DD210310A5 - Verfahren und anlage zur direkten erzeugung von eisenschwammpartikeln und fluessigem roheisen aus stueckigem eisenerz - Google Patents
Verfahren und anlage zur direkten erzeugung von eisenschwammpartikeln und fluessigem roheisen aus stueckigem eisenerz Download PDFInfo
- Publication number
- DD210310A5 DD210310A5 DD83256671A DD25667183A DD210310A5 DD 210310 A5 DD210310 A5 DD 210310A5 DD 83256671 A DD83256671 A DD 83256671A DD 25667183 A DD25667183 A DD 25667183A DD 210310 A5 DD210310 A5 DD 210310A5
- Authority
- DD
- German Democratic Republic
- Prior art keywords
- gas
- iron
- particles
- item
- grain fraction
- Prior art date
Links
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title claims abstract description 170
- 229910052742 iron Inorganic materials 0.000 title claims abstract description 85
- 238000000034 method Methods 0.000 title claims abstract description 52
- 239000007788 liquid Substances 0.000 title claims abstract description 10
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 7
- 239000002245 particle Substances 0.000 claims abstract description 71
- 230000009467 reduction Effects 0.000 claims abstract description 61
- 230000008569 process Effects 0.000 claims abstract description 13
- 238000002844 melting Methods 0.000 claims abstract description 10
- 230000008018 melting Effects 0.000 claims abstract description 10
- 239000007789 gas Substances 0.000 claims description 158
- 238000001816 cooling Methods 0.000 claims description 34
- 239000003245 coal Substances 0.000 claims description 29
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 17
- 229910052717 sulfur Inorganic materials 0.000 claims description 17
- 239000011593 sulfur Substances 0.000 claims description 17
- 239000000112 cooling gas Substances 0.000 claims description 14
- 229910000805 Pig iron Inorganic materials 0.000 claims description 10
- 239000002893 slag Substances 0.000 claims description 9
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 7
- 238000002347 injection Methods 0.000 claims description 7
- 239000007924 injection Substances 0.000 claims description 7
- 229910052760 oxygen Inorganic materials 0.000 claims description 7
- 239000001301 oxygen Substances 0.000 claims description 7
- 238000000926 separation method Methods 0.000 claims description 7
- 239000007787 solid Substances 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 238000002309 gasification Methods 0.000 claims description 6
- 238000007792 addition Methods 0.000 claims description 4
- 238000004891 communication Methods 0.000 claims description 3
- UCNNJGDEJXIUCC-UHFFFAOYSA-L hydroxy(oxo)iron;iron Chemical compound [Fe].O[Fe]=O.O[Fe]=O UCNNJGDEJXIUCC-UHFFFAOYSA-L 0.000 claims description 3
- MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical compound [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 claims description 2
- 102000005298 Iron-Sulfur Proteins Human genes 0.000 claims description 2
- 108010081409 Iron-Sulfur Proteins Proteins 0.000 claims description 2
- 238000009434 installation Methods 0.000 claims 5
- 239000012615 aggregate Substances 0.000 claims 1
- 230000015572 biosynthetic process Effects 0.000 claims 1
- 239000011362 coarse particle Substances 0.000 claims 1
- 238000000151 deposition Methods 0.000 claims 1
- 230000003009 desulfurizing effect Effects 0.000 claims 1
- 235000015243 ice cream Nutrition 0.000 claims 1
- 238000011946 reduction process Methods 0.000 claims 1
- 239000000779 smoke Substances 0.000 claims 1
- 239000002966 varnish Substances 0.000 claims 1
- 239000000463 material Substances 0.000 description 6
- 230000001914 calming effect Effects 0.000 description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 238000006477 desulfuration reaction Methods 0.000 description 4
- 230000023556 desulfurization Effects 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 3
- 239000002826 coolant Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 238000005245 sintering Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 241001311578 Calyptraea chinensis Species 0.000 description 2
- 238000003723 Smelting Methods 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 239000012159 carrier gas Substances 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 230000008878 coupling Effects 0.000 description 2
- 238000010168 coupling process Methods 0.000 description 2
- 238000005859 coupling reaction Methods 0.000 description 2
- 210000003918 fraction a Anatomy 0.000 description 2
- 230000004927 fusion Effects 0.000 description 2
- 230000036284 oxygen consumption Effects 0.000 description 2
- 230000000630 rising effect Effects 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 230000008646 thermal stress Effects 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- DJFBAPHXUBVGSS-UHFFFAOYSA-N N1=C(N)N=C(N)N=C1N.[Sn] Chemical compound N1=C(N)N=C(N)N=C1N.[Sn] DJFBAPHXUBVGSS-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 210000004556 brain Anatomy 0.000 description 1
- 239000013590 bulk material Substances 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 235000011116 calcium hydroxide Nutrition 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000000110 cooling liquid Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 239000002274 desiccant Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- -1 for example Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000003502 gasoline Substances 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000013021 overheating Methods 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- JTJMJGYZQZDUJJ-UHFFFAOYSA-N phencyclidine Chemical group C1CCCCN1C1(C=2C=CC=CC=2)CCCCC1 JTJMJGYZQZDUJJ-UHFFFAOYSA-N 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000005057 refrigeration Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000010079 rubber tapping Methods 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000000932 sedative agent Substances 0.000 description 1
- 230000001624 sedative effect Effects 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B13/00—Making spongy iron or liquid steel, by direct processes
- C21B13/14—Multi-stage processes processes carried out in different vessels or furnaces
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B13/00—Making spongy iron or liquid steel, by direct processes
- C21B13/0006—Making spongy iron or liquid steel, by direct processes obtaining iron or steel in a molten state
- C21B13/0013—Making spongy iron or liquid steel, by direct processes obtaining iron or steel in a molten state introduction of iron oxide into a bath of molten iron containing a carbon reductant
- C21B13/002—Reduction of iron ores by passing through a heated column of carbon
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B2100/00—Handling of exhaust gases produced during the manufacture of iron or steel
- C21B2100/20—Increasing the gas reduction potential of recycled exhaust gases
- C21B2100/28—Increasing the gas reduction potential of recycled exhaust gases by separation
- C21B2100/282—Increasing the gas reduction potential of recycled exhaust gases by separation of carbon dioxide
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B2100/00—Handling of exhaust gases produced during the manufacture of iron or steel
- C21B2100/40—Gas purification of exhaust gases to be recirculated or used in other metallurgical processes
- C21B2100/42—Sulphur removal
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B2100/00—Handling of exhaust gases produced during the manufacture of iron or steel
- C21B2100/40—Gas purification of exhaust gases to be recirculated or used in other metallurgical processes
- C21B2100/44—Removing particles, e.g. by scrubbing, dedusting
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/10—Reduction of greenhouse gas [GHG] emissions
- Y02P10/122—Reduction of greenhouse gas [GHG] emissions by capturing or storing CO2
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacture Of Iron (AREA)
- Medicines Containing Material From Animals Or Micro-Organisms (AREA)
- Manufacture Of Metal Powder And Suspensions Thereof (AREA)
- Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Battery Electrode And Active Subsutance (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE3242232 | 1982-11-15 | ||
| DE19833328373 DE3328373A1 (de) | 1982-11-15 | 1983-08-05 | Verfahren und anlage zur direkten erzeugung von eisenschwammpartikeln und fluessigem roheisen aus stueckigem eisenerz |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DD210310A5 true DD210310A5 (de) | 1984-06-06 |
Family
ID=25805798
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DD83256671A DD210310A5 (de) | 1982-11-15 | 1983-11-14 | Verfahren und anlage zur direkten erzeugung von eisenschwammpartikeln und fluessigem roheisen aus stueckigem eisenerz |
Country Status (12)
| Country | Link |
|---|---|
| US (2) | US4543123A (pl) |
| EP (1) | EP0111176B1 (pl) |
| AT (1) | ATE19658T1 (pl) |
| AU (1) | AU569481B2 (pl) |
| BR (1) | BR8306264A (pl) |
| CA (1) | CA1215842A (pl) |
| DD (1) | DD210310A5 (pl) |
| DE (2) | DE3328373A1 (pl) |
| ES (1) | ES527233A0 (pl) |
| PH (1) | PH20286A (pl) |
| PL (1) | PL142647B1 (pl) |
| SU (1) | SU1313354A3 (pl) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AT381117B (de) * | 1984-11-26 | 1986-08-25 | Voest Alpine Ag | Verfahren und anlage zur direktreduktion von eisenoxidteilchen und zum einschmelzen der erhaltenen eisenschwammpartikel in einem einschmelzvergaser |
Families Citing this family (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3438487A1 (de) * | 1984-10-17 | 1986-04-24 | Korf Engineering GmbH, 4000 Düsseldorf | Verfahren zur herstellung von roheisen |
| AT381116B (de) * | 1984-11-15 | 1986-08-25 | Voest Alpine Ag | Verfahren zur herstellung von fluessigem roheisen oder stahlvorprodukten sowie vorrichtung zur durchfuehrung des verfahrens |
| DE3503493A1 (de) * | 1985-01-31 | 1986-08-14 | Korf Engineering GmbH, 4000 Düsseldorf | Verfahren zur herstellung von roheisen |
| DE3504346C2 (de) * | 1985-02-06 | 1986-11-27 | Korf Engineering GmbH, 4000 Düsseldorf | Verfahren und Vorrichtung zur Erzeugung von Eisenschwammpartikeln und flüssigem Roheisen |
| US4685964A (en) * | 1985-10-03 | 1987-08-11 | Midrex International B.V. Rotterdam | Method and apparatus for producing molten iron using coal |
| DE3603894A1 (de) * | 1986-02-05 | 1987-08-06 | Korf Engineering Gmbh | Verfahren zur herstellung von fluessigem roheisen oder stahlvormaterial |
| AU604237B2 (en) * | 1987-02-16 | 1990-12-13 | Moskovsky Institut Stali I Splavov | Method and furnace for making iron-carbon intermediate products for steel production |
| AU596758B2 (en) * | 1987-11-13 | 1990-05-10 | Jp Steel Plantech Co. | Metal-making apparatus involving the smelting reduction of metallic oxides |
| US4981628A (en) * | 1988-10-11 | 1991-01-01 | Sudamet, Ltd. | Repairing refractory linings of vessels used to smelt or refine copper or nickel |
| AT390622B (de) * | 1988-10-25 | 1990-06-11 | Voest Alpine Ind Anlagen | Verfahren und anlage zur herstellung von fluessigem roheisen |
| AT394201B (de) * | 1989-02-16 | 1992-02-25 | Voest Alpine Ind Anlagen | Verfahren zur erzeugung von brennbaren gasen in einem einschmelzvergaser |
| DE4037977A1 (de) * | 1990-11-29 | 1992-06-11 | Voest Alpine Ind Anlagen | Verfahren zur herstellung von roheisen bzw. eisenschwamm |
| US5354356A (en) * | 1992-10-06 | 1994-10-11 | Bechtel Group Inc. | Method of providing fuel for an iron making process |
| US5397376A (en) * | 1992-10-06 | 1995-03-14 | Bechtel Group, Inc. | Method of providing fuel for an iron making process |
| US5320676A (en) * | 1992-10-06 | 1994-06-14 | Bechtel Group, Inc. | Low slag iron making process with injecting coolant |
| US6197088B1 (en) | 1992-10-06 | 2001-03-06 | Bechtel Group, Inc. | Producing liquid iron having a low sulfur content |
| AT402506B (de) * | 1993-01-26 | 1997-06-25 | Holderbank Financ Glarus | Verfahren zur herstellung von roheisen und zementklinker |
| US5958107A (en) * | 1993-12-15 | 1999-09-28 | Bechtel Croup, Inc. | Shift conversion for the preparation of reducing gas |
| AT406482B (de) * | 1995-07-19 | 2000-05-25 | Voest Alpine Ind Anlagen | Verfahren zur herstellung von flüssigem roheisen oder stahlvorprodukten und anlage zur durchführung des verfahrens |
| AT406480B8 (de) * | 1995-07-19 | 2000-07-25 | Voest Alpine Ind Anlagen | Verfahren zur herstellung von flüssigem roheisen oder stahlvorprodukten und anlage zur durchführung des verfahrens |
| AT406483B (de) | 1995-07-19 | 2000-05-25 | Voest Alpine Ind Anlagen | Verfahren zur herstellung von flüssigem roheisen oder stahlvorprodukten und anlage zur durchführung des verfahrens |
| AT403381B (de) | 1996-06-10 | 1998-01-26 | Voest Alpine Ind Anlagen | Verfahren und anlage zum chargieren von metallträgern in eine einschmelzvergasungszone |
| AT403696B (de) * | 1996-06-20 | 1998-04-27 | Voest Alpine Ind Anlagen | Einschmelzvergaser und anlage für die herstellung einer metallschmelze |
| AT403930B (de) * | 1996-07-11 | 1998-06-25 | Voest Alpine Ind Anlagen | Verfahren zum chargieren von metallträgern in eine einschmelzvergasungszone und anlage zur durchführung des verfahrens |
| AT404022B (de) | 1996-11-08 | 1998-07-27 | Voest Alpine Ind Anlagen | Verfahren und anlage zur herstellung von flüssigem roheisen oder stahlvorprodukten aus eisenhältigemmaterial |
| AT404362B (de) | 1996-12-17 | 1998-11-25 | Voest Alpine Ind Anlagen | Verfahren und einschmelzvergaser zur herstellung von flüssigem metall |
| AT510586B1 (de) * | 2011-05-12 | 2012-05-15 | Siemens Vai Metals Tech Gmbh | Verfahren und vorrichtung zum ausschleusen von staubpartikeln aus einer staublinie |
| CN113913579B (zh) * | 2021-10-12 | 2023-01-24 | 中冶赛迪工程技术股份有限公司 | 用于冷却热态海绵铁的循环方法 |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1353716A (en) * | 1916-10-05 | 1920-09-21 | Charles S Bradley | Production of iron and steel |
| US2747988A (en) * | 1951-04-23 | 1956-05-29 | Kenneth R Marsden | Method for the recovery of pure iron oxide and iron from oxidic iron ores |
| BE642457A (pl) * | 1963-12-23 | |||
| US3199974A (en) * | 1964-05-25 | 1965-08-10 | Hydrocarbon Research Inc | Fluidized iron ore reduction process for production of iron powder |
| DE2401540B2 (de) * | 1974-01-14 | 1975-11-13 | Fried. Krupp Gmbh, 4300 Essen | Verfahren zum Einschmelzen von Eisenschwamm |
| DE2401909C3 (de) * | 1974-01-16 | 1985-06-27 | Fried. Krupp Gmbh, 4300 Essen | Verfahren zur Herstellung von Stahl |
| US4094665A (en) * | 1977-05-13 | 1978-06-13 | Stora Kopparbergs Bergslags Ab | Method for simultaneous combined production of electrical energy and crude iron |
| DE2905339A1 (de) * | 1979-02-13 | 1980-08-21 | Metallgesellschaft Ag | Verfahren zur erzeugung von stahl |
| US4248626A (en) * | 1979-07-16 | 1981-02-03 | Midrex Corporation | Method for producing molten iron from iron oxide with coal and oxygen |
| US4316739A (en) * | 1979-07-16 | 1982-02-23 | Midrex Corporation | Method for producing molten iron |
| US4304597A (en) * | 1980-03-20 | 1981-12-08 | The Direct Reduction Corporation | System for control of sinter formation in iron oxide reducing kilns |
| CA1125505A (en) * | 1980-05-09 | 1982-06-15 | William E. Creswick | Fabricated tuyere |
| US4436551A (en) * | 1981-10-26 | 1984-03-13 | Sumitomo Heavy Industries, Ltd. | Process for making steel from direct-reduced iron |
| US4412858A (en) * | 1982-07-12 | 1983-11-01 | Hylsa, S.A. | Method of converting iron ore into molten iron |
-
1983
- 1983-08-05 DE DE19833328373 patent/DE3328373A1/de not_active Withdrawn
- 1983-11-02 AU AU20896/83A patent/AU569481B2/en not_active Ceased
- 1983-11-11 AT AT83111296T patent/ATE19658T1/de not_active IP Right Cessation
- 1983-11-11 DE DE8383111296T patent/DE3363431D1/de not_active Expired
- 1983-11-11 EP EP83111296A patent/EP0111176B1/de not_active Expired
- 1983-11-14 CA CA000441044A patent/CA1215842A/en not_active Expired
- 1983-11-14 BR BR8306264A patent/BR8306264A/pt not_active IP Right Cessation
- 1983-11-14 ES ES527233A patent/ES527233A0/es active Granted
- 1983-11-14 US US06/551,174 patent/US4543123A/en not_active Expired - Lifetime
- 1983-11-14 SU SU833661051A patent/SU1313354A3/ru active
- 1983-11-14 DD DD83256671A patent/DD210310A5/de not_active IP Right Cessation
- 1983-11-15 PL PL1983244563A patent/PL142647B1/pl unknown
- 1983-11-15 PH PH29921A patent/PH20286A/en unknown
-
1984
- 1984-08-09 US US06/639,149 patent/US4542889A/en not_active Expired - Lifetime
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AT381117B (de) * | 1984-11-26 | 1986-08-25 | Voest Alpine Ag | Verfahren und anlage zur direktreduktion von eisenoxidteilchen und zum einschmelzen der erhaltenen eisenschwammpartikel in einem einschmelzvergaser |
| US4699655A (en) * | 1984-11-26 | 1987-10-13 | Voest-Alpine Akt. | Process and a plant for the direct reduction of iron oxide particles in a shaft furnace and for smelting the obtained iron sponge particles in a meltdown gasifier |
Also Published As
| Publication number | Publication date |
|---|---|
| US4543123A (en) | 1985-09-24 |
| ATE19658T1 (de) | 1986-05-15 |
| US4542889A (en) | 1985-09-24 |
| AU2089683A (en) | 1984-05-24 |
| PH20286A (en) | 1986-11-18 |
| DE3363431D1 (en) | 1986-06-12 |
| PL142647B1 (en) | 1987-11-30 |
| BR8306264A (pt) | 1984-06-19 |
| AU569481B2 (en) | 1988-02-04 |
| CA1215842A (en) | 1986-12-30 |
| PL244563A1 (en) | 1984-07-30 |
| ES8406554A1 (es) | 1984-08-01 |
| ES527233A0 (es) | 1984-08-01 |
| DE3328373A1 (de) | 1984-05-17 |
| EP0111176A1 (de) | 1984-06-20 |
| EP0111176B1 (de) | 1986-05-07 |
| SU1313354A3 (ru) | 1987-05-23 |
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