DD292468A5 - Verfahren zur polymerisation von epoxidverbindungen - Google Patents
Verfahren zur polymerisation von epoxidverbindungen Download PDFInfo
- Publication number
- DD292468A5 DD292468A5 DD90338526A DD33852690A DD292468A5 DD 292468 A5 DD292468 A5 DD 292468A5 DD 90338526 A DD90338526 A DD 90338526A DD 33852690 A DD33852690 A DD 33852690A DD 292468 A5 DD292468 A5 DD 292468A5
- Authority
- DD
- German Democratic Republic
- Prior art keywords
- polymerization
- compound
- lewis base
- acidic
- epoxide
- Prior art date
Links
- 150000001875 compounds Chemical class 0.000 title claims abstract description 15
- 238000000034 method Methods 0.000 title claims abstract description 13
- 239000004593 Epoxy Substances 0.000 title abstract description 11
- 230000000379 polymerizing effect Effects 0.000 title 1
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 25
- 239000002879 Lewis base Substances 0.000 claims abstract description 22
- -1 epoxide compounds Chemical class 0.000 claims abstract description 22
- 150000007527 lewis bases Chemical class 0.000 claims abstract description 22
- 238000006243 chemical reaction Methods 0.000 claims abstract description 10
- 230000008569 process Effects 0.000 claims abstract description 4
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 claims description 14
- 239000003446 ligand Substances 0.000 claims description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 8
- YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 4
- 239000013522 chelant Substances 0.000 claims description 4
- 229910052739 hydrogen Chemical group 0.000 claims description 4
- 239000001257 hydrogen Chemical group 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- 229910021645 metal ion Inorganic materials 0.000 claims description 4
- 229910052757 nitrogen Inorganic materials 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 239000001301 oxygen Substances 0.000 claims description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 3
- 125000004437 phosphorous atom Chemical group 0.000 claims description 3
- 229910052717 sulfur Inorganic materials 0.000 claims description 3
- 239000011593 sulfur Substances 0.000 claims description 3
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 claims description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 2
- 150000004696 coordination complex Chemical group 0.000 claims description 2
- 125000003700 epoxy group Chemical group 0.000 claims description 2
- 150000002576 ketones Chemical class 0.000 claims description 2
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 claims description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 2
- 150000003568 thioethers Chemical class 0.000 claims 1
- 230000000977 initiatory effect Effects 0.000 abstract description 3
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 abstract 2
- APRRQJCCBSJQOQ-UHFFFAOYSA-N 4-amino-5-hydroxynaphthalene-2,7-disulfonic acid Chemical compound OS(=O)(=O)C1=CC(O)=C2C(N)=CC(S(O)(=O)=O)=CC2=C1 APRRQJCCBSJQOQ-UHFFFAOYSA-N 0.000 abstract 1
- 229940106691 bisphenol a Drugs 0.000 abstract 1
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 abstract 1
- 239000000203 mixture Substances 0.000 description 13
- 239000000654 additive Substances 0.000 description 8
- 239000000853 adhesive Substances 0.000 description 7
- 230000001070 adhesive effect Effects 0.000 description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
- 150000002460 imidazoles Chemical class 0.000 description 6
- 239000003822 epoxy resin Substances 0.000 description 5
- 229920000647 polyepoxide Polymers 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 229910017052 cobalt Inorganic materials 0.000 description 4
- 239000010941 cobalt Substances 0.000 description 4
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 4
- ZYUVGYBAPZYKSA-UHFFFAOYSA-N 5-(3-hydroxybutan-2-yl)-4-methylbenzene-1,3-diol Chemical compound CC(O)C(C)C1=CC(O)=CC(O)=C1C ZYUVGYBAPZYKSA-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- NHADDZMCASKINP-HTRCEHHLSA-N decarboxydihydrocitrinin Natural products C1=C(O)C(C)=C2[C@H](C)[C@@H](C)OCC2=C1O NHADDZMCASKINP-HTRCEHHLSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 230000007246 mechanism Effects 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 150000002924 oxiranes Chemical class 0.000 description 3
- 239000004848 polyfunctional curative Substances 0.000 description 3
- 150000003573 thiols Chemical class 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 230000001133 acceleration Effects 0.000 description 2
- 125000005595 acetylacetonate group Chemical group 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 235000015895 biscuits Nutrition 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- 239000012948 isocyanate Substances 0.000 description 2
- 150000002513 isocyanates Chemical class 0.000 description 2
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 2
- 229920002959 polymer blend Polymers 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 231100000331 toxic Toxicity 0.000 description 2
- 230000002588 toxic effect Effects 0.000 description 2
- 241000557248 Argia lugens Species 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 240000002024 Gossypium herbaceum Species 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- CUJRVFIICFDLGR-UHFFFAOYSA-N acetylacetonate Chemical compound CC(=O)[CH-]C(C)=O CUJRVFIICFDLGR-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001244 carboxylic acid anhydrides Chemical class 0.000 description 1
- 150000004697 chelate complex Chemical class 0.000 description 1
- MJSNUBOCVAKFIJ-LNTINUHCSA-N chromium;(z)-4-oxoniumylidenepent-2-en-2-olate Chemical compound [Cr].C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O MJSNUBOCVAKFIJ-LNTINUHCSA-N 0.000 description 1
- 238000003776 cleavage reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 239000013256 coordination polymer Substances 0.000 description 1
- 229920001795 coordination polymer Polymers 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000004870 electrical engineering Methods 0.000 description 1
- 238000000921 elemental analysis Methods 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 210000003608 fece Anatomy 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000004849 latent hardener Substances 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- OVARTBFNCCXQKS-UHFFFAOYSA-N propan-2-one;hydrate Chemical compound O.CC(C)=O OVARTBFNCCXQKS-UHFFFAOYSA-N 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000003385 ring cleavage reaction Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
- 238000002411 thermogravimetry Methods 0.000 description 1
Landscapes
- Epoxy Resins (AREA)
Priority Applications (18)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DD90338526A DD292468A5 (de) | 1990-03-09 | 1990-03-09 | Verfahren zur polymerisation von epoxidverbindungen |
| JP50518291A JP3215106B2 (ja) | 1990-03-09 | 1991-03-06 | エポキシド化合物の重合方法 |
| PCT/EP1991/000419 WO1991013925A1 (de) | 1990-03-09 | 1991-03-06 | Verfahren zur polymerisation von epoxidverbindungen |
| ES91905067T ES2036162T3 (es) | 1990-03-09 | 1991-03-06 | Procedimiento para la polimerizacion de compuestos epoxidicos. |
| AT91905067T ATE119174T1 (de) | 1990-03-09 | 1991-03-06 | Verfahren zur polymerisation von epoxidverbindungen. |
| EP91905067A EP0518908B1 (de) | 1990-03-09 | 1991-03-06 | Verfahren zur polymerisation von epoxidverbindungen |
| DE59104812T DE59104812D1 (de) | 1990-03-09 | 1991-03-06 | Verfahren zur polymerisation von epoxidverbindungen. |
| KR1019910701562A KR970001539B1 (ko) | 1990-03-09 | 1991-03-06 | 에폭시드 화합물의 중합 방법 |
| BR919104778A BR9104778A (pt) | 1990-03-09 | 1991-03-06 | Processo para a polimerizacao de compostos de epoxido |
| SU915010651A RU2086572C1 (ru) | 1990-03-09 | 1991-03-06 | Способ полимеризации эпоксисоединений, смесь эпоксисоединений, клеющая и уплотняющая масса, связующее |
| FI915291A FI915291A7 (fi) | 1990-03-09 | 1991-03-06 | Menetelmä epoksidiyhdisteiden polymeroimiseksi |
| CA002054212A CA2054212C (en) | 1990-03-09 | 1991-03-06 | Method for polymerization of epoxide compounds |
| NO91914377A NO914377L (no) | 1990-03-09 | 1991-11-08 | Fremgangsmaate for polymerisering av epoksidforbindelser |
| LVP-92-135A LV10116B (en) | 1990-03-09 | 1992-09-29 | Method of polimerisation of epoxy compounds |
| LTIP217A LT3106B (en) | 1990-03-09 | 1992-10-02 | Process for the polymerisation of epoxycompounds |
| GR920300130T GR920300130T1 (en) | 1990-03-09 | 1993-03-16 | Method for polymerization of epoxide compounds. |
| US08/204,782 US5395913A (en) | 1990-03-09 | 1994-03-02 | Polymerizable epoxide mixtures and process using Lewis base complexes |
| US08/313,721 US5525698A (en) | 1990-03-09 | 1994-09-27 | Polymerizable epoxide mixtures and process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DD90338526A DD292468A5 (de) | 1990-03-09 | 1990-03-09 | Verfahren zur polymerisation von epoxidverbindungen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DD292468A5 true DD292468A5 (de) | 1991-08-01 |
Family
ID=5616937
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DD90338526A DD292468A5 (de) | 1990-03-09 | 1990-03-09 | Verfahren zur polymerisation von epoxidverbindungen |
Country Status (2)
| Country | Link |
|---|---|
| DD (1) | DD292468A5 (lt) |
| LT (1) | LT3106B (lt) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4231680A1 (de) * | 1992-09-22 | 1994-03-24 | Ruetgerswerke Ag | Verfahren zur Herstellung von Metallkomplexen mit hoher Koordinationszahl und deren Verwendung |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US355166A (en) | 1886-12-28 | Separator for steam-generators | ||
| CH269230A (it) | 1948-08-13 | 1950-06-30 | Benaglio Osvaldo | Quadrante per orologi da polso e da tasca. |
| US3310602A (en) | 1962-07-26 | 1967-03-21 | Borden Co | Curing epoxide resins with aromatic amine-aldehyde coordination complexes |
| US3367913A (en) | 1966-09-09 | 1968-02-06 | Interchem Corp | Thermosetting epoxy resin composition containing a zinc chelate |
| US3553166A (en) | 1968-02-02 | 1971-01-05 | Ppg Industries Inc | Mixtures of imidazole complexes and nitrogenous compound as curing agents for epoxy resins |
| US3624032A (en) | 1969-04-24 | 1971-11-30 | Morton Int Inc | Epoxy compositions cured with carboxylic acid anhydrides and metallic salt of acetylacetone |
| US3638007A (en) | 1969-08-05 | 1972-01-25 | Herbert B Brooks | Digital control simulator |
| US3635894A (en) | 1969-11-06 | 1972-01-18 | Ppg Industries Inc | Curable epoxy resin compositions containing organoimidazolium salt |
| US3642698A (en) | 1970-05-15 | 1972-02-15 | Air Prod & Chem | Epoxy resin curing with imidazole alkyl acid phosphate salt catalyst |
| US3632427A (en) | 1970-05-15 | 1972-01-04 | Air Prod & Chem | Epoxy resin and imidazole alkyl acid phosphate fiber treatment |
| US4105667A (en) | 1970-07-17 | 1978-08-08 | Minnesota Mining And Manufacturing Company | Imidazole type curing agents |
| US3746686A (en) | 1971-07-12 | 1973-07-17 | Shell Oil Co | Process for curing polyepoxides with polycarboxylic acid salts of an imidazole compound and compositions thereof |
| US3677978A (en) | 1971-08-23 | 1972-07-18 | Ppg Industries Inc | Metal salt complexes of imidazoles as curing agents for one-part epoxy resins |
| US3792016A (en) | 1972-01-06 | 1974-02-12 | Minnesota Mining & Mfg | Metal imidazolate-catalyzed systems |
| GB1435540A (en) | 1972-07-06 | 1976-05-12 | Mccall Corp | Curable solventless composition |
| US3956241A (en) | 1974-06-07 | 1976-05-11 | Aerojet-General Corporation | Latent catalysts for epoxy resins |
| US4137275A (en) | 1976-04-27 | 1979-01-30 | Westinghouse Electric Corp. | Latent accelerators for curing epoxy resins |
| US4159976A (en) | 1977-03-10 | 1979-07-03 | Loctite Corporation | Curable systems containing epoxy resin and methanol or ethanol solvent to suppress the catalytic reaction between epoxy resin and an imidazole catalytic curing agent |
| JPS53116391A (en) | 1977-03-18 | 1978-10-11 | Shikoku Kasei Kougiyou Kk | Novel imidazoleisocyanuric adduct synthesizing method thereof polyepoxy hardening method containing same as main component polyepoxy hardening method using same as hardening improver and method of pur |
| GB8304581D0 (en) | 1983-02-18 | 1983-03-23 | Secr Defence | Curing agents for epoxy resins |
| US4473674A (en) | 1983-11-03 | 1984-09-25 | The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration | Process for improving mechanical properties of epoxy resins by addition of cobalt ions |
-
1990
- 1990-03-09 DD DD90338526A patent/DD292468A5/de not_active IP Right Cessation
-
1992
- 1992-10-02 LT LTIP217A patent/LT3106B/lt not_active IP Right Cessation
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4231680A1 (de) * | 1992-09-22 | 1994-03-24 | Ruetgerswerke Ag | Verfahren zur Herstellung von Metallkomplexen mit hoher Koordinationszahl und deren Verwendung |
Also Published As
| Publication number | Publication date |
|---|---|
| LTIP217A (en) | 1994-06-15 |
| LT3106B (en) | 1994-12-27 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| RPI | Change in the person, name or address of the patentee (searches according to art. 11 and 12 extension act) | ||
| RPI | Change in the person, name or address of the patentee (searches according to art. 11 and 12 extension act) | ||
| RPI | Change in the person, name or address of the patentee (searches according to art. 11 and 12 extension act) | ||
| ENJ | Ceased due to non-payment of renewal fee |