DD139838A5 - Verfahren zur herstellung von niederen alkenen aus methanol und/oder dimethylaether - Google Patents

Verfahren zur herstellung von niederen alkenen aus methanol und/oder dimethylaether Download PDF

Info

Publication number: DD139838A5
Authority: DD; German Democratic Republic
Prior art keywords: methanol; manganese; dimethyl ether; water; selectivity
Prior art date: 1977-12-10

Application number

DD78209628A

Other languages

German (de)

English (en)

Inventor

Friedrich Wunder

Hans-Juergen Arpe

Horst Hachenberg

Ernst I Leupold

Original Assignee

Hoechst Ag

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1977-12-10

Filing date

1978-12-08

Publication date

1980-01-23

1978-12-08 Application filed by Hoechst Ag filed Critical Hoechst Ag

1980-01-23 Publication of DD139838A5 publication Critical patent/DD139838A5/de

Links

OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 title claims description 90
-1 LOW ALKENES Chemical class 0.000 title claims description 4
238000004519 manufacturing process Methods 0.000 title description 5
LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims description 52
239000003054 catalyst Substances 0.000 claims description 26
238000006243 chemical reaction Methods 0.000 claims description 21
150000001336 alkenes Chemical class 0.000 claims description 14
238000000034 method Methods 0.000 claims description 14
YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 claims description 12
229910052782 aluminium Inorganic materials 0.000 claims description 5
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 5
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 4
229910052749 magnesium Inorganic materials 0.000 claims description 4
239000011777 magnesium Substances 0.000 claims description 4
238000002360 preparation method Methods 0.000 claims description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 27
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 21
239000002808 molecular sieve Substances 0.000 description 20
QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 17
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 16
239000005977 Ethylene Substances 0.000 description 16
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 14
229920006395 saturated elastomer Polymers 0.000 description 11
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 10
229910052748 manganese Inorganic materials 0.000 description 10
239000011572 manganese Substances 0.000 description 10
239000000203 mixture Substances 0.000 description 9
239000011148 porous material Substances 0.000 description 9
150000002696 manganese Chemical class 0.000 description 8
239000000243 solution Substances 0.000 description 8
125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 8
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 7
150000003839 salts Chemical class 0.000 description 7
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 6
239000001273 butane Substances 0.000 description 6
IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 6
OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 6
230000000052 comparative effect Effects 0.000 description 5
229930195733 hydrocarbon Natural products 0.000 description 5
239000011734 sodium Substances 0.000 description 5
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
150000002430 hydrocarbons Chemical class 0.000 description 4
229910052751 metal Inorganic materials 0.000 description 4
239000002184 metal Substances 0.000 description 4
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 3
OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 3
ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 3
239000007795 chemical reaction product Substances 0.000 description 3
238000001035 drying Methods 0.000 description 3
239000007789 gas Substances 0.000 description 3
238000005470 impregnation Methods 0.000 description 3
229940071125 manganese acetate Drugs 0.000 description 3
239000001294 propane Substances 0.000 description 3
230000008929 regeneration Effects 0.000 description 3
238000011069 regeneration method Methods 0.000 description 3
239000012266 salt solution Substances 0.000 description 3
229910052708 sodium Inorganic materials 0.000 description 3
238000005406 washing Methods 0.000 description 3
239000010457 zeolite Substances 0.000 description 3
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 description 2
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical group [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
150000001335 aliphatic alkanes Chemical class 0.000 description 2
229910000323 aluminium silicate Inorganic materials 0.000 description 2
239000007864 aqueous solution Substances 0.000 description 2
150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
229910052791 calcium Inorganic materials 0.000 description 2
239000011575 calcium Substances 0.000 description 2
239000001569 carbon dioxide Substances 0.000 description 2
229910002092 carbon dioxide Inorganic materials 0.000 description 2
229910002091 carbon monoxide Inorganic materials 0.000 description 2
150000001768 cations Chemical class 0.000 description 2
238000006297 dehydration reaction Methods 0.000 description 2
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
239000001257 hydrogen Substances 0.000 description 2
229910052739 hydrogen Inorganic materials 0.000 description 2
229910052742 iron Inorganic materials 0.000 description 2
UOGMEBQRZBEZQT-UHFFFAOYSA-L manganese(2+);diacetate Chemical compound [Mn+2].CC([O-])=O.CC([O-])=O UOGMEBQRZBEZQT-UHFFFAOYSA-L 0.000 description 2
239000000463 material Substances 0.000 description 2
TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
239000002245 particle Substances 0.000 description 2
229910052698 phosphorus Inorganic materials 0.000 description 2
239000011574 phosphorus Substances 0.000 description 2
150000003018 phosphorus compounds Chemical group 0.000 description 2
239000002904 solvent Substances 0.000 description 2
239000007858 starting material Substances 0.000 description 2
239000000126 substance Substances 0.000 description 2
239000006228 supernatant Substances 0.000 description 2
BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical class OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
FERIUCNNQQJTOY-UHFFFAOYSA-M Butyrate Chemical compound CCCC([O-])=O FERIUCNNQQJTOY-UHFFFAOYSA-M 0.000 description 1
FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Natural products CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 1
239000004215 Carbon black (E152) Substances 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
229910000722 Didymium Inorganic materials 0.000 description 1
241000224487 Didymium Species 0.000 description 1
BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 description 1
229910052688 Gadolinium Inorganic materials 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
JVTAAEKCZFNVCJ-UHFFFAOYSA-M Lactate Chemical compound CC(O)C([O-])=O JVTAAEKCZFNVCJ-UHFFFAOYSA-M 0.000 description 1
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
229910021380 Manganese Chloride Inorganic materials 0.000 description 1
GLFNIEUTAYBVOC-UHFFFAOYSA-L Manganese chloride Chemical compound Cl[Mn]Cl GLFNIEUTAYBVOC-UHFFFAOYSA-L 0.000 description 1
229910002651 NO3 Inorganic materials 0.000 description 1
229910052779 Neodymium Inorganic materials 0.000 description 1
NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
229910052777 Praseodymium Inorganic materials 0.000 description 1
XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
229910052772 Samarium Inorganic materials 0.000 description 1
229910004298 SiO 2 Inorganic materials 0.000 description 1
229910021536 Zeolite Inorganic materials 0.000 description 1
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
239000003570 air Substances 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
229910052784 alkaline earth metal Inorganic materials 0.000 description 1
150000001342 alkaline earth metals Chemical class 0.000 description 1
BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
150000001450 anions Chemical class 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
229910052788 barium Inorganic materials 0.000 description 1
DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
229910052790 beryllium Inorganic materials 0.000 description 1
ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 description 1
238000009835 boiling Methods 0.000 description 1
239000000571 coke Substances 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
238000005336 cracking Methods 0.000 description 1
230000018044 dehydration Effects 0.000 description 1
239000008367 deionised water Substances 0.000 description 1
229910021641 deionized water Inorganic materials 0.000 description 1
238000007865 diluting Methods 0.000 description 1
238000004821 distillation Methods 0.000 description 1
239000012153 distilled water Substances 0.000 description 1
UIWYJDYFSGRHKR-UHFFFAOYSA-N gadolinium atom Chemical compound [Gd] UIWYJDYFSGRHKR-UHFFFAOYSA-N 0.000 description 1
229910001683 gmelinite Inorganic materials 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
150000004677 hydrates Chemical class 0.000 description 1
239000011261 inert gas Substances 0.000 description 1
229910052746 lanthanum Inorganic materials 0.000 description 1
FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
229910052744 lithium Inorganic materials 0.000 description 1
UEGPKNKPLBYCNK-UHFFFAOYSA-L magnesium acetate Chemical compound [Mg+2].CC([O-])=O.CC([O-])=O UEGPKNKPLBYCNK-UHFFFAOYSA-L 0.000 description 1
239000011654 magnesium acetate Substances 0.000 description 1
235000011285 magnesium acetate Nutrition 0.000 description 1
229940069446 magnesium acetate Drugs 0.000 description 1
229910001629 magnesium chloride Inorganic materials 0.000 description 1
239000001630 malic acid Substances 0.000 description 1
235000011090 malic acid Nutrition 0.000 description 1
239000011565 manganese chloride Substances 0.000 description 1
235000002867 manganese chloride Nutrition 0.000 description 1
229940099607 manganese chloride Drugs 0.000 description 1
229910001437 manganese ion Inorganic materials 0.000 description 1
BHVPEUGTPDJECS-UHFFFAOYSA-L manganese(2+);diformate Chemical compound [Mn+2].[O-]C=O.[O-]C=O BHVPEUGTPDJECS-UHFFFAOYSA-L 0.000 description 1
238000002156 mixing Methods 0.000 description 1
229910052674 natrolite Inorganic materials 0.000 description 1
QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 description 1
230000007935 neutral effect Effects 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
229910017464 nitrogen compound Inorganic materials 0.000 description 1
150000002830 nitrogen compounds Chemical class 0.000 description 1
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
239000011591 potassium Substances 0.000 description 1
PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 description 1
239000000047 product Substances 0.000 description 1
230000002035 prolonged effect Effects 0.000 description 1
229910001404 rare earth metal oxide Inorganic materials 0.000 description 1
230000002468 redox effect Effects 0.000 description 1
KZUNJOHGWZRPMI-UHFFFAOYSA-N samarium atom Chemical compound [Sm] KZUNJOHGWZRPMI-UHFFFAOYSA-N 0.000 description 1
229930195734 saturated hydrocarbon Natural products 0.000 description 1
239000012047 saturated solution Substances 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
229910021653 sulphate ion Inorganic materials 0.000 description 1
229940095064 tartrate Drugs 0.000 description 1
CYTQBVOFDCPGCX-UHFFFAOYSA-N trimethyl phosphite Chemical compound COP(OC)OC CYTQBVOFDCPGCX-UHFFFAOYSA-N 0.000 description 1
229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
238000011144 upstream manufacturing Methods 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1
239000011701 zinc Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
- C10G3/42—Catalytic treatment
- C10G3/44—Catalytic treatment characterised by the catalyst used
- C10G3/48—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support
- C10G3/49—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support containing crystalline aluminosilicates, e.g. molecular sieves
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/40—Characteristics of the process deviating from typical ways of processing
- C10G2300/4006—Temperature
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/40—Characteristics of the process deviating from typical ways of processing
- C10G2300/4012—Pressure
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/20—C2-C4 olefins
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/40—Ethylene production

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Oil, Petroleum & Natural Gas (AREA)
Crystallography & Structural Chemistry (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
General Chemical & Material Sciences (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Catalysts (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

DD78209628A 1977-12-10 1978-12-08 Verfahren zur herstellung von niederen alkenen aus methanol und/oder dimethylaether DD139838A5 (de)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
DE2755229A DE2755229B2 (de)	1977-12-10	1977-12-10	Verfahren zur Herstellung von Alkenen mit 2 bis 4 Kohlenstoffatomen aus Methanol und/oder Dimethyläther

Publications (1)

Publication Number	Publication Date
DD139838A5 true DD139838A5 (de)	1980-01-23

Family

ID=6025883

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DD78209628A DD139838A5 (de)	1977-12-10	1978-12-08	Verfahren zur herstellung von niederen alkenen aus methanol und/oder dimethylaether

Country Status (10)

Country	Link
US (1)	US4247731A (pl)
EP (1)	EP0002492B1 (pl)
JP (1)	JPS5484503A (pl)
AU (1)	AU525438B2 (pl)
CA (1)	CA1104163A (pl)
DD (1)	DD139838A5 (pl)
DE (2)	DE2755229B2 (pl)
PL (1)	PL118403B1 (pl)
SU (1)	SU906362A3 (pl)
ZA (1)	ZA786890B (pl)

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE2928922A1 (de) *	1979-07-18	1981-02-12	Hoechst Ag	Verfahren zur herstellung niederer olefine aus methanol-wasser-gemischen
DE3008146A1 (de) *	1980-03-04	1981-09-17	Hoechst Ag	Verfahren zur herstellung eines aluminiumsilikat-katalysators fuer die umwandlung von wasserhaltigem methanol und/oder wasserhaltigem dimethylether in niedere olefine
EP0040015B1 (en) *	1980-05-13	1986-06-11	Imperial Chemical Industries Plc	Process for making olefins
DE3024536A1 (de) *	1980-06-28	1982-02-04	Hoechst Ag, 6000 Frankfurt	Aluminiumsilikat-katalysator
US4423274A (en) *	1980-10-03	1983-12-27	Mobil Oil Corporation	Method for converting alcohols to hydrocarbons
NZ199034A (en) *	1980-12-05	1984-11-09	Ici Australia Ltd	Production of hydrocarbons from a feed containing methanol,water and a promotor passed over aluminosilicate
US4393265A (en) *	1981-07-24	1983-07-12	E. I. Du Pont De Nemours & Co.	Light monoolefins from methanol and/or dimethyl ether
US4373109A (en) *	1981-08-05	1983-02-08	Olah George A	Bifunctional acid-base catalyzed conversion of hetero-substituted methanes into olefins
DE3132024C2 (de) *	1981-08-13	1983-12-08	Basf Ag, 6700 Ludwigshafen	Verfahren zur Herstellung von Olefinen aus Methanol und/oder Dimethylether
US4471150A (en) *	1981-12-30	1984-09-11	Mobil Oil Corporation	Catalysts for light olefin production
AU567109B2 (en) *	1982-09-30	1987-11-12	Mobil Oil Corp.	Catalytic conversion of methanol to light olefins
US4665268A (en) *	1982-09-30	1987-05-12	Mobil Oil Corporation	Catalytic conversion of methanol to light olefins
CA1216866A (en) *	1983-01-17	1987-01-20	Clarence D. Chang	Conversion of alcohols and/or ethers to olefins
US4507518A (en) *	1983-12-14	1985-03-26	Penick Corporation	Dehydration of 2,5-dimethyl-2,5-hexanediol
US4536183A (en) *	1984-04-09	1985-08-20	Lever Brothers Company	Manganese bleach activators
US4590320A (en) *	1984-08-31	1986-05-20	Mobil Oil Corporation	Conversion of methanol to olefins in a tubular reactor with light olefin co-feeding
US4601845A (en) *	1985-04-02	1986-07-22	Lever Brothers Company	Bleaching compositions containing mixed metal cations adsorbed onto aluminosilicate support materials
US4623357A (en) *	1985-04-02	1986-11-18	Lever Brothers Company	Bleach compositions
US4613720A (en) *	1986-01-14	1986-09-23	E. I. Du Pont De Nemours And Company	Boron-treated zeolite catalyst for preparing light monoolefins
US4698452A (en) *	1986-10-02	1987-10-06	Institut Nationale De La Recherche Scientifique	Ethylene light olefins from ethanol
CA2430399A1 (en) *	2003-05-28	2004-11-28	Ruth Marie Smith	Decorative pattern application kit
US7449611B2 (en) *	2005-01-31	2008-11-11	Exxonmobil Chemical Patents Inc.	Molecular sieve catalyst composition, its making and use in conversion processes
US7453020B2 (en) *	2005-01-31	2008-11-18	Exxonmobil Chemical Patents Inc.	Molecular sieve catalyst composition, its making and use in conversion processes
WO2007021394A2 (en) *	2005-08-18	2007-02-22	Exxonmobil Chemical Patents Inc.	Catalytic conversion of oxygenates to olefins
DE102012215956A1 (de) *	2012-09-10	2014-03-13	Evonik Industries Ag	Methanolbehandlung von Alumosilicat-haltigen ATAE-Spaltkatalysatoren

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Publication number	Priority date	Publication date	Assignee	Title
US3529033A (en) *	1963-05-20	1970-09-15	Mobil Oil Corp	Catalytic conversion
US3911041A (en) *	1974-09-23	1975-10-07	Mobil Oil Corp	Conversion of methanol and dimethyl ether
US3979472A (en) *	1975-03-28	1976-09-07	Mobil Oil Corporation	Process for manufacturing hydrocarbons
US4025576A (en) *	1975-04-08	1977-05-24	Mobil Oil Corporation	Process for manufacturing olefins
US4062905A (en) *	1976-08-02	1977-12-13	Mobil Oil Corporation	Manufacture of light olefins
US4079096A (en) *	1976-11-04	1978-03-14	Mobil Oil Corporation	Manufacture of light olefins
US4079095A (en) *	1976-11-04	1978-03-14	Mobil Oil Corporation	Manufacture of light olefins
US4148836A (en) *	1977-12-23	1979-04-10	Allied Chemical Corporation	Process for reducing water content of sulfuric acid in hydrocarbon alkylations

1977
- 1977-12-10 DE DE2755229A patent/DE2755229B2/de not_active Withdrawn
1978
- 1978-12-06 DE DE7878101577T patent/DE2860447D1/de not_active Expired
- 1978-12-06 EP EP78101577A patent/EP0002492B1/de not_active Expired
- 1978-12-08 JP JP15120978A patent/JPS5484503A/ja active Granted
- 1978-12-08 ZA ZA00786890A patent/ZA786890B/xx unknown
- 1978-12-08 SU SU782694552A patent/SU906362A3/ru active
- 1978-12-08 DD DD78209628A patent/DD139838A5/de unknown
- 1978-12-08 CA CA317,640A patent/CA1104163A/en not_active Expired
- 1978-12-08 AU AU42342/78A patent/AU525438B2/en not_active Expired
- 1978-12-09 PL PL1978211599A patent/PL118403B1/pl unknown
1979
- 1979-09-17 US US06/075,983 patent/US4247731A/en not_active Expired - Lifetime

Also Published As

Publication number	Publication date
JPS5484503A (en)	1979-07-05
AU525438B2 (en)	1982-11-04
EP0002492B1 (de)	1981-01-07
ZA786890B (en)	1979-12-27
DE2755229A1 (de)	1979-06-13
AU4234278A (en)	1979-06-14
JPS6138174B2 (pl)	1986-08-28
EP0002492A1 (de)	1979-06-27
PL118403B1 (en)	1981-10-31
US4247731A (en)	1981-01-27
DE2755229B2 (de)	1980-01-10
CA1104163A (en)	1981-06-30
DE2860447D1 (en)	1981-02-26
PL211599A1 (pl)	1979-07-30
SU906362A3 (ru)	1982-02-15

Publication	Publication Date	Title
EP0002492B1 (de)	1981-01-07	Verfahren zur Herstellung von niederen Alkenen aus Methanol und/oder Dimethyläther
EP0023303B1 (de)	1983-04-13	Verfahren zur Herstellung niederer Olefine aus Methanol/Wasser-Gemischen
DE2560442C2 (de)	1986-10-16	Verfahren zur Herstellung von Olefinen aus Olefinen mit kleinerer Anzahl an Kohlenstoffatomen
DE69535660T2 (de)	2008-11-13	Katalysator und Verfahren zur Herstellung von monozyklischen Aromaten
EP0132736B1 (de)	1987-10-07	Verfahren zur Herstellung von Aminen
DE2631536C2 (de)	1983-06-30	Verfahren zur Herstellung von olefinischen Kohlenwasserstoffen
DE19756292A1 (de)	1999-06-24	Katalysator zur Umwandlung paraffinischer Kohlenwasserstoffe in korrespondierende Olefine
EP0043494B1 (de)	1984-05-16	Verfahren zur Herstellung von niederen Olefinen aus Methanol und/oder Dimethylether
DE3524890C2 (de)	1994-03-17	Verfahren zur Herstellung Ethylen und Propylen
EP0129900B1 (de)	1987-07-01	Verfahren zur Gewinnung von 1-Buten aus 2-Butene enthaltenden C4-Kohlenwasserstoffgemischen
EP0036109B1 (de)	1983-10-19	Verfahren zur Herstellung von niederen Olefinen aus wasserhaltigem Methanol und/oder wasserhaltigem Dimethylether
EP0072920A1 (de)	1983-03-02	Verfahren zur Herstellung von Olefinen aus Methanol und/oder Dimethylether
DE2626840C3 (de)	1978-11-09	Verfahren zum Hydro-Cracken von Butan zu Propan
DE2660732C2 (de)	1984-05-17	Verfahren zur Herstellung von aromatischen Kohlenwasserstoffen
DE2109648A1 (de)	1971-09-23	Katalysatoren für die oxydative Dehydrierung
EP0129899B1 (de)	1987-08-19	Verfahren zur Valenzisomerisierung von Olefinen
EP0006501B1 (de)	1983-06-08	Herstellung von Olefinen aus Methanol bzw. Dimethyläther
DE1667163C3 (de)	1980-04-30	Verfahren zur Herstellung eines mit Nickelionen ausgetauschten kristallinen Aluminiumsilikatkatalysators
DE2138048A1 (de)	1972-04-13	Manganferritkatalysatoren für oxydative Dehydrierung sverfahren und Verfahren zur Dehydrierung von organischen Verbindungen
DE2560646C2 (de)	1987-05-07	Verfahren zur Herstellung von Olefinen aus Olefinen mit kleinerer Anzahl an Kohlenstoffatomen
DE3318515A1 (de)	1983-11-24	Verfahren zur herstellung von ethylbenzol
DE3330790A1 (de)	1985-03-14	Verfahren zur herstellung von methylstyrol und ethyltoluol
DE1805946A1 (de)	1969-06-26	Dehydrogenierungsverfahren
DD251710A1 (de)	1987-11-25	Verfahren zur herstellung von aromatischen kohlenwasserstoffen
DE2042730A1 (de)	1971-03-04	Mit seltenen Erden und Chrom beladener Faujasit, Verfahren zu dessen Herstellung sowie aus dem Faujasit hergestellte Kata iysatoren