DK2236229T3 - Fremgangsmåde til fremstilling af en pulverbaseret artikel - Google Patents
Fremgangsmåde til fremstilling af en pulverbaseret artikel Download PDFInfo
- Publication number
- DK2236229T3 DK2236229T3 DK09157166.1T DK09157166T DK2236229T3 DK 2236229 T3 DK2236229 T3 DK 2236229T3 DK 09157166 T DK09157166 T DK 09157166T DK 2236229 T3 DK2236229 T3 DK 2236229T3
- Authority
- DK
- Denmark
- Prior art keywords
- capsule
- powder
- steels
- gas
- article
- Prior art date
Links
- 239000000843 powder Substances 0.000 title claims description 130
- 238000004519 manufacturing process Methods 0.000 title description 25
- 239000000463 material Substances 0.000 claims description 188
- 239000002775 capsule Substances 0.000 claims description 118
- 238000000034 method Methods 0.000 claims description 52
- 239000002861 polymer material Substances 0.000 claims description 45
- 239000000203 mixture Substances 0.000 claims description 24
- 229910001220 stainless steel Inorganic materials 0.000 claims description 23
- 229910000831 Steel Inorganic materials 0.000 claims description 19
- 239000010959 steel Substances 0.000 claims description 19
- 229920000642 polymer Polymers 0.000 claims description 18
- 238000011049 filling Methods 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 8
- 229910000990 Ni alloy Inorganic materials 0.000 claims description 7
- 239000000919 ceramic Substances 0.000 claims description 7
- 229910052751 metal Inorganic materials 0.000 claims description 7
- 239000002184 metal Substances 0.000 claims description 7
- 229910000975 Carbon steel Inorganic materials 0.000 claims description 6
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 6
- 229910000531 Co alloy Inorganic materials 0.000 claims description 6
- 239000011651 chromium Substances 0.000 claims description 6
- 229910052804 chromium Inorganic materials 0.000 claims description 6
- 229910000734 martensite Inorganic materials 0.000 claims description 6
- 238000007789 sealing Methods 0.000 claims description 4
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 3
- 238000005253 cladding Methods 0.000 claims 4
- 229910001039 duplex stainless steel Inorganic materials 0.000 claims 2
- QYEXBYZXHDUPRC-UHFFFAOYSA-N B#[Ti]#B Chemical compound B#[Ti]#B QYEXBYZXHDUPRC-UHFFFAOYSA-N 0.000 claims 1
- 229910033181 TiB2 Inorganic materials 0.000 claims 1
- 239000011159 matrix material Substances 0.000 claims 1
- -1 polypropylene Polymers 0.000 description 15
- 239000007789 gas Substances 0.000 description 14
- 239000007787 solid Substances 0.000 description 9
- 238000009792 diffusion process Methods 0.000 description 8
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 7
- 229920006324 polyoxymethylene Polymers 0.000 description 7
- 239000002245 particle Substances 0.000 description 6
- 229930040373 Paraformaldehyde Natural products 0.000 description 5
- 239000004698 Polyethylene Substances 0.000 description 5
- 239000004743 Polypropylene Substances 0.000 description 5
- 229920000573 polyethylene Polymers 0.000 description 5
- 229920001155 polypropylene Polymers 0.000 description 5
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- 238000005299 abrasion Methods 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 238000005260 corrosion Methods 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 4
- 238000002309 gasification Methods 0.000 description 4
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000001513 hot isostatic pressing Methods 0.000 description 3
- 239000011156 metal matrix composite Substances 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- 238000003466 welding Methods 0.000 description 3
- 239000000080 wetting agent Substances 0.000 description 3
- 238000010146 3D printing Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229910052786 argon Inorganic materials 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- 229910001092 metal group alloy Inorganic materials 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 230000002787 reinforcement Effects 0.000 description 2
- 229910001209 Low-carbon steel Inorganic materials 0.000 description 1
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 238000000071 blow moulding Methods 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 230000001427 coherent effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000010100 freeform fabrication Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 239000000696 magnetic material Substances 0.000 description 1
- 239000003550 marker Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F7/00—Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression
- B22F7/06—Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression of composite workpieces or articles from parts, e.g. to form tipped tools
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F5/00—Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product
- B22F5/10—Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product of articles with cavities or holes, not otherwise provided for in the preceding subgroups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F5/00—Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product
- B22F5/10—Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product of articles with cavities or holes, not otherwise provided for in the preceding subgroups
- B22F5/106—Tube or ring forms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
- B22F2998/10—Processes characterised by the sequence of their steps
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Composite Materials (AREA)
- Materials Engineering (AREA)
- Powder Metallurgy (AREA)
Claims (12)
1
1. Fremgangsmåde til fremstilling af en pulverbaseret artikel (1), omfattende et afsnit (2) af et første materiale og mindst ét afsnit (3) af et andet materiale, 5 hvor fremgangsmåden omfatter følgende trin: - anbringe (100) mindst ét første legeme (11) omfattende et pulver af det andet materiale og et materiale, som kan omdannes til gas, i et udvalgt afsnit eller udvalgte afsnit i en kapsel (10), som definerer formen af artiklen (1), hvor pulveret af det andet materiale holdes af det 10 materiale, som kan omdannes til gas; - fylde (200) kapslen (10) med et pulver af det første materiale; - fjerne (300) det materiale, som kan omdannes til gas; - forsegle (400) kapslen; - opvarme (500) kapslen under forhøjet tryk til en temperatur, ved hvil- 15 ket pulverne af de første og andre materialer fortættes til en kompakt artikel, og kendetegnet ved, at legemet (11) omfatter en eller flere kapper (12) af polymermateriale, som kan omdannes til gas, og et pulver af i det mindste det første materiale eller i det mindste det andet materiale, hvor kappen eller kapperne (12) fyldes eller forfyldes med 20 mindst ét pulver af det andet materiale.
2. Fremgangsmåde ifølge krav 1, hvor legemet (11) er anbragt ved den indvendige overflade af en væg (10.1, 10.2) af kapslen (10), således at legemet (11) lukkes delvis inde i pulvermaterialet. 25
3. Fremgangsmåde ifølge krav 1, hvor legemet (11) er anbragt i en afstand fra den indvendige overflade af en væg (10.1, 10.2) af kapslen (10), således at legemet (11) lukkes delvis inde i pulvermaterialet.
4. Fremgangsmåde ifølge et af kravene 1 - 3, hvor kapslen (10) danner en hul cylinder, hvor legemet (11) er anbragt i kontakt med beklædningsoverfladen af en indvendig væg 10.2 af cylinderen 10, delvis omsluttende beklædningsoverfladen.
5. Fremgangsmåde ifølge et af kravene 1 - 3, hvor kapslen (10) danner en hul cylinder med et buet tværsnit, hvor legemet (11) er anbragt i kontakt med 2 beklædningsoverfladen af en indvendig væg 10.2 af cylinderen 10, delvis omsluttende beklædningsoverfladen.
6. Fremgangsmåde ifølge et af kravene 1-5, hvor kapslen fyldes delvis med 5 et pulver af det første materiale; hvor kappen (12) er anbragt i kapslen (10), hvor kappen (12) derefter fyldes med mindst ét pulver af det andet materiale, hvorefter kapslen (10) fyldes helt med pulveret af det første materiale.
7. Fremgangsmåde ifølge et af kravene 1 - 6, hvor flere legemer (11) er an-10 bragt i kapslen (10).
8. Fremgangsmåde ifølge krav 7, hvor legemerne (11) omfatter pulvere af forskellige materialer.
9. Fremgangsmåde ifølge et af kravene 1 - 8, hvor det første materiale er udvalgt blandt Ni-legeringer, Co-legeringer, værktøjsstål, kulstofstål, Flad-field-stål, rustfrit stål så som martensitisk rustfrit stål, kromstål, austenitisk rustfrit stål, duplex rustfrit stål eller blandinger deraf.
10. Fremgangsmåde ifølge et af kravene 1 - 9, hvor det andet, tredje eller yderligere materiale er udvalgt blandt Ni-legeringer, Co-legeringer, værktøjsstål, kulstofstål, Fladfield-stål, rustfrit stål så som martensitisk rustfrit stål, kromstål, austenitisk rustfrit stål, duplex rustfrit stål eller blandinger af de førnævnte materialer eller keramik så som Tin, TiC, WC, TiB2, metalmatrix-25 sammensætninger eller blandinger deraf.
11. Fremgangsmåde ifølge et af kravene 1-10, hvor det materiale, som kan omdannes til gas, er termisk polymermateriale, som kan omdannes til gas, hvor trinnet (300) med at fjerne polymermaterialet fra kapslen (10) omfatter 30 følgende undertrin: - anvende et vakuum i kapslen (10); - opvarme kapslen (10) til en temperatur, ved hvilken polymermaterialet omdannes til gas.
12. Fremgangsmåde ifølge et af kravene 1-11, hvor det materiale, som kan omdannes til gas, er et polymermateriale, som kemisk kan omdannes til gas, 3 hvor trinnet (300) med at fjerne polymermaterialet fra kapslen (10) omfatter følgende undertrin: - anvende et vakuum i kapslen (10); - indsprøjte en gas i kapslen, som reagerer kemisk med polymeren, så- 5 ledes at polymermaterialet omdannes til gas.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP09157166.1A EP2236229B1 (en) | 2009-04-02 | 2009-04-02 | Method for manufacturing a powder based article |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DK2236229T3 true DK2236229T3 (da) | 2015-10-05 |
Family
ID=40848255
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DK09157166.1T DK2236229T3 (da) | 2009-04-02 | 2009-04-02 | Fremgangsmåde til fremstilling af en pulverbaseret artikel |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US9205492B2 (da) |
| EP (1) | EP2236229B1 (da) |
| JP (1) | JP5882887B2 (da) |
| CN (1) | CN102387881B (da) |
| BR (1) | BRPI1010309A2 (da) |
| CA (1) | CA2757116A1 (da) |
| DK (1) | DK2236229T3 (da) |
| WO (1) | WO2010114474A1 (da) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102011080225A1 (de) * | 2011-08-01 | 2013-02-07 | Coperion Gmbh | Verfahren und Behandlungselement-Rohling zur Herstellung eines Behandlungselements für eine Schneckenmaschine |
| US9803263B2 (en) * | 2012-09-12 | 2017-10-31 | Sandvik Intellectual Property Ab | Method for manufacturing a wear resistant component |
| DE102013211844A1 (de) * | 2013-06-21 | 2014-12-24 | Heraeus Precious Metals Gmbh & Co. Kg | Pumpengehäuse aus einem magnetischen und einem nichtmagnetischen Material |
| DE102013211845A1 (de) * | 2013-06-21 | 2014-12-24 | Heraeus Precious Metals Gmbh & Co. Kg | Pumpengehäuse mit harter Innenschicht und verschweißbarer Außenschicht |
| DE102013211848A1 (de) | 2013-06-21 | 2014-12-24 | Heraeus Precious Metals Gmbh & Co. Kg | Pumpengehäuse aus mindestens zwei unterschiedlichen versinterbaren Materialien |
| US20150060042A1 (en) * | 2013-08-29 | 2015-03-05 | General Electric Company | Electrical submersible pump and pump system including additively manufactured structures and method of manufacture |
| JP2016540887A (ja) * | 2013-10-17 | 2016-12-28 | ザ エクスワン カンパニー | 3次元印刷された熱間静水圧加圧成形用容器及びその製造方法 |
| DE102014004121A1 (de) | 2014-03-24 | 2015-09-24 | Heraeus Deutschland GmbH & Co. KG | Pumpengehäuse aus mindestens drei unterschiedlichen versinterbaren Materialien |
| JP6608390B2 (ja) | 2014-04-02 | 2019-11-20 | サンドビック インテレクチュアル プロパティー アクティエボラーグ | 事前製造される構成部分による金属コンポーネントの製造方法 |
| DE102014207510B4 (de) | 2014-04-17 | 2021-12-16 | Kennametal Inc. | Zerspanungswerkzeug sowie Verfahren zum Herstellen eines Zerspanungswerkzeugs |
| DE102014207507B4 (de) | 2014-04-17 | 2021-12-16 | Kennametal Inc. | Zerspanungswerkzeug sowie Verfahren zum Herstellen eines Zerspanungswerkzeugs |
| US20170045136A1 (en) * | 2014-04-22 | 2017-02-16 | Ntn Corporation | Sintered mechanical component, device for forming powder compact, and method for forming powder compact |
| CN106660125B (zh) * | 2014-05-30 | 2023-03-17 | 诺沃皮尼奥内技术股份有限公司 | 制造涡轮机构件的方法、涡轮机构件和涡轮机 |
| US9643282B2 (en) | 2014-10-17 | 2017-05-09 | Kennametal Inc. | Micro end mill and method of manufacturing same |
| US20170175905A1 (en) * | 2015-12-22 | 2017-06-22 | Cameron International Corporation | Fluid-handling components and methods of manufacture |
| GB2570618B (en) * | 2017-07-05 | 2021-05-19 | Bodycote H I P Ltd | Components |
| NO346951B1 (en) * | 2020-12-15 | 2023-03-13 | Vetco Gray Scandinavia As | Oil and gas industry gooseneck manufactured by Hot Isostatic Pressing and a flexible pipeline assembly with an oil and gas industry gooseneck |
| US11919086B2 (en) | 2020-12-16 | 2024-03-05 | Schlumberger Technology Corporation | Hot isostatic pressing (HIP) fabrication of multi-metallic components for pressure-controlling equipment |
| US11471943B2 (en) | 2020-12-16 | 2022-10-18 | Mtc Powder Solutions Ab | Hot isostatic pressing (HIP) fabrication of multi-metallic components for pressure-controlling equipment |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3940268A (en) * | 1973-04-12 | 1976-02-24 | Crucible Inc. | Method for producing rotor discs |
| US4063939A (en) * | 1975-06-27 | 1977-12-20 | Special Metals Corporation | Composite turbine wheel and process for making same |
| JPS58189306A (ja) * | 1982-03-05 | 1983-11-05 | ロ−ルス−ロイス、パブリック、リミテッド、カンパニ− | 複合セラミック金属コンポネントの製造法 |
| DE3310038C2 (de) * | 1983-03-19 | 1985-05-09 | Fried. Krupp Gmbh, 4300 Essen | Verfahren zur Herstellung eines Verbundkörpers |
| JPS61266106A (ja) * | 1985-05-22 | 1986-11-25 | Sumitomo Metal Ind Ltd | 複合ロ−ル |
| JPS62243701A (ja) * | 1986-04-15 | 1987-10-24 | Toshiba Corp | 異種材料接合方法 |
| JPS6326301A (ja) * | 1986-07-18 | 1988-02-03 | Kubota Ltd | 積層複合筒状体の製造方法 |
| JPS6333504A (ja) * | 1986-07-25 | 1988-02-13 | Kubota Ltd | 円柱状積層体の製造方法 |
| JPH03125076A (ja) | 1989-10-09 | 1991-05-28 | Mitsubishi Heavy Ind Ltd | ピストンリングのコーテイング方法 |
| JPH05141213A (ja) | 1991-11-18 | 1993-06-08 | Sumitomo Light Metal Ind Ltd | 内燃機関用吸・排気バルブ |
| JPH0741802A (ja) * | 1993-07-29 | 1995-02-10 | Kitagawa Iron Works Co Ltd | 金属粉末射出成形法 |
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| JPH10298609A (ja) * | 1997-04-28 | 1998-11-10 | Kubota Corp | 金属系多孔質焼結体の製造方法 |
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| JP2004149826A (ja) * | 2002-10-29 | 2004-05-27 | Kinzoku Giken Kk | Hipを用いた3次元自由形状の金属粉末焼結体の製造方法及びその製造方法によって得られる金属粉末焼結体 |
| CN1970504A (zh) * | 2006-12-01 | 2007-05-30 | 华中科技大学 | 金属/陶瓷激光烧结制件的热等静压处理方法 |
| US7803313B2 (en) * | 2007-02-15 | 2010-09-28 | Precision Castparts Corp. | Method for bonding powder metallurgical parts |
-
2009
- 2009-04-02 DK DK09157166.1T patent/DK2236229T3/da active
- 2009-04-02 EP EP09157166.1A patent/EP2236229B1/en not_active Not-in-force
-
2010
- 2010-03-31 CA CA2757116A patent/CA2757116A1/en not_active Abandoned
- 2010-03-31 CN CN201080016177.0A patent/CN102387881B/zh not_active Expired - Fee Related
- 2010-03-31 US US13/262,421 patent/US9205492B2/en not_active Expired - Fee Related
- 2010-03-31 WO PCT/SE2010/050361 patent/WO2010114474A1/en not_active Ceased
- 2010-03-31 JP JP2012503373A patent/JP5882887B2/ja not_active Expired - Fee Related
- 2010-03-31 BR BRPI1010309A patent/BRPI1010309A2/pt not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| JP2012522893A (ja) | 2012-09-27 |
| CA2757116A1 (en) | 2010-10-07 |
| JP5882887B2 (ja) | 2016-03-09 |
| BRPI1010309A2 (pt) | 2016-03-15 |
| EP2236229A1 (en) | 2010-10-06 |
| WO2010114474A1 (en) | 2010-10-07 |
| US20120135166A1 (en) | 2012-05-31 |
| CN102387881B (zh) | 2015-07-01 |
| US9205492B2 (en) | 2015-12-08 |
| CN102387881A (zh) | 2012-03-21 |
| EP2236229B1 (en) | 2015-07-15 |
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