DE1720962C3 - Verfahren zum Aufpfropfen von Vinylmonomeren auf einen Hydroxylgruppen enthaltenden polymeren Stoff - Google Patents

Verfahren zum Aufpfropfen von Vinylmonomeren auf einen Hydroxylgruppen enthaltenden polymeren Stoff

Info

Publication number: DE1720962C3
Authority: DE; Germany
Prior art keywords: grafting; initiator; polymeric substance; container; solvent
Prior art date: 1966-05-20
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

DE1967J0033702

Other languages

German (de)

English (en)

Other versions

DE1720962A1 (de

DE1720962B2 (de

Inventor

Georges Sotteville Les Rouen Cuvelier

Daniel Saint-Etienne Du Rouvray Wattiez

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Institut Francais Textile et Habillement

Original Assignee

Institut Francais Textile et Habillement

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1966-05-20

Filing date

1967-05-19

Publication date

1980-02-07

1966-05-20 Priority claimed from FR62374A external-priority patent/FR1487391A/fr

1967-05-19 Application filed by Institut Francais Textile et Habillement filed Critical Institut Francais Textile et Habillement

1970-05-14 Publication of DE1720962A1 publication Critical patent/DE1720962A1/de

1973-09-06 Publication of DE1720962B2 publication Critical patent/DE1720962B2/de

1980-02-07 Application granted granted Critical

1980-02-07 Publication of DE1720962C3 publication Critical patent/DE1720962C3/de

Status Expired legal-status Critical Current

Links

239000000178 monomer Substances 0.000 title claims description 29
238000000034 method Methods 0.000 title claims description 18
239000000126 substance Substances 0.000 title claims description 14
125000002887 hydroxy group Chemical group [H]O* 0.000 title claims description 7
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 title claims description 7
229920002554 vinyl polymer Polymers 0.000 title claims description 7
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 23
239000003999 initiator Substances 0.000 claims description 21
239000002904 solvent Substances 0.000 claims description 15
239000000243 solution Substances 0.000 claims description 14
238000009835 boiling Methods 0.000 claims description 6
239000007864 aqueous solution Substances 0.000 claims description 4
150000000703 Cerium Chemical class 0.000 claims description 2
230000000694 effects Effects 0.000 claims description 2
239000007858 starting material Substances 0.000 claims description 2
230000003197 catalytic effect Effects 0.000 claims 1
239000004744 fabric Substances 0.000 description 20
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 6
229910052753 mercury Inorganic materials 0.000 description 6
239000003054 catalyst Substances 0.000 description 5
239000001913 cellulose Substances 0.000 description 5
229920002678 cellulose Polymers 0.000 description 5
229920001519 homopolymer Polymers 0.000 description 5
230000007935 neutral effect Effects 0.000 description 5
BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 4
238000006116 polymerization reaction Methods 0.000 description 4
238000011282 treatment Methods 0.000 description 4
229920000742 Cotton Polymers 0.000 description 3
ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
239000004372 Polyvinyl alcohol Substances 0.000 description 3
OZECDDHOAMNMQI-UHFFFAOYSA-H cerium(3+);trisulfate Chemical compound [Ce+3].[Ce+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O OZECDDHOAMNMQI-UHFFFAOYSA-H 0.000 description 3
238000006243 chemical reaction Methods 0.000 description 3
239000007788 liquid Substances 0.000 description 3
239000000463 material Substances 0.000 description 3
239000002609 medium Substances 0.000 description 3
229920000642 polymer Polymers 0.000 description 3
229920002451 polyvinyl alcohol Polymers 0.000 description 3
229920006395 saturated elastomer Polymers 0.000 description 3
QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 3
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 description 2
230000002378 acidificating effect Effects 0.000 description 2
230000001476 alcoholic effect Effects 0.000 description 2
229920000615 alginic acid Polymers 0.000 description 2
235000010443 alginic acid Nutrition 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
238000005341 cation exchange Methods 0.000 description 2
HSJPMRKMPBAUAU-UHFFFAOYSA-N cerium(3+);trinitrate Chemical compound [Ce+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O HSJPMRKMPBAUAU-UHFFFAOYSA-N 0.000 description 2
229920001577 copolymer Polymers 0.000 description 2
238000001035 drying Methods 0.000 description 2
238000001704 evaporation Methods 0.000 description 2
230000008020 evaporation Effects 0.000 description 2
239000000203 mixture Substances 0.000 description 2
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
229910052684 Cerium Inorganic materials 0.000 description 1
241000251730 Chondrichthyes Species 0.000 description 1
JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
150000001252 acrylic acid derivatives Chemical class 0.000 description 1
229920006397 acrylic thermoplastic Polymers 0.000 description 1
239000000783 alginic acid Substances 0.000 description 1
229960001126 alginic acid Drugs 0.000 description 1
150000004781 alginic acids Chemical class 0.000 description 1
150000001450 anions Chemical class 0.000 description 1
239000012736 aqueous medium Substances 0.000 description 1
CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
239000012159 carrier gas Substances 0.000 description 1
238000005119 centrifugation Methods 0.000 description 1
-1 cerium ions Chemical class 0.000 description 1
238000004040 coloring Methods 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
230000009849 deactivation Effects 0.000 description 1
239000012153 distilled water Substances 0.000 description 1
238000005530 etching Methods 0.000 description 1
238000000605 extraction Methods 0.000 description 1
229920000578 graft copolymer Polymers 0.000 description 1
238000010559 graft polymerization reaction Methods 0.000 description 1
238000007654 immersion Methods 0.000 description 1
238000005470 impregnation Methods 0.000 description 1
238000003780 insertion Methods 0.000 description 1
230000037431 insertion Effects 0.000 description 1
239000013067 intermediate product Substances 0.000 description 1
238000005342 ion exchange Methods 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
238000012423 maintenance Methods 0.000 description 1
229910052748 manganese Inorganic materials 0.000 description 1
239000011572 manganese Substances 0.000 description 1
239000012528 membrane Substances 0.000 description 1
YXWHESRDBJVGBS-UHFFFAOYSA-M mercury(1+);prop-2-enoate Chemical compound [Hg+].[O-]C(=O)C=C YXWHESRDBJVGBS-UHFFFAOYSA-M 0.000 description 1
150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
229910017604 nitric acid Inorganic materials 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
150000004965 peroxy acids Chemical class 0.000 description 1
JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
239000002861 polymer material Substances 0.000 description 1
239000003505 polymerization initiator Substances 0.000 description 1
229920002689 polyvinyl acetate Polymers 0.000 description 1
239000011118 polyvinyl acetate Substances 0.000 description 1
239000012254 powdered material Substances 0.000 description 1
238000012545 processing Methods 0.000 description 1
239000000047 product Substances 0.000 description 1
238000011321 prophylaxis Methods 0.000 description 1
230000035484 reaction time Effects 0.000 description 1
239000005871 repellent Substances 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
QDRKDTQENPPHOJ-UHFFFAOYSA-N sodium ethoxide Chemical compound [Na+].CC[O-] QDRKDTQENPPHOJ-UHFFFAOYSA-N 0.000 description 1
230000003068 static effect Effects 0.000 description 1
ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
230000001960 triggered effect Effects 0.000 description 1
238000005406 washing Methods 0.000 description 1
230000004584 weight gain Effects 0.000 description 1
235000019786 weight gain Nutrition 0.000 description 1

Classifications

- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M14/00—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
- D06M14/02—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials on to materials of natural origin
- D06M14/04—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials on to materials of natural origin of vegetal origin, e.g. cellulose or derivatives thereof
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M14/00—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M14/00—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
- D06M14/08—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials on to materials of synthetic origin
- D06M14/10—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials on to materials of synthetic origin of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M14/00—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
- D06M14/18—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation
- D06M14/20—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation on to materials of natural origin
- D06M14/22—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation on to materials of natural origin of vegetal origin, e.g. cellulose or derivatives thereof

Landscapes

Engineering & Computer Science (AREA)
Textile Engineering (AREA)
Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Health & Medical Sciences (AREA)
Toxicology (AREA)
Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Graft Or Block Polymers (AREA)

DE1967J0033702 1966-05-20 1967-05-19 Verfahren zum Aufpfropfen von Vinylmonomeren auf einen Hydroxylgruppen enthaltenden polymeren Stoff Expired DE1720962C3 (de)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
FR62374A FR1487391A (fr)	1966-05-20	1966-05-20	Procédé de greffage de la cellulose
FR98537A FR1522387A (fr)	1966-05-20	1967-03-13	Procédé de greffage de polymères contenant des groupes hydroxyles

Publications (3)

Publication Number	Publication Date
DE1720962A1 DE1720962A1 (de)	1970-05-14
DE1720962B2 DE1720962B2 (de)	1973-09-06
DE1720962C3 true DE1720962C3 (de)	1980-02-07

Family

ID=26170790

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DE1967J0033702 Expired DE1720962C3 (de)	1966-05-20	1967-05-19	Verfahren zum Aufpfropfen von Vinylmonomeren auf einen Hydroxylgruppen enthaltenden polymeren Stoff

Country Status (6)

Country	Link
BE (1)	BE698712A (2)
CH (2)	CH704767A4 (2)
DE (1)	DE1720962C3 (2)
FR (1)	FR1522387A (2)
GB (1)	GB1128696A (2)
NL (1)	NL156154B (2)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CA1134977A (en)	1978-09-07	1982-11-02	Sumitomo Chemical Co., Ltd.	Method for preparing highly absorbent polymers
US4279791A (en) *	1980-05-08	1981-07-21	Standard Brands Incorporated	Recovery of cerium from polymer dispersions
US4743267A (en) *	1982-06-21	1988-05-10	International Yarn Corporation Of Tennessee	Process for improving polymer fiber properties and fibers produced thereby
CA2723785C (en) *	2008-06-10	2017-08-22	Pathogen Removal And Diagnostic Technologies Inc.	Conformal coating of polymer fibers on nonwoven substrates
BRPI0922382B1 (pt) *	2008-12-16	2019-06-18	Carlsberg A/S	Material de polímero à base de celulose, recipiente para armazenamento de líquidos, material para armazenamento de alimentos e método para preparar o referido material
CN115305612A (zh) *	2022-09-14	2022-11-08	罗莱生活科技股份有限公司	一种聚酯纤维包芯纱线及其制备方法

1967
- 1967-03-13 FR FR98537A patent/FR1522387A/fr not_active Expired
- 1967-05-19 DE DE1967J0033702 patent/DE1720962C3/de not_active Expired
- 1967-05-19 BE BE698712D patent/BE698712A/xx not_active IP Right Cessation
- 1967-05-19 GB GB2330767A patent/GB1128696A/en not_active Expired
- 1967-05-19 CH CH704767D patent/CH704767A4/xx unknown
- 1967-05-19 CH CH704767A patent/CH559275A/xx not_active IP Right Cessation
- 1967-05-22 NL NL6707030A patent/NL156154B/xx not_active IP Right Cessation

Also Published As

Publication number	Publication date
NL156154B (nl)	1978-03-15
FR1522387A (fr)	1968-04-26
BE698712A (2)	1967-11-03
GB1128696A (en)	1968-10-02
DE1720962A1 (de)	1970-05-14
CH559275A (en)	1975-02-28
DE1720962B2 (de)	1973-09-06
NL6707030A (2)	1967-11-21
CH704767A4 (2)	1974-09-13

Legal Events

Date	Code	Title	Description
1980-02-07	C3	Grant after two publication steps (3rd publication)

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