DD158244A5 - Verfahren zur herstellung von homo-und copolymerisaten - Google Patents

Verfahren zur herstellung von homo-und copolymerisaten Download PDF

Info

Publication number: DD158244A5
Authority: DD; German Democratic Republic
Prior art keywords: beta; carboxylic acid; acid amides; acrylic; unsaturated
Prior art date: 1978-12-27

Application number

DD79228049A

Other languages

German (de)

English (en)

Inventor

Erich Kuester

Bernhard Goossens

Kurt Dahmen

Eduard Barthell

Original Assignee

Stockhausen & Cie Chem Fab

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1978-12-27

Filing date

1979-12-21

Publication date

1983-01-05

1978-12-27 Priority claimed from DE19782856383 external-priority patent/DE2856383C2/de

1979-03-24 Priority claimed from DE19792911642 external-priority patent/DE2911642C2/de

1979-12-21 Application filed by Stockhausen & Cie Chem Fab filed Critical Stockhausen & Cie Chem Fab

1983-01-05 Publication of DD158244A5 publication Critical patent/DD158244A5/de

Links

238000004519 manufacturing process Methods 0.000 title description 2
238000004770 highest occupied molecular orbital Methods 0.000 title 1
HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims abstract description 16
238000000034 method Methods 0.000 claims abstract description 14
238000006116 polymerization reaction Methods 0.000 claims abstract description 11
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical class CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims abstract description 6
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims abstract description 5
238000002360 preparation method Methods 0.000 claims abstract description 5
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 4
239000001257 hydrogen Substances 0.000 claims abstract description 4
229910052739 hydrogen Inorganic materials 0.000 claims abstract description 4
229920001577 copolymer Polymers 0.000 claims description 20
239000000178 monomer Substances 0.000 claims description 15
FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 claims description 8
239000000725 suspension Substances 0.000 claims description 8
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical class C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 6
125000004432 carbon atom Chemical group C* 0.000 claims description 6
VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 4
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 4
239000003999 initiator Substances 0.000 claims description 4
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 4
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 4
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 3
QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 claims description 3
125000000217 alkyl group Chemical group 0.000 claims description 3
150000001412 amines Chemical class 0.000 claims description 3
229920001567 vinyl ester resin Polymers 0.000 claims description 3
KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 claims description 2
OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 2
125000001931 aliphatic group Chemical group 0.000 claims description 2
125000003118 aryl group Chemical group 0.000 claims description 2
125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims description 2
125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 claims description 2
239000001530 fumaric acid Substances 0.000 claims description 2
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 2
239000011976 maleic acid Substances 0.000 claims description 2
239000007858 starting material Substances 0.000 claims description 2
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims 3
GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 claims 1
150000003926 acrylamides Chemical class 0.000 claims 1
XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims 1
QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims 1
150000001450 anions Chemical class 0.000 claims 1
125000005395 methacrylic acid group Chemical class 0.000 claims 1
125000000325 methylidene group Chemical group [H]C([H])=* 0.000 claims 1
230000014759 maintenance of location Effects 0.000 abstract description 12
229920000642 polymer Polymers 0.000 abstract description 9
-1 N-substituted carboxylic acid amides Chemical class 0.000 abstract description 8
239000000654 additive Substances 0.000 abstract description 8
238000004062 sedimentation Methods 0.000 abstract description 5
150000003141 primary amines Chemical class 0.000 abstract description 3
239000003054 catalyst Substances 0.000 abstract description 2
238000006243 chemical reaction Methods 0.000 abstract description 2
238000007056 transamidation reaction Methods 0.000 abstract description 2
230000003311 flocculating effect Effects 0.000 abstract 2
239000002480 mineral oil Substances 0.000 abstract 2
125000003277 amino group Chemical group 0.000 abstract 1
229920006317 cationic polymer Polymers 0.000 abstract 1
238000010438 heat treatment Methods 0.000 abstract 1
239000013067 intermediate product Substances 0.000 abstract 1
239000012808 vapor phase Substances 0.000 abstract 1
150000007934 α,β-unsaturated carboxylic acids Chemical class 0.000 abstract 1
239000000047 product Substances 0.000 description 14
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
229920001519 homopolymer Polymers 0.000 description 11
239000000243 solution Substances 0.000 description 9
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 8
OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 7
238000012360 testing method Methods 0.000 description 7
230000000996 additive effect Effects 0.000 description 6
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
LXEKPEMOWBOYRF-UHFFFAOYSA-N [2-[(1-azaniumyl-1-imino-2-methylpropan-2-yl)diazenyl]-2-methylpropanimidoyl]azanium;dichloride Chemical group Cl.Cl.NC(=N)C(C)(C)N=NC(C)(C)C(N)=N LXEKPEMOWBOYRF-UHFFFAOYSA-N 0.000 description 4
239000007864 aqueous solution Substances 0.000 description 4
230000007935 neutral effect Effects 0.000 description 4
150000001875 compounds Chemical class 0.000 description 3
230000000694 effects Effects 0.000 description 3
238000005189 flocculation Methods 0.000 description 3
230000016615 flocculation Effects 0.000 description 3
239000000203 mixture Substances 0.000 description 3
239000000126 substance Substances 0.000 description 3
MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical compound [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
150000001408 amides Chemical class 0.000 description 2
150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
239000003795 chemical substances by application Substances 0.000 description 2
239000002270 dispersing agent Substances 0.000 description 2
GMSCBRSQMRDRCD-UHFFFAOYSA-N dodecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCOC(=O)C(C)=C GMSCBRSQMRDRCD-UHFFFAOYSA-N 0.000 description 2
238000002474 experimental method Methods 0.000 description 2
239000000945 filler Substances 0.000 description 2
239000008394 flocculating agent Substances 0.000 description 2
238000000227 grinding Methods 0.000 description 2
238000002329 infrared spectrum Methods 0.000 description 2
238000005342 ion exchange Methods 0.000 description 2
239000000314 lubricant Substances 0.000 description 2
229910052757 nitrogen Inorganic materials 0.000 description 2
150000002978 peroxides Chemical class 0.000 description 2
USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 2
239000000843 powder Substances 0.000 description 2
239000007787 solid Substances 0.000 description 2
238000010998 test method Methods 0.000 description 2
238000004065 wastewater treatment Methods 0.000 description 2
ZDWGIAJCNSCJKJ-UHFFFAOYSA-N 2-methylprop-2-enenitrile;prop-2-enamide Chemical compound CC(=C)C#N.NC(=O)C=C ZDWGIAJCNSCJKJ-UHFFFAOYSA-N 0.000 description 1
RALRVIPTUXSBPO-UHFFFAOYSA-N 4-[4-chloro-3-(trifluoromethyl)phenyl]piperidin-4-ol Chemical compound C=1C=C(Cl)C(C(F)(F)F)=CC=1C1(O)CCNCC1 RALRVIPTUXSBPO-UHFFFAOYSA-N 0.000 description 1
OZAIFHULBGXAKX-VAWYXSNFSA-N AIBN Substances N#CC(C)(C)\N=N\C(C)(C)C#N OZAIFHULBGXAKX-VAWYXSNFSA-N 0.000 description 1
239000005995 Aluminium silicate Substances 0.000 description 1
OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
239000004971 Cross linker Substances 0.000 description 1
235000002918 Fraxinus excelsior Nutrition 0.000 description 1
241000294754 Macroptilium atropurpureum Species 0.000 description 1
LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 1
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
238000010521 absorption reaction Methods 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
229920006322 acrylamide copolymer Polymers 0.000 description 1
235000012211 aluminium silicate Nutrition 0.000 description 1
239000003957 anion exchange resin Substances 0.000 description 1
239000002956 ash Substances 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
230000009286 beneficial effect Effects 0.000 description 1
235000019400 benzoyl peroxide Nutrition 0.000 description 1
150000003857 carboxamides Chemical class 0.000 description 1
125000002091 cationic group Chemical group 0.000 description 1
239000003610 charcoal Substances 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
239000004927 clay Substances 0.000 description 1
239000003245 coal Substances 0.000 description 1
239000000084 colloidal system Substances 0.000 description 1
238000007334 copolymerization reaction Methods 0.000 description 1
229920006037 cross link polymer Polymers 0.000 description 1
YQHLDYVWEZKEOX-UHFFFAOYSA-N cumene hydroperoxide Chemical compound OOC(C)(C)C1=CC=CC=C1 YQHLDYVWEZKEOX-UHFFFAOYSA-N 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
239000012024 dehydrating agents‎ Substances 0.000 description 1
239000003085 diluting agent Substances 0.000 description 1
WBZKQQHYRPRKNJ-UHFFFAOYSA-L disulfite Chemical compound [O-]S(=O)S([O-])(=O)=O WBZKQQHYRPRKNJ-UHFFFAOYSA-L 0.000 description 1
230000008030 elimination Effects 0.000 description 1
238000003379 elimination reaction Methods 0.000 description 1
239000000839 emulsion Substances 0.000 description 1
238000007720 emulsion polymerization reaction Methods 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
238000010528 free radical solution polymerization reaction Methods 0.000 description 1
150000002432 hydroperoxides Chemical class 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
238000005259 measurement Methods 0.000 description 1
150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
ZIUHHBKFKCYYJD-UHFFFAOYSA-N n,n'-methylenebisacrylamide Chemical compound C=CC(=O)NCNC(=O)C=C ZIUHHBKFKCYYJD-UHFFFAOYSA-N 0.000 description 1
238000000655 nuclear magnetic resonance spectrum Methods 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
230000000379 polymerizing effect Effects 0.000 description 1
150000004032 porphyrins Chemical class 0.000 description 1
230000001681 protective effect Effects 0.000 description 1
238000010926 purge Methods 0.000 description 1
230000005855 radiation Effects 0.000 description 1
150000003254 radicals Chemical class 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
239000010802 sludge Substances 0.000 description 1
239000002904 solvent Substances 0.000 description 1
238000001228 spectrum Methods 0.000 description 1
238000010557 suspension polymerization reaction Methods 0.000 description 1
229910052723 transition metal Inorganic materials 0.000 description 1
150000003624 transition metals Chemical class 0.000 description 1
230000001960 triggered effect Effects 0.000 description 1
229920002554 vinyl polymer Polymers 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/54—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/52—Amides or imides
- C08F20/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/52—Amides or imides
- C08F20/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
- C08F20/60—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide containing nitrogen in addition to the carbonamido nitrogen
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M145/00—Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
- C10M145/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M149/00—Lubricating compositions characterised by the additive being a macromolecular compound containing nitrogen
- C10M149/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M149/00—Lubricating compositions characterised by the additive being a macromolecular compound containing nitrogen
- C10M149/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M149/06—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an amido or imido group
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/41—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing ionic groups
- D21H17/44—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing ionic groups cationic
- D21H17/45—Nitrogen-containing groups
- D21H17/455—Nitrogen-containing groups comprising tertiary amine or being at least partially quaternised
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/02—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/02—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2217/024—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an amido or imido group
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/02—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2217/028—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a nitrogen-containing hetero ring
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/06—Macromolecular compounds obtained by functionalisation op polymers with a nitrogen containing compound

Landscapes

Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Organic Chemistry (AREA)
Polymers & Plastics (AREA)
General Chemical & Material Sciences (AREA)
Medicinal Chemistry (AREA)
Health & Medical Sciences (AREA)
Oil, Petroleum & Natural Gas (AREA)
Hydrology & Water Resources (AREA)
Water Supply & Treatment (AREA)
Engineering & Computer Science (AREA)
Environmental & Geological Engineering (AREA)
Life Sciences & Earth Sciences (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Separation Of Suspended Particles By Flocculating Agents (AREA)
Polysaccharides And Polysaccharide Derivatives (AREA)

DD79228049A 1978-12-27 1979-12-21 Verfahren zur herstellung von homo-und copolymerisaten DD158244A5 (de)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
DE19782856383 DE2856383C2 (de)	1978-12-27	1978-12-27	Verfahren zur Herstellung von alpha, beta -ungesättigten N-substituierten Säureamiden und ihre Verwendung zur Herstellung von Polymerisaten sowie das N-(2,2-Dimethyl-3-dimethylaminopropyl)-crotonsäureamid
DE19792911642 DE2911642C2 (de)	1979-03-24	1979-03-24	Verfahren zur Herstellung von α,β-ungesättigten N-substituierten Carbonsäureamiden und ihre Verwendung zur Herstellung von Polymerisaten sowie das N-(N',N',2,2 Tetramethyl-3-aminopropyl)-methacrylamid

Publications (1)

Publication Number	Publication Date
DD158244A5 true DD158244A5 (de)	1983-01-05

Family

ID=25777091

Family Applications (2)

Application Number	Title	Priority Date	Filing Date
DD79228049A DD158244A5 (de)	1978-12-27	1979-12-21	Verfahren zur herstellung von homo-und copolymerisaten
DD79218050A DD148213A5 (de)	1978-12-27	1979-12-21	Verfahren zur herstellung von alpha-beta-ungesaettigten n-substituierten carbonsaeureamiden

Family Applications After (1)

Application Number	Title	Priority Date	Filing Date
DD79218050A DD148213A5 (de)	1978-12-27	1979-12-21	Verfahren zur herstellung von alpha-beta-ungesaettigten n-substituierten carbonsaeureamiden

Country Status (9)

Country	Link
US (2)	US4408073A (fr)
EP (2)	EP0013416B1 (fr)
AT (1)	ATE15377T1 (fr)
BR (1)	BR7908569A (fr)
CA (1)	CA1129883A (fr)
DD (2)	DD158244A5 (fr)
DE (2)	DE2967515D1 (fr)
PL (1)	PL130693B1 (fr)
RO (1)	RO79816A (fr)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE3209800C2 (de) *	1982-03-18	1990-03-08	Chemische Fabrik Stockhausen GmbH, 4150 Krefeld	Verfahren zur Herstellung von N-(tert. Aminoalkyl)acrylamiden
DE3402599C2 (de) *	1984-01-26	1986-02-27	Chemische Fabrik Stockhausen GmbH, 4150 Krefeld	Verfahren zur Herstellung von N-substituierten α,ß-ungesättigten Carbonsäureamiden
US4754056A (en) *	1985-04-05	1988-06-28	Desoto, Inc.	Radiation-curable coatings containing reactive pigment dispersants
US4673705A (en) *	1985-04-05	1987-06-16	Desoto, Inc.	Radiation-curable coatings containing reactive pigment dispersants
GB8512937D0 (en) *	1985-05-22	1985-06-26	Allied Colloids Ltd	Water treatment
DE3544909A1 (de) *	1985-12-19	1987-06-25	Stockhausen Chem Fab Gmbh	Copolymere aus acrylamid und dimethylaminopropylacrylamid als flockungsmittel und verfahren zum entwaessern von klaerschlaemmen unter verwendung dieser flockungsmittel
DE3800199A1 (de) *	1988-01-07	1989-07-20	Sandoz Ag	Seitenkettenhaltige vinylpolymere
US4954538A (en) *	1988-12-19	1990-09-04	American Cyanamid Company	Micro-emulsified glyoxalated acrylamide polymers
CA2040996A1 (fr) *	1990-05-02	1991-11-03	Robert L. Albright	Methode et composition permettant de reduire la cholesterolemie
US5498678A (en) *	1992-12-21	1996-03-12	Rohm And Haas Company	Suspension polymerization process for water-soluble monomers
US5451397A (en) *	1992-12-21	1995-09-19	Rohm And Haas Company	Bile acid sequestrant
US5858886A (en) *	1996-07-02	1999-01-12	Milliken Research Corporation	Low permeability airbag fabric
GB2354001A (en) *	1998-05-02	2001-03-14	Bp Chem Int Ltd	Polymers and their uses
GB9810370D0 (en) *	1998-05-14	1998-07-15	Bp Exploration Operating	Polymer products and their uses in oil
DE19829757A1 (de)	1998-07-03	2000-01-05	Stockhausen Chem Fab Gmbh	Wässrige Klebemitteldispersionen und deren Verwendung zur Herstellung von mehrlagigen Papieren
US7425595B2 (en) *	2003-12-15	2008-09-16	Absorbent Technologies, Inc.	Superabsorbent polymer products including a beneficial additive and methods of making and application
AU2004299877A1 (en) *	2003-12-15	2005-06-30	Absorbent Technologies, Inc.	A superabsorbent polymer product including a bioactive, growth-promoting additive
CA2576967A1 (fr) *	2004-08-27	2006-03-09	Absorbent Technologies, Inc.	Polymeres superabsorbants utilises dans des applications agricoles
US20070167330A1 (en) *	2006-01-17	2007-07-19	Savich Milan H	Superabsorbent polymer applicator
US7607259B2 (en) *	2006-01-17	2009-10-27	Absorbent Technologies, Inc.	Superabsorbent polymer root dip
US20070163172A1 (en) *	2006-01-17	2007-07-19	Savich Milan H	Biodegradable mat containing superabsorbent polymers
US7687661B2 (en) *	2006-03-15	2010-03-30	Battelle Memorial Institute	Method for conversion of β-hydroxy carbonyl compounds
US20070219397A1 (en) *	2006-03-15	2007-09-20	Battelle Memorial Institute	Method for conversion of beta-hydroxy carbonyl compounds
US9596801B2 (en)	2010-10-25	2017-03-21	Vjs Investments Limited	Superabsorbent polymer seed coatings and associated methods

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US2649438A (en) *	1950-10-28	1953-08-18	Ind Rayon Corp	Copolymers of acrylonitrile and basic acrylamides
US2980657A (en) *	1954-07-06	1961-04-18	Rohm & Haas	Quaternary ammonium compounds of polymers of acrylamido type and methods for making them
US3043822A (en) *	1957-08-01	1962-07-10	Ciba Ltd	New polymerization process
US3188228A (en) *	1958-05-14	1965-06-08	Du Pont	Method of graft polymerizing an organic compound to a solid shaped condensation polymer structure
US3170901A (en) *	1960-12-27	1965-02-23	Rohm & Hans Company	Novel quaternary ammonium compounds and polymers thereof
US3424820A (en) *	1966-12-21	1969-01-28	Du Pont	Graft copolymers of amine compounds on polyamide and polyester substrates
US3883491A (en) *	1969-06-11	1975-05-13	Lubrizol Corp	Novel N-3-aminoalkyl amides, polymers thereof, and method for their preparation
DE2233337A1 (de) *	1969-06-11	1974-01-10	Lubrizol Corp	Polymerisate von amiden und ihre verwendung als flockungsmittel
US3856689A (en) *	1969-06-11	1974-12-24	Lubrizol Corp	Oil-soluble polymers of n-3-aminoalkyl acrylamides, and lubricants containing them
US3666810A (en) *	1969-06-11	1972-05-30	Lubrizol Corp	Novel n-3-aminoalkyl amides, polymers thereof, and method for their preparation
US3661868A (en) *	1970-05-01	1972-05-09	Dow Chemical Co	Flocculant
NL7308872A (fr) *	1972-07-12	1974-01-15
NL7309742A (fr) *	1972-07-24	1974-01-28
US3914303A (en) *	1972-09-01	1975-10-21	Cpc International Inc	Preparation of N,N-dialkylacylamides
GB1510689A (en) *	1974-12-19	1978-05-10	Sumitomo Chemical Co	Preparation of water-soluble cationic high polymer
US4031138A (en) *	1976-03-18	1977-06-21	Texaco Development Corporation	Stable substituted acrylamides or methacrylamides
DE2623838A1 (de) *	1976-05-28	1977-12-15	Basf Ag	Verfahren zur herstellung von n-substituierten acrylamiden
IN151693B (fr) *	1978-05-05	1983-07-02	Stockhausen & Cie Chem Fab
DE2819735C2 (de) *	1978-05-05	1982-09-16	Chemische Fabrik Stockhausen GmbH, 4150 Krefeld	Verfahren zur Herstellung von α,β-ungesättigten N-substituierten Säureamiden

1979
- 1979-12-21 DD DD79228049A patent/DD158244A5/de unknown
- 1979-12-21 DD DD79218050A patent/DD148213A5/de unknown
- 1979-12-21 DE DE7979105340T patent/DE2967515D1/de not_active Expired
- 1979-12-21 EP EP79105340A patent/EP0013416B1/fr not_active Expired
- 1979-12-21 EP EP81103346A patent/EP0038573B1/fr not_active Expired
- 1979-12-21 DE DE8181103346T patent/DE2967510D1/de not_active Expired
- 1979-12-21 AT AT81103346T patent/ATE15377T1/de active
- 1979-12-24 PL PL1979220782A patent/PL130693B1/pl unknown
- 1979-12-26 RO RO7999706A patent/RO79816A/fr unknown
- 1979-12-26 US US06/107,245 patent/US4408073A/en not_active Expired - Lifetime
- 1979-12-27 CA CA342,641A patent/CA1129883A/fr not_active Expired
- 1979-12-27 BR BR7908569A patent/BR7908569A/pt unknown
1983
- 1983-07-11 US US06/512,496 patent/US4528350A/en not_active Expired - Fee Related

Also Published As

Publication number	Publication date
DE2967510D1 (en)	1985-10-10
US4408073A (en)	1983-10-04
RO79816A (fr)	1983-02-01
PL220782A1 (en)	1983-01-03
EP0038573B1 (fr)	1985-09-04
PL130693B1 (en)	1984-08-31
EP0038573A1 (fr)	1981-10-28
EP0013416A1 (fr)	1980-07-23
RO79816B (ro)	1983-01-30
ATE15377T1 (de)	1985-09-15
EP0013416B1 (fr)	1985-09-18
DD148213A5 (de)	1981-05-13
CA1129883A (fr)	1982-08-17
BR7908569A (pt)	1980-09-16
US4528350A (en)	1985-07-09
DE2967515D1 (en)	1985-10-24

Publication	Publication Date	Title
EP0038573B1 (fr)	1985-09-04	Polymères d'amides N-substitués d'acides carboxyliques alpha-bêta-insaturés et leur utilisation comme adjuvants de sédimentation, de floculation, de déshydratation et de rétention
DE2205908C2 (de)	1982-12-09	Verfahren zur Flockung von in wäßrigen Medien suspendierten Feststoffen
DE60311467T2 (de)	2007-11-08	Dispersion von wasserlöslichem polymer, herstellungsverfahren dafür und verwendungsverfahren dafür
EP1353975B2 (fr)	2010-09-01	Procede de production de dispersions polymeres eau-dans-eau
DE68921053T2 (de)	1995-06-01	Hochleistungs-Polymer-Flokkuliermittel.
DE69026744T2 (de)	1996-10-17	Amphoterer Elektrolyt, Verfahren zur Herstellung und Entwässerungsmittel für organische Schlämme
DE3544909C2 (fr)	1991-10-24
DE3720194A1 (de)	1987-12-23	Vinylamincopolymere, verwendung als ausflockungsmittel und verfahren zu ihrer herstellung
DE2142742C2 (de)	1982-09-30	Verfahren zur Herstellung von Ammoniumpolyacrylaten
DE2821359A1 (de)	1978-11-23	Kationische polyelektrolyte auf der basis von acrylamid und dimethylaminoaethylacrylat, verfahren zu deren herstellung und verwendung derselben
DE3624813A1 (de)	1988-03-10	Amphotere wasserloesliche polymere, verfahren zu ihrer herstellung und ihre verwendung als dispergierhilfsmittel
DE2538281B2 (de)	1980-07-17	Retentions- und Flockungsmittel auf Basis von Polyacrylamiden
EP0331066A2 (fr)	1989-09-06	Polymérisat
DE3533337A1 (de)	1986-04-24	Verfahren zur herstellung von hochgradig wasserabsorbierendem harz
EP0055801A2 (fr)	1982-07-14	Procédé d'épaississement de systèmes aqueux
WO2004020490A1 (fr)	2004-03-11	Polyelectrolytes cationiques respectueux de l'environnement
DE2304586C3 (de)	1978-08-03	Anionische Papierleimungsmittel auf der Basis von Carboxylgruppen und Dicarbonsäureimidgruppen enthaltenden Copolymerisaten
DE69500248T2 (de)	1997-11-13	Polymerampholyte, Polymermikroemulsionen, Verfahren zu deren Herstellung und deren Verwendung als Flokkulierungsmittel
DE1595744A1 (de)	1970-04-30	Verfahren zur Herstellung von kationischen Vinyllactamacrylamid-Kopolymeren
DE69003614T2 (de)	1994-03-10	Amphotere hydrophile Polymere, Verfahren zu deren Herstellung und deren Verwendung als absorbierende Mittel.
DE2557324C2 (de)	1983-06-09	Verfahren zur Herstellung von sedimentationsstabilen Wasser-in-Öl-Dispersionen von Acrylamidpolymerisaten
DE1055235B (de)	1959-04-16	Verfahren zur Herstellung von Methylolderivaten aminolysierter Acrylsaeureesterpolymerisate
EP0068159A1 (fr)	1983-01-05	Copolymères réticulés gonflables par l'eau, leur préparation et usage
DE69016299T2 (de)	1995-05-24	Hilfsmittel für die Herstellung von Papier.
EP0068225B1 (fr)	1985-11-27	Emploi de polymères hydrosolubles de Di-C1-C3 alcoyl-aminonéo-pentyl(méth)acrylates comme agents de rétention, d'égouttage et de floculation