DD296692A5 - Wasserloesliche, niedermolekulare copolymere, verfahren zur herstellung und waschmittelzusammensetzungen enthaltend solche copolymere - Google Patents

Wasserloesliche, niedermolekulare copolymere, verfahren zur herstellung und waschmittelzusammensetzungen enthaltend solche copolymere Download PDF

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Publication number: DD296692A5
Authority: DD; German Democratic Republic
Prior art keywords: acid; monoethylenically unsaturated; monomer; water; copolymer
Prior art date: 1990-02-06

Application number

DD90343179A

Other languages

German (de)

English (en)

Inventor

Kathleen A Hughes

Graham Swift

Original Assignee

��@��@��@��k��

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1990-02-06

Filing date

1990-07-31

Publication date

1991-12-12

Family has litigation

First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=23888219&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=DD296692(A5) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.

1990-07-31 Application filed by ��@��@��@��k�� filed Critical ��@��@��@��k��

1991-12-12 Publication of DD296692A5 publication Critical patent/DD296692A5/de

Links

229920001577 copolymer Polymers 0.000 title claims abstract description 59
238000000034 method Methods 0.000 title claims abstract description 51
239000003599 detergent Substances 0.000 title claims abstract description 21
239000000203 mixture Substances 0.000 title claims abstract description 21
238000002360 preparation method Methods 0.000 title claims abstract description 10
239000000178 monomer Substances 0.000 claims abstract description 93
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 28
238000006243 chemical reaction Methods 0.000 claims abstract description 24
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims abstract description 23
150000001991 dicarboxylic acids Chemical class 0.000 claims abstract description 22
OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims abstract description 19
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims abstract description 19
239000011976 maleic acid Substances 0.000 claims abstract description 16
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims abstract description 15
150000002763 monocarboxylic acids Chemical class 0.000 claims abstract description 11
125000005907 alkyl ester group Chemical group 0.000 claims abstract description 4
238000006116 polymerization reaction Methods 0.000 claims description 31
239000003999 initiator Substances 0.000 claims description 27
150000003839 salts Chemical class 0.000 claims description 22
239000007787 solid Substances 0.000 claims description 21
239000010949 copper Substances 0.000 claims description 16
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 14
229910052802 copper Inorganic materials 0.000 claims description 14
150000001879 copper Chemical class 0.000 claims description 13
-1 phosphoethyl Chemical group 0.000 claims description 10
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
150000008064 anhydrides Chemical class 0.000 claims description 7
125000004432 carbon atom Chemical group C* 0.000 claims description 7
VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 6
239000002585 base Substances 0.000 claims description 5
LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 claims description 5
150000002762 monocarboxylic acid derivatives Chemical class 0.000 claims description 5
JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 claims description 4
SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 claims description 4
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 4
ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 claims description 4
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 4
BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 4
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 4
XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 claims description 4
125000005395 methacrylic acid group Chemical class 0.000 claims description 4
239000003505 polymerization initiator Substances 0.000 claims description 4
LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 claims description 3
229910052783 alkali metal Inorganic materials 0.000 claims description 3
150000001875 compounds Chemical class 0.000 claims description 3
239000001530 fumaric acid Substances 0.000 claims description 3
229920005646 polycarboxylate Polymers 0.000 claims description 3
CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 claims description 3
229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 claims description 2
CIOXZGOUEYHNBF-UHFFFAOYSA-N (carboxymethoxy)succinic acid Chemical class OC(=O)COC(C(O)=O)CC(O)=O CIOXZGOUEYHNBF-UHFFFAOYSA-N 0.000 claims description 2
OSSNTDFYBPYIEC-UHFFFAOYSA-N 1-ethenylimidazole Chemical compound C=CN1C=CN=C1 OSSNTDFYBPYIEC-UHFFFAOYSA-N 0.000 claims description 2
DPBJAVGHACCNRL-UHFFFAOYSA-N 2-(dimethylamino)ethyl prop-2-enoate Chemical compound CN(C)CCOC(=O)C=C DPBJAVGHACCNRL-UHFFFAOYSA-N 0.000 claims description 2
OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 claims description 2
RUMACXVDVNRZJZ-UHFFFAOYSA-N 2-methylpropyl 2-methylprop-2-enoate Chemical compound CC(C)COC(=O)C(C)=C RUMACXVDVNRZJZ-UHFFFAOYSA-N 0.000 claims description 2
CUTWSDAQYCQTGD-UHFFFAOYSA-N 2-prop-2-enoyloxypropanoic acid Chemical compound OC(=O)C(C)OC(=O)C=C CUTWSDAQYCQTGD-UHFFFAOYSA-N 0.000 claims description 2
QZPSOSOOLFHYRR-UHFFFAOYSA-N 3-hydroxypropyl prop-2-enoate Chemical compound OCCCOC(=O)C=C QZPSOSOOLFHYRR-UHFFFAOYSA-N 0.000 claims description 2
HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 2
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 2
239000004641 Diallyl-phthalate Substances 0.000 claims description 2
JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims description 2
WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 claims description 2
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 2
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 2
GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 claims description 2
229920002125 Sokalan® Polymers 0.000 claims description 2
229920002472 Starch Polymers 0.000 claims description 2
DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 claims description 2
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 2
125000000129 anionic group Chemical group 0.000 claims description 2
QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 claims description 2
PVEOYINWKBTPIZ-UHFFFAOYSA-N but-3-enoic acid Chemical compound OC(=O)CC=C PVEOYINWKBTPIZ-UHFFFAOYSA-N 0.000 claims description 2
CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 2
239000001913 cellulose Substances 0.000 claims description 2
229920002678 cellulose Polymers 0.000 claims description 2
HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical compound OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 claims description 2
229940018557 citraconic acid Drugs 0.000 claims description 2
150000001860 citric acid derivatives Chemical class 0.000 claims description 2
LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 claims description 2
SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 claims description 2
125000002768 hydroxyalkyl group Chemical group 0.000 claims description 2
HNEGQIOMVPPMNR-NSCUHMNNSA-N mesaconic acid Chemical compound OC(=O)C(/C)=C/C(O)=O HNEGQIOMVPPMNR-NSCUHMNNSA-N 0.000 claims description 2
FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 claims description 2
HNEGQIOMVPPMNR-UHFFFAOYSA-N methylfumaric acid Natural products OC(=O)C(C)=CC(O)=O HNEGQIOMVPPMNR-UHFFFAOYSA-N 0.000 claims description 2
229940088644 n,n-dimethylacrylamide Drugs 0.000 claims description 2
YLGYACDQVQQZSW-UHFFFAOYSA-N n,n-dimethylprop-2-enamide Chemical compound CN(C)C(=O)C=C YLGYACDQVQQZSW-UHFFFAOYSA-N 0.000 claims description 2
ZQXSMRAEXCEDJD-UHFFFAOYSA-N n-ethenylformamide Chemical compound C=CNC=O ZQXSMRAEXCEDJD-UHFFFAOYSA-N 0.000 claims description 2
YPHQUSNPXDGUHL-UHFFFAOYSA-N n-methylprop-2-enamide Chemical compound CNC(=O)C=C YPHQUSNPXDGUHL-UHFFFAOYSA-N 0.000 claims description 2
PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims description 2
229910052700 potassium Inorganic materials 0.000 claims description 2
239000011591 potassium Substances 0.000 claims description 2
USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims description 2
229910052708 sodium Inorganic materials 0.000 claims description 2
239000011734 sodium Substances 0.000 claims description 2
FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical class [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 claims description 2
235000019832 sodium triphosphate Nutrition 0.000 claims description 2
239000008107 starch Substances 0.000 claims description 2
235000019698 starch Nutrition 0.000 claims description 2
CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 claims description 2
RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical class [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 claims description 2
LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 claims description 2
229920002554 vinyl polymer Polymers 0.000 claims description 2
NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 claims description 2
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims 3
ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims 2
IRLPACMLTUPBCL-KQYNXXCUSA-N 5'-adenylyl sulfate Chemical compound C1=NC=2C(N)=NC=NC=2N1[C@@H]1O[C@H](COP(O)(=O)OS(O)(=O)=O)[C@@H](O)[C@H]1O IRLPACMLTUPBCL-KQYNXXCUSA-N 0.000 claims 1
QEVGZEDELICMKH-UHFFFAOYSA-N Diglycolic acid Chemical class OC(=O)COCC(O)=O QEVGZEDELICMKH-UHFFFAOYSA-N 0.000 claims 1
229910001870 ammonium persulfate Inorganic materials 0.000 claims 1
239000004584 polyacrylic acid Substances 0.000 claims 1
229920000515 polycarbonate Polymers 0.000 claims 1
239000004417 polycarbonate Substances 0.000 claims 1
239000002270 dispersing agent Substances 0.000 abstract description 6
239000002455 scale inhibitor Substances 0.000 abstract description 6
125000001931 aliphatic group Chemical group 0.000 abstract description 4
239000003112 inhibitor Substances 0.000 abstract description 4
JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 abstract description 3
238000007334 copolymerization reaction Methods 0.000 abstract description 3
229910001431 copper ion Inorganic materials 0.000 abstract description 3
238000004519 manufacturing process Methods 0.000 abstract description 2
238000004140 cleaning Methods 0.000 abstract 1
238000007720 emulsion polymerization reaction Methods 0.000 abstract 1
239000004575 stone Substances 0.000 abstract 1
239000000243 solution Substances 0.000 description 48
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 27
229920000642 polymer Polymers 0.000 description 17
229910052751 metal Inorganic materials 0.000 description 15
239000002184 metal Substances 0.000 description 15
238000005227 gel permeation chromatography Methods 0.000 description 12
229910021645 metal ion Inorganic materials 0.000 description 10
238000007792 addition Methods 0.000 description 7
XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
239000007864 aqueous solution Substances 0.000 description 5
230000015572 biosynthetic process Effects 0.000 description 5
230000000052 comparative effect Effects 0.000 description 5
239000008367 deionised water Substances 0.000 description 5
229910021641 deionized water Inorganic materials 0.000 description 5
238000003786 synthesis reaction Methods 0.000 description 5
238000010923 batch production Methods 0.000 description 4
ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 4
FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 4
238000010992 reflux Methods 0.000 description 4
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
239000003795 chemical substances by application Substances 0.000 description 3
JZCCFEFSEZPSOG-UHFFFAOYSA-L copper(II) sulfate pentahydrate Chemical compound O.O.O.O.O.[Cu+2].[O-]S([O-])(=O)=O JZCCFEFSEZPSOG-UHFFFAOYSA-L 0.000 description 3
230000003472 neutralizing effect Effects 0.000 description 3
PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 3
239000000126 substance Substances 0.000 description 3
150000003573 thiols Chemical class 0.000 description 3
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
239000002253 acid Substances 0.000 description 2
239000000654 additive Substances 0.000 description 2
238000010924 continuous production Methods 0.000 description 2
229910000365 copper sulfate Inorganic materials 0.000 description 2
229910000366 copper(II) sulfate Inorganic materials 0.000 description 2
238000005260 corrosion Methods 0.000 description 2
230000007797 corrosion Effects 0.000 description 2
239000003205 fragrance Substances 0.000 description 2
239000007788 liquid Substances 0.000 description 2
150000002739 metals Chemical class 0.000 description 2
239000000843 powder Substances 0.000 description 2
239000012266 salt solution Substances 0.000 description 2
XHZPRMZZQOIPDS-UHFFFAOYSA-N 2-Methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid Chemical compound OS(=O)(=O)CC(C)(C)NC(=O)C=C XHZPRMZZQOIPDS-UHFFFAOYSA-N 0.000 description 1
GNSFRPWPOGYVLO-UHFFFAOYSA-N 3-hydroxypropyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCO GNSFRPWPOGYVLO-UHFFFAOYSA-N 0.000 description 1
229920002126 Acrylic acid copolymer Polymers 0.000 description 1
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
102000004190 Enzymes Human genes 0.000 description 1
108090000790 Enzymes Proteins 0.000 description 1
KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical class [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 1
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
239000003082 abrasive agent Substances 0.000 description 1
230000001133 acceleration Effects 0.000 description 1
239000004480 active ingredient Substances 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
125000005250 alkyl acrylate group Chemical group 0.000 description 1
239000000908 ammonium hydroxide Substances 0.000 description 1
150000003863 ammonium salts Chemical class 0.000 description 1
239000003945 anionic surfactant Substances 0.000 description 1
125000004429 atom Chemical group 0.000 description 1
125000000751 azo group Chemical group [*]N=N[*] 0.000 description 1
239000011324 bead Substances 0.000 description 1
239000007853 buffer solution Substances 0.000 description 1
239000003054 catalyst Substances 0.000 description 1
230000003197 catalytic effect Effects 0.000 description 1
125000002091 cationic group Chemical group 0.000 description 1
OZECDDHOAMNMQI-UHFFFAOYSA-H cerium(3+);trisulfate Chemical compound [Ce+3].[Ce+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O OZECDDHOAMNMQI-UHFFFAOYSA-H 0.000 description 1
229910000333 cerium(III) sulfate Inorganic materials 0.000 description 1
239000000460 chlorine Substances 0.000 description 1
229910052801 chlorine Inorganic materials 0.000 description 1
229910017052 cobalt Inorganic materials 0.000 description 1
239000010941 cobalt Substances 0.000 description 1
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
MEYVLGVRTYSQHI-UHFFFAOYSA-L cobalt(2+) sulfate heptahydrate Chemical compound O.O.O.O.O.O.O.[Co+2].[O-]S([O-])(=O)=O MEYVLGVRTYSQHI-UHFFFAOYSA-L 0.000 description 1
230000003750 conditioning effect Effects 0.000 description 1
ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 1
XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 description 1
OPQARKPSCNTWTJ-UHFFFAOYSA-L copper(ii) acetate Chemical compound [Cu+2].CC([O-])=O.CC([O-])=O OPQARKPSCNTWTJ-UHFFFAOYSA-L 0.000 description 1
230000007423 decrease Effects 0.000 description 1
238000010586 diagram Methods 0.000 description 1
125000001142 dicarboxylic acid group Chemical group 0.000 description 1
238000005553 drilling Methods 0.000 description 1
239000000975 dye Substances 0.000 description 1
230000000694 effects Effects 0.000 description 1
239000000945 filler Substances 0.000 description 1
238000009472 formulation Methods 0.000 description 1
230000002070 germicidal effect Effects 0.000 description 1
229920006158 high molecular weight polymer Polymers 0.000 description 1
239000003752 hydrotrope Substances 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
230000005764 inhibitory process Effects 0.000 description 1
150000002484 inorganic compounds Chemical class 0.000 description 1
239000002563 ionic surfactant Substances 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
SURQXAFEQWPFPV-UHFFFAOYSA-L iron(2+) sulfate heptahydrate Chemical compound O.O.O.O.O.O.O.[Fe+2].[O-]S([O-])(=O)=O SURQXAFEQWPFPV-UHFFFAOYSA-L 0.000 description 1
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
229920003145 methacrylic acid copolymer Polymers 0.000 description 1
238000006386 neutralization reaction Methods 0.000 description 1
229910052759 nickel Inorganic materials 0.000 description 1
239000002736 nonionic surfactant Substances 0.000 description 1
230000003287 optical effect Effects 0.000 description 1
150000002894 organic compounds Chemical class 0.000 description 1
125000000864 peroxy group Chemical group O(O*)* 0.000 description 1
JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
239000004014 plasticizer Substances 0.000 description 1
230000001376 precipitating effect Effects 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
230000009257 reactivity Effects 0.000 description 1
229910000029 sodium carbonate Inorganic materials 0.000 description 1
239000002689 soil Substances 0.000 description 1
239000004094 surface-active agent Substances 0.000 description 1
230000002194 synthesizing effect Effects 0.000 description 1
UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
238000004260 weight control Methods 0.000 description 1
239000011701 zinc Substances 0.000 description 1
150000003751 zinc Chemical class 0.000 description 1
229910052726 zirconium Inorganic materials 0.000 description 1
239000002888 zwitterionic surfactant Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Health & Medical Sciences (AREA)
Polymers & Plastics (AREA)
Medicinal Chemistry (AREA)
Wood Science & Technology (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Oil, Petroleum & Natural Gas (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Detergent Compositions (AREA)
Polymerisation Methods In General (AREA)
Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
Graft Or Block Polymers (AREA)

DD90343179A 1990-02-06 1990-07-31 Wasserloesliche, niedermolekulare copolymere, verfahren zur herstellung und waschmittelzusammensetzungen enthaltend solche copolymere DD296692A5 (de)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US07/475,580 US5055540A (en)	1990-02-06	1990-02-06	Process for efficient molecular weight control in copolymerization

Publications (1)

Publication Number	Publication Date
DD296692A5 true DD296692A5 (de)	1991-12-12

Family

ID=23888219

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DD90343179A DD296692A5 (de)	1990-02-06	1990-07-31	Wasserloesliche, niedermolekulare copolymere, verfahren zur herstellung und waschmittelzusammensetzungen enthaltend solche copolymere

Country Status (18)

Country	Link
US (1)	US5055540A (da)
EP (1)	EP0441022B1 (da)
JP (1)	JP3054873B2 (da)
KR (1)	KR100190513B1 (da)
CN (2)	CN1030322C (da)
AT (1)	ATE123297T1 (da)
AU (1)	AU644803B2 (da)
BR (1)	BR9003959A (da)
CA (1)	CA2022705C (da)
DD (1)	DD296692A5 (da)
DE (1)	DE69019814T2 (da)
DK (1)	DK0441022T3 (da)
ES (1)	ES2073532T3 (da)
IE (1)	IE902758A1 (da)
NZ (2)	NZ243407A (da)
PH (1)	PH27560A (da)
PT (1)	PT94976A (da)
ZA (1)	ZA906080B (da)

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US5409629A (en) *	1991-07-19	1995-04-25	Rohm And Haas Company	Use of acrylic acid/ethyl acrylate copolymers for enhanced clay soil removal in liquid laundry detergents
US5268437A (en) *	1992-01-22	1993-12-07	Rohm And Haas Company	High temperature aqueous polymerization process
EP0875553A1 (en) *	1993-01-26	1998-11-04	National Starch And Chemical Investment Holding Corporation	Detergent composition
US5866012A (en) *	1993-01-26	1999-02-02	National Starch And Chemical Investment Holding Corporation	Multifunctional maleate polymers
WO1994018296A1 (de) *	1993-02-05	1994-08-18	Henkel Kommanditgesellschaft Auf Aktien	Gerüststoff für wasch- oder reinigungsmittel
US5431846A (en) *	1993-05-20	1995-07-11	Lever Brothers Company, Division Of Conopco, Inc.	Copolymers and detergent compositions containing them
ES2072812B1 (es) *	1993-05-28	1996-02-16	Derypol S A	Procedimiento para la preparacion de copolimeros de acidos dicarboxilicos
EP0630965A1 (en) *	1993-06-23	1994-12-28	The Procter & Gamble Company	Concentrated liquid hard surface detergent compositions containing maleic acid-olefin copolymers
DE69417538T2 (de) *	1993-07-20	2000-01-05	Nippon Shokubai Co. Ltd., Osaka	Maleinsäurecopolymer, verfahren zur herstellung und dessen anwendung
DE4405621A1 (de) *	1994-02-22	1995-08-24	Basf Ag	Verfahren zur Herstellung von Copolymerisaten aus Vinylestern und monoethylenisch ungesättigten Carbonsäuren und ihre Verwendung
US6335404B1 (en) *	1994-04-05	2002-01-01	Rohm And Haas Company	Aqueous process for preparing aqueous weight carboxyl containing polymers
CA2151112A1 (en) *	1994-06-13	1995-12-14	Michael Bennett Freeman	High temperature polymerization process and products therefrom
DE4420920A1 (de) *	1994-06-16	1995-12-21	Basf Ag	Vinylformiateinheiten enthaltende Copolymerisate, Verfahren zu ihrer Herstellung und ihre Verwendung in Wasch- und Reinigungsmitteln
JP2001081108A (ja) *	1999-09-16	2001-03-27	Sekisui Chem Co Ltd	ビニル系低分子量重合体の製造方法及びビニル系低分子量重合体、並びに、トナー用バインダー樹脂組成物及びトナー
TWI236483B (en)	2000-07-07	2005-07-21	Nippon Catalytic Chem Ind	Low molecular weight (methyl) acrylic acid (acrylate) polymer and preparation process and use thereof
KR100370773B1 (ko) *	2000-09-14	2003-02-05	김성진	쌀겨첨가 방식제의 제조방법 및 그 방식제
BRPI0407625B1 (pt) *	2003-02-24	2013-07-09		composição para tratar superfícies metálicas, camada passivadora sobre uma superfície metálica, superfície, processo para formar uma camada passivadora sobre uma superfície metálica, uso de uma composição, sistema em uma superfície metálica, e, processo para formar um sistema de revestimento
CN100389137C (zh) *	2004-12-30	2008-05-21	中国石油化工股份有限公司	一种丁烯二酸聚合物的制备方法
KR100626552B1 (ko) *	2005-04-06	2006-09-22	김수동	잔류단량제와 개시제 잔류물이 적게 함유된폴리아크릴아마이드 공중합체의 제조
CN100509683C (zh) *	2006-09-30	2009-07-08	江苏博特新材料有限公司	一种低分子量共聚物分散剂及其制备方法
EP2207822A4 (en) *	2007-11-09	2012-04-11	Procter & Gamble	CLEANING COMPOSITIONS WITH MONOCARBOXYLIC MONOMERS, DICARBOXYLIC ACID MONOMERS AND MONOMERS WITH SULPHONIC ACID GROUPS
EP2260070B1 (en) *	2008-03-31	2015-07-22	Nippon Shokubai Co., Ltd.	Sulfonic group-containing, maleic acid-based, water-soluble copolymer aqueous solution and powder obtained by drying the aqueous solution
EP2221324B1 (en) *	2009-02-18	2013-01-16	Rohm and Haas Company	Process for making improved aliphatic dicarboxylic acid copolymers
US20100234264A1 (en) *	2009-03-13	2010-09-16	Marianne Patricia Creamer	Scale-reducing additive for automatic dishwashing systems
EP2228426A1 (en) *	2009-03-13	2010-09-15	Rohm and Haas Company	Scale-reducing additive for automatic dishwashing systems
US20110021410A1 (en) *	2009-07-27	2011-01-27	Ecolab Usa Inc.	Novel formulation of a ware washing solid controlling hardness
KR101118625B1 (ko)	2010-03-24	2012-03-06	회명산업 주식회사	수용성 절삭유
CN103539270B (zh) *	2013-11-14	2014-11-05	南京林业大学	Aa/ba/amps三元无磷聚合型缓蚀阻垢剂及其制备方法
US9279097B1 (en)	2014-08-14	2016-03-08	Ecolab USA, Inc.	Polymers for industrial laundry detergents
CN109486271A (zh) *	2018-09-11	2019-03-19	郑州林海环保材料有限公司	一种涂料有机分散剂及其制备方法

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US2789099A (en) *	1953-09-04	1957-04-16	Union Carbide & Carbon Corp	Polymerization of acrylic acid in aqueous solution
FR2514746B1 (fr) *	1981-10-20	1985-05-31	Coatex Sa	Agent inhibiteur d'incrustations et de precipitation pour le traitement des eaux industrielles et/ou domestiques
US4485223A (en) *	1981-10-29	1984-11-27	Pfizer Inc.	(Meth)acrylic acid/itaconic acid copolymers, their preparation and use as antiscalants
DK274983A (da) *	1982-06-16	1983-12-17	Albright & Wilson	Polymere af umaette syrer samt fremgangsmaade til fremstilling deraf
DE3233778A1 (de) *	1982-09-11	1984-03-15	Basf Ag, 6700 Ludwigshafen	Verfahren einer kontinuierlichen herstellung von copolymerisaten aus monoethylenisch ungesaettigten mono- und dicarbonsaeuren
DE3426368A1 (de) *	1984-07-18	1986-01-23	Basf Ag, 6700 Ludwigshafen	Copolymerisate fuer wasch- und reinigungsmittel
US4659793A (en) *	1986-03-03	1987-04-21	Alco Chemical Corporation	Preparation of aqueous solutions of copolymers of dicarboxylic acids having a low dicarboxylic acid monomer content
DE3716543A1 (de) *	1987-05-16	1988-11-24	Basf Ag	Verwendung von wasserloeslichen copolymerisaten, die monomere mit mindestens zwei ethylenisch ungesaettigten doppelbindungen einpolymerisiert enthalten, in wasch- und reinigungsmitteln
DE3716544A1 (de) *	1987-05-16	1988-11-24	Basf Ag	Verwendung von wasserloeslichen copolymerisaten, die monomere mit mindestens zwei ethylenisch ungesaettigten doppelbindungen einpolymerisiert enthalten, in wasch- und reinigungsmitteln
DE68911729T2 (de) *	1988-04-11	1994-07-21	Nippon Catalytic Chem Ind	Verfahren zur Herstellung eines Polymers von Maleinsäure und Wasserbehandlungsmittel und diese Polymere enthaltender Zusatz für Waschmittel.
US5244988A (en) *	1989-05-17	1993-09-14	Rohm And Haas Company	Maleate polymerization process

1990
- 1990-02-06 US US07/475,580 patent/US5055540A/en not_active Expired - Lifetime
- 1990-07-30 IE IE275890A patent/IE902758A1/en unknown
- 1990-07-31 ES ES90308429T patent/ES2073532T3/es not_active Expired - Lifetime
- 1990-07-31 AU AU60044/90A patent/AU644803B2/en not_active Ceased
- 1990-07-31 AT AT90308429T patent/ATE123297T1/de active
- 1990-07-31 NZ NZ243407A patent/NZ243407A/en unknown
- 1990-07-31 NZ NZ234722A patent/NZ234722A/xx unknown
- 1990-07-31 DK DK90308429.1T patent/DK0441022T3/da active
- 1990-07-31 EP EP90308429A patent/EP0441022B1/en not_active Expired - Lifetime
- 1990-07-31 DD DD90343179A patent/DD296692A5/de not_active IP Right Cessation
- 1990-07-31 PH PH40932A patent/PH27560A/en unknown
- 1990-07-31 DE DE69019814T patent/DE69019814T2/de not_active Expired - Fee Related
- 1990-08-02 ZA ZA906080A patent/ZA906080B/xx unknown
- 1990-08-03 CA CA002022705A patent/CA2022705C/en not_active Expired - Fee Related
- 1990-08-10 BR BR909003959A patent/BR9003959A/pt not_active IP Right Cessation
- 1990-08-13 PT PT94976A patent/PT94976A/pt not_active Application Discontinuation
- 1990-10-03 JP JP2266140A patent/JP3054873B2/ja not_active Expired - Fee Related
- 1990-10-18 KR KR1019900016576A patent/KR100190513B1/ko not_active Expired - Fee Related
1991
- 1991-02-06 CN CN91100772A patent/CN1030322C/zh not_active Expired - Fee Related
1994
- 1994-08-01 CN CN94114814A patent/CN1100134A/zh active Pending

Also Published As

Publication number	Publication date
ES2073532T3 (es)	1995-08-16
ATE123297T1 (de)	1995-06-15
PT94976A (pt)	1991-09-30
DE69019814D1 (de)	1995-07-06
KR100190513B1 (ko)	1999-06-01
EP0441022A3 (en)	1991-10-16
US5055540A (en)	1991-10-08
DE69019814T2 (de)	1995-12-07
AU644803B2 (en)	1993-12-23
EP0441022A2 (en)	1991-08-14
CN1100134A (zh)	1995-03-15
JP3054873B2 (ja)	2000-06-19
CA2022705C (en)	2001-05-29
NZ243407A (en)	1994-01-26
ZA906080B (en)	1991-10-30
CN1053925A (zh)	1991-08-21
BR9003959A (pt)	1991-11-12
CA2022705A1 (en)	1991-08-07
DK0441022T3 (da)	1995-07-24
NZ234722A (en)	1994-01-26
PH27560A (en)	1993-08-18
JPH03234713A (ja)	1991-10-18
AU6004490A (en)	1991-08-08
EP0441022B1 (en)	1995-05-31
KR910015602A (ko)	1991-09-30
CN1030322C (zh)	1995-11-22
IE902758A1 (en)	1991-08-14

Legal Events

Date	Code	Title	Description
2000-01-20	ENJ	Ceased due to non-payment of renewal fee

Publication	Publication Date	Title
DD296692A5 (de)	1991-12-12	Wasserloesliche, niedermolekulare copolymere, verfahren zur herstellung und waschmittelzusammensetzungen enthaltend solche copolymere
DE69011409T2 (de)	1994-12-15	Verfahren zur Herstellung von wasserlöslichen Copolymeren von aliphatischer monoethylenisch ungesättigter Dicarbonsäure und ungesättigte Monomere.
DE69507066T2 (de)	1999-08-19	Wässeriges Verfahren zur Herstellung von Polymeren mit niedrigem Molekulargewicht
DE69432876T2 (de)	2004-06-03	Multifunktionale Maleat Polymere
DE4300772C2 (de)	1997-03-27	Wasserlösliche, biologisch abbaubare Copolymere auf Basis von ungesättigten Mono- und Dicarbonsäuren, Verfahren zu ihrer Herstellung und ihre Verwendung
DE69313882T2 (de)	1998-03-19	Wässriges Hochtemperaturpolymerisationsverfahren
EP0471710B1 (de)	1994-02-16	Copolymerisate, die polyalkylenoxid-blöcke enthaltende monomere einpolymerisiert enthalten, ihre herstellung und ihre verwendung
EP0451508B1 (de)	1995-06-07	Verfahren zur Herstellung von Homo- und Copolymerisaten monoethylenisch ungesättigter Dicarbonsäuren und ihre Verwendung
DE4415623A1 (de)	1995-11-09	Verwendung von Pfropfpolymerisaten von monoethylenisch ungesättigten Dicarbonsäuren auf hydrierten Sacchariden als Zusatz zu Wasch- und Reinigungsmitteln
DE3233778A1 (de)	1984-03-15	Verfahren einer kontinuierlichen herstellung von copolymerisaten aus monoethylenisch ungesaettigten mono- und dicarbonsaeuren
EP0075820B1 (de)	1986-08-13	Verfahren zur Herstellung von Copolymerisaten aus monoethylenisch ungesättigten Mono- und Dicarbonsäuren
EP0337259A2 (de)	1989-10-18	Verwendung von wasserlöslichen Copolymerisaten auf Basis von monoethylenisch ungesättigten Carbonsäuren
DE19503546A1 (de)	1996-08-08	Wasserlösliche oder wasserdispergierbare Pfropfpolymerisate, Verfahren zu ihrer Herstellung und ihre Verwendung
DE3233776A1 (de)	1984-03-15	Verfahren zur herstellung von copolymerisaten aus monoethylenisch ungesaettigten mono- und dicarbonsaeuren
EP0292766A1 (de)	1988-11-30	Verwendung von wasserlöslichen Copolymerisaten, die Monomere mit mindestens zwei ethylenisch ungesättigten Doppelbindungen einpolymerisiert enthalten, in Wasch-und Reinigungsmitteln
EP0344591B1 (de)	1993-05-05	Verfahren zur Herstellung von wasserlöslichen Polymerisaten und ihre Verwendung
DE69020299T2 (de)	1995-10-26	Verfahren zur Herstellung von Kesselstein verhindernden Mitteln.
EP0377448A2 (de)	1990-07-11	Verwendung von Copolymerisaten aus 1,2-Di-alkoxyethylenen und monoethylenisch ungesättigten Dicarbonsäureanhydriden in Waschmitteln und Waschmittel, die diese Copolymerisate enthalten
EP0791023B1 (de)	1999-01-07	Verfahren zur herstellung von terpolymeren
EP1761622B1 (de)	2009-02-25	Verfahren zur herstellung von granulären oder pulverförmigen waschmittelzusammensetzungen
DE4036226A1 (de)	1992-05-21	Erdoelmitteldestillate mit verbesserten fliesseigenschaften in der kaelte
DE69021610T2 (de)	1996-01-18	Maleinsäureanhydridcopolymere.
DE2910133A1 (de)	1980-09-25	Gerueststoffsubstanzen fuer wasch- und reinigungsmittel, die aus einer mischung aus acrylsaeurecopolymerisaten und polymaleinsaeure bestehen
DE3744592C2 (de)	1996-04-18	Wasserlösliche Polymerisate enthaltende Geschirrspülmittel
EP0906397A2 (de)	1999-04-07	Verwendung von copolymeren zur erhöhung der lösegeschwindigkeit von teilchenförmigen waschmittelformulierungen in wasser