DK0725086T3 - Understøttet metallocenkatalysator til (co)polymerisation af olefiner - Google Patents

Understøttet metallocenkatalysator til (co)polymerisation af olefiner

Info

Publication number
DK0725086T3
DK0725086T3 DK96200191T DK96200191T DK0725086T3 DK 0725086 T3 DK0725086 T3 DK 0725086T3 DK 96200191 T DK96200191 T DK 96200191T DK 96200191 T DK96200191 T DK 96200191T DK 0725086 T3 DK0725086 T3 DK 0725086T3
Authority
DK
Denmark
Prior art keywords
metal
catalyst
constituted
olefins
polymerization
Prior art date
Application number
DK96200191T
Other languages
English (en)
Inventor
Antonio Proto
Liliana Gila
Evelina Ballato
Diego Vigliarolo
Gabriele Lugli
Original Assignee
Enichem Spa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Enichem Spa filed Critical Enichem Spa
Application granted granted Critical
Publication of DK0725086T3 publication Critical patent/DK0725086T3/da

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
DK96200191T 1995-02-01 1996-01-27 Understøttet metallocenkatalysator til (co)polymerisation af olefiner DK0725086T3 (da)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ITMI950167A IT1272939B (it) 1995-02-01 1995-02-01 Catalizzatore metallocenico supportato per la (co)polimerizzazione delle olefine

Publications (1)

Publication Number Publication Date
DK0725086T3 true DK0725086T3 (da) 2001-10-01

Family

ID=11370383

Family Applications (1)

Application Number Title Priority Date Filing Date
DK96200191T DK0725086T3 (da) 1995-02-01 1996-01-27 Understøttet metallocenkatalysator til (co)polymerisation af olefiner

Country Status (9)

Country Link
US (1) US5861352A (da)
EP (1) EP0725086B1 (da)
JP (1) JPH08333412A (da)
AT (1) ATE203547T1 (da)
DE (1) DE69614010T2 (da)
DK (1) DK0725086T3 (da)
ES (1) ES2159679T3 (da)
GR (1) GR3036494T3 (da)
IT (1) IT1272939B (da)

Families Citing this family (39)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR9508487A (pt) * 1994-08-03 1997-12-30 Exxon Chemical Patents Inc Composição de catalisador iônico suportado
US6143686A (en) * 1994-08-03 2000-11-07 Exxon Chemical Patents, Inc. Supported ionic catalyst compositions
IT1283010B1 (it) * 1996-05-15 1998-04-03 Enichem Spa Complesso metallocenico supportato e procedimento per la sua prepa- razione
US5747404A (en) * 1996-05-28 1998-05-05 Lyondell Petrochemical Company Polysiloxane supported metallocene catalysts
EP0839834B1 (en) 1996-10-30 2001-06-13 Repsol Quimica S.A. Catalyst systems for the polymerization and copolymerization of alpha-olefins
DE69703728T2 (de) * 1996-10-31 2001-06-28 Repsol Quimica S.A., Madrid Katalysatorsysteme für die Polymerisation und Copolymerisation von Alpha-Olefinen
US5783512A (en) * 1996-12-18 1998-07-21 The Dow Chemical Company Catalyst component dispersion comprising an ionic compound and solid addition polymerization catalysts containing the same
CN1264869C (zh) 1997-08-21 2006-07-19 住友化学工业株式会社 改性粒子 ,用其制成的载体 ,用其制成的烯烃聚合用催化剂成分 ,用其制成的烯烃聚合用催化剂以及烯烃聚合物制备方法
EP0933383A1 (en) * 1998-01-29 1999-08-04 Union Carbide Chemicals & Plastics Technology Corporation Catalyst composition for the polymerization of olefins
PT953581E (pt) 1998-04-27 2004-07-30 Repsol Quimica Sa Sistemas cataliticos para a polimerizacao e a copolimerizacao de alfa-olefinas
ES2216473T3 (es) * 1998-04-29 2004-10-16 Repsol Quimica S.A. Preparacion y uso de componentes de catalizador heterogeneos para polimerizacion de olefinas.
US6300271B1 (en) * 1998-05-18 2001-10-09 Phillips Petroleum Company Compositions that can produce polymers
US6107230A (en) * 1998-05-18 2000-08-22 Phillips Petroleum Company Compositions that can produce polymers
US6165929A (en) 1998-05-18 2000-12-26 Phillips Petroleum Company Compositions that can produce polymers
US6194343B1 (en) * 1999-03-11 2001-02-27 University Of Waterloo Bridged “tethered” metallocenes
US6040261A (en) * 1999-04-15 2000-03-21 Equistar Chemicals, Lp Supported single-site catalyst and olefin polymerization process
US6376415B1 (en) * 1999-09-28 2002-04-23 Phillips Petroleum Company Organometal catalyst compositions
NO20013880L (no) 2000-08-22 2002-02-25 Rohm & Haas Matriks og fremgangsmåte for fremstilling av polyolefiner
WO2004024739A1 (en) * 2002-09-12 2004-03-25 Dow Global Technologies Inc. Preparation of metal amide complexes
EP1543014B1 (en) * 2002-09-12 2006-10-04 Dow Global Technologies Inc. Preparation of metal complexes
EP1543049B1 (en) * 2002-09-17 2009-02-11 Dow Global Technologies Inc. Improved process for manufacture of polymers
KR100690345B1 (ko) * 2004-09-03 2007-03-09 주식회사 엘지화학 담지 메탈로센 촉매, 그 제조방법 및 이를 이용한폴리올레핀의 제조방법
CA2621307C (en) * 2005-09-09 2014-12-02 Sk Energy Co., Ltd. Homogeneous catalyst system for producing ethylene homopolymer or ethylene copolymers with alpha-olefins
KR101141359B1 (ko) * 2005-09-09 2012-05-03 에스케이이노베이션 주식회사 에틸렌 단독중합체 또는 α-올레핀과의 공중합체 제조용균일 촉매계
JP5128289B2 (ja) 2005-12-06 2013-01-23 株式会社トリケミカル研究所 ハフニウム系化合物、ハフニウム系薄膜形成材料、及びハフニウム系薄膜形成方法
EP2029790A1 (en) * 2006-06-02 2009-03-04 L'AIR LIQUIDE, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Method of forming high-k dielectric films based on novel titanium, zirconium, and hafnium precursors and their use for semiconductor manufacturing
CN101959897A (zh) 2008-02-27 2011-01-26 乔治洛德方法研究和开发液化空气有限公司 使用原子层沉积(ald)法在基底上形成含钛层的方法
US7884165B2 (en) * 2008-07-14 2011-02-08 Chevron Phillips Chemical Company Lp Half-metallocene catalyst compositions and their polymer products
US8309748B2 (en) 2011-01-25 2012-11-13 Chevron Phillips Chemical Company Lp Half-metallocene compounds and catalyst compositions
US8895679B2 (en) 2012-10-25 2014-11-25 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US8937139B2 (en) 2012-10-25 2015-01-20 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US9034991B2 (en) 2013-01-29 2015-05-19 Chevron Phillips Chemical Company Lp Polymer compositions and methods of making and using same
US8877672B2 (en) 2013-01-29 2014-11-04 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US9499571B2 (en) 2014-12-23 2016-11-22 L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Germanium- and zirconium-containing compositions for vapor deposition of zirconium-containing films
US9663547B2 (en) 2014-12-23 2017-05-30 L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Silicon- and Zirconium-containing compositions for vapor deposition of Zirconium-containing films
US10106568B2 (en) 2016-10-28 2018-10-23 L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Hafnium-containing film forming compositions for vapor deposition of hafnium-containing films
GB201714756D0 (en) 2017-09-13 2017-10-25 Lucite Int Uk Ltd A catalyst and a process for the production of ethylenicallly unsaturated carboxylic acids or esters
TWI873083B (zh) * 2018-09-14 2025-02-21 英商三菱化學英國有限公司 用於製造乙烯性不飽和羧酸或酯之催化劑及方法
US11806694B2 (en) 2020-03-12 2023-11-07 Mitsubishi Chemical UK Limited Catalyst and a process for the production of ethylenically unsaturated carboxylic acids or esters

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0314797B1 (en) * 1987-04-20 1997-07-02 Mitsui Petrochemical Industries, Ltd. Olefin polymerization catalyst and process for polymerizing olefin
US5202398A (en) * 1987-06-05 1993-04-13 Hoechst Aktiengesellschaft Process for the preparation of a 1-olefin polymer
US5466766A (en) * 1991-05-09 1995-11-14 Phillips Petroleum Company Metallocenes and processes therefor and therewith
CA2068939C (en) * 1991-05-20 1996-04-09 Takashi Ueda Olefin polymerization catalyst and olefin polymerization
JP2955400B2 (ja) * 1991-07-16 1999-10-04 三井化学株式会社 オレフィン重合用固体触媒成分の製造方法
IT1256603B (it) * 1992-10-30 1995-12-12 Enichem Polimeri Catalizzatore e procedimento per (co) polimerizzare le alfa-olefine

Also Published As

Publication number Publication date
DE69614010T2 (de) 2002-03-21
DE69614010D1 (de) 2001-08-30
ITMI950167A0 (it) 1995-02-01
US5861352A (en) 1999-01-19
ATE203547T1 (de) 2001-08-15
ES2159679T3 (es) 2001-10-16
GR3036494T3 (en) 2001-11-30
EP0725086B1 (en) 2001-07-25
EP0725086A3 (en) 1997-05-28
JPH08333412A (ja) 1996-12-17
EP0725086A2 (en) 1996-08-07
ITMI950167A1 (it) 1996-08-01
IT1272939B (it) 1997-07-01

Similar Documents

Publication Publication Date Title
DK0725086T3 (da) Understøttet metallocenkatalysator til (co)polymerisation af olefiner
DK0752428T3 (da) Metallocenkatalysator til (co)polymerisation af alfa-olefiner
DK0955304T3 (da) Metallocenkomplekser med bro til (co)polymerisation af olefiner
LV10213A (lv) Parejas grupas metala savienojums un katalizators stereoregulara polimera iegusanai
RU95112455A (ru) Инденильные соединения, компонент катализатора для полимеризации олефинов, способ полимеризации олефинов, полиолефин
EP0472741A4 (en) Olefin polymerization catalyst
BR9407034A (pt) Complexos de titânio ( I) ou zircônio (II) e catalisadores de polimerização por adição dos mesmos
AU7916587A (en) New supported polymerization catalyst
AU2089192A (en) Bridged, chiral metallocenes, processes for their preparation and their use as catalysts
CA2127447A1 (en) Alpha-Olefin Polymerization Catalysts Comprising Supported Cyclopentadienyl Group 6B Metal Oxo, Thio, Imido and Phosphido Compounds and Process for Polymerizing Alpha-Olefins
DE69319690D1 (de) Katalysator und Verfahren zur (Co)Polymerisation von Alpha-Olefinen
DK0791607T3 (da) Substitueret metallocenkatalysator til (co)polymerisation af olefiner
SI0757996T1 (en) Catalyst for the (co)polymerization of olefins and process using the same
KR880701742A (ko) α-올레핀의 중합용 촉매 및 중합법
ITMI921593A1 (it) Articoli formati per uso biomedicale
AU6306196A (en) Catalyst compositions comprising organometallic compounds
KR960029351A (ko) 메탈로센 담지 촉매 및 그 제조방법 그리고 이를 이용한 이중 분자량 분포를 갖는 중합체의 제조방법
TH23227A (th) "แคทาลิสห์ และขบวนการสำหรับการโพลีเมอไรเซชื่นของโอลิฟิน"