water; ammonium glyphosate; drying
Prior art date: 1999-07-29

Application number

CZ2002255A

Other languages

Czech (cs)

English (en)

Inventor

Richard M. Kramer

Original Assignee

Monsanto Technology Llc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1999-07-29

Filing date

2000-07-26

Publication date

2002-08-14

2000-07-26 Application filed by Monsanto Technology Llc filed Critical Monsanto Technology Llc

2002-08-14 Publication of CZ2002255A3 publication Critical patent/CZ2002255A3/cs

Links

PDYXIVPKOMYDOK-UHFFFAOYSA-N Glyphosate-monoammonium Chemical compound [NH4+].OC(=O)CNCP(O)([O-])=O PDYXIVPKOMYDOK-UHFFFAOYSA-N 0.000 title claims abstract description 128
239000000843 powder Substances 0.000 title claims abstract description 41
238000004519 manufacturing process Methods 0.000 title claims description 24
239000000203 mixture Substances 0.000 claims abstract description 131
238000009472 formulation Methods 0.000 claims abstract description 97
238000000034 method Methods 0.000 claims abstract description 89
XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical compound OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 claims abstract description 77
239000005562 Glyphosate Substances 0.000 claims abstract description 76
229940097068 glyphosate Drugs 0.000 claims abstract description 76
239000002245 particle Substances 0.000 claims abstract description 71
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 71
239000004094 surface-active agent Substances 0.000 claims abstract description 66
230000008569 process Effects 0.000 claims abstract description 55
239000007787 solid Substances 0.000 claims abstract description 51
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 50
239000002253 acid Substances 0.000 claims abstract description 47
238000001035 drying Methods 0.000 claims abstract description 42
-1 ammonium cations Chemical class 0.000 claims abstract description 25
239000007795 chemical reaction product Substances 0.000 claims abstract description 24
229910021529 ammonia Inorganic materials 0.000 claims abstract description 16
238000002156 mixing Methods 0.000 claims abstract description 12
239000012431 aqueous reaction media Substances 0.000 claims abstract description 7
239000007864 aqueous solution Substances 0.000 claims abstract description 6
239000002002 slurry Substances 0.000 claims description 41
239000008187 granular material Substances 0.000 claims description 38
239000007788 liquid Substances 0.000 claims description 23
239000012530 fluid Substances 0.000 claims description 20
238000000227 grinding Methods 0.000 claims description 16
238000003756 stirring Methods 0.000 claims description 11
238000002360 preparation method Methods 0.000 claims description 6
239000012634 fragment Substances 0.000 claims description 3
239000002904 solvent Substances 0.000 claims description 2
239000002585 base Substances 0.000 claims 5
239000003513 alkali Substances 0.000 claims 1
238000001125 extrusion Methods 0.000 abstract description 41
239000012429 reaction media Substances 0.000 abstract description 2
238000011143 downstream manufacturing Methods 0.000 abstract 1
239000000047 product Substances 0.000 description 55
238000012360 testing method Methods 0.000 description 36
239000000463 material Substances 0.000 description 24
230000002363 herbicidal effect Effects 0.000 description 21
239000000243 solution Substances 0.000 description 19
238000012512 characterization method Methods 0.000 description 18
238000001694 spray drying Methods 0.000 description 18
239000004009 herbicide Substances 0.000 description 16
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 15
239000007921 spray Substances 0.000 description 14
238000006243 chemical reaction Methods 0.000 description 12
238000005469 granulation Methods 0.000 description 12
230000003179 granulation Effects 0.000 description 12
150000003839 salts Chemical class 0.000 description 12
229910000831 Steel Inorganic materials 0.000 description 11
238000012545 processing Methods 0.000 description 11
239000010959 steel Substances 0.000 description 11
208000004998 Abdominal Pain Diseases 0.000 description 10
238000010521 absorption reaction Methods 0.000 description 10
238000001179 sorption measurement Methods 0.000 description 9
238000005549 size reduction Methods 0.000 description 8
239000007789 gas Substances 0.000 description 7
229920003171 Poly (ethylene oxide) Polymers 0.000 description 6
229920001343 polytetrafluoroethylene Polymers 0.000 description 6
239000004810 polytetrafluoroethylene Substances 0.000 description 6
239000000126 substance Substances 0.000 description 6
230000008021 deposition Effects 0.000 description 5
241000196324 Embryophyta Species 0.000 description 4
239000004480 active ingredient Substances 0.000 description 4
238000013459 approach Methods 0.000 description 4
230000015572 biosynthetic process Effects 0.000 description 4
239000000919 ceramic Substances 0.000 description 4
238000005520 cutting process Methods 0.000 description 4
238000002036 drum drying Methods 0.000 description 4
238000002347 injection Methods 0.000 description 4
239000007924 injection Substances 0.000 description 4
238000006386 neutralization reaction Methods 0.000 description 4
238000012216 screening Methods 0.000 description 4
GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 4
239000000725 suspension Substances 0.000 description 4
ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 3
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
238000010669 acid-base reaction Methods 0.000 description 3
125000000217 alkyl group Chemical group 0.000 description 3
239000001099 ammonium carbonate Substances 0.000 description 3
125000002091 cationic group Chemical group 0.000 description 3
239000011344 liquid material Substances 0.000 description 3
238000012986 modification Methods 0.000 description 3
230000004048 modification Effects 0.000 description 3
230000003472 neutralizing effect Effects 0.000 description 3
239000004814 polyurethane Substances 0.000 description 3
238000005096 rolling process Methods 0.000 description 3
238000013341 scale-up Methods 0.000 description 3
238000007790 scraping Methods 0.000 description 3
238000005507 spraying Methods 0.000 description 3
CYEJMVLDXAUOPN-UHFFFAOYSA-N 2-dodecylphenol Chemical compound CCCCCCCCCCCCC1=CC=CC=C1O CYEJMVLDXAUOPN-UHFFFAOYSA-N 0.000 description 2
229910000013 Ammonium bicarbonate Inorganic materials 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
239000002202 Polyethylene glycol Substances 0.000 description 2
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
235000010724 Wisteria floribunda Nutrition 0.000 description 2
STHZKBDBKDCJFE-UHFFFAOYSA-N [O-2].[Al+3].[O-2].[Al+3].[O-2].[Al+3].[O-2].[Al+3] Chemical compound [O-2].[Al+3].[O-2].[Al+3].[O-2].[Al+3].[O-2].[Al+3] STHZKBDBKDCJFE-UHFFFAOYSA-N 0.000 description 2
238000009825 accumulation Methods 0.000 description 2
239000003463 adsorbent Substances 0.000 description 2
150000003973 alkyl amines Chemical class 0.000 description 2
235000012538 ammonium bicarbonate Nutrition 0.000 description 2
239000000908 ammonium hydroxide Substances 0.000 description 2
239000002280 amphoteric surfactant Substances 0.000 description 2
239000012736 aqueous medium Substances 0.000 description 2
239000012298 atmosphere Substances 0.000 description 2
238000012993 chemical processing Methods 0.000 description 2
239000003795 chemical substances by application Substances 0.000 description 2
150000001875 compounds Chemical class 0.000 description 2
DTPCFIHYWYONMD-UHFFFAOYSA-N decaethylene glycol Polymers OCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO DTPCFIHYWYONMD-UHFFFAOYSA-N 0.000 description 2
238000013461 design Methods 0.000 description 2
239000003599 detergent Substances 0.000 description 2
230000000694 effects Effects 0.000 description 2
238000005516 engineering process Methods 0.000 description 2
230000002349 favourable effect Effects 0.000 description 2
239000012535 impurity Substances 0.000 description 2
239000004615 ingredient Substances 0.000 description 2
239000002609 medium Substances 0.000 description 2
229910052751 metal Inorganic materials 0.000 description 2
239000002184 metal Substances 0.000 description 2
VUWDAOLDXOYMIZ-UHFFFAOYSA-N nonadecan-1-amine;hydrochloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCCC[NH3+] VUWDAOLDXOYMIZ-UHFFFAOYSA-N 0.000 description 2
TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
238000010951 particle size reduction Methods 0.000 description 2
229920001223 polyethylene glycol Polymers 0.000 description 2
238000012805 post-processing Methods 0.000 description 2
230000009467 reduction Effects 0.000 description 2
235000010265 sodium sulphite Nutrition 0.000 description 2
239000011343 solid material Substances 0.000 description 2
229910001220 stainless steel Inorganic materials 0.000 description 2
239000010935 stainless steel Substances 0.000 description 2
239000005711 Benzoic acid Substances 0.000 description 1
WPYMKLBDIGXBTP-UHFFFAOYSA-N Benzoic acid Natural products OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
241001417527 Pempheridae Species 0.000 description 1
239000002250 absorbent Substances 0.000 description 1
230000002745 absorbent Effects 0.000 description 1
230000002411 adverse Effects 0.000 description 1
238000004220 aggregation Methods 0.000 description 1
230000002776 aggregation Effects 0.000 description 1
125000005210 alkyl ammonium group Chemical group 0.000 description 1
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
235000012501 ammonium carbonate Nutrition 0.000 description 1
150000003863 ammonium salts Chemical class 0.000 description 1
BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
229910052921 ammonium sulfate Inorganic materials 0.000 description 1
235000011130 ammonium sulphate Nutrition 0.000 description 1
239000013011 aqueous formulation Substances 0.000 description 1
239000007900 aqueous suspension Substances 0.000 description 1
235000010233 benzoic acid Nutrition 0.000 description 1
150000001559 benzoic acids Chemical class 0.000 description 1
238000004364 calculation method Methods 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
125000004432 carbon atom Chemical group C* 0.000 description 1
150000001732 carboxylic acid derivatives Chemical group 0.000 description 1
239000003093 cationic surfactant Substances 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
238000002485 combustion reaction Methods 0.000 description 1
239000000470 constituent Substances 0.000 description 1
238000001816 cooling Methods 0.000 description 1
239000013078 crystal Substances 0.000 description 1
238000002425 crystallisation Methods 0.000 description 1
230000008025 crystallization Effects 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
230000001627 detrimental effect Effects 0.000 description 1
238000010586 diagram Methods 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
238000005265 energy consumption Methods 0.000 description 1
238000011156 evaluation Methods 0.000 description 1
239000013020 final formulation Substances 0.000 description 1
239000010419 fine particle Substances 0.000 description 1
230000006870 function Effects 0.000 description 1
239000000499 gel Substances 0.000 description 1
150000002334 glycols Chemical class 0.000 description 1
239000011874 heated mixture Substances 0.000 description 1
125000001183 hydrocarbyl group Chemical group 0.000 description 1
230000002209 hydrophobic effect Effects 0.000 description 1
230000006872 improvement Effects 0.000 description 1
238000009434 installation Methods 0.000 description 1
JJWLVOIRVHMVIS-UHFFFAOYSA-N isopropylamine Chemical class CC(C)N JJWLVOIRVHMVIS-UHFFFAOYSA-N 0.000 description 1
238000010902 jet-milling Methods 0.000 description 1
238000004898 kneading Methods 0.000 description 1
229910052743 krypton Inorganic materials 0.000 description 1
DNNSSWSSYDEUBZ-UHFFFAOYSA-N krypton atom Chemical compound [Kr] DNNSSWSSYDEUBZ-UHFFFAOYSA-N 0.000 description 1
239000006193 liquid solution Substances 0.000 description 1
239000011159 matrix material Substances 0.000 description 1
235000013372 meat Nutrition 0.000 description 1
238000003701 mechanical milling Methods 0.000 description 1
238000002844 melting Methods 0.000 description 1
230000008018 melting Effects 0.000 description 1
238000003801 milling Methods 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
XKLJHFLUAHKGGU-UHFFFAOYSA-N nitrous amide Chemical compound ON=N XKLJHFLUAHKGGU-UHFFFAOYSA-N 0.000 description 1
235000012149 noodles Nutrition 0.000 description 1
238000005457 optimization Methods 0.000 description 1
238000004806 packaging method and process Methods 0.000 description 1
239000011236 particulate material Substances 0.000 description 1
239000013618 particulate matter Substances 0.000 description 1
235000011837 pasties Nutrition 0.000 description 1
230000008447 perception Effects 0.000 description 1
230000035699 permeability Effects 0.000 description 1
235000020030 perry Nutrition 0.000 description 1
238000007747 plating Methods 0.000 description 1
229920002635 polyurethane Polymers 0.000 description 1
238000004321 preservation Methods 0.000 description 1
238000010298 pulverizing process Methods 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
229930195734 saturated hydrocarbon Natural products 0.000 description 1
238000007873 sieving Methods 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
159000000000 sodium salts Chemical class 0.000 description 1
239000007790 solid phase Substances 0.000 description 1
238000003860 storage Methods 0.000 description 1
238000005320 surfactant adsorption Methods 0.000 description 1
238000010998 test method Methods 0.000 description 1
238000005979 thermal decomposition reaction Methods 0.000 description 1
238000012546 transfer Methods 0.000 description 1
MERBOASPEBJVLI-UHFFFAOYSA-N trialuminum oxygen(2-) Chemical compound [O--].[O--].[O--].[Al+3].[Al+3].[Al+3] MERBOASPEBJVLI-UHFFFAOYSA-N 0.000 description 1
NRZWQKGABZFFKE-UHFFFAOYSA-N trimethylsulfonium Chemical class C[S+](C)C NRZWQKGABZFFKE-UHFFFAOYSA-N 0.000 description 1
229930195735 unsaturated hydrocarbon Natural products 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
- C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
- C07F9/3813—N-Phosphonomethylglycine; Salts or complexes thereof
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/12—Powders or granules
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals

Landscapes

Life Sciences & Earth Sciences (AREA)
Health & Medical Sciences (AREA)
General Health & Medical Sciences (AREA)
Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Pest Control & Pesticides (AREA)
Agronomy & Crop Science (AREA)
Plant Pathology (AREA)
Engineering & Computer Science (AREA)
Dentistry (AREA)
Wood Science & Technology (AREA)
Zoology (AREA)
Environmental Sciences (AREA)
Molecular Biology (AREA)
Biochemistry (AREA)
Toxicology (AREA)
Agricultural Chemicals And Associated Chemicals (AREA)
Physical Or Chemical Processes And Apparatus (AREA)

CZ2002255A 1999-07-29 2000-07-26 Způsob výroby amonium glyfosatu ve formě práąku CZ2002255A3 (cs)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US14628199P	1999-07-29	1999-07-29

Publications (1)

Publication Number	Publication Date
CZ2002255A3 true CZ2002255A3 (cs)	2002-08-14

Family

ID=22516647

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CZ2002255A CZ2002255A3 (cs)	1999-07-29	2000-07-26	Způsob výroby amonium glyfosatu ve formě práąku

Country Status (22)

Country	Link
US (1)	US6448434B1 (de)
EP (1)	EP1199927B1 (de)
JP (1)	JP2003505477A (de)
KR (1)	KR20020029078A (de)
CN (1)	CN1180689C (de)
AR (1)	AR024993A1 (de)
AT (1)	ATE244985T1 (de)
AU (1)	AU763848C (de)
BR (1)	BR0012839A (de)
CA (1)	CA2377735C (de)
CO (1)	CO5200797A1 (de)
CZ (1)	CZ2002255A3 (de)
DE (1)	DE60003929T2 (de)
DK (1)	DK1199927T3 (de)
HU (1)	HUP0202337A3 (de)
IL (1)	IL147661A0 (de)
MX (1)	MXPA02001083A (de)
PL (1)	PL364930A1 (de)
RU (1)	RU2002104998A (de)
TW (1)	TWI244372B (de)
WO (1)	WO2001008480A1 (de)
ZA (1)	ZA200110543B (de)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
ES2230134T3 (es)	1999-07-28	2005-05-01	Monsanto Technology Llc	Procedimiento para fabricar una pasta de glifosato de amonio procesable corriente abajo.
US6599858B1 (en) *	1999-07-29	2003-07-29	Monsanto Technology Llc	Process for making ammonium glyphosate flakes
US6734142B2 (en)	2001-04-23	2004-05-11	Monsanto Technology Llc	Ammonium glyphosate compositions and process for their preparation
US6983323B2 (en)	2002-08-12	2006-01-03	Tippingpoint Technologies, Inc.	Multi-level packet screening with dynamically selected filtering criteria
EP2292095A2 (de) *	2002-08-31	2011-03-09	Monsanto Technology LLC	Pestizid-Zusammensetzungen, die Dicarbonsäuren oder deren Derivate enthalten
WO2004019684A2 (en) *	2002-08-31	2004-03-11	Monsanto Technology Llc	Process for the preparation of a dry pesticidal composition containing a dicarbodylate component
US20050037924A1 (en) *	2002-08-31	2005-02-17	Monsanto Technology Llc	Sodium glyphosate compositions and process for their preparation
AR037559A1 (es) *	2002-11-19	2004-11-17	Atanor S A	Una formulacion herbicida solida de n-fosfonometilglicina, bajo la forma de polvo, granulos o escamas, soluble o dispersable en agua, y el procedimiento para preparar dicha composicion
ITMI20051138A1 (it) *	2005-06-17	2006-12-18	Sipcam Spa	Processo per preparare granuli di glifosate ammonico
BRPI0605346B1 (pt) *	2006-12-15	2016-03-08	Ricardo Amaral Remer	processo para obtenção de sal de amônio de glifosato sólido, ingrediente ativo sólido solúvel em água para defensivo agrícola, processo de controle de pragas agrícolas e uso de um ingrediente ativo.
CN101524085B (zh) *	2009-04-21	2012-07-04	山东潍坊润丰化工有限公司	一种草甘膦铵盐水溶性粒剂的制备方法
CN101570324B (zh) *	2009-06-16	2013-05-08	吴伦飞	从草甘膦母液中回收亚磷酸盐的方法
CN101570547B (zh) *	2009-06-16	2012-07-04	吴伦飞	草甘膦母液的处理方法
CN101692809B (zh) *	2009-09-30	2013-04-10	四川省乐山市福华通达农药科技有限公司	一种草甘膦铵盐粒剂的制备方法
CN103327817B (zh) *	2010-10-25	2016-03-02	斯特潘公司	基于由天然油复分解生成的组合物的草甘膦制剂
KR102676309B1 (ko)	2019-11-22	2024-06-19	(주)에스티알바이오텍	시킴산 생산용 미생물 및 이를 이용한 시킴산 생산 방법
CN115594712B (zh) *	2022-10-08	2023-12-19	湖北泰盛化工有限公司	一种气固非均相草甘膦连续氨化的方法

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BR8600462A (pt)	1986-02-04	1987-09-01	Monsanto Brasil	Formulacao herbicida
US5070197A (en)	1986-03-20	1991-12-03	Uniroyal Chemical Company, Inc.	Dry reactive processing
US5047079A (en)	1986-08-18	1991-09-10	Ici Americas Inc.	Method of preparation and use of solid, phytoactive compositions
NZ231897A (en)	1988-12-30	1992-09-25	Monsanto Co	Dry water-soluble granular composition comprising glyphosate and a liquid surfactant
NO901662L (no) *	1989-04-17	1990-12-21	Monsanto Co	Toert herbicid preparat med forbedret vannopploeselighet.
WO1992012637A1 (en)	1991-01-24	1992-08-06	Monsanto Company	Improved glyphosate formulations
IL101539A (en)	1991-04-16	1998-09-24	Monsanto Europe Sa	Non-hygroscopic mono-ammonium salts of n-phosphonomethyl glycine derivatives their preparation and pesticidal compositons containing them
US5266553A (en)	1991-10-21	1993-11-30	Riverdale Chemical Company	Method of manufacturing a dry water-soluble herbicidal salt composition
MY111437A (en)	1992-07-31	2000-05-31	Monsanto Co	Improved glyphosate herbicide formulation.
WO1994010844A1 (en)	1992-11-06	1994-05-26	Zeneca Limited	Dry water-dispersible glyphosate phytoactive formulation
US5633397A (en)	1995-06-07	1997-05-27	Monsanto Company	Preparation of ammonium glyphosate via a gas-solid reaction system
US5614468A (en)	1995-06-07	1997-03-25	Monsanto Company	Preparation of ammonium glyphosate using aqueous ammonium hydroxide in a liquid-solid reaction system

2000
- 2000-07-25 US US09/624,949 patent/US6448434B1/en not_active Expired - Lifetime
- 2000-07-26 JP JP2001513228A patent/JP2003505477A/ja active Pending
- 2000-07-26 AU AU63783/00A patent/AU763848C/en not_active Ceased
- 2000-07-26 EP EP00950719A patent/EP1199927B1/de not_active Expired - Lifetime
- 2000-07-26 BR BR0012839-2A patent/BR0012839A/pt not_active IP Right Cessation
- 2000-07-26 CA CA002377735A patent/CA2377735C/en not_active Expired - Fee Related
- 2000-07-26 AT AT00950719T patent/ATE244985T1/de not_active IP Right Cessation
- 2000-07-26 IL IL14766100A patent/IL147661A0/xx unknown
- 2000-07-26 CZ CZ2002255A patent/CZ2002255A3/cs unknown
- 2000-07-26 KR KR1020027000377A patent/KR20020029078A/ko not_active Withdrawn
- 2000-07-26 DK DK00950719T patent/DK1199927T3/da active
- 2000-07-26 PL PL00364930A patent/PL364930A1/xx not_active Application Discontinuation
- 2000-07-26 MX MXPA02001083A patent/MXPA02001083A/es active IP Right Grant
- 2000-07-26 CN CNB008110417A patent/CN1180689C/zh not_active Expired - Fee Related
- 2000-07-26 DE DE60003929T patent/DE60003929T2/de not_active Expired - Fee Related
- 2000-07-26 HU HU0202337A patent/HUP0202337A3/hu unknown
- 2000-07-26 WO PCT/US2000/020340 patent/WO2001008480A1/en not_active Ceased
- 2000-07-26 RU RU2002104998/15A patent/RU2002104998A/ru unknown
- 2000-07-28 AR ARP000103942A patent/AR024993A1/es active IP Right Grant
- 2000-07-31 CO CO00057308A patent/CO5200797A1/es not_active Application Discontinuation
- 2000-10-07 TW TW089115241A patent/TWI244372B/zh active
2001
- 2001-12-21 ZA ZA200110543A patent/ZA200110543B/xx unknown

Also Published As

Publication number	Publication date
AU763848B2 (en)	2003-07-31
CO5200797A1 (es)	2002-09-27
ATE244985T1 (de)	2003-08-15
HUP0202337A3 (en)	2003-01-28
RU2002104998A (ru)	2004-01-27
CN1365252A (zh)	2002-08-21
US6448434B1 (en)	2002-09-10
WO2001008480A1 (en)	2001-02-08
MXPA02001083A (es)	2002-08-20
IL147661A0 (en)	2002-08-14
HUP0202337A2 (hu)	2002-11-28
CA2377735C (en)	2008-07-22
AU6378300A (en)	2001-02-19
ZA200110543B (en)	2003-03-24
JP2003505477A (ja)	2003-02-12
PL364930A1 (en)	2004-12-27
CN1180689C (zh)	2004-12-22
TWI244372B (en)	2005-12-01
EP1199927A1 (de)	2002-05-02
KR20020029078A (ko)	2002-04-17
DK1199927T3 (da)	2003-11-10
EP1199927B1 (de)	2003-07-16
BR0012839A (pt)	2002-04-30
DE60003929D1 (de)	2003-08-21
DE60003929T2 (de)	2004-07-15
CA2377735A1 (en)	2001-02-08
AU763848C (en)	2004-08-19
AR024993A1 (es)	2002-11-06

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CZ2002255A3 (cs)	2002-08-14	Způsob výroby amonium glyfosatu ve formě práąku
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WO2000077148A1 (fr)	2000-12-21	Granules destines a porter un tensioactif et leur procede de production
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AU635514C (en)	2000-02-10	Improved glyphosate formulations
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