DD202737A5 - Verfahren zur aufarbeitung von galvanischen elementen - Google Patents
Verfahren zur aufarbeitung von galvanischen elementen Download PDFInfo
- Publication number
- DD202737A5 DD202737A5 DD82241157A DD24115782A DD202737A5 DD 202737 A5 DD202737 A5 DD 202737A5 DD 82241157 A DD82241157 A DD 82241157A DD 24115782 A DD24115782 A DD 24115782A DD 202737 A5 DD202737 A5 DD 202737A5
- Authority
- DD
- German Democratic Republic
- Prior art keywords
- cells
- mercury
- electrolysis
- acid treatment
- temperatures
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 18
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims abstract description 22
- 229910052753 mercury Inorganic materials 0.000 claims abstract description 19
- 238000005868 electrolysis reaction Methods 0.000 claims abstract description 15
- 229910052793 cadmium Inorganic materials 0.000 claims abstract description 11
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims abstract description 11
- 238000010306 acid treatment Methods 0.000 claims abstract description 8
- 238000010438 heat treatment Methods 0.000 claims abstract description 6
- 238000001704 evaporation Methods 0.000 claims abstract description 4
- 230000008020 evaporation Effects 0.000 claims abstract description 4
- 239000007788 liquid Substances 0.000 claims abstract description 3
- 230000029087 digestion Effects 0.000 claims abstract 2
- 239000000243 solution Substances 0.000 claims description 16
- 229910052709 silver Inorganic materials 0.000 claims description 11
- 239000004332 silver Substances 0.000 claims description 11
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 8
- 229910052737 gold Inorganic materials 0.000 claims description 8
- 239000010931 gold Substances 0.000 claims description 8
- 239000010802 sludge Substances 0.000 claims description 8
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 7
- 229910017604 nitric acid Inorganic materials 0.000 claims description 7
- 229910021607 Silver chloride Inorganic materials 0.000 claims description 6
- 238000000926 separation method Methods 0.000 claims description 6
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 claims description 6
- 229920003023 plastic Polymers 0.000 claims description 5
- 239000004033 plastic Substances 0.000 claims description 5
- 239000002244 precipitate Substances 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- 229910021538 borax Inorganic materials 0.000 claims description 3
- 238000005260 corrosion Methods 0.000 claims description 3
- 230000007797 corrosion Effects 0.000 claims description 3
- 239000004328 sodium tetraborate Substances 0.000 claims description 3
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 3
- 229910000497 Amalgam Inorganic materials 0.000 claims description 2
- 239000007791 liquid phase Substances 0.000 claims description 2
- 239000006193 liquid solution Substances 0.000 claims description 2
- 238000011084 recovery Methods 0.000 claims description 2
- 229910001220 stainless steel Inorganic materials 0.000 claims description 2
- 239000010935 stainless steel Substances 0.000 claims description 2
- 238000007669 thermal treatment Methods 0.000 claims description 2
- 239000000470 constituent Substances 0.000 claims 2
- 239000003929 acidic solution Substances 0.000 claims 1
- 238000001914 filtration Methods 0.000 claims 1
- 210000004027 cell Anatomy 0.000 abstract 3
- 210000003850 cellular structure Anatomy 0.000 abstract 1
- 238000012958 reprocessing Methods 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 description 12
- 239000002184 metal Substances 0.000 description 12
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 8
- 150000002739 metals Chemical class 0.000 description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 239000003792 electrolyte Substances 0.000 description 5
- 239000011701 zinc Substances 0.000 description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 4
- 229910052725 zinc Inorganic materials 0.000 description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 229910001385 heavy metal Inorganic materials 0.000 description 2
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 2
- 229910000474 mercury oxide Inorganic materials 0.000 description 2
- UKWHYYKOEPRTIC-UHFFFAOYSA-N mercury(ii) oxide Chemical compound [Hg]=O UKWHYYKOEPRTIC-UHFFFAOYSA-N 0.000 description 2
- 229940008718 metallic mercury Drugs 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Chemical compound [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 2
- 238000010626 work up procedure Methods 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000005267 amalgamation Methods 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 230000009172 bursting Effects 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- VNNRSPGTAMTISX-UHFFFAOYSA-N chromium nickel Chemical compound [Cr].[Ni] VNNRSPGTAMTISX-UHFFFAOYSA-N 0.000 description 1
- 239000000567 combustion gas Substances 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 239000010791 domestic waste Substances 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000012065 filter cake Substances 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 239000000383 hazardous chemical Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 231100001231 less toxic Toxicity 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 229910001923 silver oxide Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/52—Reclaiming serviceable parts of waste cells or batteries, e.g. recycling
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/54—Reclaiming serviceable parts of waste accumulators
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/84—Recycling of batteries or fuel cells
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Electrolytic Production Of Metals (AREA)
- Processing Of Solid Wastes (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT291181A AT373731B (de) | 1981-06-30 | 1981-06-30 | Verfahren zur aufarbeitung von galvanischen elementen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DD202737A5 true DD202737A5 (de) | 1983-09-28 |
Family
ID=3542260
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DD82241157A DD202737A5 (de) | 1981-06-30 | 1982-06-28 | Verfahren zur aufarbeitung von galvanischen elementen |
Country Status (7)
| Country | Link |
|---|---|
| EP (1) | EP0069117B1 (cs) |
| AT (1) | AT373731B (cs) |
| CS (1) | CS236481B2 (cs) |
| DD (1) | DD202737A5 (cs) |
| DE (1) | DE3267566D1 (cs) |
| HU (1) | HU193479B (cs) |
| YU (1) | YU134182A (cs) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0521242A3 (en) * | 1991-07-01 | 1993-09-22 | Mitsui Mining & Smelting Co., Ltd. | Method of processing used battery |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3402196A1 (de) * | 1984-01-24 | 1985-07-25 | Metallgesellschaft Ag, 6000 Frankfurt | Verfahren zur aufarbeitung von klein-batterien |
| AT377124B (de) * | 1983-02-01 | 1985-02-11 | Voest Alpine Ag | Einrichtung zum thermischen aufschliessen von gebrauchten galvanischen elementen |
| AT381807B (de) * | 1984-04-10 | 1986-12-10 | Voest Alpine Ag | Verfahren zur rueckgewinnung von metallen aus gebrauchten galvanischen elementen |
| AT386492B (de) * | 1985-02-06 | 1988-08-25 | Voest Alpine Ag | Verfahren zur oxidativ-thermischen vorbehandlung von galvanischen elementen fuer die nachfolgende abtrennung von schwermetallen sowie vorrichtung zur durchfuehrung dieses verfahrens |
| WO1988004476A1 (en) * | 1986-12-12 | 1988-06-16 | R.T.I. International B.V. | Process for the recycling of electrical batteries, assembled printed circuit boards and electronic components |
| FR2658664B1 (fr) * | 1990-02-19 | 1992-06-19 | Zouari Yasmine | Procede de destruction des piles electriques usagees et de recuperation de differents constituants. |
| DE4020227A1 (de) * | 1990-06-26 | 1992-01-02 | Celi Antonio Maria Dipl Ing | Verfahren und vorrichtung zur aufarbeitung verbrauchter geraetebatterien |
| NL9001825A (nl) * | 1990-08-15 | 1992-03-02 | Tno | Terugwinning van cd en ni uit batterijen. |
| DE4034137C1 (cs) * | 1990-10-26 | 1991-10-10 | Kernforschungszentrum Karlsruhe Gmbh, 7500 Karlsruhe, De | |
| CA2110400A1 (en) * | 1992-04-01 | 1993-10-14 | Jozef Hanulik | Process for recycling solids, powders and sludges contaminated with mercury |
| DE4336124A1 (de) * | 1993-10-22 | 1995-04-27 | Gewerk Keramchemie | Verfahren zur hydrometallurgischen Aufbereitung von verbrauchten Haushalts- und Gerätebatterien |
| GB9414812D0 (en) * | 1994-07-22 | 1994-09-14 | Atomic Energy Authority Uk | The disposal of organic materials encased in metal |
| CN102168284B (zh) * | 2011-03-18 | 2012-05-23 | 北京中航长力能源科技有限公司 | 一种插块式锌空气电池锌电极的回收电解方法 |
| CN119687460B (zh) * | 2025-02-25 | 2025-04-22 | 湖南世度锂电循环科技有限公司 | 一种磷酸铁锂电解液回收装置 |
-
1981
- 1981-06-30 AT AT291181A patent/AT373731B/de not_active IP Right Cessation
-
1982
- 1982-06-09 HU HU821861A patent/HU193479B/hu unknown
- 1982-06-21 YU YU134182A patent/YU134182A/xx unknown
- 1982-06-25 CS CS824765A patent/CS236481B2/cs unknown
- 1982-06-25 EP EP82890094A patent/EP0069117B1/de not_active Expired
- 1982-06-25 DE DE8282890094T patent/DE3267566D1/de not_active Expired
- 1982-06-28 DD DD82241157A patent/DD202737A5/de unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0521242A3 (en) * | 1991-07-01 | 1993-09-22 | Mitsui Mining & Smelting Co., Ltd. | Method of processing used battery |
Also Published As
| Publication number | Publication date |
|---|---|
| AT373731B (de) | 1984-02-10 |
| DE3267566D1 (en) | 1986-01-02 |
| YU134182A (en) | 1984-12-31 |
| CS236481B2 (en) | 1985-05-15 |
| EP0069117B1 (de) | 1985-11-21 |
| ATA291181A (de) | 1983-06-15 |
| EP0069117A1 (de) | 1983-01-05 |
| HU193479B (en) | 1987-10-28 |
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