DK1525351T3 - Fremgangsmåde til behandling af arkitektoniske tekstiler ved hjælp af imprægnering med en tværforbindelig silikoneelastomersammensætning - Google Patents
Fremgangsmåde til behandling af arkitektoniske tekstiler ved hjælp af imprægnering med en tværforbindelig silikoneelastomersammensætning Download PDFInfo
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- DK1525351T3 DK1525351T3 DK03750833.0T DK03750833T DK1525351T3 DK 1525351 T3 DK1525351 T3 DK 1525351T3 DK 03750833 T DK03750833 T DK 03750833T DK 1525351 T3 DK1525351 T3 DK 1525351T3
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- Denmark
- Prior art keywords
- silicone
- optionally
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- 239000000203 mixture Substances 0.000 title claims description 61
- 229920001296 polysiloxane Polymers 0.000 title claims description 61
- 239000004753 textile Substances 0.000 title claims description 34
- 238000000034 method Methods 0.000 title claims description 32
- 238000005470 impregnation Methods 0.000 claims description 27
- 239000007788 liquid Substances 0.000 claims description 24
- 239000002131 composite material Substances 0.000 claims description 23
- 238000004132 cross linking Methods 0.000 claims description 18
- 239000012528 membrane Substances 0.000 claims description 18
- 239000011347 resin Substances 0.000 claims description 15
- 229920005989 resin Polymers 0.000 claims description 15
- 239000003054 catalyst Substances 0.000 claims description 14
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 13
- 150000001875 compounds Chemical class 0.000 claims description 13
- 229920001971 elastomer Polymers 0.000 claims description 13
- 239000000806 elastomer Substances 0.000 claims description 13
- 238000000576 coating method Methods 0.000 claims description 12
- 239000011248 coating agent Substances 0.000 claims description 11
- 239000002657 fibrous material Substances 0.000 claims description 10
- 230000000694 effects Effects 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 9
- 239000010703 silicon Substances 0.000 claims description 9
- 229910052710 silicon Inorganic materials 0.000 claims description 9
- 125000003342 alkenyl group Chemical group 0.000 claims description 8
- 125000000217 alkyl group Chemical group 0.000 claims description 8
- 239000000835 fiber Substances 0.000 claims description 8
- 229910052751 metal Inorganic materials 0.000 claims description 8
- 239000002184 metal Substances 0.000 claims description 8
- 239000000470 constituent Substances 0.000 claims description 6
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 claims description 6
- 239000011521 glass Substances 0.000 claims description 6
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 6
- 125000004469 siloxy group Chemical group [SiH3]O* 0.000 claims description 6
- 229910052799 carbon Inorganic materials 0.000 claims description 5
- 125000004432 carbon atom Chemical group C* 0.000 claims description 5
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 5
- 239000012764 mineral filler Substances 0.000 claims description 5
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- 238000002360 preparation method Methods 0.000 claims description 5
- 239000000377 silicon dioxide Substances 0.000 claims description 5
- 229920002994 synthetic fiber Polymers 0.000 claims description 5
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 claims description 5
- 125000003118 aryl group Chemical group 0.000 claims description 4
- 125000005843 halogen group Chemical group 0.000 claims description 4
- 239000003112 inhibitor Substances 0.000 claims description 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 4
- 239000000243 solution Substances 0.000 claims description 4
- 239000012209 synthetic fiber Substances 0.000 claims description 4
- 229910052801 chlorine Inorganic materials 0.000 claims description 3
- 239000000460 chlorine Substances 0.000 claims description 3
- 238000010790 dilution Methods 0.000 claims description 3
- 239000012895 dilution Substances 0.000 claims description 3
- 238000004945 emulsification Methods 0.000 claims description 3
- 229910052731 fluorine Inorganic materials 0.000 claims description 3
- 239000011737 fluorine Substances 0.000 claims description 3
- 239000013538 functional additive Substances 0.000 claims description 3
- 230000005499 meniscus Effects 0.000 claims description 3
- 230000000630 rising effect Effects 0.000 claims description 3
- GRWPYGBKJYICOO-UHFFFAOYSA-N 2-methylpropan-2-olate;titanium(4+) Chemical compound [Ti+4].CC(C)(C)[O-].CC(C)(C)[O-].CC(C)(C)[O-].CC(C)(C)[O-] GRWPYGBKJYICOO-UHFFFAOYSA-N 0.000 claims description 2
- 241000531908 Aramides Species 0.000 claims description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 2
- 244000025254 Cannabis sativa Species 0.000 claims description 2
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 claims description 2
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 claims description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
- 239000004215 Carbon black (E152) Substances 0.000 claims description 2
- 229920003043 Cellulose fiber Polymers 0.000 claims description 2
- 229920000742 Cotton Polymers 0.000 claims description 2
- 239000004593 Epoxy Substances 0.000 claims description 2
- 241000208202 Linaceae Species 0.000 claims description 2
- 235000004431 Linum usitatissimum Nutrition 0.000 claims description 2
- 239000004952 Polyamide Substances 0.000 claims description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 2
- 229920000297 Rayon Polymers 0.000 claims description 2
- 150000004703 alkoxides Chemical class 0.000 claims description 2
- 125000002947 alkylene group Chemical group 0.000 claims description 2
- 239000004760 aramid Substances 0.000 claims description 2
- 229920003235 aromatic polyamide Polymers 0.000 claims description 2
- 229910052796 boron Inorganic materials 0.000 claims description 2
- 235000009120 camo Nutrition 0.000 claims description 2
- 239000000919 ceramic Substances 0.000 claims description 2
- 235000005607 chanvre indien Nutrition 0.000 claims description 2
- 239000013522 chelant Substances 0.000 claims description 2
- 239000011487 hemp Substances 0.000 claims description 2
- 229930195733 hydrocarbon Natural products 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- 229910052748 manganese Inorganic materials 0.000 claims description 2
- 150000002739 metals Chemical class 0.000 claims description 2
- 150000001282 organosilanes Chemical class 0.000 claims description 2
- 239000000049 pigment Substances 0.000 claims description 2
- 229920002647 polyamide Polymers 0.000 claims description 2
- 229920000098 polyolefin Polymers 0.000 claims description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 2
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 2
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 2
- 229920003051 synthetic elastomer Polymers 0.000 claims description 2
- 239000005061 synthetic rubber Substances 0.000 claims description 2
- 229910052719 titanium Inorganic materials 0.000 claims description 2
- 210000002268 wool Anatomy 0.000 claims description 2
- 229910052726 zirconium Inorganic materials 0.000 claims description 2
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 claims 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims 1
- 239000000853 adhesive Substances 0.000 claims 1
- 230000001070 adhesive effect Effects 0.000 claims 1
- 238000005520 cutting process Methods 0.000 claims 1
- 239000004615 ingredient Substances 0.000 claims 1
- 150000003961 organosilicon compounds Chemical class 0.000 claims 1
- 150000002989 phenols Chemical class 0.000 claims 1
- 238000010186 staining Methods 0.000 claims 1
- 239000000725 suspension Substances 0.000 claims 1
- 238000005303 weighing Methods 0.000 claims 1
- -1 polydimethylsiloxane Polymers 0.000 description 33
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 15
- 239000004744 fabric Substances 0.000 description 11
- 239000000945 filler Substances 0.000 description 11
- 229920002379 silicone rubber Polymers 0.000 description 10
- 239000012530 fluid Substances 0.000 description 9
- 229920002545 silicone oil Polymers 0.000 description 8
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 6
- 229910052697 platinum Inorganic materials 0.000 description 6
- 150000003254 radicals Chemical class 0.000 description 6
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 6
- 238000002156 mixing Methods 0.000 description 5
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- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 4
- QYLFHLNFIHBCPR-UHFFFAOYSA-N 1-ethynylcyclohexan-1-ol Chemical compound C#CC1(O)CCCCC1 QYLFHLNFIHBCPR-UHFFFAOYSA-N 0.000 description 3
- 125000004122 cyclic group Chemical group 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 238000001000 micrograph Methods 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 230000009257 reactivity Effects 0.000 description 3
- 239000004447 silicone coating Substances 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- CIUQDSCDWFSTQR-UHFFFAOYSA-N [C]1=CC=CC=C1 Chemical compound [C]1=CC=CC=C1 CIUQDSCDWFSTQR-UHFFFAOYSA-N 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- FFUAGWLWBBFQJT-UHFFFAOYSA-N hexamethyldisilazane Chemical compound C[Si](C)(C)N[Si](C)(C)C FFUAGWLWBBFQJT-UHFFFAOYSA-N 0.000 description 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
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- 238000006116 polymerization reaction Methods 0.000 description 2
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- 239000002904 solvent Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
- 239000010455 vermiculite Substances 0.000 description 2
- 229910052902 vermiculite Inorganic materials 0.000 description 2
- 235000019354 vermiculite Nutrition 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000002759 woven fabric Substances 0.000 description 2
- 125000006273 (C1-C3) alkyl group Chemical group 0.000 description 1
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 1
- SMCLTAARQYTXLW-UHFFFAOYSA-N 1,1-diphenylprop-2-yn-1-ol Chemical compound C=1C=CC=CC=1C(C#C)(O)C1=CC=CC=C1 SMCLTAARQYTXLW-UHFFFAOYSA-N 0.000 description 1
- 125000004179 3-chlorophenyl group Chemical group [H]C1=C([H])C(*)=C([H])C(Cl)=C1[H] 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- 229910052774 Proactinium Inorganic materials 0.000 description 1
- 229910020447 SiO2/2 Inorganic materials 0.000 description 1
- 238000007259 addition reaction Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
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- 235000011116 calcium hydroxide Nutrition 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 125000004218 chloromethyl group Chemical group [H]C([H])(Cl)* 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 125000004772 dichloromethyl group Chemical group [H]C(Cl)(Cl)* 0.000 description 1
- 125000001028 difluoromethyl group Chemical group [H]C(F)(F)* 0.000 description 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000004079 fireproofing Methods 0.000 description 1
- 125000004216 fluoromethyl group Chemical group [H]C([H])(F)* 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 229910021485 fumed silica Inorganic materials 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 229920001600 hydrophobic polymer Polymers 0.000 description 1
- 238000006459 hydrosilylation reaction Methods 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 125000000040 m-tolyl group Chemical group [H]C1=C([H])C(*)=C([H])C(=C1[H])C([H])([H])[H] 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- WCYWZMWISLQXQU-UHFFFAOYSA-N methyl Chemical compound [CH3] WCYWZMWISLQXQU-UHFFFAOYSA-N 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000003261 o-tolyl group Chemical group [H]C1=C([H])C(*)=C(C([H])=C1[H])C([H])([H])[H] 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 125000005375 organosiloxane group Chemical group 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 125000003854 p-chlorophenyl group Chemical group [H]C1=C([H])C(*)=C([H])C([H])=C1Cl 0.000 description 1
- 125000001037 p-tolyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)C([H])([H])[H] 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 150000003003 phosphines Chemical class 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- 235000013824 polyphenols Nutrition 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- JUJWROOIHBZHMG-UHFFFAOYSA-N pyridine Substances C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 150000003284 rhodium compounds Chemical class 0.000 description 1
- 238000004626 scanning electron microscopy Methods 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- 125000005023 xylyl group Chemical group 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
- D06N3/128—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with silicon polymers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249924—Noninterengaged fiber-containing paper-free web or sheet which is not of specified porosity
- Y10T428/24994—Fiber embedded in or on the surface of a polymeric matrix
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31652—Of asbestos
- Y10T428/31663—As siloxane, silicone or silane
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Laminated Bodies (AREA)
- Reinforced Plastic Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Claims (9)
1. Fremgangsmåde til fremstillingen afen arkitektonisk silikonemembran med en vægt på mellem 400 og 1500 g/m2, ved imprægnering af et arkitektonisk tekstil med mindst én silikone, omfattende de følgende essentielle trin: -li = positivt heltalat påføre et arkitektonisk tekstil en flydende silikonesammensætning, som kan tværbindes til en elastomer, omfattende (a) mindst ét polyorganosiloxan (POS) med, per molekyle, mindst to alkenylgrupper, fortrinsvis C2-C6, forbundet til silicium; (b) mindst ét polyorganosiloxan med, per molekyle, mindst tre hydrogenatomer forbundet til silicium; (c) en katalytisk effektiv mængde af mindst én katalysator, fortrinsvis bestående af mindst ét metal tilhørende platingruppen; (d) eventuelt, mindst én hæftegrund; (e) eventuelt, et mineral-fyldstof; (f) eventuelt, mindst én tværbindingsinhibitor; (g) eventuelt, mindst ét polyorganosiloxanresin; og (h) eventuelt, funktionelle additiver til at give specifikke egenskaber; - Hi = positivt heltaltværbinding af silikonesammensætningen; -III- eventuelt mindst én anden driftssekvens omfattende trinnene li > 2 og Ili > 2 (hvor i er et positivt heltal) svarende til den samme definition som den givet ovenfor for trinnene li og Ili; kendetegnet ved, at trin Ii=1 er et trin til imprægnering helt til kernen af det arkitektoniske tekstil under anvendelse af en flydende silikonesammensætning > med: * en dynamisk viskositet på mellem 1000 og 7000 mPa.s, ved 25 °C, og mere fortrinsvis på mellem 2000 og 5000 mPa.s ved 25 °C før tværbinding, * og, efter fuldendt tværbinding ved hærdning i en blæseovn i 30 minutter ved 150 °C, mindst én af de følgende mekaniske egenskaber: - en Shore A-hårdhed på mindst 2, fortrinsvis mellem 5 og 65; - en trækbrudspænding på mindst 0,5 N.mm'1, fortrinsvis på mindst 0,1 N.mm'1 og mere fortrinsvis på mindst 2 N.mm'1; - en strækning ved brud på mindst 50 %, fortrinsvis på mindst 100 % og mere fortrinsvis på mindst 200 %, > og endvidere er flydende og opnået uden at skulle anvende hverken fortynding eller opløsning eller emulgering, den arkitektoniske silikonemembran derved opnået har en kapillærstigning på mindre end 20 mm, fortrinsvis på mindre end 10 mm og endnu mere fortrinsvis lig med 0, hvor kapillærstigningen måles i henhold til en T-test udført som følgende: - afskæring af en strimmel på 2 x 20 cm af et fibersilikonematerialekomposit, - klargøring af en beholder, som indeholder et farvet blæk (eksempelvis kuglepensblæk), - vertikal ophængning af den afskårne strimmel af fibermaterialekomposit over beholderen med blæk således at strimlen kan bringes i kontakt med blækket, - definering af 0-niveauet som menisklinjen af blækket på strimlen, - kompositstrimlen efterlades på sin plads indtil den stigende front af blæk er i ligevægt, - måling af højden (H) i millimeter, svarende til forskellen mellem 0-niveauet og det maksimale stigningsniveau af blækket langs strimlen, hvor kapillærstigningen defineres med afstanden H.
2. Fremgangsmåde ifølge krav 1, kendetegnet ved, at imprægneringstrinnet omfatter en pigment-farvning.
3. Fremgangsmåde ifølge det ene eller det andet af kravene 1 og 2, kendetegnet ved, at den omfatter mindst ét trin III, i hvilket trin li > 2 til påføring af flydende silikone, er en coating ved brug af en flydende silikonesammensætning som kan tværbindes til en elastomer.
4. Fremgangsmåde ifølge et hvilket som helst af kravene 1 til 3, kendetegnet ved, at det valgte polyorganosiloxan (a) har enheder af formel: WaZbSiO(4-(a+b))/2 (a.l) hvori: - W er en alkenylgruppe, - Z er en monovalent carbonhydridgruppe, som ikke har nogen uønsket virkning på aktiviteten af katalysatoren og valgt fra alkylgrupper med 1 til 8 carbonatomer inkluderet, eventuelt substitueret med mindst ét halogenatom, og fra arylgrupper, - a er 1 eller 2, b er 0, 1 eller 2 og a + b er mellem 1 og 3, og - eventuelt, mindst én del af de andre enheder er enheder af gennemsnitlig formel: WcSiO(4-c)/2 (a.2) i hvilken W har den samme betydning som ovenfor og c har en værdi mellem 0 og 3.
5. Fremgangsmåde ifølge et hvilket som helst af kravene 1 til 4, ifølge hvilken polyorganosiloxanet (b) indeholder siloxylenheder af formel: HdLeSiO(4-(d+e))/2 (b.l) hvori: - L er en monovalent carbonhydridgruppe, som ikke har nogen uønsket virkning på aktiviteten af katalysatoren og valgt fra alkylgrupper med 1 til 8 carbonatomer inkluderet, eventuelt substitueret med mindst ét halogenatom, og fra arylgrupper; - d er 1 eller 2, e er 0, 1 eller 2 og d + e har en værdi mellem 1 og 3; - eventuelt, mindst én del af de andre enheder er enheder af gennemsnitlig Iformel: LgSlO(4-g)/2 (b.2) i hvilken L har den samme betydning som ovenfor og g har en værdi mellem 0 og 3.
6. Fremgangsmåde ifølge et hvilket som helst af kravene 1 til 5, kendetegnet ved, at andelene af (a) og af (b) er således at molforholdet af hydrogenatomerne forbundet til silicium i (b) til alkenylradikalerne forbundet til silicium i (a) er mellem 0,4 og 10.
7. Fremgangsmåde ifølge et hvilket som helst af kravene 1 til 6, i hvilken hæftegrunderen omfatter: (d.l) mindst ét alkoxyleret organosilan, som opfylder den følgende generelle formel:
i hvilken:
- R1, R2, R3 er hydrogenerede eller carbonhydridradikaler identiske eller forskellige fra hinanden og repræsenterer hydrogen, et C1-C4 lineært forgrenet alkyl eller en phenyl eventuelt substitueret med mindst ét C1-C3 alkyl; - A er en C1-C4 lineært eller forgrenet alkylen; - G er en valensbinding; - R4 og R5 er radikaler, identiske eller forskellige, og repræsenterer et lineært eller forgrenet C1-C4 alkyl; - x' = 0 eller 1; - x = 0 til 2, hvor nævnte forbindelse (d.l) fortrinsvis er vinyltrimethoxysilan (VTMS); (d.2) mindst én organosiliciumforbindelse omfattende mindst ét epoxyradikal, hvor nævnte forbindelse (d.2) fortrinsvis er 3-glycidoxypropyltrimethoxysilan (GLYMO); og (d.3) mindst ét metal M-chelat og/eller et metalalkoxid af generel formel M (OJ)n, hvor n = valens af M og J = Ci-Cs lineært eller forgrenet alkyl, hvor M vælges fra gruppen bestående af: Ti, Zr, Ge, Li, Mn, Fe, Al, Mg, hvor nævnte forbindelse (d.3) er fortrinsvis tert-butyl-titanat.
8. Fremgangsmåde ifølge et hvilket som helst af kravene 1 til 7, i hvilken hæftegrunderener til stede i en mængde på 0,1 til 10 vægtprocent i forhold til alle bestanddelene.
9. Fremgangsmåde ifølge et hvilket som helst af kravene 1 til 8, kendetegnet ved, at det coatede arkitektoniske tekstil, som er en konstituent, er dannet af et fibrøst supportmateriale valgt fra gruppen af materialer omfattende: glas, silika, metaller, keramik, siliciumcarbid, carbon, bor, basalt, naturlige fibre, såsom bomuld, uld, hamp, hør, kunstfibre, såsom viskose eller cellulosefibre, syntetiske fibre, såsom polyestere, polyamider, polyacryler, "chlorfibre", polyolefiner, syntetiske gummier, polyvinylalkohol, aramider, "fluorfibre", phenoler.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0209673A FR2843134B1 (fr) | 2002-07-30 | 2002-07-30 | Procede de traitement par impregnation de textiles architecturaux par une composition silicone reticulable en elastomere et textile architectural ainsi revetu |
| PCT/FR2003/002317 WO2004013403A2 (fr) | 2002-07-30 | 2003-07-22 | Procede de traitement par impregnation de textiles architecturaux par une composition silicone reticulable en elastomere et textile architectural ainsi revetu |
Publications (1)
| Publication Number | Publication Date |
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| DK1525351T3 true DK1525351T3 (da) | 2018-11-19 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
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| DK03750833.0T DK1525351T3 (da) | 2002-07-30 | 2003-07-22 | Fremgangsmåde til behandling af arkitektoniske tekstiler ved hjælp af imprægnering med en tværforbindelig silikoneelastomersammensætning |
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| Country | Link |
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| US (1) | US20060115656A1 (da) |
| EP (1) | EP1525351B1 (da) |
| JP (1) | JP2005534481A (da) |
| CN (1) | CN100390352C (da) |
| AU (1) | AU2003269046A1 (da) |
| CA (1) | CA2493951A1 (da) |
| DK (1) | DK1525351T3 (da) |
| ES (1) | ES2692776T3 (da) |
| FR (1) | FR2843134B1 (da) |
| PT (1) | PT1525351T (da) |
| SI (1) | SI1525351T1 (da) |
| TR (1) | TR201816057T4 (da) |
| WO (1) | WO2004013403A2 (da) |
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| DE102007039263A1 (de) * | 2007-08-20 | 2009-02-26 | Sattler Ag | Selbstklebendes Printmedium |
| US9434137B2 (en) * | 2008-08-08 | 2016-09-06 | Saint-Gobain Performance Plastics Corporation | Thermal spray masking tape |
| EP2331722A4 (en) * | 2008-08-08 | 2013-07-31 | Saint Gobain Performance Plast | COVER BELT FOR THE THERMAL SPRAYING |
| GB0818864D0 (en) * | 2008-10-15 | 2008-11-19 | Dow Corning | Fabric and fibre conditioning additives |
| CN101613952B (zh) * | 2009-07-30 | 2011-06-15 | 中国人民解放军国防科学技术大学 | 连续碳化硅纤维制造用油剂及其应用工艺 |
| BR112012002556B1 (pt) * | 2009-08-04 | 2019-11-05 | Dsm Ip Assets Bv | fibras revestidas de alta resistencia |
| US9593209B2 (en) | 2009-10-22 | 2017-03-14 | Dow Corning Corporation | Process for preparing clustered functional polyorganosiloxanes, and methods for their use |
| FR2957611B1 (fr) * | 2010-03-16 | 2015-03-27 | Jean Charles Barbotin | Nappe architecture en elastomere comportant au moins un trame textile et pouvant etre electro-conductrice |
| EP2954022B1 (en) | 2013-02-11 | 2019-05-01 | Dow Silicones Corporation | Clustered functional polyorganosiloxanes, processes for forming same and methods for their use |
| US9670392B2 (en) | 2013-02-11 | 2017-06-06 | Dow Corning Corporation | Stable thermal radical curable silicone adhesive compositions |
| ES2895424T3 (es) | 2013-02-11 | 2022-02-21 | Dow Silicones Corp | Composiciones adhesivas de silicona termofusibles curables por humedad que incluyen una resina reactiva de siloxano con grupos alcoxi funcionales |
| CN105189685B (zh) * | 2013-02-11 | 2017-08-08 | 道康宁公司 | 用于形成导热热自由基固化有机硅组合物的方法 |
| US9718925B2 (en) | 2013-02-11 | 2017-08-01 | Dow Corning Corporation | Curable silicone compositions comprising clustered functional polyorganosiloxanes and silicone reactive diluents |
| WO2014124388A1 (en) | 2013-02-11 | 2014-08-14 | Dow Corning Corporation | Alkoxy-functional organopolysiloxane resin and polymer and related methods for forming same |
| US20140272409A1 (en) * | 2013-03-14 | 2014-09-18 | Samson Rope Technologies | Fiber structures, systems, and methods for fabricating rope structures with improved lubricity |
| CN103132327B (zh) * | 2013-03-18 | 2014-07-09 | 中国人民解放军国防科学技术大学 | 一种连续SiC纤维用上浆剂及其制备方法与应用 |
| CN104176973B (zh) * | 2013-05-23 | 2016-09-07 | 闫炳润 | 硅烷水泥混凝土防腐防水剂及其制备方法 |
| CN104694004B (zh) * | 2015-02-17 | 2020-03-31 | 成都拓利科技股份有限公司 | 一种无溶剂防污闪有机硅涂料及其制备方法 |
| US9573661B1 (en) | 2015-07-16 | 2017-02-21 | Samson Rope Technologies | Systems and methods for controlling recoil of rope under failure conditions |
| JP6699569B2 (ja) * | 2017-01-23 | 2020-05-27 | 信越化学工業株式会社 | 自己接着性シリコーンゲル組成物及びその硬化物、並びに封止方法及び充填方法 |
| KR102394963B1 (ko) | 2017-02-08 | 2022-05-04 | 엘켐 실리콘즈 유에스에이 코포레이션 | 열 관리가 개선된 이차 배터리 팩 |
| KR102457711B1 (ko) * | 2017-03-15 | 2022-10-24 | 신에쓰 가가꾸 고교 가부시끼가이샤 | 난연성 에어백, 난연성 에어백의 제조 방법, 및 난연성 에어백용 부가 경화형 액상 실리콘 고무 조성물 |
| NL2018671B1 (en) * | 2017-04-10 | 2018-10-19 | Klomp Beheer B V | Method for providing objects with a protective coating of silicone elastomer |
| KR101864422B1 (ko) * | 2017-11-28 | 2018-06-05 | (주)제이에스바이오코켐 | 합성직물원단용 실리콘 코팅제 및 합성직물원단에 실리콘 코팅제를 코팅하는 방법 |
| FR3084281B1 (fr) * | 2018-07-25 | 2020-12-25 | Ferrari Serge Sas | Membrane non combustible imper-respirante |
| CN112812737B (zh) * | 2021-01-07 | 2022-11-25 | 成都民航六维航化有限责任公司 | 一种用于飞机防火墙耐高温阻燃的有机硅密封剂 |
| CN116289225B (zh) * | 2021-12-20 | 2024-04-02 | 四川大学 | 一种基于聚联硼硅氧烷改性的纤维及其制备方法 |
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| JP3268801B2 (ja) * | 1991-11-22 | 2002-03-25 | ジーイー東芝シリコーン株式会社 | シリコーンゴム組成物およびシリコーンゴム加工布 |
| US5401566A (en) * | 1993-08-26 | 1995-03-28 | Wacker Silicones Corporation | Coated fabrics for air bags |
| JP2938340B2 (ja) * | 1994-03-29 | 1999-08-23 | 信越化学工業株式会社 | 熱伝導性複合シート |
| DE19645721A1 (de) * | 1996-11-06 | 1998-05-07 | Wacker Chemie Gmbh | Vernetzbare Organopolysiloxanmassen |
-
2002
- 2002-07-30 FR FR0209673A patent/FR2843134B1/fr not_active Expired - Lifetime
-
2003
- 2003-07-22 SI SI200332581T patent/SI1525351T1/sl unknown
- 2003-07-22 ES ES03750833.0T patent/ES2692776T3/es not_active Expired - Lifetime
- 2003-07-22 US US10/522,705 patent/US20060115656A1/en not_active Abandoned
- 2003-07-22 TR TR2018/16057T patent/TR201816057T4/tr unknown
- 2003-07-22 WO PCT/FR2003/002317 patent/WO2004013403A2/fr not_active Ceased
- 2003-07-22 AU AU2003269046A patent/AU2003269046A1/en not_active Abandoned
- 2003-07-22 JP JP2004525464A patent/JP2005534481A/ja active Pending
- 2003-07-22 CA CA 2493951 patent/CA2493951A1/fr not_active Abandoned
- 2003-07-22 DK DK03750833.0T patent/DK1525351T3/da active
- 2003-07-22 EP EP03750833.0A patent/EP1525351B1/fr not_active Expired - Lifetime
- 2003-07-22 CN CNB038206196A patent/CN100390352C/zh not_active Expired - Lifetime
- 2003-07-22 PT PT03750833T patent/PT1525351T/pt unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CN1697900A (zh) | 2005-11-16 |
| ES2692776T3 (es) | 2018-12-05 |
| WO2004013403A3 (fr) | 2004-04-08 |
| FR2843134A1 (fr) | 2004-02-06 |
| SI1525351T1 (sl) | 2018-12-31 |
| US20060115656A1 (en) | 2006-06-01 |
| EP1525351B1 (fr) | 2018-08-08 |
| WO2004013403A2 (fr) | 2004-02-12 |
| EP1525351A2 (fr) | 2005-04-27 |
| FR2843134B1 (fr) | 2006-09-22 |
| PT1525351T (pt) | 2018-11-15 |
| AU2003269046A1 (en) | 2004-02-23 |
| TR201816057T4 (tr) | 2018-11-21 |
| CA2493951A1 (fr) | 2004-02-12 |
| CN100390352C (zh) | 2008-05-28 |
| JP2005534481A (ja) | 2005-11-17 |
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