DD144552A5 - Verfahren zur herstellung lichtstabilisierter phosphorhaltiger polyester - Google Patents

Verfahren zur herstellung lichtstabilisierter phosphorhaltiger polyester Download PDF

Info

Publication number: DD144552A5
Authority: DD; German Democratic Republic
Prior art keywords: phosphorus; polyester; acid; groups; ester
Prior art date: 1978-06-29

Application number

DD79213937A

Other languages

German (de)

English (en)

Inventor

Erich Bloecker

Franz Jakob

Original Assignee

Hoechst Ag

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1978-06-29

Filing date

1979-06-24

Publication date

1980-10-22

1979-06-24 Application filed by Hoechst Ag filed Critical Hoechst Ag

1980-10-22 Publication of DD144552A5 publication Critical patent/DD144552A5/de

Links

229920000728 polyester Polymers 0.000 title claims abstract description 64
238000004519 manufacturing process Methods 0.000 title abstract description 6
239000002253 acid Substances 0.000 title description 21
229910052698 phosphorus Inorganic materials 0.000 claims abstract description 37
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 33
239000011574 phosphorus Substances 0.000 claims abstract description 30
-1 phosphoric acid triesters Chemical class 0.000 claims abstract description 23
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 20
NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Substances OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims abstract description 16
238000000034 method Methods 0.000 claims abstract description 14
125000002947 alkylene group Chemical group 0.000 claims abstract description 12
229910000147 aluminium phosphate Inorganic materials 0.000 claims abstract description 11
150000001875 compounds Chemical class 0.000 claims abstract description 11
230000008569 process Effects 0.000 claims abstract description 11
KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims abstract description 10
125000004432 carbon atom Chemical group C* 0.000 claims abstract description 10
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims abstract description 7
238000006068 polycondensation reaction Methods 0.000 claims abstract description 7
230000006641 stabilisation Effects 0.000 claims abstract description 7
238000011105 stabilization Methods 0.000 claims abstract description 7
125000000217 alkyl group Chemical group 0.000 claims abstract description 5
230000032050 esterification Effects 0.000 claims abstract description 5
238000005886 esterification reaction Methods 0.000 claims abstract description 5
150000002927 oxygen compounds Chemical class 0.000 claims abstract description 5
OJURWUUOVGOHJZ-UHFFFAOYSA-N methyl 2-[(2-acetyloxyphenyl)methyl-[2-[(2-acetyloxyphenyl)methyl-(2-methoxy-2-oxoethyl)amino]ethyl]amino]acetate Chemical compound C=1C=CC=C(OC(C)=O)C=1CN(CC(=O)OC)CCN(CC(=O)OC)CC1=CC=CC=C1OC(C)=O OJURWUUOVGOHJZ-UHFFFAOYSA-N 0.000 claims abstract description 3
229920001515 polyalkylene glycol Chemical group 0.000 claims abstract description 3
238000005809 transesterification reaction Methods 0.000 claims description 9
238000002360 preparation method Methods 0.000 claims description 4
125000003827 glycol group Chemical group 0.000 claims description 3
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract description 16
150000002148 esters Chemical class 0.000 abstract description 13
238000006243 chemical reaction Methods 0.000 abstract description 10
125000004437 phosphorous atom Chemical group 0.000 abstract description 5
229920000642 polymer Polymers 0.000 abstract description 3
ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 abstract description 2
MPQXHAGKBWFSNV-UHFFFAOYSA-N oxidophosphanium Chemical class [PH3]=O MPQXHAGKBWFSNV-UHFFFAOYSA-N 0.000 abstract description 2
QXFUBAAEKCHBQY-UHFFFAOYSA-N 3-[hydroxy(methyl)phosphoryl]propanoic acid Chemical compound CP(O)(=O)CCC(O)=O QXFUBAAEKCHBQY-UHFFFAOYSA-N 0.000 abstract 1
ACVYVLVWPXVTIT-UHFFFAOYSA-N phosphinic acid Chemical compound O[PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-N 0.000 abstract 1
150000003014 phosphoric acid esters Chemical class 0.000 description 16
239000000835 fiber Substances 0.000 description 14
229920000139 polyethylene terephthalate Polymers 0.000 description 14
239000005020 polyethylene terephthalate Substances 0.000 description 14
239000003381 stabilizer Substances 0.000 description 14
101000588924 Anthopleura elegantissima Delta-actitoxin-Ael1a Proteins 0.000 description 12
235000011007 phosphoric acid Nutrition 0.000 description 10
239000000049 pigment Substances 0.000 description 10
150000007513 acids Chemical class 0.000 description 7
239000003054 catalyst Substances 0.000 description 7
239000000203 mixture Substances 0.000 description 7
229910019142 PO4 Inorganic materials 0.000 description 6
230000002378 acidificating effect Effects 0.000 description 6
WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 description 6
235000021317 phosphate Nutrition 0.000 description 6
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 5
150000002334 glycols Chemical class 0.000 description 5
WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 4
125000004185 ester group Chemical group 0.000 description 4
125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
239000004408 titanium dioxide Substances 0.000 description 4
229920001634 Copolyester Polymers 0.000 description 3
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
230000008901 benefit Effects 0.000 description 3
230000015572 biosynthetic process Effects 0.000 description 3
239000004611 light stabiliser Substances 0.000 description 3
239000006224 matting agent Substances 0.000 description 3
CAAULPUQFIIOTL-UHFFFAOYSA-N methyl dihydrogen phosphate Chemical compound COP(O)(O)=O CAAULPUQFIIOTL-UHFFFAOYSA-N 0.000 description 3
230000007935 neutral effect Effects 0.000 description 3
239000000047 product Substances 0.000 description 3
239000000126 substance Substances 0.000 description 3
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 2
239000002202 Polyethylene glycol Substances 0.000 description 2
239000000654 additive Substances 0.000 description 2
230000000996 additive effect Effects 0.000 description 2
230000000903 blocking effect Effects 0.000 description 2
238000004132 cross linking Methods 0.000 description 2
230000007423 decrease Effects 0.000 description 2
150000001991 dicarboxylic acids Chemical class 0.000 description 2
MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 2
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
XHXFXVLFKHQFAL-UHFFFAOYSA-N phosphoryl trichloride Chemical compound ClP(Cl)(Cl)=O XHXFXVLFKHQFAL-UHFFFAOYSA-N 0.000 description 2
238000001782 photodegradation Methods 0.000 description 2
229920001521 polyalkylene glycol ether Polymers 0.000 description 2
229920001223 polyethylene glycol Polymers 0.000 description 2
239000011541 reaction mixture Substances 0.000 description 2
230000000087 stabilizing effect Effects 0.000 description 2
OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
150000005691 triesters Chemical class 0.000 description 2
DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 description 1
PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 1
DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 1
RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
KKUKTXOBAWVSHC-UHFFFAOYSA-N Dimethylphosphate Chemical compound COP(O)(=O)OC KKUKTXOBAWVSHC-UHFFFAOYSA-N 0.000 description 1
101150054274 Hnrnpd gene Proteins 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
PHGBTOBVWQJBKT-UHFFFAOYSA-N OC(=O)P(O)=O Chemical class OC(=O)P(O)=O PHGBTOBVWQJBKT-UHFFFAOYSA-N 0.000 description 1
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 1
229910010413 TiO 2 Inorganic materials 0.000 description 1
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 1
238000005299 abrasion Methods 0.000 description 1
230000002411 adverse Effects 0.000 description 1
238000005054 agglomeration Methods 0.000 description 1
230000002776 aggregation Effects 0.000 description 1
125000005907 alkyl ester group Chemical group 0.000 description 1
BNMJSBUIDQYHIN-UHFFFAOYSA-N butyl dihydrogen phosphate Chemical class CCCCOP(O)(O)=O BNMJSBUIDQYHIN-UHFFFAOYSA-N 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
230000015556 catabolic process Effects 0.000 description 1
230000008859 change Effects 0.000 description 1
238000007385 chemical modification Methods 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
150000001805 chlorine compounds Chemical class 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
238000010924 continuous production Methods 0.000 description 1
239000013078 crystal Substances 0.000 description 1
238000006731 degradation reaction Methods 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
150000002009 diols Chemical class 0.000 description 1
239000000975 dye Substances 0.000 description 1
230000000694 effects Effects 0.000 description 1
239000003063 flame retardant Substances 0.000 description 1
239000011888 foil Substances 0.000 description 1
239000007789 gas Substances 0.000 description 1
125000005842 heteroatom Chemical group 0.000 description 1
BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
229910000041 hydrogen chloride Inorganic materials 0.000 description 1
IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
230000007062 hydrolysis Effects 0.000 description 1
238000006460 hydrolysis reaction Methods 0.000 description 1
230000003301 hydrolyzing effect Effects 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
230000002452 interceptive effect Effects 0.000 description 1
238000002844 melting Methods 0.000 description 1
229910021645 metal ion Inorganic materials 0.000 description 1
229910001463 metal phosphate Inorganic materials 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
SAWKFRBJGLMMES-UHFFFAOYSA-N methylphosphine Chemical compound PC SAWKFRBJGLMMES-UHFFFAOYSA-N 0.000 description 1
239000003607 modifier Substances 0.000 description 1
DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 1
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
239000003921 oil Substances 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
239000010452 phosphate Substances 0.000 description 1
AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
150000003009 phosphonic acids Chemical class 0.000 description 1
150000003016 phosphoric acids Chemical class 0.000 description 1
229910000073 phosphorus hydride Inorganic materials 0.000 description 1
238000007539 photo-oxidation reaction Methods 0.000 description 1
239000006187 pill Substances 0.000 description 1
229920001707 polybutylene terephthalate Polymers 0.000 description 1
239000010695 polyglycol Substances 0.000 description 1
229920000151 polyglycol Polymers 0.000 description 1
229920006324 polyoxymethylene Polymers 0.000 description 1
229920000166 polytrimethylene carbonate Polymers 0.000 description 1
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
235000013772 propylene glycol Nutrition 0.000 description 1
238000011084 recovery Methods 0.000 description 1
230000033764 rhythmic process Effects 0.000 description 1
238000007127 saponification reaction Methods 0.000 description 1
239000002904 solvent Substances 0.000 description 1
238000009987 spinning Methods 0.000 description 1
239000007858 starting material Substances 0.000 description 1
125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
150000003512 tertiary amines Chemical class 0.000 description 1
239000004753 textile Substances 0.000 description 1
239000003017 thermal stabilizer Substances 0.000 description 1
239000010936 titanium Substances 0.000 description 1
229910052719 titanium Inorganic materials 0.000 description 1
238000007666 vacuum forming Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L85/00—Compositions of macromolecular compounds obtained by reactions forming a linkage in the main chain of the macromolecule containing atoms other than silicon, sulfur, nitrogen, oxygen and carbon; Compositions of derivatives of such polymers
- C08L85/02—Compositions of macromolecular compounds obtained by reactions forming a linkage in the main chain of the macromolecule containing atoms other than silicon, sulfur, nitrogen, oxygen and carbon; Compositions of derivatives of such polymers containing phosphorus
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
- C08G63/692—Polyesters containing atoms other than carbon, hydrogen and oxygen containing phosphorus
- C08G63/6924—Polyesters containing atoms other than carbon, hydrogen and oxygen containing phosphorus derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/6926—Dicarboxylic acids and dihydroxy compounds
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G79/00—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule
- C08G79/02—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule a linkage containing phosphorus
- C08G79/04—Phosphorus linked to oxygen or to oxygen and carbon
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/521—Esters of phosphoric acids, e.g. of H3PO4

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Polyesters Or Polycarbonates (AREA)
Artificial Filaments (AREA)
Diaphragms For Electromechanical Transducers (AREA)
Compositions Of Macromolecular Compounds (AREA)
Treatments Of Macromolecular Shaped Articles (AREA)
Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)

DD79213937A 1978-06-29 1979-06-24 Verfahren zur herstellung lichtstabilisierter phosphorhaltiger polyester DD144552A5 (de)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
DE2828463A DE2828463C2 (de)	1978-06-29	1978-06-29	Verfahren zur Herstellung linearer, lichtstabilisierter mit TiO2 mattierter Polyester

Publications (1)

Publication Number	Publication Date
DD144552A5 true DD144552A5 (de)	1980-10-22

Family

ID=6043048

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DD79213937A DD144552A5 (de)	1978-06-29	1979-06-24	Verfahren zur herstellung lichtstabilisierter phosphorhaltiger polyester

Country Status (13)

Country	Link
EP (1)	EP0006603B1 (fr)
JP (1)	JPS557888A (fr)
AT (1)	ATE774T1 (fr)
BR (1)	BR7904113A (fr)
DD (1)	DD144552A5 (fr)
DE (2)	DE2828463C2 (fr)
DK (1)	DK274579A (fr)
ES (1)	ES481810A1 (fr)
FI (1)	FI792034A7 (fr)
NO (1)	NO792179L (fr)
PT (1)	PT69846A (fr)
RO (1)	RO78142A (fr)
ZA (1)	ZA793251B (fr)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE3300315A1 (de) *	1983-01-07	1984-07-12	Dynamit Nobel Ag, 5210 Troisdorf	Verfahren zur herstellung von hellfarbigen polyestern unter verwendung von titankatalysatoren
IT1217348B (it) *	1988-03-23	1990-03-22	Enichem Sintesi	Copoliestere lineare contenente fosforo,procedimento per la sua preparazione e suo uso quale agente antifiamma
US5151494A (en) *	1991-01-04	1992-09-29	Hoechst Celanese Corporation	Flame resistant, low pilling polyester fiber
US5145941A (en) *	1991-01-04	1992-09-08	Hoechst Celanese Corporation	Flame resistant, low pilling polyester fiber
US5180793A (en) *	1991-12-31	1993-01-19	Hoechst Celanese Corporation	Flame resistant, low pilling polyester fiber
JP5174980B1 (ja)	2012-06-12	2013-04-03	ニチアス株式会社	自動車用防音カバーおよび自動車用防音カバーの製造方法
CN115976685B (zh) *	2021-10-15	2024-12-27	上海慧翌新材料科技有限公司	一种抗热氧降解功能型无锑聚酯纤维的制造方法

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB769220A (en) *	1953-09-30	1957-03-06	Du Pont	Polyglycol terephthalates
US3097184A (en) *	1958-05-31	1963-07-09	Hoechst Ag	Modified, phosphorus-containing polyester resins and process for preparing same
DD102714A1 (fr) *	1973-03-15	1973-12-20
DE2412216B2 (de) *	1974-03-14	1979-12-13	Davy International Ag, 6000 Frankfurt	Verfahren zur Herstellung von linearen Polyestern

1978
- 1978-06-29 DE DE2828463A patent/DE2828463C2/de not_active Expired
1979
- 1979-06-22 ES ES481810A patent/ES481810A1/es not_active Expired
- 1979-06-24 DD DD79213937A patent/DD144552A5/de unknown
- 1979-06-25 DE DE7979102103T patent/DE2962332D1/de not_active Expired
- 1979-06-25 EP EP79102103A patent/EP0006603B1/fr not_active Expired
- 1979-06-25 AT AT79102103T patent/ATE774T1/de active
- 1979-06-26 RO RO7997962A patent/RO78142A/fr unknown
- 1979-06-27 FI FI792034A patent/FI792034A7/fi not_active Application Discontinuation
- 1979-06-28 BR BR7904113A patent/BR7904113A/pt unknown
- 1979-06-28 JP JP8082379A patent/JPS557888A/ja active Pending
- 1979-06-28 NO NO792179A patent/NO792179L/no unknown
- 1979-06-28 DK DK274579A patent/DK274579A/da not_active Application Discontinuation
- 1979-06-28 PT PT69846A patent/PT69846A/pt unknown
- 1979-06-29 ZA ZA793251A patent/ZA793251B/xx unknown

Also Published As

Publication number	Publication date
ZA793251B (en)	1980-07-30
NO792179L (no)	1980-01-03
BR7904113A (pt)	1980-03-25
DE2962332D1 (en)	1982-04-29
FI792034A7 (fi)	1981-01-01
RO78142A (fr)	1982-02-01
DE2828463C2 (de)	1980-08-28
ATE774T1 (de)	1982-04-15
DK274579A (da)	1979-12-30
JPS557888A (en)	1980-01-21
ES481810A1 (es)	1980-02-16
PT69846A (de)	1979-07-01
DE2828463B1 (de)	1979-12-13
EP0006603A1 (fr)	1980-01-09
EP0006603B1 (fr)	1982-03-24

Publication	Publication Date	Title
DE2660334C2 (de)	1986-10-16	Verwendung von bestimmten Phosphor enthaltenden Verbindungen zum Flammfestmachen von Polyestern
DE2236037C3 (de)	1975-04-17	Schwer entflammbare Fäden und Fasern aus Polyester
DE2708790C2 (de)	1982-02-25	Lineare Homo- oder Copolyester, Verfahren zur Herstellung der Polyester und ihre Verwendung
DE2242002C3 (de)	1978-08-24	Flammwidrige synthetische lineare Polyester sowie deren Verwendung
DE2346787B2 (de)	1979-01-04	Schwer entflammbare lineare Polyester, Verfahren zu deren Herstellung und deren Verwendung
DE4205093A1 (de)	1992-12-17	Verfahren zur herstellung eines polymers auf polybutylenterephtalat-basis
DD144552A5 (de)	1980-10-22	Verfahren zur herstellung lichtstabilisierter phosphorhaltiger polyester
AT259232B (de)	1968-01-10	Verfahren zur Herstellung von faser und filmbildenden Polyestern
DE2746338A1 (de)	1978-04-20	Feuerfeste copolyester mit phosphongruppen
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