DK2173176T3 - Fremgangsmåder og formuleringer til reducering og hæmning af vækst af koncentrationen af mikrober i vandbaserede fluider - Google Patents
Fremgangsmåder og formuleringer til reducering og hæmning af vækst af koncentrationen af mikrober i vandbaserede fluider Download PDFInfo
- Publication number
- DK2173176T3 DK2173176T3 DK08826631.7T DK08826631T DK2173176T3 DK 2173176 T3 DK2173176 T3 DK 2173176T3 DK 08826631 T DK08826631 T DK 08826631T DK 2173176 T3 DK2173176 T3 DK 2173176T3
- Authority
- DK
- Denmark
- Prior art keywords
- water
- hydroxymethyl
- tetrakis
- glutaraldehyde
- phosphonium sulfate
- Prior art date
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Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N35/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical
- A01N35/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical containing aliphatically bound aldehyde or keto groups, or thio analogues thereof; Derivatives thereof, e.g. acetals
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/50—Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M141/00—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential
- C10M141/10—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential at least one of them being an organic phosphorus-containing compound
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/08—Aldehydes; Ketones
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/16—Nitriles
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/20—Containing nitrogen-to-oxygen bonds
- C10M2215/202—Containing nitrogen-to-oxygen bonds containing nitro groups
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/22—Heterocyclic nitrogen compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
- C10M2219/104—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/06—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/16—Antiseptic; (micro) biocidal or bactericidal
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Plant Pathology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Dentistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Materials Engineering (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Purification Treatments By Anaerobic Or Anaerobic And Aerobic Bacteria Or Animals (AREA)
- Pest Control & Pesticides (AREA)
- Treatment Of Biological Wastes In General (AREA)
Claims (10)
1. Fremgangsmåde til reducering eller hæmning afvækst i koncentrationen af anaerobe mikrober i en vandbaseret fluid i et anaerobt miljø eller i en anaerob del af et system, der anvendes med en vand baseret fluid, hvilken fremgangsmåde omfatter: etablering af kontakt mellem den vandbaserede fluid og glutaraldehyd samt tetrakis(hydroxymethyl)phosphoniumsulfat, hvor vægtforholdet mellem tetrakis(hydroxymethyl)phosphoniumsulfat og glutaraldehyd ligger i intervallet fra 3,5:1 til 6:1; og den vandbaserede fluid under kontakttrinet er i det væsentlige fri for kvaternære ammoniumforbindelser og addukter mellem formaldehyde og C2-C6-alifatisk glycol eller C2-C6-alifatisk glycol(mono-Ci-C4-alkylether).
2. Fremgangsmåde ifølge krav 1, hvor den vandbaserede fluid er vand eller fluid fra et oliefelt eller gasfelt, carbonhydridolie og -gas, pulp- eller papirvand eller opslæmning, kølevand, kedelvand, industrielt procesvand, ballastvand, spildevand, en metalforarbejdningsfluid, en vandbaseret opslæmning, en blæk eller tapesamlingsforbindelse, et vandbaseret husholdningsprodukt eller et personligt plejeprodukt, latex, maling, en belægning eller et system, der anvendes dermed.
3. Fremgangsmåde ifølge krav 1 eller krav 2, hvor den kombinerede koncentration af glutaraldehyd og tetrakis(hydroxymethyl)phosphoniumsulfat i den vandbaserede fluid ligger i intervallet fra 5 ppm til 1500 ppm.
4. Fremgangsmåde ifølge krav 1 eller krav 2, hvor den kombinerede koncentration af glutaraldehyd og tetrakis(hydroxymethyl)phosphoniumsulfat i den vandbaserede fluid ligger i intervallet fra 10 ppm til 500 ppm.
5. Fremgangsmåde ifølge et hvilket som helst af kravene 1-4, hvor den vandbaserede fluid under kontakttrinet indbefatter mindst én anionisk polymer, ét demulgeringsmiddel, én korrosionshæmmer, én kedelstenshæmmer og/eller ét overfladeaktivt stof.
6. Fremgangsmåde ifølge et hvilket som helst af kravene 1-5, hvor glutaraldehyd og tetrakis(hydroxymethyl)phosphoniumsulfat tilsættes til den vandbaserede fluid i det væsentlige samtidig.
7. Fremgangsmåde ifølge krav 1, hvor kontakten omfatter: etablering af kontakt mellem den vandbaserede fluid og glutaraldehyd samt tetrakis(hydroxymethyl)phosphoniumsulfat ved et første forhold mellem tetrakis(hydroxymethyl)phosphoniumsulfatog glutaraldehyd i intervallet fra 3,5:1 til 6:1; og etablering af kontakt mellem den vandbaserede fluid og glutaraldehyd samt tetrakis(hydroxymethyl)phosphoniumsulfat ved et andet forhold mellem tetrakis(hydroxymethyl)phosphoniumsulfatog glutaraldehyd i intervallet fra 3,5:1 til 6:1, hvor det første forhold er forskelligt fra det andet forhold.
8. Formulering til reducering eller hæmning afvækst i koncentrationen af anaerobe mikrober i en vandbaseret fluid i et anaerobt miljø eller i en anaerob del af et system, der anvendes med en vand baseret fluid, hvilken formulering omfatter: glutaraldehyd og tetrakis(hydroxymethyl)phosphoniumsulfat; hvor formuleringen er fri for kvaternære ammoniumforbindelser og addukter mellem formaldehyd og C2-C6-alifatisk glycol eller C2-C6-alifatisk glycol(mono-CrC4-alkylether), og forholdet mellem tetrakis(hydroxymethyl)phosphoniumsulfat og glutaraldehyd ligger i intervallet fra 3,5:1 til 6:1.
9. Formulering ifølge krav 8, der yderligere omfatter vand.
10. Formulering ifølge krav 8 eller krav 9, hvor formuleringen indbefatter mindst én anionisk polymer, ét demulgeringsmiddel, én korrosionshæmmer, én kedelstenshæmmer og/eller ét overfladeaktivt stof.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US95161607P | 2007-07-24 | 2007-07-24 | |
| PCT/US2008/070652 WO2009015089A2 (en) | 2007-07-24 | 2008-07-21 | Methods of and formulations for reducing and inhibiting the growth of the concentration of microbes in water-based fluids and systems used with them |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DK2173176T3 true DK2173176T3 (da) | 2017-12-04 |
Family
ID=40282107
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DK08826631.7T DK2173176T3 (da) | 2007-07-24 | 2008-07-21 | Fremgangsmåder og formuleringer til reducering og hæmning af vækst af koncentrationen af mikrober i vandbaserede fluider |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US8952199B2 (da) |
| EP (1) | EP2173176B1 (da) |
| AR (1) | AR068085A1 (da) |
| BR (1) | BRPI0812700B1 (da) |
| DK (1) | DK2173176T3 (da) |
| NO (1) | NO2173176T3 (da) |
| WO (1) | WO2009015089A2 (da) |
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9139796B2 (en) | 2007-07-24 | 2015-09-22 | Dow Global Technologies Llc | Methods of and formulations for reducing and inhibiting the growth of the concentration of microbes in water-based fluids and systems used with them |
| US8778370B2 (en) * | 2009-01-16 | 2014-07-15 | Sterilex Corporation | Method and composition for inhibiting growth of microorganisms in industrial process waters in the presence of anionic anti-fouling additives |
| CA2752474C (en) * | 2009-02-12 | 2017-06-20 | Rhodia Operations | Methods for controlling depolymerization of polymer compositions |
| AU2014201142B2 (en) * | 2009-05-26 | 2015-07-02 | Dow Global Technologies Llc | Glutaraldehyde based biocidal compositions and methods of use |
| EP2458986B1 (en) * | 2009-07-27 | 2016-08-31 | Dow Global Technologies LLC | Synergistic antimicrobial composition |
| EP2485588B1 (en) * | 2009-10-20 | 2013-12-11 | Dow Global Technologies LLC | Synergistic antimicrobial composition |
| US10301454B2 (en) * | 2010-12-08 | 2019-05-28 | Juan Antonio MAYER GOYENECHEA CABALLERO | Water-based elastomeric composition for impregnating textile material and uses thereof |
| GB2488768A (en) * | 2011-03-07 | 2012-09-12 | Rhodia Operations | Treatment of hydrocarbon-containing systems |
| CA2844824A1 (en) | 2011-09-15 | 2013-03-21 | Dow Global Technologies Llc | Biocidal compositions and methods of use |
| BR112014007445B1 (pt) | 2011-10-13 | 2019-05-07 | Dow Global Technologies Llc | Composição, e, método para o controle de micro-orgasnismos em um sistema aquoso ou que contém água. |
| US9018141B2 (en) | 2012-01-06 | 2015-04-28 | Kemira Oyj | Biocidal system and methods of use |
| CN103803761A (zh) * | 2014-02-27 | 2014-05-21 | 常州大学 | 撬装式采油废水处理设备 |
| CN104430494A (zh) * | 2014-12-05 | 2015-03-25 | 中国石油天然气股份有限公司 | 一种适合化学驱的杀菌剂及其制备方法与应用 |
| CN107399864A (zh) * | 2017-08-17 | 2017-11-28 | 河海大学 | 一种高含盐含油废水综合处理系统及工艺 |
| US20200390102A1 (en) | 2017-12-19 | 2020-12-17 | DDP Specialty Electronic Materials US, Inc. | Synergistic antimicrobial composition |
| BR112022024705A2 (pt) | 2020-06-04 | 2023-02-28 | Nutrition & Biosciences Usa 4 Inc | Composição, método para produzir um composto de éter ou éster de copolímero de enxerto, método de floculação e método de absorção |
| CN112479491A (zh) * | 2020-11-18 | 2021-03-12 | 三桶油环保科技(宜兴)有限公司 | 一种压裂返排液深度处理及排放方法 |
| WO2022178073A1 (en) | 2021-02-19 | 2022-08-25 | Nutrition & Biosciences USA 4, Inc. | Polysaccharide derivatives for detergent compositions |
| EP4334364A1 (en) | 2021-05-04 | 2024-03-13 | Nutrition & Biosciences USA 4, Inc. | Compositions comprising oxidized insoluble alpha-glucan |
| WO2022235655A1 (en) | 2021-05-04 | 2022-11-10 | Nutrition & Biosciences USA 4, Inc. | Compositions comprising insoluble alpha-glucan |
| EP4426362A1 (en) | 2021-11-05 | 2024-09-11 | Nutrition & Biosciences USA 4, Inc. | Glucan derivatives for microbial control |
| WO2024112740A1 (en) | 2022-11-23 | 2024-05-30 | Nutrition & Biosciences USA 4, Inc. | Hygienic treatment of surfaces with compositions comprising hydrophobically modified alpha-glucan derivative |
| WO2025072417A1 (en) | 2023-09-29 | 2025-04-03 | Nutrition & Biosciences USA 4, Inc. | Polysaccharide derivatives |
| WO2025072419A1 (en) | 2023-09-29 | 2025-04-03 | Nutrition & Biosciences Usa 1, Llc | Crosslinked alpha-glucan derivatives |
| WO2025072416A1 (en) | 2023-09-29 | 2025-04-03 | Nutrition & Biosciences USA 4, Inc. | Polysaccharide derivatives |
| WO2026039397A1 (en) | 2024-08-13 | 2026-02-19 | Nutrition & Biosciences USA 4, Inc. | Alpha-glucan graft copolymer derivatives |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| GB2178959B (en) * | 1985-07-17 | 1989-07-26 | Grace W R & Co | Biocidal mixture |
| GB2178960B (en) | 1985-08-06 | 1990-03-21 | Albright & Wilson | Novel biocidal mixture |
| GB8904844D0 (en) | 1989-03-03 | 1989-04-12 | Albright & Wilson | Biocidal compositions and treatments |
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| JP3933198B2 (ja) | 1994-10-26 | 2007-06-20 | ファルマシア・アンド・アップジョン・カンパニー | フェニルオキサゾリジノン抗菌剤 |
| US5670055A (en) | 1996-08-08 | 1997-09-23 | Nalco Chemical Company | Use of the linear alkylbenzene sulfonate as a biofouling control agent |
| DE19722858B4 (de) | 1997-05-23 | 2004-01-29 | Schülke & Mayr GmbH | Zusammensetzungen auf der Basis von Iodpropinyl- und Formaldehyd-Depot-Verbindungen und deren Verwendung als Konservierungsmittel |
| JP3811710B2 (ja) * | 1997-08-28 | 2006-08-23 | 株式会社片山化学工業研究所 | 工業用殺菌・静菌剤及び工業的殺菌・静菌方法 |
| NZ505301A (en) | 1997-12-23 | 2002-05-31 | Rhodia Cons Spec Ltd | Biocidal synergistic composition comprising THP and at least one polymeric or copolymeric THP-compatable non-surfactant biopenetrant |
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| JP4395879B2 (ja) | 1999-04-01 | 2010-01-13 | 栗田工業株式会社 | 紙パルプ工業用抗菌剤組成物及びそれを用いた抗菌方法 |
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| US20030228373A1 (en) | 2002-01-22 | 2003-12-11 | Lonza Inc. | Composition including a triamine and a biocide and a method for inhibiting the growth of microorganisms with the same |
| KR20050058426A (ko) | 2002-08-20 | 2005-06-16 | 론자 인코포레이티드 | 알데히드 공여자와 탈히드로아세트산의 안정한, 저 유리 포름알데히드의, 상승적인 항균성 조성물 |
| DE10244442A1 (de) | 2002-09-24 | 2004-04-01 | Schülke & Mayr GmbH | Emissionsarme Formaldehyd-Depot-Zubereitungen und deren Verwendung |
| US7219735B2 (en) | 2002-11-01 | 2007-05-22 | Innovative Chemical Technologies Canada Ltd. | Packer fluid |
| RU2323746C2 (ru) | 2003-06-20 | 2008-05-10 | РОДИА ЮКей ЛИМИТЕД | Разобщающие агенты |
| GB0402395D0 (en) | 2004-02-03 | 2004-03-10 | Rhodia Cons Spec Ltd | Synergistic biocidal compositions |
| US20080004189A1 (en) | 2006-06-29 | 2008-01-03 | Weatherford/Lamb, Inc. | Effervescent biocide compositions for oilfield applications |
| US9139796B2 (en) | 2007-07-24 | 2015-09-22 | Dow Global Technologies Llc | Methods of and formulations for reducing and inhibiting the growth of the concentration of microbes in water-based fluids and systems used with them |
-
2008
- 2008-07-21 US US12/669,657 patent/US8952199B2/en active Active
- 2008-07-21 NO NO08826631A patent/NO2173176T3/no unknown
- 2008-07-21 DK DK08826631.7T patent/DK2173176T3/da active
- 2008-07-21 WO PCT/US2008/070652 patent/WO2009015089A2/en not_active Ceased
- 2008-07-21 EP EP08826631.7A patent/EP2173176B1/en active Active
- 2008-07-21 BR BRPI0812700A patent/BRPI0812700B1/pt active IP Right Grant
- 2008-07-23 AR ARP080103196A patent/AR068085A1/es active IP Right Grant
Also Published As
| Publication number | Publication date |
|---|---|
| US8952199B2 (en) | 2015-02-10 |
| WO2009015089A3 (en) | 2009-11-26 |
| EP2173176B1 (en) | 2017-09-06 |
| BRPI0812700B1 (pt) | 2020-04-28 |
| US20100298275A1 (en) | 2010-11-25 |
| AR068085A1 (es) | 2009-11-04 |
| EP2173176A2 (en) | 2010-04-14 |
| WO2009015089A2 (en) | 2009-01-29 |
| BRPI0812700A2 (pt) | 2019-08-27 |
| NO2173176T3 (da) | 2018-02-03 |
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