DD283655A5 - Verfahren zur elektrolytischen gewinnung eines metalls durch elektrolyse einer schmelze unter verwendung einer sich nicht verbrauchenden anode - Google Patents
Verfahren zur elektrolytischen gewinnung eines metalls durch elektrolyse einer schmelze unter verwendung einer sich nicht verbrauchenden anode Download PDFInfo
- Publication number
- DD283655A5 DD283655A5 DD89326219A DD32621989A DD283655A5 DD 283655 A5 DD283655 A5 DD 283655A5 DD 89326219 A DD89326219 A DD 89326219A DD 32621989 A DD32621989 A DD 32621989A DD 283655 A5 DD283655 A5 DD 283655A5
- Authority
- DD
- German Democratic Republic
- Prior art keywords
- metal
- oxide
- anode
- alloy
- ceramic
- Prior art date
Links
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 54
- 239000002184 metal Substances 0.000 title claims abstract description 54
- 238000000034 method Methods 0.000 title claims abstract description 29
- 238000005868 electrolysis reaction Methods 0.000 title claims abstract description 16
- 239000000155 melt Substances 0.000 title claims abstract description 13
- 239000000956 alloy Substances 0.000 claims abstract description 61
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 60
- 239000000919 ceramic Substances 0.000 claims abstract description 52
- 238000000576 coating method Methods 0.000 claims abstract description 46
- 239000000758 substrate Substances 0.000 claims abstract description 45
- 239000011248 coating agent Substances 0.000 claims abstract description 42
- 230000004888 barrier function Effects 0.000 claims abstract description 32
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000001301 oxygen Substances 0.000 claims abstract description 26
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 26
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000005751 Copper oxide Substances 0.000 claims abstract description 21
- 229910000431 copper oxide Inorganic materials 0.000 claims abstract description 21
- 239000011224 oxide ceramic Substances 0.000 claims abstract description 21
- 229910052574 oxide ceramic Inorganic materials 0.000 claims abstract description 21
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000011651 chromium Substances 0.000 claims abstract description 17
- 229910000423 chromium oxide Inorganic materials 0.000 claims abstract description 17
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 11
- 238000005363 electrowinning Methods 0.000 claims abstract description 10
- 230000001681 protective effect Effects 0.000 claims abstract description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 52
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 27
- 239000011253 protective coating Substances 0.000 claims description 19
- 229910052759 nickel Inorganic materials 0.000 claims description 17
- 229910052782 aluminium Inorganic materials 0.000 claims description 15
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 15
- 229910052742 iron Inorganic materials 0.000 claims description 14
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 14
- 150000002739 metals Chemical class 0.000 claims description 11
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 10
- 229910017052 cobalt Inorganic materials 0.000 claims description 8
- 239000010941 cobalt Substances 0.000 claims description 8
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 8
- 239000006104 solid solution Substances 0.000 claims description 8
- 229910052697 platinum Inorganic materials 0.000 claims description 7
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 6
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 6
- 229910052748 manganese Inorganic materials 0.000 claims description 6
- 239000011572 manganese Substances 0.000 claims description 6
- NQNBVCBUOCNRFZ-UHFFFAOYSA-N nickel ferrite Chemical compound [Ni]=O.O=[Fe]O[Fe]=O NQNBVCBUOCNRFZ-UHFFFAOYSA-N 0.000 claims description 6
- 229910052758 niobium Inorganic materials 0.000 claims description 6
- 239000010955 niobium Substances 0.000 claims description 6
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 6
- 229910052715 tantalum Inorganic materials 0.000 claims description 6
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims description 6
- 229910052726 zirconium Inorganic materials 0.000 claims description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 5
- 239000003792 electrolyte Substances 0.000 claims description 5
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 5
- 229910052737 gold Inorganic materials 0.000 claims description 5
- 239000010931 gold Substances 0.000 claims description 5
- 229910052735 hafnium Inorganic materials 0.000 claims description 5
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims description 5
- 229910052763 palladium Inorganic materials 0.000 claims description 5
- 150000003839 salts Chemical class 0.000 claims description 5
- 229910052710 silicon Inorganic materials 0.000 claims description 5
- 239000010703 silicon Substances 0.000 claims description 5
- 229910052719 titanium Inorganic materials 0.000 claims description 5
- 239000010936 titanium Substances 0.000 claims description 5
- 229910052720 vanadium Inorganic materials 0.000 claims description 5
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 claims description 5
- 229910052727 yttrium Inorganic materials 0.000 claims description 5
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims description 5
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 4
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 4
- NPXOKRUENSOPAO-UHFFFAOYSA-N Raney nickel Chemical compound [Al].[Ni] NPXOKRUENSOPAO-UHFFFAOYSA-N 0.000 claims description 4
- 239000011737 fluorine Substances 0.000 claims description 4
- 229910052731 fluorine Inorganic materials 0.000 claims description 4
- 229910052750 molybdenum Inorganic materials 0.000 claims description 4
- 239000011733 molybdenum Substances 0.000 claims description 4
- 229910000510 noble metal Inorganic materials 0.000 claims description 4
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 4
- 229910052721 tungsten Inorganic materials 0.000 claims description 4
- 239000010937 tungsten Substances 0.000 claims description 4
- 229910000838 Al alloy Inorganic materials 0.000 claims description 3
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims description 3
- 230000008018 melting Effects 0.000 claims description 3
- 238000002844 melting Methods 0.000 claims description 3
- UQWLEJDCBWVKSN-UHFFFAOYSA-N platinum zirconium Chemical compound [Zr].[Pt] UQWLEJDCBWVKSN-UHFFFAOYSA-N 0.000 claims description 3
- 229910001404 rare earth metal oxide Inorganic materials 0.000 claims description 3
- 229910052566 spinel group Inorganic materials 0.000 claims description 3
- ROLJWXCAVGNMAK-UHFFFAOYSA-N [Ce]=O Chemical compound [Ce]=O ROLJWXCAVGNMAK-UHFFFAOYSA-N 0.000 claims description 2
- 150000001785 cerium compounds Chemical class 0.000 claims description 2
- 229910001093 Zr alloy Inorganic materials 0.000 claims 1
- 229910000420 cerium oxide Inorganic materials 0.000 claims 1
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 claims 1
- XVVDIUTUQBXOGG-UHFFFAOYSA-N [Ce].FOF Chemical compound [Ce].FOF XVVDIUTUQBXOGG-UHFFFAOYSA-N 0.000 abstract description 14
- 229910052684 Cerium Inorganic materials 0.000 abstract description 7
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 abstract description 7
- 238000004873 anchoring Methods 0.000 abstract description 2
- 238000000605 extraction Methods 0.000 abstract 1
- 239000010410 layer Substances 0.000 description 36
- 230000003647 oxidation Effects 0.000 description 27
- 238000007254 oxidation reaction Methods 0.000 description 27
- 239000010949 copper Substances 0.000 description 23
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 19
- 229910052802 copper Inorganic materials 0.000 description 19
- 238000005524 ceramic coating Methods 0.000 description 16
- 229910001026 inconel Inorganic materials 0.000 description 16
- 238000005253 cladding Methods 0.000 description 15
- 239000002131 composite material Substances 0.000 description 11
- 239000000203 mixture Substances 0.000 description 11
- 238000009792 diffusion process Methods 0.000 description 8
- 238000011065 in-situ storage Methods 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 7
- 229910000480 nickel oxide Inorganic materials 0.000 description 7
- 239000002344 surface layer Substances 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- 229910000881 Cu alloy Inorganic materials 0.000 description 5
- 229910000792 Monel Inorganic materials 0.000 description 5
- 238000000137 annealing Methods 0.000 description 5
- 239000012298 atmosphere Substances 0.000 description 5
- 229910001610 cryolite Inorganic materials 0.000 description 5
- 230000001590 oxidative effect Effects 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 4
- 238000004458 analytical method Methods 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 4
- 238000005260 corrosion Methods 0.000 description 4
- 238000010285 flame spraying Methods 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000007750 plasma spraying Methods 0.000 description 4
- -1 Aluminum Chemical class 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 229910000934 Monel 400 Inorganic materials 0.000 description 3
- 229910018054 Ni-Cu Inorganic materials 0.000 description 3
- 229910018481 Ni—Cu Inorganic materials 0.000 description 3
- 230000032683 aging Effects 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000000470 constituent Substances 0.000 description 3
- OANFWJQPUHQWDL-UHFFFAOYSA-N copper iron manganese nickel Chemical compound [Mn].[Fe].[Ni].[Cu] OANFWJQPUHQWDL-UHFFFAOYSA-N 0.000 description 3
- 238000000151 deposition Methods 0.000 description 3
- 238000005566 electron beam evaporation Methods 0.000 description 3
- 238000009713 electroplating Methods 0.000 description 3
- 239000010408 film Substances 0.000 description 3
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 3
- 229910044991 metal oxide Inorganic materials 0.000 description 3
- 150000004706 metal oxides Chemical class 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- 239000002243 precursor Substances 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- 229910002482 Cu–Ni Inorganic materials 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000011247 coating layer Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 229910001055 inconels 600 Inorganic materials 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 238000007747 plating Methods 0.000 description 2
- 239000010970 precious metal Substances 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 238000003466 welding Methods 0.000 description 2
- QYEXBYZXHDUPRC-UHFFFAOYSA-N B#[Ti]#B Chemical compound B#[Ti]#B QYEXBYZXHDUPRC-UHFFFAOYSA-N 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 229910001006 Constantan Inorganic materials 0.000 description 1
- 229910000599 Cr alloy Inorganic materials 0.000 description 1
- 229910017566 Cu-Mn Inorganic materials 0.000 description 1
- 229910017871 Cu—Mn Inorganic materials 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 1
- 229910001030 Iron–nickel alloy Inorganic materials 0.000 description 1
- 229910052777 Praseodymium Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 229910033181 TiB2 Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 230000001464 adherent effect Effects 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 239000012300 argon atmosphere Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- ABDBNWQRPYOPDF-UHFFFAOYSA-N carbonofluoridic acid Chemical compound OC(F)=O ABDBNWQRPYOPDF-UHFFFAOYSA-N 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 description 1
- CEQAPXDOWOUYNT-UHFFFAOYSA-M cerium(3+) oxygen(2-) fluoride Chemical compound [O--].[F-].[Ce+3] CEQAPXDOWOUYNT-UHFFFAOYSA-M 0.000 description 1
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000001427 coherent effect Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- YOCUPQPZWBBYIX-UHFFFAOYSA-N copper nickel Chemical compound [Ni].[Cu] YOCUPQPZWBBYIX-UHFFFAOYSA-N 0.000 description 1
- 229910000365 copper sulfate Inorganic materials 0.000 description 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 1
- 239000002019 doping agent Substances 0.000 description 1
- 238000004070 electrodeposition Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 229910000856 hastalloy Inorganic materials 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 229910001293 incoloy Inorganic materials 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 229910000765 intermetallic Inorganic materials 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 239000002905 metal composite material Substances 0.000 description 1
- KERTUBUCQCSNJU-UHFFFAOYSA-L nickel(2+);disulfamate Chemical group [Ni+2].NS([O-])(=O)=O.NS([O-])(=O)=O KERTUBUCQCSNJU-UHFFFAOYSA-L 0.000 description 1
- 229910001235 nimonic Inorganic materials 0.000 description 1
- 229910052575 non-oxide ceramic Inorganic materials 0.000 description 1
- 239000011225 non-oxide ceramic Substances 0.000 description 1
- 238000000399 optical microscopy Methods 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 150000002927 oxygen compounds Chemical class 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 229910000753 refractory alloy Inorganic materials 0.000 description 1
- 229910052702 rhenium Inorganic materials 0.000 description 1
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910000601 superalloy Inorganic materials 0.000 description 1
- 229910052716 thallium Inorganic materials 0.000 description 1
- BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910000859 α-Fe Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
- C25C7/06—Operating or servicing
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C26/00—Coating not provided for in groups C23C2/00 - C23C24/00
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
- C25C3/06—Electrolytic production, recovery or refining of metals by electrolysis of melts of aluminium
- C25C3/08—Cell construction, e.g. bottoms, walls, cathodes
- C25C3/12—Anodes
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
- C25C7/02—Electrodes; Connections thereof
- C25C7/025—Electrodes; Connections thereof used in cells for the electrolysis of melts
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrochemistry (AREA)
- Mechanical Engineering (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
- Electrolytic Production Of Metals (AREA)
- Chemically Coating (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP87810503 | 1987-09-02 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DD283655A5 true DD283655A5 (de) | 1990-10-17 |
Family
ID=8198416
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DD89326219A DD283655A5 (de) | 1987-09-02 | 1989-03-02 | Verfahren zur elektrolytischen gewinnung eines metalls durch elektrolyse einer schmelze unter verwendung einer sich nicht verbrauchenden anode |
Country Status (11)
| Country | Link |
|---|---|
| US (3) | US5069771A (fr) |
| EP (4) | EP0306100A1 (fr) |
| CN (1) | CN1042737A (fr) |
| AU (4) | AU2428988A (fr) |
| BR (2) | BR8807682A (fr) |
| CA (3) | CA1306148C (fr) |
| DD (1) | DD283655A5 (fr) |
| DE (2) | DE3879819T2 (fr) |
| ES (2) | ES2039594T3 (fr) |
| NO (1) | NO302904B1 (fr) |
| WO (4) | WO1989001994A1 (fr) |
Families Citing this family (71)
| Publication number | Priority date | Publication date | Assignee | Title |
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| EP0257709B1 (fr) * | 1986-08-21 | 1993-01-13 | MOLTECH Invent S.A. | Composé oxygéné de cérium, anode stable pour l'électrolyse de sels fondus et procédé de production |
| AU2428988A (en) * | 1987-09-02 | 1989-03-31 | Eltech Systems Corporation | Non-consumable anode for molten salt electrolysis |
| EP0422142B1 (fr) * | 1989-03-07 | 1995-05-24 | Moltech Invent S.A. | Substrat d'anode revetu d'oxycomposes de terres rares |
| US5131776A (en) * | 1990-07-13 | 1992-07-21 | Binney & Smith Inc. | Aqueous permanent coloring composition for a marker |
| CA2483324C (fr) * | 1991-06-11 | 2008-05-06 | Qualcomm Incorporated | Vocodeur a debit variable |
| US5279715A (en) * | 1991-09-17 | 1994-01-18 | Aluminum Company Of America | Process and apparatus for low temperature electrolysis of oxides |
| US5254232A (en) * | 1992-02-07 | 1993-10-19 | Massachusetts Institute Of Technology | Apparatus for the electrolytic production of metals |
| US5725744A (en) * | 1992-03-24 | 1998-03-10 | Moltech Invent S.A. | Cell for the electrolysis of alumina at low temperatures |
| US5284562A (en) * | 1992-04-17 | 1994-02-08 | Electrochemical Technology Corp. | Non-consumable anode and lining for aluminum electrolytic reduction cell |
| AU669407B2 (en) * | 1994-01-18 | 1996-06-06 | Brooks Rand, Ltd. | Non-consumable anode and lining for aluminum electrolytic reduction cell |
| US5510010A (en) * | 1994-03-01 | 1996-04-23 | Carrier Corporation | Copper article with protective coating |
| US5510008A (en) * | 1994-10-21 | 1996-04-23 | Sekhar; Jainagesh A. | Stable anodes for aluminium production cells |
| US5566011A (en) * | 1994-12-08 | 1996-10-15 | Luncent Technologies Inc. | Antiflector black matrix having successively a chromium oxide layer, a molybdenum layer and a second chromium oxide layer |
| JP3373076B2 (ja) * | 1995-02-17 | 2003-02-04 | トヨタ自動車株式会社 | 耐摩耗性Cu基合金 |
| US5904828A (en) * | 1995-09-27 | 1999-05-18 | Moltech Invent S.A. | Stable anodes for aluminium production cells |
| IT1291604B1 (it) * | 1997-04-18 | 1999-01-11 | De Nora Spa | Anodo per l'evoluzione di ossigeno in elettroliti contenenti fluoruri o loro derivati |
| US6416649B1 (en) | 1997-06-26 | 2002-07-09 | Alcoa Inc. | Electrolytic production of high purity aluminum using ceramic inert anodes |
| US6162334A (en) * | 1997-06-26 | 2000-12-19 | Alcoa Inc. | Inert anode containing base metal and noble metal useful for the electrolytic production of aluminum |
| US6217739B1 (en) | 1997-06-26 | 2001-04-17 | Alcoa Inc. | Electrolytic production of high purity aluminum using inert anodes |
| US6423195B1 (en) | 1997-06-26 | 2002-07-23 | Alcoa Inc. | Inert anode containing oxides of nickel, iron and zinc useful for the electrolytic production of metals |
| US6372119B1 (en) | 1997-06-26 | 2002-04-16 | Alcoa Inc. | Inert anode containing oxides of nickel iron and cobalt useful for the electrolytic production of metals |
| US6821312B2 (en) * | 1997-06-26 | 2004-11-23 | Alcoa Inc. | Cermet inert anode materials and method of making same |
| US6423204B1 (en) | 1997-06-26 | 2002-07-23 | Alcoa Inc. | For cermet inert anode containing oxide and metal phases useful for the electrolytic production of metals |
| CA2212471C (fr) * | 1997-08-06 | 2003-04-01 | Tony Addona | Methode de formation d'une anode de ceramique d'oxyde dans un reacteur a arc de plasma |
| CN1055140C (zh) * | 1997-11-19 | 2000-08-02 | 西北有色金属研究院 | 一种用于稀土熔盐电解的陶瓷阳极及其制备方法 |
| ES2230828T3 (es) * | 1998-01-20 | 2005-05-01 | Moltech Invent S.A. | Anodos de base metalica sin carbono para celdas de produccion de aluminio. |
| CA2317595A1 (fr) * | 1998-01-20 | 1999-07-22 | Moltech Invent S.A. | Anodes metalliques exemptes de carbone a revetement de surface pour des cellules electrolytiques de production d'aluminium |
| US6113758A (en) * | 1998-07-30 | 2000-09-05 | Moltech Invent S.A. | Porous non-carbon metal-based anodes for aluminium production cells |
| US6365018B1 (en) * | 1998-07-30 | 2002-04-02 | Moltech Invent S.A. | Surface coated non-carbon metal-based anodes for aluminium production cells |
| EP1049816A1 (fr) * | 1998-01-20 | 2000-11-08 | MOLTECH Invent S.A. | Anodes metalliques exemptes de carbone a activite electrocatalytique pour des cellules electrolytiques de production d'aluminium |
| US6103090A (en) * | 1998-07-30 | 2000-08-15 | Moltech Invent S.A. | Electrocatalytically active non-carbon metal-based anodes for aluminium production cells |
| DE69933854T2 (de) * | 1998-01-20 | 2007-05-31 | Moltech Invent S.A. | Aufschlämmung zum beschichten von kohlenstofffreien anoden auf metallbasis für zellen zur aluminiumherstellung |
| US6248227B1 (en) * | 1998-07-30 | 2001-06-19 | Moltech Invent S.A. | Slow consumable non-carbon metal-based anodes for aluminium production cells |
| EP1112394A1 (fr) * | 1998-07-30 | 2001-07-04 | MOLTECH Invent S.A. | Cellules d'extraction electrolytique de l'aluminium avec anodes a base de metal aux dimensions stables |
| DE69921491T2 (de) * | 1998-07-30 | 2005-10-27 | Moltech Invent S.A. | Mehrschichtige, kohlenstofffreie anoden auf basis von metallen für aluminium-elektrogewinnungszellen |
| US6372099B1 (en) * | 1998-07-30 | 2002-04-16 | Moltech Invent S.A. | Cells for the electrowinning of aluminium having dimensionally stable metal-based anodes |
| US6425992B1 (en) | 1998-07-30 | 2002-07-30 | Moltech Invent S.A. | Surface coated non-carbon metal-based anodes |
| US6083362A (en) * | 1998-08-06 | 2000-07-04 | University Of Chicago | Dimensionally stable anode for electrolysis, method for maintaining dimensions of anode during electrolysis |
| DE60018464T2 (de) * | 1999-12-09 | 2005-07-28 | Moltech Invent S.A. | Anoden auf basis von metallen für elektrolysezellen zur aluminiumgewinnung |
| US6419813B1 (en) | 2000-11-25 | 2002-07-16 | Northwest Aluminum Technologies | Cathode connector for aluminum low temperature smelting cell |
| US6419812B1 (en) | 2000-11-27 | 2002-07-16 | Northwest Aluminum Technologies | Aluminum low temperature smelting cell metal collection |
| NZ527308A (en) * | 2001-03-07 | 2005-03-24 | Moltech Invent S | Cell for the electrowinning of alumimium operating with metal-based anodes with a series of plates made of aluminium wettable reticulated porous material |
| AU2002247933B2 (en) * | 2001-04-12 | 2007-07-26 | Vittorio De Nora | Metal-based anodes for aluminum production cells |
| US6741061B2 (en) * | 2001-05-24 | 2004-05-25 | Comair Rotron, Inc. | Efficient stator |
| US6537438B2 (en) | 2001-08-27 | 2003-03-25 | Alcoa Inc. | Method for protecting electrodes during electrolysis cell start-up |
| US6692631B2 (en) | 2002-02-15 | 2004-02-17 | Northwest Aluminum | Carbon containing Cu-Ni-Fe anodes for electrolysis of alumina |
| US6558525B1 (en) | 2002-03-01 | 2003-05-06 | Northwest Aluminum Technologies | Anode for use in aluminum producing electrolytic cell |
| US6723222B2 (en) | 2002-04-22 | 2004-04-20 | Northwest Aluminum Company | Cu-Ni-Fe anodes having improved microstructure |
| US7077945B2 (en) * | 2002-03-01 | 2006-07-18 | Northwest Aluminum Technologies | Cu—Ni—Fe anode for use in aluminum producing electrolytic cell |
| US7255894B2 (en) * | 2002-04-16 | 2007-08-14 | Moltech Invent S.A. | Non-carbon anodes for aluminium electrowinning and other oxidation resistant components with slurry-applied coatings |
| AU2002348943A1 (en) * | 2002-09-11 | 2004-04-30 | Moltech Invent S.A. | Non-carbon anodes for aluminium electrowinning and other oxidation resistant components with iron oxide-containing coatings |
| US7033469B2 (en) * | 2002-11-08 | 2006-04-25 | Alcoa Inc. | Stable inert anodes including an oxide of nickel, iron and aluminum |
| US6758991B2 (en) | 2002-11-08 | 2004-07-06 | Alcoa Inc. | Stable inert anodes including a single-phase oxide of nickel and iron |
| US7811425B2 (en) * | 2004-03-18 | 2010-10-12 | Moltech Invent S.A. | Non-carbon anodes with active coatings |
| US7846308B2 (en) * | 2004-03-18 | 2010-12-07 | Riotinto Alcan International Limited | Non-carbon anodes |
| WO2007105125A2 (fr) * | 2006-03-10 | 2007-09-20 | Moltech Invent S.A. | Cellule d'extraction electrolytique d'aluminium avec croute renforcee |
| US20070278107A1 (en) * | 2006-05-30 | 2007-12-06 | Northwest Aluminum Technologies | Anode for use in aluminum producing electrolytic cell |
| US7718319B2 (en) | 2006-09-25 | 2010-05-18 | Board Of Regents, The University Of Texas System | Cation-substituted spinel oxide and oxyfluoride cathodes for lithium ion batteries |
| US20080172861A1 (en) * | 2007-01-23 | 2008-07-24 | Holmes Alan G | Methods for manufacturing motor core parts with magnetic orientation |
| WO2008132818A1 (fr) * | 2007-04-20 | 2008-11-06 | Mitsui Chemicals, Inc. | Électrolyseur, électrodes utilisées pour celui-ci et procédé d'électrolyse |
| US20090016948A1 (en) * | 2007-07-12 | 2009-01-15 | Young Edgar D | Carbon and fuel production from atmospheric CO2 and H2O by artificial photosynthesis and method of operation thereof |
| KR20110060926A (ko) * | 2008-09-08 | 2011-06-08 | 리오 틴토 알칸 인터내셔널 리미티드 | 알루미늄 환원 셀용의 고전류 밀도에서 작동하는 산소 발생 금속 애노드 |
| US7888283B2 (en) * | 2008-12-12 | 2011-02-15 | Lihong Huang | Iron promoted nickel based catalysts for hydrogen generation via auto-thermal reforming of ethanol |
| WO2011140209A2 (fr) | 2010-05-04 | 2011-11-10 | The George Washington University | Procédés de production de fer et d'acier |
| US8764962B2 (en) * | 2010-08-23 | 2014-07-01 | Massachusetts Institute Of Technology | Extraction of liquid elements by electrolysis of oxides |
| CN103014769A (zh) * | 2012-11-26 | 2013-04-03 | 中国铝业股份有限公司 | 一种铝电解用合金惰性阳极及其制备方法 |
| CN103540960B (zh) * | 2013-09-30 | 2016-08-17 | 赣南师范学院 | 一种稀土镁镍基储氢合金的制备方法 |
| CN104131315B (zh) * | 2014-08-20 | 2017-11-07 | 赣南师范大学 | 一种稀土镁镍基储氢合金电解共析合金化方法 |
| CN106435324A (zh) * | 2016-10-31 | 2017-02-22 | 张家港沙工科技服务有限公司 | 一种机械设备用低电阻复合管 |
| CN109811368B (zh) * | 2019-03-20 | 2021-03-16 | 武汉大学 | 用于熔盐电解体系的锂离子强化型惰性阳极及其制备方法 |
| EP3839084A1 (fr) * | 2019-12-20 | 2021-06-23 | David Jarvis | Alliage métallique |
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| US2548514A (en) * | 1945-08-23 | 1951-04-10 | Bramley Jenny | Process of producing secondaryelectron-emitting surfaces |
| US3804740A (en) * | 1972-02-01 | 1974-04-16 | Nora Int Co | Electrodes having a delafossite surface |
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| US4173518A (en) * | 1974-10-23 | 1979-11-06 | Sumitomo Aluminum Smelting Company, Limited | Electrodes for aluminum reduction cells |
| US4157943A (en) * | 1978-07-14 | 1979-06-12 | The International Nickel Company, Inc. | Composite electrode for electrolytic processes |
| FR2434213A1 (fr) * | 1978-08-24 | 1980-03-21 | Solvay | Procede pour la production electrolytique d'hydrogene en milieu alcalin |
| GB2069529A (en) * | 1980-01-17 | 1981-08-26 | Diamond Shamrock Corp | Cermet anode for electrowinning metals from fused salts |
| CA1181616A (fr) * | 1980-11-10 | 1985-01-29 | Aluminum Company Of America | Compositions pour electrodes inertes |
| US4374761A (en) * | 1980-11-10 | 1983-02-22 | Aluminum Company Of America | Inert electrode formulations |
| US4478693A (en) * | 1980-11-10 | 1984-10-23 | Aluminum Company Of America | Inert electrode compositions |
| US4374050A (en) * | 1980-11-10 | 1983-02-15 | Aluminum Company Of America | Inert electrode compositions |
| US4399008A (en) * | 1980-11-10 | 1983-08-16 | Aluminum Company Of America | Composition for inert electrodes |
| GB8301001D0 (en) * | 1983-01-14 | 1983-02-16 | Eltech Syst Ltd | Molten salt electrowinning method |
| US4484997A (en) * | 1983-06-06 | 1984-11-27 | Great Lakes Carbon Corporation | Corrosion-resistant ceramic electrode for electrolytic processes |
| US4620905A (en) * | 1985-04-25 | 1986-11-04 | Aluminum Company Of America | Electrolytic production of metals using a resistant anode |
| ATE70094T1 (de) * | 1986-08-21 | 1991-12-15 | Moltech Invent Sa | Metall-keramikverbundwerkstoff, formkoerper und verfahren zu dessen herstellung. |
| AU2428988A (en) * | 1987-09-02 | 1989-03-31 | Eltech Systems Corporation | Non-consumable anode for molten salt electrolysis |
-
1988
- 1988-08-30 AU AU24289/88A patent/AU2428988A/en not_active Abandoned
- 1988-08-30 WO PCT/EP1988/000788 patent/WO1989001994A1/fr not_active Ceased
- 1988-08-30 US US07/350,475 patent/US5069771A/en not_active Expired - Fee Related
- 1988-08-30 DE DE8888201854T patent/DE3879819T2/de not_active Expired - Fee Related
- 1988-08-30 WO PCT/EP1988/000787 patent/WO1989001993A1/fr not_active Ceased
- 1988-08-30 US US07/350,480 patent/US4960494A/en not_active Expired - Lifetime
- 1988-08-30 BR BR888807682A patent/BR8807682A/pt not_active Application Discontinuation
- 1988-08-30 BR BR888807683A patent/BR8807683A/pt not_active Application Discontinuation
- 1988-08-30 ES ES198888201854T patent/ES2039594T3/es not_active Expired - Lifetime
- 1988-08-30 EP EP88201852A patent/EP0306100A1/fr not_active Withdrawn
- 1988-08-30 AU AU23276/88A patent/AU614995B2/en not_active Ceased
- 1988-08-30 EP EP88201851A patent/EP0306099B1/fr not_active Expired - Lifetime
- 1988-08-30 EP EP88201854A patent/EP0306102B1/fr not_active Expired - Lifetime
- 1988-08-30 US US07/350,477 patent/US4956068A/en not_active Expired - Lifetime
- 1988-08-30 AU AU23200/88A patent/AU2320088A/en not_active Abandoned
- 1988-08-30 WO PCT/EP1988/000786 patent/WO1989001992A1/fr not_active Ceased
- 1988-08-30 WO PCT/EP1988/000785 patent/WO1989001991A1/fr not_active Ceased
- 1988-08-30 DE DE8888201851T patent/DE3875040T2/de not_active Expired - Fee Related
- 1988-08-30 AU AU24243/88A patent/AU615002B2/en not_active Ceased
- 1988-08-30 EP EP88201853A patent/EP0306101A1/fr not_active Withdrawn
- 1988-08-30 ES ES88201851T patent/ES2052688T3/es not_active Expired - Lifetime
- 1988-09-01 CA CA000576282A patent/CA1306148C/fr not_active Expired - Lifetime
- 1988-09-01 CA CA000576279A patent/CA1328243C/fr not_active Expired - Fee Related
- 1988-09-01 CA CA000576281A patent/CA1306147C/fr not_active Expired - Lifetime
- 1988-11-18 CN CN88107981A patent/CN1042737A/zh active Pending
-
1989
- 1989-03-02 DD DD89326219A patent/DD283655A5/de not_active IP Right Cessation
-
1990
- 1990-03-01 NO NO900995A patent/NO302904B1/no unknown
Also Published As
| Publication number | Publication date |
|---|---|
| US4956068A (en) | 1990-09-11 |
| NO302904B1 (no) | 1998-05-04 |
| CA1306148C (fr) | 1992-08-11 |
| US5069771A (en) | 1991-12-03 |
| AU2428988A (en) | 1989-03-31 |
| AU2424388A (en) | 1989-03-31 |
| ES2052688T3 (es) | 1994-07-16 |
| CA1306147C (fr) | 1992-08-11 |
| WO1989001994A1 (fr) | 1989-03-09 |
| EP0306102B1 (fr) | 1993-03-31 |
| CA1328243C (fr) | 1994-04-05 |
| EP0306100A1 (fr) | 1989-03-08 |
| AU2320088A (en) | 1989-03-31 |
| AU614995B2 (en) | 1991-09-19 |
| WO1989001992A1 (fr) | 1989-03-09 |
| NO900995D0 (no) | 1990-03-01 |
| EP0306099A1 (fr) | 1989-03-08 |
| WO1989001993A1 (fr) | 1989-03-09 |
| DE3879819D1 (de) | 1993-05-06 |
| AU2327688A (en) | 1989-03-31 |
| NO900995L (no) | 1990-03-01 |
| BR8807683A (pt) | 1990-06-26 |
| EP0306099B1 (fr) | 1992-09-30 |
| EP0306102A1 (fr) | 1989-03-08 |
| WO1989001991A1 (fr) | 1989-03-09 |
| BR8807682A (pt) | 1990-06-26 |
| EP0306101A1 (fr) | 1989-03-08 |
| US4960494A (en) | 1990-10-02 |
| AU615002B2 (en) | 1991-09-19 |
| DE3879819T2 (de) | 1993-07-08 |
| DE3875040D1 (de) | 1992-11-05 |
| DE3875040T2 (de) | 1993-02-25 |
| CN1042737A (zh) | 1990-06-06 |
| ES2039594T3 (es) | 1993-10-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| NAB | Public notice for inspection of provisional exclusive patent accord. to par 17/1 dd-patg. | ||
| ENJ | Ceased due to non-payment of renewal fee |