DD139861A5 - Verfahren zur herstellung von dreiblockcopolymere - Google Patents

Verfahren zur herstellung von dreiblockcopolymere Download PDF

Info

Publication number: DD139861A5
Authority: DD; German Democratic Republic
Prior art keywords: block; polymer; polymerization; styrene; monomer
Prior art date: 1977-12-20

Application number

DD78209876A

Other languages

German (de)

English (en)

Inventor

Paolo Giusti

Original Assignee

Anic Spa

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1977-12-20

Filing date

1978-12-18

Publication date

1980-01-23

1978-12-18 Application filed by Anic Spa filed Critical Anic Spa

1980-01-23 Publication of DD139861A5 publication Critical patent/DD139861A5/de

Links

238000000034 method Methods 0.000 title claims description 18
230000008569 process Effects 0.000 title claims description 8
238000002360 preparation method Methods 0.000 title claims description 3
229920001577 copolymer Polymers 0.000 title description 13
229920000642 polymer Polymers 0.000 claims description 33
VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims description 30
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 30
238000006116 polymerization reaction Methods 0.000 claims description 17
239000000178 monomer Substances 0.000 claims description 13
238000006243 chemical reaction Methods 0.000 claims description 8
150000001875 compounds Chemical class 0.000 claims description 8
229920000428 triblock copolymer Polymers 0.000 claims description 8
TXQHJLUVWZNSLH-UHFFFAOYSA-N 5-ethenyl-2,5-dimethylcyclohexa-1,3-diene Chemical compound CC1(C=C)CC=C(C=C1)C TXQHJLUVWZNSLH-UHFFFAOYSA-N 0.000 claims description 5
239000004215 Carbon black (E152) Substances 0.000 claims description 3
125000004432 carbon atom Chemical group C* 0.000 claims description 3
239000003054 catalyst Substances 0.000 claims description 3
230000003197 catalytic effect Effects 0.000 claims description 3
229930195733 hydrocarbon Natural products 0.000 claims description 3
229910052782 aluminium Inorganic materials 0.000 claims description 2
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
239000004033 plastic Substances 0.000 claims description 2
229920003023 plastic Polymers 0.000 claims description 2
239000002841 Lewis acid Substances 0.000 claims 2
150000007517 lewis acids Chemical class 0.000 claims 2
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 1
238000007334 copolymerization reaction Methods 0.000 claims 1
125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 1
125000005843 halogen group Chemical group 0.000 claims 1
OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 14
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 12
YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 9
239000004793 Polystyrene Substances 0.000 description 9
229920002223 polystyrene Polymers 0.000 description 9
ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 8
238000000605 extraction Methods 0.000 description 8
229920002367 Polyisobutene Polymers 0.000 description 7
239000000463 material Substances 0.000 description 7
239000002904 solvent Substances 0.000 description 7
238000004458 analytical method Methods 0.000 description 6
239000011541 reaction mixture Substances 0.000 description 6
238000005194 fractionation Methods 0.000 description 5
230000009477 glass transition Effects 0.000 description 5
229920002725 thermoplastic elastomer Polymers 0.000 description 5
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
229920000034 Plastomer Polymers 0.000 description 4
229920001971 elastomer Polymers 0.000 description 4
229920001519 homopolymer Polymers 0.000 description 4
239000000203 mixture Substances 0.000 description 4
229920006395 saturated elastomer Polymers 0.000 description 4
238000001228 spectrum Methods 0.000 description 4
238000003756 stirring Methods 0.000 description 4
-1 vinyl ether compounds Chemical class 0.000 description 4
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 3
230000009102 absorption Effects 0.000 description 3
238000010521 absorption reaction Methods 0.000 description 3
125000002091 cationic group Chemical group 0.000 description 3
239000000460 chlorine Substances 0.000 description 3
238000002474 experimental method Methods 0.000 description 3
230000032683 aging Effects 0.000 description 2
VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
229920006125 amorphous polymer Polymers 0.000 description 2
229910052786 argon Inorganic materials 0.000 description 2
230000008901 benefit Effects 0.000 description 2
229910052801 chlorine Inorganic materials 0.000 description 2
239000000806 elastomer Substances 0.000 description 2
239000011521 glass Substances 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
239000007788 liquid Substances 0.000 description 2
UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 2
230000003647 oxidation Effects 0.000 description 2
238000007254 oxidation reaction Methods 0.000 description 2
239000005060 rubber Substances 0.000 description 2
125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 2
RUVINXPYWBROJD-ONEGZZNKSA-N trans-anethole Chemical compound COC1=CC=C(\C=C\C)C=C1 RUVINXPYWBROJD-ONEGZZNKSA-N 0.000 description 2
BNGXYYYYKUGPPF-UHFFFAOYSA-M (3-methylphenyl)methyl-triphenylphosphanium;chloride Chemical compound [Cl-].CC1=CC=CC(C[P+](C=2C=CC=CC=2)(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 BNGXYYYYKUGPPF-UHFFFAOYSA-M 0.000 description 1
UHKPXKGJFOKCGG-UHFFFAOYSA-N 2-methylprop-1-ene;styrene Chemical compound CC(C)=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 UHKPXKGJFOKCGG-UHFFFAOYSA-N 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
238000004566 IR spectroscopy Methods 0.000 description 1
239000005062 Polybutadiene Substances 0.000 description 1
239000000654 additive Substances 0.000 description 1
229940011037 anethole Drugs 0.000 description 1
125000000129 anionic group Chemical group 0.000 description 1
150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
125000004429 atom Chemical group 0.000 description 1
RFRXIWQYSOIBDI-UHFFFAOYSA-N benzarone Chemical compound CCC=1OC2=CC=CC=C2C=1C(=O)C1=CC=C(O)C=C1 RFRXIWQYSOIBDI-UHFFFAOYSA-N 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
229910052796 boron Inorganic materials 0.000 description 1
229910052794 bromium Inorganic materials 0.000 description 1
229920005549 butyl rubber Polymers 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
125000001309 chloro group Chemical group Cl* 0.000 description 1
NEHMKBQYUWJMIP-NJFSPNSNSA-N chloro(114C)methane Chemical compound [14CH3]Cl NEHMKBQYUWJMIP-NJFSPNSNSA-N 0.000 description 1
HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 description 1
238000001816 cooling Methods 0.000 description 1
239000003431 cross linking reagent Substances 0.000 description 1
125000004122 cyclic group Chemical group 0.000 description 1
229920000359 diblock copolymer Polymers 0.000 description 1
YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 1
238000000113 differential scanning calorimetry Methods 0.000 description 1
238000004455 differential thermal analysis Methods 0.000 description 1
AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 1
230000000694 effects Effects 0.000 description 1
230000007613 environmental effect Effects 0.000 description 1
229960003750 ethyl chloride Drugs 0.000 description 1
125000000524 functional group Chemical group 0.000 description 1
229910052736 halogen Inorganic materials 0.000 description 1
150000002367 halogens Chemical class 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
239000003999 initiator Substances 0.000 description 1
230000009878 intermolecular interaction Effects 0.000 description 1
230000008863 intramolecular interaction Effects 0.000 description 1
229910052740 iodine Inorganic materials 0.000 description 1
238000012690 ionic polymerization Methods 0.000 description 1
238000002955 isolation Methods 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
239000011159 matrix material Substances 0.000 description 1
230000007246 mechanism Effects 0.000 description 1
238000002844 melting Methods 0.000 description 1
230000008018 melting Effects 0.000 description 1
GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 1
229940073584 methylene chloride Drugs 0.000 description 1
230000004048 modification Effects 0.000 description 1
238000012986 modification Methods 0.000 description 1
KKFHAJHLJHVUDM-UHFFFAOYSA-N n-vinylcarbazole Chemical compound C1=CC=C2N(C=C)C3=CC=CC=C3C2=C1 KKFHAJHLJHVUDM-UHFFFAOYSA-N 0.000 description 1
125000004433 nitrogen atom Chemical group N* 0.000 description 1
125000004430 oxygen atom Chemical group O* 0.000 description 1
RUVINXPYWBROJD-UHFFFAOYSA-N para-methoxyphenyl Natural products COC1=CC=C(C=CC)C=C1 RUVINXPYWBROJD-UHFFFAOYSA-N 0.000 description 1
229910052698 phosphorus Inorganic materials 0.000 description 1
229920002857 polybutadiene Polymers 0.000 description 1
229920001195 polyisoprene Polymers 0.000 description 1
230000000379 polymerizing effect Effects 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
108090000623 proteins and genes Proteins 0.000 description 1
230000001105 regulatory effect Effects 0.000 description 1
239000007858 starting material Substances 0.000 description 1
125000001424 substituent group Chemical group 0.000 description 1
229920001897 terpolymer Polymers 0.000 description 1
239000012815 thermoplastic material Substances 0.000 description 1
230000007704 transition Effects 0.000 description 1
229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
239000004636 vulcanized rubber Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F295/00—Macromolecular compounds obtained by polymerisation using successively different catalyst types without deactivating the intermediate polymer

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Graft Or Block Polymers (AREA)
Polymerization Catalysts (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

DD78209876A 1977-12-20 1978-12-18 Verfahren zur herstellung von dreiblockcopolymere DD139861A5 (de)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
IT30946/77A IT1089976B (it)	1977-12-20	1977-12-20	Compolimeri a tre blocchi e procedimento per la loro produzione

Publications (1)

Publication Number	Publication Date
DD139861A5 true DD139861A5 (de)	1980-01-23

Family

ID=11232821

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DD78209876A DD139861A5 (de)	1977-12-20	1978-12-18	Verfahren zur herstellung von dreiblockcopolymere

Country Status (15)

Country	Link
US (1)	US4262095A (cs)
JP (1)	JPS5490391A (cs)
BE (1)	BE872905A (cs)
CA (1)	CA1118931A (cs)
CS (1)	CS213367B2 (cs)
DD (1)	DD139861A5 (cs)
DE (1)	DE2855133C2 (cs)
DK (1)	DK568378A (cs)
ES (1)	ES476696A1 (cs)
FI (1)	FI783893A7 (cs)
FR (1)	FR2412575A1 (cs)
IT (1)	IT1089976B (cs)
NL (1)	NL7812215A (cs)
SE (1)	SE7813082L (cs)
ZA (1)	ZA786985B (cs)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
IT1149951B (it) *	1980-04-10	1986-12-10	Anic Spa	Procedimento per la preparazione di copolimeti termoelastomerici a tre blocchi
IT1152433B (it) *	1982-07-14	1986-12-31	Montedison Spa	Copolimeri a blocchi delle olefine con monomeri vinilaromatici
CA2104382A1 (en) *	1991-02-19	1992-08-20	Makoto Yamamoto	Thermoplastic resin composition
US5276094A (en) *	1992-11-12	1994-01-04	Polysar Rubber Corp.	Compositions of butyl elastomers and block copolymers of polyisobutylene

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
NL288289A (cs) *	1962-01-29
US3649579A (en) *	1969-01-27	1972-03-14	Minnesota Mining & Mfg	Block copolymer compositions
JPS4825419B1 (cs) *	1969-11-20	1973-07-28
FR2120302A5 (cs) *	1970-12-29	1972-08-18	Aquitaine Total Organico
NL7113482A (cs) *	1971-10-01	1973-04-03
US3992483A (en) *	1975-09-25	1976-11-16	Phillips Petroleum Company	Promoters in the polymerization of monovinyl-aromatic compounds with primary lithium initiators

1977
- 1977-12-20 IT IT30946/77A patent/IT1089976B/it active
1978
- 1978-11-29 US US05/964,459 patent/US4262095A/en not_active Expired - Lifetime
- 1978-12-06 CA CA000317480A patent/CA1118931A/en not_active Expired
- 1978-12-07 FR FR7834540A patent/FR2412575A1/fr active Granted
- 1978-12-13 ZA ZA00786985A patent/ZA786985B/xx unknown
- 1978-12-15 NL NL7812215A patent/NL7812215A/xx not_active Application Discontinuation
- 1978-12-18 DD DD78209876A patent/DD139861A5/de unknown
- 1978-12-18 DK DK568378A patent/DK568378A/da not_active Application Discontinuation
- 1978-12-18 FI FI783893A patent/FI783893A7/fi unknown
- 1978-12-18 JP JP15504378A patent/JPS5490391A/ja active Pending
- 1978-12-19 ES ES476696A patent/ES476696A1/es not_active Expired
- 1978-12-19 SE SE7813082A patent/SE7813082L/xx unknown
- 1978-12-19 CS CS788572A patent/CS213367B2/cs unknown
- 1978-12-20 DE DE2855133A patent/DE2855133C2/de not_active Expired
- 1978-12-20 BE BE192431A patent/BE872905A/xx unknown

Also Published As

Publication number	Publication date
FR2412575A1 (fr)	1979-07-20
BE872905A (fr)	1979-06-20
FI783893A7 (fi)	1979-06-21
US4262095A (en)	1981-04-14
SE7813082L (sv)	1979-06-21
CA1118931A (en)	1982-02-23
DK568378A (da)	1979-06-21
DE2855133C2 (de)	1981-12-17
ES476696A1 (es)	1979-10-16
DE2855133A1 (de)	1979-06-21
NL7812215A (nl)	1979-06-22
ZA786985B (en)	1979-11-28
JPS5490391A (en)	1979-07-18
IT1089976B (it)	1985-06-18
CS213367B2 (en)	1982-04-09
FR2412575B1 (cs)	1982-02-19

Publication	Publication Date	Title
DE2366477C2 (cs)	1988-01-14
DE2550226C2 (de)	1984-12-13	Verzweigte Blockcopolymerisate und Verfahren zu ihrer Herstellung
DE2541511C2 (de)	1982-06-03	Verfahren zur Herstellung eines Blockcopolymerengemisches
DE1928856C3 (de)	1975-05-22	Verfahren zur Herstellung von Homo- oder Copolymerisaten von konjugierten Dienen
DE69029541T2 (de)	1997-07-10	Dreiblockcopolymerisate, die mindestens einen Acrylblock enthalten, ein Verfahren zu ihrer Herstellung und ihre Verwendung zur Herstellung von elastomeren Erzeugnissen
EP0026916B1 (de)	1983-01-19	Verfahren zur Herstellung von Mischungen linearer Dreiblockcopolymerisate sowie Formteile aus diesen
DE2034989C2 (cs)	1988-04-14
DE1745225B2 (de)	1977-08-18	Verfahren zur herstellung von block- copolymerisaten
DE2509577C2 (de)	1984-09-13	Ringöffnungspolymerisation von Cyclopenten
DE2460009A1 (de)	1975-07-10	Polymerisationsverfahren und dadurch hergestelltes polymerisat
DE1300242B (cs)	1977-12-29
DE2550227A1 (de)	1977-05-18	Verzweigte blockcopolymerisate und verfahren zu ihrer herstellung
DE1813765B1 (de)	1970-12-23	Verfahren zum Copolymerisieren von konjugierten Dienen,die 4-12 C-Atome enthalten,mit vinylsubstituierten aromatischen Kohlenwasserstoffen
DE3735403A1 (de)	1989-05-03	Verzweigte copolymerisate und verfahren zu ihrer herstellung
DE1595343C3 (de)	1974-06-20	Verfahren zum Herstellen scMagfester Styrol-Acrylnitrilmischpolymerisate
DE1520693A1 (de)	1970-02-26	Verfahren zur Polymerisation von alpha-Olefinen
DD139861A5 (de)	1980-01-23	Verfahren zur herstellung von dreiblockcopolymere
DE1270820C2 (de)	1979-03-22	Verfahren zur herstellung von block-mischpolymerisaten
DE1816089B2 (de)	1971-12-09	Verfahren zum herstellen von regellosen coplymeren aus conjugierten dienen mit 4 12 kohlenstoffatomen und vinylsubstitu ierten aromatischen kohlenwasserstoffen
DE2348923C3 (de)	1979-02-22	Verfahren zur Herstellung von Blockcopolymeren
DE1795229B2 (de)	1979-03-01	Verfahren zur Herstellung eines Polymerengemisches
DE69121769T2 (de)	1997-02-20	Verfahren zur Herstellung von transparentem schlagfestem Styrolharz
DE1816089C (de)	1972-07-20	Verfahren zum Herstellen von regellosen Copolymeren aus konjugierten Dienen mit 4-12 Kohlenstoffatomen und vinylsubstituierten aromatischen Kohlenwasserstoffen
DE1745197A1 (de)	1971-08-12	Polymerisationsverfahren
DE1295814B (de)	1969-05-22	Verfahren zur Herstellung von Polypropylen