DD295828A5 - Tieftemperaturkatalysatoren fuer oxydative kopplungsverfahren - Google Patents

Tieftemperaturkatalysatoren fuer oxydative kopplungsverfahren Download PDF

Info

Publication number: DD295828A5
Authority: DD; German Democratic Republic
Prior art keywords: catalyst; halogen; compound; oxidative coupling; metal
Prior art date: 1989-09-19

Application number

DD90344087A

Other languages

German (de)

English (en)

Inventor

Kenneth D Campbell

Original Assignee

Union Carbide Chemicals And Plastics Co. Inc.,Us

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1989-09-19

Filing date

1990-09-18

Publication date

1991-11-14

1990-09-18 Application filed by Union Carbide Chemicals And Plastics Co. Inc.,Us filed Critical Union Carbide Chemicals And Plastics Co. Inc.,Us

1991-11-14 Publication of DD295828A5 publication Critical patent/DD295828A5/de

Links

238000010168 coupling process Methods 0.000 title description 7
239000003054 catalyst Substances 0.000 claims abstract description 140
238000000034 method Methods 0.000 claims abstract description 75
229910052751 metal Inorganic materials 0.000 claims abstract description 52
239000002184 metal Substances 0.000 claims abstract description 52
229910052736 halogen Inorganic materials 0.000 claims abstract description 45
150000002367 halogens Chemical class 0.000 claims abstract description 45
238000005691 oxidative coupling reaction Methods 0.000 claims abstract description 41
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 37
150000001335 aliphatic alkanes Chemical class 0.000 claims abstract description 31
230000008569 process Effects 0.000 claims abstract description 31
229930195733 hydrocarbon Natural products 0.000 claims abstract description 26
150000002430 hydrocarbons Chemical class 0.000 claims abstract description 26
229910052759 nickel Inorganic materials 0.000 claims abstract description 21
229910017052 cobalt Inorganic materials 0.000 claims abstract description 19
239000010941 cobalt Substances 0.000 claims abstract description 19
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 19
239000004215 Carbon black (E152) Substances 0.000 claims abstract description 13
150000001875 compounds Chemical class 0.000 claims abstract description 8
150000003284 rhodium compounds Chemical class 0.000 claims abstract description 5
238000006243 chemical reaction Methods 0.000 claims description 73
239000007789 gas Substances 0.000 claims description 54
239000000463 material Substances 0.000 claims description 28
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 17
229910052760 oxygen Inorganic materials 0.000 claims description 17
239000001301 oxygen Substances 0.000 claims description 17
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 16
239000000460 chlorine Substances 0.000 claims description 11
150000004820 halides Chemical class 0.000 claims description 11
229910052801 chlorine Inorganic materials 0.000 claims description 10
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 7
239000000654 additive Substances 0.000 claims description 7
230000000996 additive effect Effects 0.000 claims description 7
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 7
229910052794 bromium Inorganic materials 0.000 claims description 7
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 6
229910052783 alkali metal Inorganic materials 0.000 claims description 6
150000001340 alkali metals Chemical class 0.000 claims description 6
125000004432 carbon atom Chemical group C* 0.000 claims description 6
125000004430 oxygen atom Chemical group O* 0.000 claims description 6
ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 5
239000011630 iodine Substances 0.000 claims description 5
229910052740 iodine Inorganic materials 0.000 claims description 5
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 4
239000012433 hydrogen halide Substances 0.000 claims description 4
229910000039 hydrogen halide Inorganic materials 0.000 claims description 4
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 4
CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims description 3
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 3
229910052788 barium Inorganic materials 0.000 claims description 3
DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 3
125000001309 chloro group Chemical group Cl* 0.000 claims description 3
XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 claims description 3
150000001341 alkaline earth metal compounds Chemical class 0.000 claims description 2
230000001808 coupling effect Effects 0.000 claims description 2
150000003438 strontium compounds Chemical class 0.000 claims 3
150000001869 cobalt compounds Chemical class 0.000 claims 2
150000001553 barium compounds Chemical class 0.000 claims 1
239000002585 base Substances 0.000 claims 1
150000002736 metal compounds Chemical class 0.000 claims 1
150000002816 nickel compounds Chemical class 0.000 claims 1
150000002978 peroxides Chemical class 0.000 claims 1
230000002787 reinforcement Effects 0.000 claims 1
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 81
230000000694 effects Effects 0.000 description 24
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 18
239000005977 Ethylene Substances 0.000 description 18
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 18
239000000376 reactant Substances 0.000 description 16
229910052784 alkaline earth metal Inorganic materials 0.000 description 14
238000007254 oxidation reaction Methods 0.000 description 14
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 13
239000010949 copper Substances 0.000 description 12
KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 12
-1 methane Chemical class 0.000 description 12
230000003647 oxidation Effects 0.000 description 12
HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 description 11
229910052802 copper Inorganic materials 0.000 description 11
229960003750 ethyl chloride Drugs 0.000 description 11
OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 10
150000001342 alkaline earth metals Chemical class 0.000 description 10
229910052742 iron Inorganic materials 0.000 description 10
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 9
239000010453 quartz Substances 0.000 description 9
235000002639 sodium chloride Nutrition 0.000 description 9
239000003513 alkali Substances 0.000 description 8
238000001035 drying Methods 0.000 description 8
239000011572 manganese Substances 0.000 description 8
CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 7
239000007788 liquid Substances 0.000 description 7
VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 7
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 6
101100496858 Mus musculus Colec12 gene Proteins 0.000 description 6
230000015572 biosynthetic process Effects 0.000 description 6
230000008878 coupling Effects 0.000 description 6
238000005859 coupling reaction Methods 0.000 description 6
239000011133 lead Substances 0.000 description 6
229910052748 manganese Inorganic materials 0.000 description 6
NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 6
239000000047 product Substances 0.000 description 6
229910052703 rhodium Inorganic materials 0.000 description 6
239000010948 rhodium Substances 0.000 description 6
MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 6
150000003839 salts Chemical class 0.000 description 6
229910052725 zinc Inorganic materials 0.000 description 6
239000011701 zinc Substances 0.000 description 6
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 5
229910052799 carbon Inorganic materials 0.000 description 5
230000001965 increasing effect Effects 0.000 description 5
230000001590 oxidative effect Effects 0.000 description 5
230000008929 regeneration Effects 0.000 description 5
238000011069 regeneration method Methods 0.000 description 5
239000007787 solid Substances 0.000 description 5
239000000243 solution Substances 0.000 description 5
238000003786 synthesis reaction Methods 0.000 description 5
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
229910018072 Al 2 O 3 Inorganic materials 0.000 description 4
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
229950005499 carbon tetrachloride Drugs 0.000 description 4
238000006555 catalytic reaction Methods 0.000 description 4
229910052804 chromium Inorganic materials 0.000 description 4
239000011651 chromium Substances 0.000 description 4
239000008367 deionised water Substances 0.000 description 4
229910021641 deionized water Inorganic materials 0.000 description 4
230000008021 deposition Effects 0.000 description 4
238000005470 impregnation Methods 0.000 description 4
229910052745 lead Inorganic materials 0.000 description 4
239000000395 magnesium oxide Substances 0.000 description 4
150000002739 metals Chemical class 0.000 description 4
230000036961 partial effect Effects 0.000 description 4
229910052697 platinum Inorganic materials 0.000 description 4
239000000126 substance Substances 0.000 description 4
229910052723 transition metal Inorganic materials 0.000 description 4
150000003624 transition metals Chemical class 0.000 description 4
229910013553 LiNO Inorganic materials 0.000 description 3
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
230000002411 adverse Effects 0.000 description 3
229910052797 bismuth Inorganic materials 0.000 description 3
238000009835 boiling Methods 0.000 description 3
230000003197 catalytic effect Effects 0.000 description 3
150000001805 chlorine compounds Chemical class 0.000 description 3
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
238000004519 manufacturing process Methods 0.000 description 3
229910044991 metal oxide Inorganic materials 0.000 description 3
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
150000002823 nitrates Chemical class 0.000 description 3
229910052757 nitrogen Inorganic materials 0.000 description 3
229910000510 noble metal Inorganic materials 0.000 description 3
229910052709 silver Inorganic materials 0.000 description 3
FVAUCKIRQBBSSJ-UHFFFAOYSA-M sodium iodide Chemical compound [Na+].[I-] FVAUCKIRQBBSSJ-UHFFFAOYSA-M 0.000 description 3
229910052719 titanium Inorganic materials 0.000 description 3
239000010936 titanium Substances 0.000 description 3
229910052726 zirconium Inorganic materials 0.000 description 3
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
230000009471 action Effects 0.000 description 2
AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Chemical compound [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 description 2
QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 2
229910052792 caesium Inorganic materials 0.000 description 2
150000004649 carbonic acid derivatives Chemical class 0.000 description 2
239000012084 conversion product Substances 0.000 description 2
229910001882 dioxygen Inorganic materials 0.000 description 2
238000010494 dissociation reaction Methods 0.000 description 2
230000005593 dissociations Effects 0.000 description 2
239000011491 glass wool Substances 0.000 description 2
150000004679 hydroxides Chemical class 0.000 description 2
239000012535 impurity Substances 0.000 description 2
239000004615 ingredient Substances 0.000 description 2
229910052746 lanthanum Inorganic materials 0.000 description 2
FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 2
229910052744 lithium Inorganic materials 0.000 description 2
AMXOYNBUYSYVKV-UHFFFAOYSA-M lithium bromide Chemical compound [Li+].[Br-] AMXOYNBUYSYVKV-UHFFFAOYSA-M 0.000 description 2
230000008018 melting Effects 0.000 description 2
238000002844 melting Methods 0.000 description 2
150000004706 metal oxides Chemical class 0.000 description 2
229910052763 palladium Inorganic materials 0.000 description 2
239000002245 particle Substances 0.000 description 2
IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 2
239000001294 propane Substances 0.000 description 2
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
230000009257 reactivity Effects 0.000 description 2
FGDZQCVHDSGLHJ-UHFFFAOYSA-M rubidium chloride Chemical compound [Cl-].[Rb+] FGDZQCVHDSGLHJ-UHFFFAOYSA-M 0.000 description 2
239000000377 silicon dioxide Substances 0.000 description 2
239000004332 silver Substances 0.000 description 2
JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 description 2
239000011780 sodium chloride Substances 0.000 description 2
IATRAKWUXMZMIY-UHFFFAOYSA-N strontium oxide Chemical compound [O-2].[Sr+2] IATRAKWUXMZMIY-UHFFFAOYSA-N 0.000 description 2
239000000725 suspension Substances 0.000 description 2
229910000314 transition metal oxide Inorganic materials 0.000 description 2
229910052720 vanadium Inorganic materials 0.000 description 2
235000014692 zinc oxide Nutrition 0.000 description 2
WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 description 1
238000004438 BET method Methods 0.000 description 1
ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
229910052684 Cerium Inorganic materials 0.000 description 1
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
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ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
229910002651 NO3 Inorganic materials 0.000 description 1
NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
229910052777 Praseodymium Inorganic materials 0.000 description 1
239000012494 Quartz wool Substances 0.000 description 1
229910004298 SiO 2 Inorganic materials 0.000 description 1
229910052776 Thorium Inorganic materials 0.000 description 1
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
229910052770 Uranium Inorganic materials 0.000 description 1
229910000287 alkaline earth metal oxide Inorganic materials 0.000 description 1
150000001336 alkenes Chemical class 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
229910052787 antimony Inorganic materials 0.000 description 1
WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
229910052786 argon Inorganic materials 0.000 description 1
150000001491 aromatic compounds Chemical class 0.000 description 1
125000004429 atom Chemical group 0.000 description 1
NKQIMNKPSDEDMO-UHFFFAOYSA-L barium bromide Chemical compound [Br-].[Br-].[Ba+2] NKQIMNKPSDEDMO-UHFFFAOYSA-L 0.000 description 1
229910001620 barium bromide Inorganic materials 0.000 description 1
WDIHJSXYQDMJHN-UHFFFAOYSA-L barium chloride Chemical compound [Cl-].[Cl-].[Ba+2] WDIHJSXYQDMJHN-UHFFFAOYSA-L 0.000 description 1
229910001626 barium chloride Inorganic materials 0.000 description 1
SGUXGJPBTNFBAD-UHFFFAOYSA-L barium iodide Chemical compound [I-].[I-].[Ba+2] SGUXGJPBTNFBAD-UHFFFAOYSA-L 0.000 description 1
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239000011324 bead Substances 0.000 description 1
230000008901 benefit Effects 0.000 description 1
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ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 description 1
JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
229910052796 boron Inorganic materials 0.000 description 1
229910052793 cadmium Inorganic materials 0.000 description 1
BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
239000001110 calcium chloride Substances 0.000 description 1
229910001628 calcium chloride Inorganic materials 0.000 description 1
BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
239000000292 calcium oxide Substances 0.000 description 1
ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
239000001569 carbon dioxide Substances 0.000 description 1
229910002092 carbon dioxide Inorganic materials 0.000 description 1
239000000969 carrier Substances 0.000 description 1
238000007036 catalytic synthesis reaction Methods 0.000 description 1
ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
230000008859 change Effects 0.000 description 1
NEHMKBQYUWJMIP-NJFSPNSNSA-N chloro(114C)methane Chemical compound [14CH3]Cl NEHMKBQYUWJMIP-NJFSPNSNSA-N 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
INPLXZPZQSLHBR-UHFFFAOYSA-N cobalt(2+);sulfide Chemical compound [S-2].[Co+2] INPLXZPZQSLHBR-UHFFFAOYSA-N 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
238000009833 condensation Methods 0.000 description 1
230000005494 condensation Effects 0.000 description 1
239000000470 constituent Substances 0.000 description 1
238000010276 construction Methods 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
230000007423 decrease Effects 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
238000006731 degradation reaction Methods 0.000 description 1
238000001514 detection method Methods 0.000 description 1
239000003085 diluting agent Substances 0.000 description 1
238000010790 dilution Methods 0.000 description 1
239000012895 dilution Substances 0.000 description 1
238000006471 dimerization reaction Methods 0.000 description 1
239000002019 doping agent Substances 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
239000002360 explosive Substances 0.000 description 1
238000011049 filling Methods 0.000 description 1
229910052733 gallium Inorganic materials 0.000 description 1
238000004817 gas chromatography Methods 0.000 description 1
229910052732 germanium Inorganic materials 0.000 description 1
GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
125000005843 halogen group Chemical group 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
239000001307 helium Substances 0.000 description 1
229910052734 helium Inorganic materials 0.000 description 1
SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
BICAGYDGRXJYGD-UHFFFAOYSA-N hydrobromide;hydrochloride Chemical class Cl.Br BICAGYDGRXJYGD-UHFFFAOYSA-N 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
BDAGIHXWWSANSR-NJFSPNSNSA-N hydroxyformaldehyde Chemical compound O[14CH]=O BDAGIHXWWSANSR-NJFSPNSNSA-N 0.000 description 1
238000007654 immersion Methods 0.000 description 1
230000001771 impaired effect Effects 0.000 description 1
229910052738 indium Inorganic materials 0.000 description 1
APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
230000006698 induction Effects 0.000 description 1
230000001939 inductive effect Effects 0.000 description 1
239000011261 inert gas Substances 0.000 description 1
230000002401 inhibitory effect Effects 0.000 description 1
239000000543 intermediate Substances 0.000 description 1
150000004694 iodide salts Chemical class 0.000 description 1
PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
229910052741 iridium Inorganic materials 0.000 description 1
GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
229910000311 lanthanide oxide Inorganic materials 0.000 description 1
AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
150000001247 metal acetylides Chemical class 0.000 description 1
229910000000 metal hydroxide Inorganic materials 0.000 description 1
KHHRVQOSAIVZEK-UHFFFAOYSA-N methane;oxonickel Chemical compound C.[Ni]=O KHHRVQOSAIVZEK-UHFFFAOYSA-N 0.000 description 1
239000000203 mixture Substances 0.000 description 1
239000002808 molecular sieve Substances 0.000 description 1
MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 description 1
229910052750 molybdenum Inorganic materials 0.000 description 1
239000011733 molybdenum Substances 0.000 description 1
239000012452 mother liquor Substances 0.000 description 1
229910052762 osmium Inorganic materials 0.000 description 1
SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 1
239000007800 oxidant agent Substances 0.000 description 1
238000005839 oxidative dehydrogenation reaction Methods 0.000 description 1
RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
239000008188 pellet Substances 0.000 description 1
230000000737 periodic effect Effects 0.000 description 1
229910052698 phosphorus Inorganic materials 0.000 description 1
239000011574 phosphorus Substances 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
239000011591 potassium Substances 0.000 description 1
239000001103 potassium chloride Substances 0.000 description 1
235000011164 potassium chloride Nutrition 0.000 description 1
PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 description 1
229910001404 rare earth metal oxide Inorganic materials 0.000 description 1
230000002829 reductive effect Effects 0.000 description 1
229910052702 rhenium Inorganic materials 0.000 description 1
WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
229940102127 rubidium chloride Drugs 0.000 description 1
238000005070 sampling Methods 0.000 description 1
229910052706 scandium Inorganic materials 0.000 description 1
SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 description 1
239000002002 slurry Substances 0.000 description 1
239000011734 sodium Substances 0.000 description 1
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
235000009518 sodium iodide Nutrition 0.000 description 1
239000002904 solvent Substances 0.000 description 1
229910052566 spinel group Inorganic materials 0.000 description 1
229910052712 strontium Inorganic materials 0.000 description 1
CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
229910000018 strontium carbonate Inorganic materials 0.000 description 1
229910001631 strontium chloride Inorganic materials 0.000 description 1
AHBGXTDRMVNFER-UHFFFAOYSA-L strontium dichloride Chemical compound [Cl-].[Cl-].[Sr+2] AHBGXTDRMVNFER-UHFFFAOYSA-L 0.000 description 1
238000000859 sublimation Methods 0.000 description 1
230000008022 sublimation Effects 0.000 description 1
229910052717 sulfur Inorganic materials 0.000 description 1
150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
YBBRCQOCSYXUOC-UHFFFAOYSA-N sulfuryl dichloride Chemical compound ClS(Cl)(=O)=O YBBRCQOCSYXUOC-UHFFFAOYSA-N 0.000 description 1
229910052716 thallium Inorganic materials 0.000 description 1
BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 description 1
229910052718 tin Inorganic materials 0.000 description 1
239000011135 tin Substances 0.000 description 1
OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
230000009466 transformation Effects 0.000 description 1
238000000844 transformation Methods 0.000 description 1
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
229910052721 tungsten Inorganic materials 0.000 description 1
239000010937 tungsten Substances 0.000 description 1
DNYWZCXLKNTFFI-UHFFFAOYSA-N uranium Chemical compound [U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U] DNYWZCXLKNTFFI-UHFFFAOYSA-N 0.000 description 1
GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
229920002554 vinyl polymer Polymers 0.000 description 1
229910052727 yttrium Inorganic materials 0.000 description 1
VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
239000011787 zinc oxide Substances 0.000 description 1
RNWHGQJWIACOKP-UHFFFAOYSA-N zinc;oxygen(2-) Chemical class [O-2].[Zn+2] RNWHGQJWIACOKP-UHFFFAOYSA-N 0.000 description 1
229910001928 zirconium oxide Inorganic materials 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/76—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
- C07C2/82—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen oxidative coupling
- C07C2/84—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen oxidative coupling catalytic
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
- C07C2521/04—Alumina
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Catalysts (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

DD90344087A 1989-09-19 1990-09-18 Tieftemperaturkatalysatoren fuer oxydative kopplungsverfahren DD295828A5 (de)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US40937589A	1989-09-19	1989-09-19

Publications (1)

Publication Number	Publication Date
DD295828A5 true DD295828A5 (de)	1991-11-14

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ID=23620212

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DD90344087A DD295828A5 (de)	1989-09-19	1990-09-18	Tieftemperaturkatalysatoren fuer oxydative kopplungsverfahren

Country Status (9)

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EP (1)	EP0418975A1 (ja)
JP (1)	JPH04501871A (ja)
CN (1)	CN1050864A (ja)
AU (1)	AU6259890A (ja)
CA (1)	CA2025595A1 (ja)
DD (1)	DD295828A5 (ja)
NO (1)	NO904073L (ja)
WO (1)	WO1991004237A1 (ja)
ZA (1)	ZA907443B (ja)

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CN1046098C (zh) *	1993-06-18	1999-11-03	中国科学院大连化学物理研究所	水蒸汽稀释下甲烷氧化偶联催化剂
US7838708B2 (en)	2001-06-20	2010-11-23	Grt, Inc.	Hydrocarbon conversion process improvements
MXPA06000470A (es)	2003-07-15	2006-08-23	Grt Inc	Sintesis de hidrocarburos.
US20050171393A1 (en)	2003-07-15	2005-08-04	Lorkovic Ivan M.	Hydrocarbon synthesis
US7244867B2 (en)	2004-04-16	2007-07-17	Marathon Oil Company	Process for converting gaseous alkanes to liquid hydrocarbons
US20080275284A1 (en)	2004-04-16	2008-11-06	Marathon Oil Company	Process for converting gaseous alkanes to liquid hydrocarbons
US8173851B2 (en)	2004-04-16	2012-05-08	Marathon Gtf Technology, Ltd.	Processes for converting gaseous alkanes to liquid hydrocarbons
US20060100469A1 (en)	2004-04-16	2006-05-11	Waycuilis John J	Process for converting gaseous alkanes to olefins and liquid hydrocarbons
US8642822B2 (en)	2004-04-16	2014-02-04	Marathon Gtf Technology, Ltd.	Processes for converting gaseous alkanes to liquid hydrocarbons using microchannel reactor
US7674941B2 (en)	2004-04-16	2010-03-09	Marathon Gtf Technology, Ltd.	Processes for converting gaseous alkanes to liquid hydrocarbons
EP1993951B1 (en)	2006-02-03	2014-07-30	GRT, Inc.	Separation of light gases from bromine
CN101817720A (zh)	2006-02-03	2010-09-01	Grt公司	天然气转化为液体烃的连续方法
AU2008256606A1 (en)	2007-05-24	2008-12-04	Grt, Inc.	Zone reactor incorporating reversible hydrogen halide capture and release
US8282810B2 (en)	2008-06-13	2012-10-09	Marathon Gtf Technology, Ltd.	Bromine-based method and system for converting gaseous alkanes to liquid hydrocarbons using electrolysis for bromine recovery
NZ591207A (en)	2008-07-18	2013-03-28	Grt Inc	Continuous process for converting natural gas to liquid hydrocarbons
US8198495B2 (en)	2010-03-02	2012-06-12	Marathon Gtf Technology, Ltd.	Processes and systems for the staged synthesis of alkyl bromides
US8367884B2 (en)	2010-03-02	2013-02-05	Marathon Gtf Technology, Ltd.	Processes and systems for the staged synthesis of alkyl bromides
US8815050B2 (en)	2011-03-22	2014-08-26	Marathon Gtf Technology, Ltd.	Processes and systems for drying liquid bromine
US8436220B2 (en)	2011-06-10	2013-05-07	Marathon Gtf Technology, Ltd.	Processes and systems for demethanization of brominated hydrocarbons
US8829256B2 (en)	2011-06-30	2014-09-09	Gtc Technology Us, Llc	Processes and systems for fractionation of brominated hydrocarbons in the conversion of natural gas to liquid hydrocarbons
US8802908B2 (en)	2011-10-21	2014-08-12	Marathon Gtf Technology, Ltd.	Processes and systems for separate, parallel methane and higher alkanes' bromination
US9193641B2 (en)	2011-12-16	2015-11-24	Gtc Technology Us, Llc	Processes and systems for conversion of alkyl bromides to higher molecular weight hydrocarbons in circulating catalyst reactor-regenerator systems
CN104014348B (zh) *	2014-06-06	2016-06-01	安徽师范大学	一种镍/贵金属/α相氢氧化镍纳米复合材料、制备方法及其应用
EP4360753A4 (en) *	2021-06-25	2025-06-18	Niterra Co., Ltd.	Dehydrogenation reaction catalyst, composite catalyst and supported catalyst

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US4465893A (en) *	1982-08-25	1984-08-14	Olah George A	Oxidative condensation of natural gas or methane into gasoline range hydrocarbons
US4654459A (en) *	1984-12-18	1987-03-31	Atlantic Richfield Company	Alkali promoted manganese oxide compositions containing barium carbonate
DE3503664A1 (de) *	1985-02-04	1986-08-07	Akzo Gmbh, 5600 Wuppertal	Verfahren zur herstellung von ethylen-ethan-gemischen
DE3534530A1 (de) *	1985-09-27	1987-04-09	Manfred Prof Dr Baerns	Kontinuierliches verfahren zur oxidativen kopplung von methan zu c(pfeil abwaerts)2(pfeil abwaerts)(pfeil abwaerts)+(pfeil abwaerts)-kohlenwasserstoffen in gegenwart von katalysatoren

1990
- 1990-09-18 CA CA002025595A patent/CA2025595A1/en not_active Abandoned
- 1990-09-18 DD DD90344087A patent/DD295828A5/de not_active IP Right Cessation
- 1990-09-18 CN CN90108680A patent/CN1050864A/zh active Pending
- 1990-09-18 NO NO90904073A patent/NO904073L/no unknown
- 1990-09-18 EP EP90202474A patent/EP0418975A1/en not_active Withdrawn
- 1990-09-18 AU AU62598/90A patent/AU6259890A/en not_active Abandoned
- 1990-09-18 ZA ZA907443A patent/ZA907443B/xx unknown
- 1990-09-19 JP JP2513763A patent/JPH04501871A/ja active Pending
- 1990-09-19 WO PCT/US1990/005216 patent/WO1991004237A1/en not_active Ceased

Also Published As

Publication number	Publication date
AU6259890A (en)	1991-03-28
WO1991004237A1 (en)	1991-04-04
NO904073D0 (no)	1990-09-18
CA2025595A1 (en)	1991-03-20
EP0418975A1 (en)	1991-03-27
ZA907443B (en)	1991-07-31
NO904073L (no)	1991-03-20
JPH04501871A (ja)	1992-04-02
CN1050864A (zh)	1991-04-24

Legal Events

Date	Code	Title	Description
1995-06-08	ENJ	Ceased due to non-payment of renewal fee

Publication	Publication Date	Title
DD295829A5 (de)	1991-11-14	Silberhaltige katalysatoren fuer oxydative kupplungsverfahren
DD300536A5 (de)	1992-06-17	Doppelperovskitkatalysatoren für oxydative Kupplung
DE3787591T2 (de)	1994-01-27	Mit Bor promotierte reduzierfähige Metalloxide und Verfahren zu deren Verwendung.
DD300538A5 (de)	1992-06-17	Oxydatives Kupplungsverfahren mit einem höheren Verhältnis von Ethen zu Ethan
DD300537A5 (de)	1992-06-17	Dampfphasenmodifizierungsmittel zur oxydativen kupplung
DE69923878T2 (de)	2006-02-23	Katalysator enthaltend i) Cr oder Mo, ii) W und iii) Sb zur oxidativen Dehydrierung von niederen Alkanen und Verfahren zur Herstellung von Olefinen
DE60306973T2 (de)	2007-01-25	Verfahren zur katalytischen Dehydrierung von Kohlenwasserstoffen unter Verwendung von Kohlendioxid als weiches Oxidationsmittel
US6635793B2 (en)	2003-10-21	Preparation of epoxides from alkanes using lanthanide-promoted silver catalysts
DE1468141B1 (de)	1970-12-03	Verfahren zur Chlorierung von Olefinen,die 2 bis 5 Kohlenstoffatome aufweisen,oder von Benzol
CA2025595A1 (en)	1991-03-20	Low temperature catalysts for oxidative coupling processes
DE112017005604T5 (de)	2019-09-12	Sr-Ce-Yb-O-KATALYSATOREN FÜR DIE OXIDATIVE KOPPLUNG VON METHAN
US20190283007A1 (en)	2019-09-19	Catalysts for soft oxidation coupling of methane to ethylene and ethane
DE2118344A1 (de)	1971-11-25	Verfahren zur Herstellung von Metallferriten und deren Verwendung zum oxydativen Dehydrieren von organischen Verbindungen
DE69921020T2 (de)	2006-03-02	Mangan-enthaltender Katalysator zur oxidativen Dehydrierung von niederen Alkanen und Verfahren zur herstellung von Olefinen
DE2803318A1 (de)	1979-08-09	Verfahren zur herstellung von glyoxal
DE2540067A1 (de)	1976-04-08	Verfahren zur herstellung von vinylchlorid
DE2164806B2 (de)	1973-08-16	Verwendung von oxydkatalysatoren zur herstellung von 1,5-dimethylnaphthalin und/oder 1,6-dimethylnaphthalin
US4861936A (en)	1989-08-29	Boron-promoted reducible metal oxides and methods of their use
DE68902807T2 (de)	1993-01-14	Chemisches verfahren und katalysator zu seiner durchfuehrung.
US6392066B1 (en)	2002-05-21	Epoxidation of olefins using lanthanide-promoted silver catalysts
DE2633785A1 (de)	1977-02-17	Verfahren zur herstellung von alkylenglykolestern
DE1237554B (de)	1967-03-30	Verfahren zur Herstellung von gegebenenfalls methylsubstituiertem Allylchlorid
DD300540A5 (de)	1992-06-17	Strontium und/oder Barium enthaltende Katalysatoren für oxydative Kupplungsverfahren
DE2159764A1 (de)	1973-06-07	Verfahren zur herstellung von hochkonzentrierten hydroperoxiden
DE1952777C3 (de)	1978-11-09	Verfahren zum Kuppeln eines Alkans mit einem Alkan, Alken, aromatischem Kohlenwasserstoff, einer Alkancarbonsäure oder Gemischen hiervon