DK166644B1 - Fremgangsmaade til fremstilling af en stabil 5-chlor-4-isothiazolin-3-onoploesning og anvendelse af denne oploesning som biocid eller konserveringsmiddel - Google Patents

Fremgangsmaade til fremstilling af en stabil 5-chlor-4-isothiazolin-3-onoploesning og anvendelse af denne oploesning som biocid eller konserveringsmiddel Download PDF

Info

Publication number: DK166644B1
Authority: DK; Denmark
Prior art keywords: solution; hydrogen; polyol; solvent; salt
Prior art date: 1985-03-08

Application number

DK073286A

Other languages

Danish (da)

English (en)

Other versions

DK73286D0 (da

DK73286A (da

Inventor

David Richard Amick

Original Assignee

Rohm & Haas

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1985-03-08

Filing date

1986-02-14

Publication date

1993-06-28

Family has litigation

First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=24851196&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=DK166644(B1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.

1986-02-14 Application filed by Rohm & Haas filed Critical Rohm & Haas

1986-02-14 Publication of DK73286D0 publication Critical patent/DK73286D0/da

1986-09-09 Publication of DK73286A publication Critical patent/DK73286A/da

1993-06-28 Application granted granted Critical

1993-06-28 Publication of DK166644B1 publication Critical patent/DK166644B1/da

Links

238000000034 method Methods 0.000 title claims description 10
150000003839 salts Chemical class 0.000 claims abstract description 20
239000002904 solvent Substances 0.000 claims abstract description 18
229910052739 hydrogen Inorganic materials 0.000 claims abstract description 9
125000000217 alkyl group Chemical group 0.000 claims abstract description 8
239000001257 hydrogen Substances 0.000 claims abstract description 8
XFIPRDRBFGJGIZ-UHFFFAOYSA-N 5-chloro-1,2-thiazol-3-one Chemical class ClC1=CC(=O)NS1 XFIPRDRBFGJGIZ-UHFFFAOYSA-N 0.000 claims abstract description 6
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 6
239000007864 aqueous solution Substances 0.000 claims abstract description 4
230000003115 biocidal effect Effects 0.000 claims abstract description 4
230000002335 preservative effect Effects 0.000 claims abstract description 3
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 18
229920005862 polyol Polymers 0.000 claims description 9
150000003077 polyols Chemical class 0.000 claims description 9
230000000087 stabilizing effect Effects 0.000 claims description 8
239000000243 solution Substances 0.000 claims description 7
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 6
239000003755 preservative agent Substances 0.000 claims description 5
VUWCWMOCWKCZTA-UHFFFAOYSA-N 1,2-thiazol-4-one Chemical class O=C1CSN=C1 VUWCWMOCWKCZTA-UHFFFAOYSA-N 0.000 claims description 4
239000003139 biocide Substances 0.000 claims description 4
229910002651 NO3 Inorganic materials 0.000 claims description 3
NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 3
ALQSHHUCVQOPAS-UHFFFAOYSA-N Pentane-1,5-diol Chemical compound OCCCCCO ALQSHHUCVQOPAS-UHFFFAOYSA-N 0.000 claims description 3
DHNRXBZYEKSXIM-UHFFFAOYSA-N chloromethylisothiazolinone Chemical compound CN1SC(Cl)=CC1=O DHNRXBZYEKSXIM-UHFFFAOYSA-N 0.000 claims description 3
229920001451 polypropylene glycol Polymers 0.000 claims description 3
229940100484 5-chloro-2-methyl-4-isothiazolin-3-one Drugs 0.000 claims description 2
125000004432 carbon atom Chemical group C* 0.000 claims description 2
150000002431 hydrogen Chemical group 0.000 claims description 2
238000004519 manufacturing process Methods 0.000 claims description 2
SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 claims 1
ZLTPDFXIESTBQG-UHFFFAOYSA-N isothiazole Chemical compound C=1C=NSC=1 ZLTPDFXIESTBQG-UHFFFAOYSA-N 0.000 claims 1
239000000203 mixture Substances 0.000 abstract description 5
230000006641 stabilisation Effects 0.000 abstract description 4
238000011105 stabilization Methods 0.000 abstract description 4
JLHMJWHSBYZWJJ-UHFFFAOYSA-N 1,2-thiazole 1-oxide Chemical compound O=S1C=CC=N1 JLHMJWHSBYZWJJ-UHFFFAOYSA-N 0.000 abstract description 2
125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 3
238000002144 chemical decomposition reaction Methods 0.000 abstract 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
239000004480 active ingredient Substances 0.000 description 6
230000015572 biosynthetic process Effects 0.000 description 6
239000000047 product Substances 0.000 description 6
239000002537 cosmetic Substances 0.000 description 4
239000006185 dispersion Substances 0.000 description 4
239000000446 fuel Substances 0.000 description 4
238000004128 high performance liquid chromatography Methods 0.000 description 4
239000003921 oil Substances 0.000 description 4
ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
239000000839 emulsion Substances 0.000 description 3
238000006386 neutralization reaction Methods 0.000 description 3
150000002823 nitrates Chemical class 0.000 description 3
238000002360 preparation method Methods 0.000 description 3
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
150000001412 amines Chemical class 0.000 description 2
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
230000007797 corrosion Effects 0.000 description 2
238000005260 corrosion Methods 0.000 description 2
230000000694 effects Effects 0.000 description 2
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
238000009472 formulation Methods 0.000 description 2
IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 2
229910000041 hydrogen chloride Inorganic materials 0.000 description 2
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
150000004005 nitrosamines Chemical class 0.000 description 2
239000012457 nonaqueous media Substances 0.000 description 2
150000007530 organic bases Chemical class 0.000 description 2
239000003960 organic solvent Substances 0.000 description 2
238000001556 precipitation Methods 0.000 description 2
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
239000003381 stabilizer Substances 0.000 description 2
GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 2
FKPCCLRWSGMEJU-UHFFFAOYSA-N 1,2-thiazole 1-oxide;hydrochloride Chemical compound Cl.O=S1C=CC=N1 FKPCCLRWSGMEJU-UHFFFAOYSA-N 0.000 description 1
QCQCHGYLTSGIGX-GHXANHINSA-N 4-[[(3ar,5ar,5br,7ar,9s,11ar,11br,13as)-5a,5b,8,8,11a-pentamethyl-3a-[(5-methylpyridine-3-carbonyl)amino]-2-oxo-1-propan-2-yl-4,5,6,7,7a,9,10,11,11b,12,13,13a-dodecahydro-3h-cyclopenta[a]chrysen-9-yl]oxy]-2,2-dimethyl-4-oxobutanoic acid Chemical compound N([C@@]12CC[C@@]3(C)[C@]4(C)CC[C@H]5C(C)(C)[C@@H](OC(=O)CC(C)(C)C(O)=O)CC[C@]5(C)[C@H]4CC[C@@H]3C1=C(C(C2)=O)C(C)C)C(=O)C1=CN=CC(C)=C1 QCQCHGYLTSGIGX-GHXANHINSA-N 0.000 description 1
229920001131 Pulp (paper) Polymers 0.000 description 1
239000011230 binding agent Substances 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
230000000711 cancerogenic effect Effects 0.000 description 1
231100000315 carcinogenic Toxicity 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
238000001816 cooling Methods 0.000 description 1
239000010730 cutting oil Substances 0.000 description 1
-1 cyclic tertiary amines Chemical class 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
230000008030 elimination Effects 0.000 description 1
238000003379 elimination reaction Methods 0.000 description 1
239000004744 fabric Substances 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
150000002484 inorganic compounds Chemical class 0.000 description 1
229910010272 inorganic material Inorganic materials 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
MGIYRDNGCNKGJU-UHFFFAOYSA-N isothiazolinone Chemical compound O=C1C=CSN1 MGIYRDNGCNKGJU-UHFFFAOYSA-N 0.000 description 1
239000010985 leather Substances 0.000 description 1
238000010907 mechanical stirring Methods 0.000 description 1
239000002184 metal Substances 0.000 description 1
229910001960 metal nitrate Inorganic materials 0.000 description 1
BEGLCMHJXHIJLR-UHFFFAOYSA-N methylisothiazolinone Chemical compound CN1SC=CC1=O BEGLCMHJXHIJLR-UHFFFAOYSA-N 0.000 description 1
230000003641 microbiacidal effect Effects 0.000 description 1
229940124561 microbicide Drugs 0.000 description 1
230000003472 neutralizing effect Effects 0.000 description 1
XKLJHFLUAHKGGU-UHFFFAOYSA-N nitrous amide Chemical compound ON=N XKLJHFLUAHKGGU-UHFFFAOYSA-N 0.000 description 1
125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
239000011368 organic material Substances 0.000 description 1
229920000620 organic polymer Polymers 0.000 description 1
239000003973 paint Substances 0.000 description 1
XLMFDCKSFJWJTP-UHFFFAOYSA-N pentane-2,3-diol Chemical compound CCC(O)C(C)O XLMFDCKSFJWJTP-UHFFFAOYSA-N 0.000 description 1
125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
239000002243 precursor Substances 0.000 description 1
UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
230000035939 shock Effects 0.000 description 1
239000010802 sludge Substances 0.000 description 1
239000007787 solid Substances 0.000 description 1
238000003860 storage Methods 0.000 description 1
125000001424 substituent group Chemical group 0.000 description 1
239000000758 substrate Substances 0.000 description 1
125000005270 trialkylamine group Chemical group 0.000 description 1
ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
YFTHZRPMJXBUME-UHFFFAOYSA-N tripropylamine Chemical compound CCCN(CCC)CCC YFTHZRPMJXBUME-UHFFFAOYSA-N 0.000 description 1
239000002023 wood Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D275/00—Heterocyclic compounds containing 1,2-thiazole or hydrogenated 1,2-thiazole rings
- C07D275/02—Heterocyclic compounds containing 1,2-thiazole or hydrogenated 1,2-thiazole rings not condensed with other rings
- C07D275/03—Heterocyclic compounds containing 1,2-thiazole or hydrogenated 1,2-thiazole rings not condensed with other rings with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/22—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing ingredients stabilising the active ingredients
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2

Landscapes

Life Sciences & Earth Sciences (AREA)
General Health & Medical Sciences (AREA)
Organic Chemistry (AREA)
Health & Medical Sciences (AREA)
Chemical & Material Sciences (AREA)
Dentistry (AREA)
Zoology (AREA)
Plant Pathology (AREA)
Environmental Sciences (AREA)
Engineering & Computer Science (AREA)
Agronomy & Crop Science (AREA)
Wood Science & Technology (AREA)
Pest Control & Pesticides (AREA)
Toxicology (AREA)
Agricultural Chemicals And Associated Chemicals (AREA)
Thiazole And Isothizaole Compounds (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Cosmetics (AREA)
Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Plural Heterocyclic Compounds (AREA)

DK073286A 1985-03-08 1986-02-14 Fremgangsmaade til fremstilling af en stabil 5-chlor-4-isothiazolin-3-onoploesning og anvendelse af denne oploesning som biocid eller konserveringsmiddel DK166644B1 (da)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US70975585A	1985-03-08	1985-03-08
US70975585		1985-03-08

Publications (3)

Publication Number	Publication Date
DK73286D0 DK73286D0 (da)	1986-02-14
DK73286A DK73286A (da)	1986-09-09
DK166644B1 true DK166644B1 (da)	1993-06-28

Family

ID=24851196

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DK073286A DK166644B1 (da)	1985-03-08	1986-02-14	Fremgangsmaade til fremstilling af en stabil 5-chlor-4-isothiazolin-3-onoploesning og anvendelse af denne oploesning som biocid eller konserveringsmiddel

Country Status (16)

Country	Link
EP (1)	EP0194146B2 (fr)
JP (1)	JPH0657702B2 (fr)
AT (1)	ATE43337T1 (fr)
AU (1)	AU588574B2 (fr)
BR (1)	BR8600818A (fr)
CA (1)	CA1264660A (fr)
DE (1)	DE3663517D1 (fr)
DK (1)	DK166644B1 (fr)
ES (1)	ES8802422A1 (fr)
GR (1)	GR860555B (fr)
HU (1)	HU198914B (fr)
IL (1)	IL78022A (fr)
MX (1)	MX166403B (fr)
NO (1)	NO167781C (fr)
PT (1)	PT82140B (fr)
ZA (1)	ZA861556B (fr)

Families Citing this family (30)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
USRE34185E (en) *	1985-03-08	1993-02-23	Rohm And Haas Company	Stabilization of non-aqueous solutions of 3-isothiazolones
US4824957A (en) *	1985-03-08	1989-04-25	Rohm And Haas Commpany	Stabilization of non-aqueous solutions of 3-isothiazolones
CA1334824C (fr) *	1987-02-11	1995-03-21	Stewart Nelson Paul	Protecteurs de biocides
IL87111A (en) *	1987-07-23	1994-02-27	Bromine Compounds Ltd	Method for stabilizing compositions of isothiazolinones
US4906274A (en) *	1987-11-06	1990-03-06	Rohm And Haas Company	Organic stabilizers
JPH01175905A (ja) *	1987-12-29	1989-07-12	Katayama Chem Works Co Ltd	イソチアゾロン含有非医療用殺菌水性製剤
CA1328175C (fr) *	1988-05-16	1994-04-05	John Robert Mattox	Stabilisants a epoxyde pour compositions biocides
DE68904828T2 (de) *	1988-06-08	1993-06-03	Ichikawa Gosei Kagaku Kk	Verfahren zur stabilisierung einer 3-isothiazolon-loesung.
JPH0745366B2 (ja) *	1988-12-12	1995-05-17	治梅川	安定な工業用殺菌組成物
US5198455A (en) *	1989-01-03	1993-03-30	Rohm And Haas Company	Organic stabilizers
GB8902449D0 (en) *	1989-02-03	1989-03-22	Rohm & Haas	Antisapstain wood treatment
GB8913513D0 (en) *	1989-06-13	1989-08-02	Ici Plc	Composition
JPH0641457B2 (ja) *	1989-07-17	1994-06-01	ソマール株式会社	イソチアゾロン系化合物の安定化溶液
CA2027241A1 (fr) *	1989-10-24	1991-04-25	Andrew B. Law	Combinaisons stabilisees a base de sel metallique et de 3-isothiazolone
US5112396A (en) *	1990-02-05	1992-05-12	Rohm And Haas Company	Anti-sapstain wood treatment
GB9003871D0 (en) *	1990-02-21	1990-04-18	Rohm & Haas	Stabilization of isothiazolones
IL96820A (en) *	1990-12-28	1995-06-29	Bromine Compounds Ltd	Stabilized isothiazolinone formulations
US5160526A (en) *	1991-11-21	1992-11-03	Rohm And Haas Company	Alkene stabilizers for 3-isothiazolone compounds
JP3558368B2 (ja) *	1994-06-06	2004-08-25	ロームアンドハースカンパニー	３−イソチアゾロンおよび安定剤を含有する水性組成物
US5716917A (en) *	1996-09-24	1998-02-10	Cincinnati Milacron Inc.	Machining fluid composition and method of machining
US5807503A (en) *	1997-09-08	1998-09-15	Morton International, Inc.	Low temperature-stabilized isothiazolinone concentrates
US6322778B1 (en)	1998-02-10	2001-11-27	Johnson & Johnson Consumer Companies, Inc.	Hair conditioning compositions comprising a quaternary ammonium compound
JP3722268B2 (ja)	1998-09-03	2005-11-30	栗田工業株式会社	抗菌性組成物
US6403533B2 (en) *	2000-01-27	2002-06-11	Rohm And Haas Company	Stabilized microbicide formulation
EP1161866A1 (fr)	2000-06-07	2001-12-12	Aventis CropScience S.A.	Nouvelles compositions herbicides
EP1161868A1 (fr) *	2000-06-07	2001-12-12	Aventis Cropscience S.A.	Nouvelles compositions herbicides
ES2264605B1 (es) *	2004-07-02	2007-12-16	Labiana Development, S.L.	"procedimiento para la obtencion de 2-alquilisotiazolonas y de sus formulaciones en forma estable solas o asociadas a otras moleculas con actividad biocida".
DE102005012123A1 (de)	2005-03-16	2006-09-28	Schülke & Mayr GmbH	Isothiazolon-haltiges Konservierungsmittel mit verbesserter Wirksamkeit
AU2007202261B2 (en) *	2006-06-02	2012-06-28	Rohm And Haas Company	Microbicidal composition
US12408668B2 (en)	2019-06-03	2025-09-09	Chemicrea Inc.	Stable microbicide composition

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4241214A (en) *	1971-05-12	1980-12-23	Rohm And Haas Company	Metal salt complexes of 3-isothiazolones
US3870795A (en) *	1973-02-28	1975-03-11	Rohm & Haas	Stabilization of solutions of 3-isothiazolones employing certain metal nitrates and nitrites
US4067878A (en) *	1976-03-05	1978-01-10	Rohm And Haas Company	Stabilization of solutions of 3-isothiazolones
GB2004747B (en) *	1977-09-30	1982-02-17	Ici Ltd	Compositions of matter
JPS6021564B2 (ja) *	1979-07-25	1985-05-28	クミアイ化学工業株式会社	防菌防藻剤
JPS5754104A (ja) *	1980-09-18	1982-03-31	Takeda Chem Ind Ltd	Satsukinsoseibutsu
IL75598A (en) *	1984-06-27	1990-07-12	Rohm & Haas	Stabilized aqueous solutions of 5-chloro-3-isothiazolones,their preparation and their use
GB8416314D0 (en) *	1984-06-27	1984-08-01	Rohm & Haas	Stabilization of aqueous solutions

1986
- 1986-02-14 DK DK073286A patent/DK166644B1/da not_active IP Right Cessation
- 1986-02-24 CA CA000502523A patent/CA1264660A/fr not_active Expired - Fee Related
- 1986-02-26 BR BR8600818A patent/BR8600818A/pt not_active IP Right Cessation
- 1986-02-27 GR GR860555A patent/GR860555B/el unknown
- 1986-03-03 IL IL78022A patent/IL78022A/xx not_active IP Right Cessation
- 1986-03-03 AU AU54326/86A patent/AU588574B2/en not_active Ceased
- 1986-03-03 ZA ZA861556A patent/ZA861556B/xx unknown
- 1986-03-04 MX MX001752A patent/MX166403B/es unknown
- 1986-03-05 ES ES552685A patent/ES8802422A1/es not_active Expired
- 1986-03-05 PT PT82140A patent/PT82140B/pt not_active IP Right Cessation
- 1986-03-05 NO NO860817A patent/NO167781C/no unknown
- 1986-03-06 DE DE8686301579T patent/DE3663517D1/de not_active Expired
- 1986-03-06 EP EP86301579A patent/EP0194146B2/fr not_active Expired - Lifetime
- 1986-03-06 AT AT86301579T patent/ATE43337T1/de not_active IP Right Cessation
- 1986-03-07 JP JP61050263A patent/JPH0657702B2/ja not_active Expired - Lifetime
- 1986-03-07 HU HU86974A patent/HU198914B/hu not_active IP Right Cessation

Also Published As

Publication number	Publication date
JPS61212576A (ja)	1986-09-20
EP0194146B1 (fr)	1989-05-24
ES552685A0 (es)	1988-06-01
NO167781B (no)	1991-09-02
BR8600818A (pt)	1986-11-11
NO860817L (no)	1986-09-09
ZA861556B (en)	1987-05-27
GR860555B (en)	1986-06-06
JPH0657702B2 (ja)	1994-08-03
EP0194146B2 (fr)	1994-01-26
DK73286D0 (da)	1986-02-14
ES8802422A1 (es)	1988-06-01
IL78022A (en)	1990-08-31
MX166403B (es)	1993-01-07
EP0194146A2 (fr)	1986-09-10
PT82140B (pt)	1988-04-21
NO167781C (no)	1991-12-11
AU5432686A (en)	1986-09-11
HUT42462A (en)	1987-07-28
AU588574B2 (en)	1989-09-21
DE3663517D1 (en)	1989-06-29
PT82140A (en)	1986-04-01
EP0194146A3 (en)	1986-12-30
DK73286A (da)	1986-09-09
HU198914B (en)	1989-12-28
CA1264660A (fr)	1990-01-23
IL78022A0 (en)	1986-07-31
ATE43337T1 (de)	1989-06-15

Legal Events

Date	Code	Title	Description
1993-06-28	B1	Patent granted (law 1993)
1999-05-17	PBP	Patent lapsed

Publication	Publication Date	Title
DK166644B1 (da)	1993-06-28	Fremgangsmaade til fremstilling af en stabil 5-chlor-4-isothiazolin-3-onoploesning og anvendelse af denne oploesning som biocid eller konserveringsmiddel
EP0166611B2 (fr)	1999-03-10	Stabilisation de solutions aqueuses de 5-chloro-3-isothiazolones
US5376695A (en)	1994-12-27	Stabilized aqueous solutions of 3-isothiazolones
KR970007930B1 (ko)	1997-05-19	유기 안정제
KR0136103B1 (ko)	1998-04-25	안정된 3-이소티아졸론 조성물 및 그 이용방법
US4824957A (en)	1989-04-25	Stabilization of non-aqueous solutions of 3-isothiazolones
DK150693B (da)	1987-06-01	Kemisk forbindelse med fungicid virkning til ikke-laegemiddelanvendelse, og anvendelse deraf
KR0171601B1 (ko)	1999-02-01	3-이소티아졸론의 안정화방법 및 안정한 3-이소티아졸론 조성물
KR0158368B1 (ko)	1998-11-16	안정화 3-이소티아졸론 조성물 및 그 용법
KR0151951B1 (ko)	1998-10-01	안정화 이소티아졸론 살균조성물
USRE34185E (en)	1993-02-23	Stabilization of non-aqueous solutions of 3-isothiazolones
EP0447041A1 (fr)	1991-09-18	Utilisation d'hexaméthylènetétramine comme stabilisateur pour des 3-isothiazolones
KR100385714B1 (ko)	2003-05-27	안정화된 이소티아졸론 용액 및 이소티아졸론의 안정화 방법
JPH0310622B2 (fr)	1991-02-14
US5534487A (en)	1996-07-09	Stabilization of 3-isothiazolone solutions
US3973034A (en)	1976-08-03	Certain stabilized dithiocarbomate pesticidal compositions and methods of using same
IE64269B1 (en)	1995-07-26	Organic stabilizers for isothiazolones
KR100240122B1 (ko)	2000-02-01	이소티아졸론 무수용액 제조 방법
KR100324907B1 (ko)	2004-12-17	안정화된 이소티아졸론 조성물
KR100421127B1 (ko)	2004-05-24	3-이소티아졸론및안정화제를함유한수성조성물
SU265611A1 (fr)
US2883408A (en)	1959-04-21	Lower alkyl mercury salts of hydroxylower-alkyl mercaptans
KR100324908B1 (ko)	2004-12-17	안정화된3-이소티아졸론용액
PL248343B1 (pl)	2025-12-01	Czwartorzędowe sole amoniowe z kationem 1-alkilochininy oraz anionem 4-chloro-2-metylofenoksyoctanowym, sposób ich otrzymywania oraz zastosowanie jako algicydy