DD242413A1 - Verfahren zur herstellung von lithiumhaltigen polymerisationsinitiatoren - Google Patents

Verfahren zur herstellung von lithiumhaltigen polymerisationsinitiatoren Download PDF

Info

Publication number: DD242413A1
Authority: DD; German Democratic Republic
Prior art keywords: divinylbenzene; lithium; polymerization initiators; molar ratio; initiators
Prior art date: 1982-08-30

Application number

DD24286382A

Other languages

German (de)

English (en)

Inventor

Volker Griehl

Elisabeth Anton

Hans-Peter Schulz

Original Assignee

Buna Chem Werke Veb

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1982-08-30

Filing date

1982-08-30

Publication date

1987-01-28

1982-08-30 Application filed by Buna Chem Werke Veb filed Critical Buna Chem Werke Veb

1982-08-30 Priority to DD24286382A priority Critical patent/DD242413A1/de

1983-03-18 Priority to DE19833309748 priority patent/DE3309748A1/de

1983-04-07 Priority to FR8305709A priority patent/FR2530642B1/fr

1983-07-15 Priority to GB08319201A priority patent/GB2124228B/en

1983-08-24 Priority to CS615483A priority patent/CS237293B1/cs

1987-01-28 Publication of DD242413A1 publication Critical patent/DD242413A1/de

Links

239000003505 polymerization initiator Substances 0.000 title claims abstract description 8
238000004519 manufacturing process Methods 0.000 title 1
MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 claims abstract description 49
MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 claims abstract description 15
238000000034 method Methods 0.000 claims abstract description 12
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims abstract description 10
229910052744 lithium Inorganic materials 0.000 claims abstract description 10
229930195733 hydrocarbon Natural products 0.000 claims abstract description 9
150000002430 hydrocarbons Chemical class 0.000 claims abstract description 9
239000004215 Carbon black (E152) Substances 0.000 claims abstract description 8
239000002904 solvent Substances 0.000 claims abstract description 8
239000000203 mixture Substances 0.000 claims abstract description 7
238000002360 preparation method Methods 0.000 claims abstract description 6
CCZVEWRRAVASGL-UHFFFAOYSA-N lithium;2-methanidylpropane Chemical compound [Li+].CC(C)[CH2-] CCZVEWRRAVASGL-UHFFFAOYSA-N 0.000 claims abstract description 4
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 15
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 12
KVNYFPKFSJIPBJ-UHFFFAOYSA-N 1,2-diethylbenzene Chemical compound CCC1=CC=CC=C1CC KVNYFPKFSJIPBJ-UHFFFAOYSA-N 0.000 claims description 10
-1 alkyl monolithium compound Chemical class 0.000 claims description 10
ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims description 7
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 4
150000001412 amines Chemical class 0.000 claims description 3
JLTDJTHDQAWBAV-UHFFFAOYSA-N N,N-dimethylaniline Chemical compound CN(C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-N 0.000 claims description 2
230000015572 biosynthetic process Effects 0.000 abstract description 7
238000003786 synthesis reaction Methods 0.000 abstract description 7
238000006243 chemical reaction Methods 0.000 abstract description 3
150000001875 compounds Chemical class 0.000 abstract description 3
238000000926 separation method Methods 0.000 abstract description 3
229920006250 telechelic polymer Polymers 0.000 abstract description 3
WGOPGODQLGJZGL-UHFFFAOYSA-N lithium;butane Chemical compound [Li+].CC[CH-]C WGOPGODQLGJZGL-UHFFFAOYSA-N 0.000 abstract 1
239000003999 initiator Substances 0.000 description 15
239000000243 solution Substances 0.000 description 7
229910052783 alkali metal Inorganic materials 0.000 description 5
MPMBRWOOISTHJV-UHFFFAOYSA-N but-1-enylbenzene Chemical compound CCC=CC1=CC=CC=C1 MPMBRWOOISTHJV-UHFFFAOYSA-N 0.000 description 5
238000006263 metalation reaction Methods 0.000 description 4
238000010539 anionic addition polymerization reaction Methods 0.000 description 3
125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
239000011541 reaction mixture Substances 0.000 description 3
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
150000001340 alkali metals Chemical class 0.000 description 2
150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
238000004132 cross linking Methods 0.000 description 2
150000002736 metal compounds Chemical class 0.000 description 2
239000000178 monomer Substances 0.000 description 2
150000002900 organolithium compounds Chemical class 0.000 description 2
229920000642 polymer Polymers 0.000 description 2
239000000047 product Substances 0.000 description 2
PRJNEUBECVAVAG-UHFFFAOYSA-N 1,3-bis(ethenyl)benzene Chemical compound C=CC1=CC=CC(C=C)=C1 PRJNEUBECVAVAG-UHFFFAOYSA-N 0.000 description 1
WEERVPDNCOGWJF-UHFFFAOYSA-N 1,4-bis(ethenyl)benzene Chemical compound C=CC1=CC=C(C=C)C=C1 WEERVPDNCOGWJF-UHFFFAOYSA-N 0.000 description 1
MCSXGCZMEPXKIW-UHFFFAOYSA-N 3-hydroxy-4-[(4-methyl-2-nitrophenyl)diazenyl]-N-(3-nitrophenyl)naphthalene-2-carboxamide Chemical compound Cc1ccc(N=Nc2c(O)c(cc3ccccc23)C(=O)Nc2cccc(c2)[N+]([O-])=O)c(c1)[N+]([O-])=O MCSXGCZMEPXKIW-UHFFFAOYSA-N 0.000 description 1
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
239000003513 alkali Substances 0.000 description 1
230000029936 alkylation Effects 0.000 description 1
238000005804 alkylation reaction Methods 0.000 description 1
125000000129 anionic group Chemical group 0.000 description 1
239000008346 aqueous phase Substances 0.000 description 1
229910052786 argon Inorganic materials 0.000 description 1
150000001491 aromatic compounds Chemical class 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
229920001577 copolymer Polymers 0.000 description 1
150000001993 dienes Chemical class 0.000 description 1
238000010790 dilution Methods 0.000 description 1
239000012895 dilution Substances 0.000 description 1
229920001002 functional polymer Polymers 0.000 description 1
230000007062 hydrolysis Effects 0.000 description 1
238000006460 hydrolysis reaction Methods 0.000 description 1
229910052750 molybdenum Inorganic materials 0.000 description 1
239000011733 molybdenum Substances 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
230000035484 reaction time Effects 0.000 description 1
230000009257 reactivity Effects 0.000 description 1
238000003756 stirring Methods 0.000 description 1
150000003512 tertiary amines Chemical class 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1

Landscapes

Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Polymerization Catalysts (AREA)

DD24286382A 1982-07-23 1982-08-30 Verfahren zur herstellung von lithiumhaltigen polymerisationsinitiatoren DD242413A1 (de)

Priority Applications (5)

Application Number	Priority Date	Filing Date	Title
DD24286382A DD242413A1 (de)	1982-08-30	1982-08-30	Verfahren zur herstellung von lithiumhaltigen polymerisationsinitiatoren
DE19833309748 DE3309748A1 (de)	1982-07-23	1983-03-18	Verfahren zur herstellung mehrfunktioneller polymerisationsinitiatoren
FR8305709A FR2530642B1 (fr)	1982-07-23	1983-04-07	Procede pour la preparation d'initiateurs de polymerisation multifonctionnels
GB08319201A GB2124228B (en)	1982-07-23	1983-07-15	Organo-lithium polymerization initiator
CS615483A CS237293B1 (en)	1982-08-30	1983-08-24	Processing of poly-functional initiators of polymerization

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
DD24286382A DD242413A1 (de)	1982-08-30	1982-08-30	Verfahren zur herstellung von lithiumhaltigen polymerisationsinitiatoren

Publications (1)

Publication Number	Publication Date
DD242413A1 true DD242413A1 (de)	1987-01-28

Family

ID=5540908

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DD24286382A DD242413A1 (de)	1982-07-23	1982-08-30	Verfahren zur herstellung von lithiumhaltigen polymerisationsinitiatoren

Country Status (2)

Country	Link
CS (1)	CS237293B1 (cs)
DD (1)	DD242413A1 (cs)

1982
- 1982-08-30 DD DD24286382A patent/DD242413A1/de not_active IP Right Cessation
1983
- 1983-08-24 CS CS615483A patent/CS237293B1/cs unknown

Also Published As

Publication number	Publication date
CS237293B1 (en)	1985-07-16

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Date	Code	Title	Description
1998-07-02	ENJ	Ceased due to non-payment of renewal fee