DK2201837T3 - Anvendelse af polymerer af kvaternære ammoniumforbindelser - Google Patents
Anvendelse af polymerer af kvaternære ammoniumforbindelser Download PDFInfo
- Publication number
- DK2201837T3 DK2201837T3 DK09174896.2T DK09174896T DK2201837T3 DK 2201837 T3 DK2201837 T3 DK 2201837T3 DK 09174896 T DK09174896 T DK 09174896T DK 2201837 T3 DK2201837 T3 DK 2201837T3
- Authority
- DK
- Denmark
- Prior art keywords
- polymer
- polymerization
- degree
- polymers
- quaternary ammonium
- Prior art date
Links
- 229920000642 polymer Polymers 0.000 title claims description 93
- 150000003856 quaternary ammonium compounds Chemical class 0.000 title claims description 32
- 238000006116 polymerization reaction Methods 0.000 claims description 47
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 46
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 18
- 239000003795 chemical substances by application Substances 0.000 claims description 15
- 238000004659 sterilization and disinfection Methods 0.000 claims description 14
- 150000003839 salts Chemical class 0.000 claims description 13
- 241000195493 Cryptophyta Species 0.000 claims description 11
- -1 halogen ion Chemical class 0.000 claims description 11
- 230000002265 prevention Effects 0.000 claims description 11
- JUSZROWIGBIXOS-UHFFFAOYSA-N 1-(dimethylamino)propan-2-ol;hydrochloride Chemical compound [Cl-].CC(O)C[NH+](C)C JUSZROWIGBIXOS-UHFFFAOYSA-N 0.000 claims description 8
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 5
- 239000000654 additive Substances 0.000 claims description 4
- 239000000645 desinfectant Substances 0.000 claims description 4
- 229910052736 halogen Inorganic materials 0.000 claims description 4
- 230000000249 desinfective effect Effects 0.000 claims description 3
- 239000002738 chelating agent Substances 0.000 claims description 2
- 239000008394 flocculating agent Substances 0.000 claims description 2
- 229910052757 nitrogen Inorganic materials 0.000 claims description 2
- CNGMQNNDKGEIMZ-UHFFFAOYSA-N 1-aminopropan-2-ol;hydron;chloride Chemical compound Cl.CC(O)CN CNGMQNNDKGEIMZ-UHFFFAOYSA-N 0.000 claims 1
- 239000000975 dye Substances 0.000 claims 1
- 239000003205 fragrance Substances 0.000 claims 1
- 238000003287 bathing Methods 0.000 description 32
- 229940027983 antiseptic and disinfectant quaternary ammonium compound Drugs 0.000 description 23
- 238000012423 maintenance Methods 0.000 description 17
- 230000007774 longterm Effects 0.000 description 9
- 239000000178 monomer Substances 0.000 description 8
- 230000003115 biocidal effect Effects 0.000 description 7
- 239000003344 environmental pollutant Substances 0.000 description 7
- 231100000719 pollutant Toxicity 0.000 description 7
- 238000011282 treatment Methods 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 5
- 239000013505 freshwater Substances 0.000 description 5
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 4
- 239000002518 antifoaming agent Substances 0.000 description 4
- 229910052801 chlorine Inorganic materials 0.000 description 4
- 239000000460 chlorine Substances 0.000 description 4
- 150000001805 chlorine compounds Chemical class 0.000 description 4
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 description 4
- 239000007800 oxidant agent Substances 0.000 description 4
- 230000009182 swimming Effects 0.000 description 4
- SGHZXLIDFTYFHQ-UHFFFAOYSA-L Brilliant Blue Chemical compound [Na+].[Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C(=CC=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 SGHZXLIDFTYFHQ-UHFFFAOYSA-L 0.000 description 3
- HMEKVHWROSNWPD-UHFFFAOYSA-N Erioglaucine A Chemical compound [NH4+].[NH4+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C(=CC=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 HMEKVHWROSNWPD-UHFFFAOYSA-N 0.000 description 3
- 229910001385 heavy metal Inorganic materials 0.000 description 3
- 230000007794 irritation Effects 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 150000002927 oxygen compounds Chemical class 0.000 description 3
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 3
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 2
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 description 2
- NJSSICCENMLTKO-HRCBOCMUSA-N [(1r,2s,4r,5r)-3-hydroxy-4-(4-methylphenyl)sulfonyloxy-6,8-dioxabicyclo[3.2.1]octan-2-yl] 4-methylbenzenesulfonate Chemical compound C1=CC(C)=CC=C1S(=O)(=O)O[C@H]1C(O)[C@@H](OS(=O)(=O)C=2C=CC(C)=CC=2)[C@@H]2OC[C@H]1O2 NJSSICCENMLTKO-HRCBOCMUSA-N 0.000 description 2
- 230000002353 algacidal effect Effects 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000003139 biocide Substances 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 229940073507 cocamidopropyl betaine Drugs 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- DUYCTCQXNHFCSJ-UHFFFAOYSA-N dtpmp Chemical compound OP(=O)(O)CN(CP(O)(O)=O)CCN(CP(O)(=O)O)CCN(CP(O)(O)=O)CP(O)(O)=O DUYCTCQXNHFCSJ-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 2
- 239000003352 sequestering agent Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000001225 therapeutic effect Effects 0.000 description 2
- 101100168642 Arabidopsis thaliana CRN gene Proteins 0.000 description 1
- 101100045632 Arabidopsis thaliana TCX2 gene Proteins 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 150000003868 ammonium compounds Chemical class 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 244000052616 bacterial pathogen Species 0.000 description 1
- CADWTSSKOVRVJC-UHFFFAOYSA-N benzyl(dimethyl)azanium;chloride Chemical class [Cl-].C[NH+](C)CC1=CC=CC=C1 CADWTSSKOVRVJC-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 230000001364 causal effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000001332 colony forming effect Effects 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 150000002390 heteroarenes Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 150000002466 imines Chemical class 0.000 description 1
- 150000008040 ionic compounds Chemical class 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 150000003867 organic ammonium compounds Chemical class 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- 101150103732 sol2 gene Proteins 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/76—Treatment of water, waste water, or sewage by oxidation with halogens or compounds of halogens
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
- A01N33/02—Amines; Quaternary ammonium compounds
- A01N33/12—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/42—Nature of the water, waste water, sewage or sludge to be treated from bathing facilities, e.g. swimming pools
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Pest Control & Pesticides (AREA)
- Dentistry (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Agronomy & Crop Science (AREA)
- Hydrology & Water Resources (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Cosmetics (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Claims (13)
1. Anvendelse af polymerer af kvaternære ammoniumforbindelser eller saltene deraf til desinficering og algeforebyggelse i badevand, kendetegnet ved, at mindst to polymerer af kvaternære ammoniumforbindelser eller saltene deraf anvendes, hvor mindst en polymer har en polymeriseringsgrad på 30 til 55, og mindst en yderligere polymer har en polymeriseringsgrad på 120 til 160.
2. Anvendelse ifølge krav 1, kendetegnet ved, at mindst to polymerer af en kvaternær ammoniumforbindelse eller saltene deraf anvendes, hvor mindst en polymer har en polymeriseringsgrad på 35 til 50, og mindst en yderligere polymer har en polymeriseringsgrad på 130 til 150.
3. Anvendelse ifølge krav 1 eller 2, kendetegnet ved, at polymererne har den almene formel
hvor Ri og R2 er ens eller forskellige og hver især vælges fra Ci-C4-alkylen, n og m er ens eller forskellige og hver især betegner et helt tal fra 1 til 3, X' betegner en egnet modion, fortrinsvis en halogenion, særligt foretrukket chlorid, og p for mindst en polymer udgør 30 < p < 55 og for mindst en yderligere polymer udgør 120 < p ^ 160.
4. Anvendelse ifølge krav 3, kendetegnet ved, at Ri og R2 er ens og hver især betegner en methylgruppe, n og m er ens og hver især betegner 1, X' betegner chlorid, og p for mindst en polymer udgør 30 ^ p^ 55 og for mindst en yderligere polymer udgør 120 ^ p ^ 160.
5. Anvendelse ifølge krav 3 eller 4, kendetegnet ved, at p for mindst en polymer udgør 35 < p < 50 og for mindst en yderligere polymer udgør 130 < p < 150.
6. Anvendelse ifølge et af kravene 1 til 5, kendetegnet ved, at mindst en polymer er et polymert N,N-dimethyl-2-hydroxypropylammoniumchlorid med en polymeriseringsgrad på 50, og mindst en yderligere polymer er et polymert N,N-dimethyl-2-hydroxypropylammoniumchlorid med en polymeriseringsgrad på 130.
7. Middel til desinficering og algeforebyggelse i badevand, kendetegnet ved, at det omfatter mindst to polymerer af kvaternære ammoniumforbindelser eller saltene deraf, hvor mindst en polymer har en polymeriseringsgrad på 30 til 55, og mindst en yderligere polymer har en polymeriseringsgrad på 120 til 160.
8. Middel ifølge krav 7, kendetegnet ved, at det omfatter mindst to polymerer af en kvaternær ammoniumforbindelse eller saltene deraf, hvor mindst en polymer har en polymeriseringsgrad på 30 til 55, og mindst en yderligere polymer har en polymeriseringsgrad på 120 til 160.
9. Middel ifølge krav 7 eller 8, kendetegnet ved, at polymererne har den almene formel
hvor Ri og R2 er ens eller forskellige og hver især vælges fra C-i-C4-alkylen, n og m er ens eller forskellige og hver især betegner et helt tal fra 1 til 3, X' betegner en egnet modion, fortrinsvis en halogenion, særligt foretrukket chlorid, og p for mindst en polymer udgør 30 < p < 55 og for mindst en yderligere polymer udgør 120 < p < 160.
10. Middel ifølge krav 9, kendetegnet ved, at R1 og R2 er ens og hver især betegner en methylgruppe, n og m er ens og hver især betegner 1, X' betegner chlorid, og p for mindst en polymer udgør 30 < p < 55 og for mindst en yderligere polymer udgør 120 ^ p ^ 160.
11. Middel ifølge krav 9 eller 10, kendetegnet ved, at p for mindst en polymer udgør 35 ^ p ^ 50 og for mindst en yderligere polymer udgør 130 ^ p ^ 150.
12. Middel ifølge et af kravene 7 til 11, kendetegnet ved, at det omfatter mindst en polymer af N,N-dimethyl-2-hydroxypropylammoniumchlorid med en polymeriseringsgrad på 50 og mindst en yderligere polymer af N,N-dimethyl-2-hydroxypropylammoniumchlorid med en polymeriseringsgrad på 130.
13. Middel ifølge et af kravene 7 til 12, kendetegnet ved, at det omfatter yderligere tilsætningsstoffer til desinficeringsmidler til desinficering af vand og algeforebyggelse, valgt fra gruppen, der omfatter flokkuleringsmidler, chelat-dannere, antiskummidler, farvestoffer, duftstoffer, hudplejemidler og kombinationer heraf.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT0173508A AT507062B1 (de) | 2008-11-07 | 2008-11-07 | Verwendung von polymeren quaternärer ammoniumverbindungen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DK2201837T3 true DK2201837T3 (da) | 2014-03-03 |
Family
ID=41664424
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DK09174896.2T DK2201837T3 (da) | 2008-11-07 | 2009-11-03 | Anvendelse af polymerer af kvaternære ammoniumforbindelser |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP2201837B1 (da) |
| AT (1) | AT507062B1 (da) |
| DK (1) | DK2201837T3 (da) |
| ES (1) | ES2458517T3 (da) |
| PL (1) | PL2201837T3 (da) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2589835C1 (ru) * | 2015-04-29 | 2016-07-10 | Общество с ограниченной ответственностью "Международный институт эколого-технологических проблем" | Средство для дезинфекции |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| LU86123A1 (fr) * | 1985-10-17 | 1987-06-02 | Fabricom Air Conditioning Sa | Procede de desinfection d'eaux |
| DE3840103C2 (de) * | 1988-11-28 | 1994-10-06 | Bayrol Chem Fab Gmbh | Verfahren zum Entkeimen und Entalgung von Wasser |
| CA2041871C (en) * | 1990-05-09 | 2000-07-11 | Ruth A. Rosenthal | Contact lens cleaning and disinfecting with combinations of polymeric quaternary ammonium compounds and enzymes |
| US5096601A (en) * | 1990-10-09 | 1992-03-17 | Calgon Corporation | Method for controlling zebra mussels using quaternary ammonium compositions |
| AU2079497A (en) * | 1996-03-18 | 1997-10-10 | Bio-Lab, Inc. | Water clarifying compositions |
| WO2000009453A1 (en) * | 1998-08-12 | 2000-02-24 | Clear Value, Inc. | Clarification of water and wastewater |
| JP3542940B2 (ja) * | 2001-04-27 | 2004-07-14 | 日華化学株式会社 | 殺菌消毒剤、抗菌性薬剤及び抗菌性材料 |
-
2008
- 2008-11-07 AT AT0173508A patent/AT507062B1/de not_active IP Right Cessation
-
2009
- 2009-11-03 EP EP09174896.2A patent/EP2201837B1/de active Active
- 2009-11-03 ES ES09174896.2T patent/ES2458517T3/es active Active
- 2009-11-03 DK DK09174896.2T patent/DK2201837T3/da active
- 2009-11-03 PL PL09174896T patent/PL2201837T3/pl unknown
Also Published As
| Publication number | Publication date |
|---|---|
| EP2201837A3 (de) | 2012-09-05 |
| EP2201837B1 (de) | 2014-01-15 |
| PL2201837T3 (pl) | 2014-06-30 |
| AT507062B1 (de) | 2010-02-15 |
| AT507062A4 (de) | 2010-02-15 |
| ES2458517T3 (es) | 2014-05-05 |
| EP2201837A2 (de) | 2010-06-30 |
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