DK2376599T3 - Fremgangsmåde til fremstilling af en bioolie med reduceret mineralindhold - Google Patents
Fremgangsmåde til fremstilling af en bioolie med reduceret mineralindhold Download PDFInfo
- Publication number
- DK2376599T3 DK2376599T3 DK09835786.6T DK09835786T DK2376599T3 DK 2376599 T3 DK2376599 T3 DK 2376599T3 DK 09835786 T DK09835786 T DK 09835786T DK 2376599 T3 DK2376599 T3 DK 2376599T3
- Authority
- DK
- Denmark
- Prior art keywords
- oil
- biomass material
- bio
- biomass
- pyrolytic
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 35
- 239000012075 bio-oil Substances 0.000 title claims description 31
- 229910052500 inorganic mineral Inorganic materials 0.000 title claims description 26
- 239000011707 mineral Substances 0.000 title claims description 26
- 238000004519 manufacturing process Methods 0.000 title description 3
- 239000002028 Biomass Substances 0.000 claims description 51
- 239000000463 material Substances 0.000 claims description 34
- 239000003921 oil Substances 0.000 claims description 29
- 239000002245 particle Substances 0.000 claims description 20
- 150000002736 metal compounds Chemical class 0.000 claims description 17
- 239000003054 catalyst Substances 0.000 claims description 11
- 239000007788 liquid Substances 0.000 claims description 11
- 239000003125 aqueous solvent Substances 0.000 claims description 10
- 238000000605 extraction Methods 0.000 claims description 8
- 229910052751 metal Inorganic materials 0.000 claims description 8
- 239000002184 metal Substances 0.000 claims description 8
- 238000000926 separation method Methods 0.000 claims description 6
- 239000007787 solid Substances 0.000 claims description 6
- 239000002904 solvent Substances 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 5
- 239000000470 constituent Substances 0.000 claims description 5
- 238000005119 centrifugation Methods 0.000 claims description 4
- 238000001914 filtration Methods 0.000 claims description 4
- 238000004821 distillation Methods 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 239000011817 metal compound particle Substances 0.000 claims description 2
- 238000002791 soaking Methods 0.000 claims description 2
- 239000007864 aqueous solution Substances 0.000 claims 2
- 235000010755 mineral Nutrition 0.000 description 23
- 238000006243 chemical reaction Methods 0.000 description 16
- 239000002956 ash Substances 0.000 description 15
- 238000000197 pyrolysis Methods 0.000 description 8
- 229920005610 lignin Polymers 0.000 description 7
- 230000003197 catalytic effect Effects 0.000 description 5
- 239000008346 aqueous phase Substances 0.000 description 4
- 229920002678 cellulose Polymers 0.000 description 4
- 239000001913 cellulose Substances 0.000 description 4
- 239000000446 fuel Substances 0.000 description 4
- 239000002029 lignocellulosic biomass Substances 0.000 description 4
- 239000012071 phase Substances 0.000 description 4
- 239000010703 silicon Substances 0.000 description 4
- 229910052710 silicon Inorganic materials 0.000 description 4
- 229920002488 Hemicellulose Polymers 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 3
- 238000000855 fermentation Methods 0.000 description 3
- 230000004151 fermentation Effects 0.000 description 3
- 230000007062 hydrolysis Effects 0.000 description 3
- 238000006460 hydrolysis reaction Methods 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 235000002918 Fraxinus excelsior Nutrition 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 239000012084 conversion product Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 229910010272 inorganic material Inorganic materials 0.000 description 2
- 239000011147 inorganic material Substances 0.000 description 2
- 239000012263 liquid product Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 108010059892 Cellulase Proteins 0.000 description 1
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 238000005903 acid hydrolysis reaction Methods 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000013522 chelant Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000005115 demineralization Methods 0.000 description 1
- 230000002328 demineralizing effect Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000010932 ethanolysis reaction Methods 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 229940072033 potash Drugs 0.000 description 1
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 1
- 235000015320 potassium carbonate Nutrition 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000011085 pressure filtration Methods 0.000 description 1
- 230000002062 proliferating effect Effects 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 239000010902 straw Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000000108 ultra-filtration Methods 0.000 description 1
- 238000005199 ultracentrifugation Methods 0.000 description 1
- 238000005292 vacuum distillation Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/06—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by destructive hydrogenation
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G21/00—Refining of hydrocarbon oils, in the absence of hydrogen, by extraction with selective solvents
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G31/00—Refining of hydrocarbon oils, in the absence of hydrogen, by methods not otherwise provided for
- C10G31/09—Refining of hydrocarbon oils, in the absence of hydrogen, by methods not otherwise provided for by filtration
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G31/00—Refining of hydrocarbon oils, in the absence of hydrogen, by methods not otherwise provided for
- C10G31/10—Refining of hydrocarbon oils, in the absence of hydrogen, by methods not otherwise provided for with the aid of centrifugal force
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1011—Biomass
- C10G2300/1014—Biomass of vegetal origin
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/201—Impurities
- C10G2300/205—Metal content
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Fats And Perfumes (AREA)
- Processing Of Solid Wastes (AREA)
Claims (13)
1. Fremgangsmåde til omdannelse af biomassemateriale, der omfatter mineraler, til en stabiliseret bioolie, hvilken fremgangsmåde omfatter trinnene (i) at udsætte biomassematerialet for et opløsningsmiddel under betingelser, der muliggør ekstraktion af mindst en del af mineralerne fra biomassematerialet; (ii) at omdanne mindst en del af biomassematerialet til en pyrolytisk olie med partikler af metalforbindelser suspenderet deri; og (iii) at fjerne mindst en del af de suspenderede metalforbindelser fra den pyrolytiske olie med en væ-ske/faststof-separationsteknik til opnåelse af en bioolie med et reduceret metalindhold.
2. Fremgangsmåde ifølge krav 1, hvor trin (ii) omfatter at opvarme biomassematerialet, og/eller pyrolytiske biomassedampe frembragt af biomassematerialet i nærvær af en katalysator.
3. Fremgangsmåde ifølge krav 2, hvor metalforbindelserne stammer mindst delvist fra katalysatoren.
4. Fremgangsmåde ifølge krav 1, hvor trin (i) omfatter at bringe biomassematerialet i kontakt med et vandigt opløsningsmiddel eller en vandig opløsning ved en temperatur i området 20 til 120 °C.
5. Fremgangsmåde ifølge krav 4, hvor det vandige opløsningsmiddel eller den vandige opløsning omfatter enten en syre eller en base.
6. Fremgangsmåde ifølge krav 4, hvor trin (i) omfatter at gennemvæde biomassematerialet i det vandige opløsningsmiddel og fjerne det vandige opløsningsmiddel fra biomassematerialet ved mekanisk påvirkning.
7. Fremgangsmåde ifølge krav 1, hvor mindst en del af metalforbindelserne er til stede i form af suspenderede partikler med en partikelstørrelse i området fra 1 nm til 100 pm.
8. Fremgangsmåde ifølge krav 7, hvor de suspenderede partikler har en gennemsnitlig partikelstørrelse fra 10 til 100 pm.
9. Fremgangsmåde ifølge krav 1, hvor den pyrolytiske olie yderligere omfatter metal, der er chelateret af en eller flere bestanddele af den pyrolytiske olie.
10. Fremgangsmåde ifølge krav 1, hvor trin (iii) omfatter centrifugering.
11. Fremgangsmåde ifølge krav 1, hvor trin (iii) omfatter filtrering.
12. Fremgangsmåde ifølge krav 1, hvor trin (iii) omfatter ekstraktion.
13. Fremgangsmåde ifølge krav 1, hvor trin (iii) omfatter destillation under reduceret tryk.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US14012108P | 2008-12-23 | 2008-12-23 | |
| PCT/US2009/069264 WO2010075429A1 (en) | 2008-12-23 | 2009-12-22 | Bio-oil having reduced mineral content, and process for making |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DK2376599T3 true DK2376599T3 (da) | 2017-07-24 |
Family
ID=42288126
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DK09835786.6T DK2376599T3 (da) | 2008-12-23 | 2009-12-22 | Fremgangsmåde til fremstilling af en bioolie med reduceret mineralindhold |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US8876925B2 (da) |
| EP (1) | EP2376599B1 (da) |
| CN (1) | CN102300958A (da) |
| BR (1) | BRPI0922426A2 (da) |
| CA (1) | CA2747512C (da) |
| DK (1) | DK2376599T3 (da) |
| WO (1) | WO2010075429A1 (da) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8288599B2 (en) | 2008-06-30 | 2012-10-16 | Kior, Inc. | Co-processing solid biomass in a conventional petroleum refining process unit |
| CN102438969A (zh) | 2009-05-22 | 2012-05-02 | 科伊奥股份有限公司 | 利用氢源处理生物质 |
| EP2530135B1 (de) * | 2011-05-30 | 2022-05-25 | GEA Mechanical Equipment GmbH | Verfahren zur Klärung von Pyrolyseöl |
| US9193924B2 (en) * | 2011-06-16 | 2015-11-24 | Uop Llc | Methods and apparatuses for forming low-metal biomass-derived pyrolysis oil |
| US9109177B2 (en) | 2011-12-12 | 2015-08-18 | Ensyn Renewables, Inc. | Systems and methods for renewable fuel |
| US9611197B1 (en) | 2013-03-15 | 2017-04-04 | Inaeris Technologies, Llc | Method of removing undesirable solid components from a renewable or non-renewable feed and apparatus used in same |
| EP3013922A4 (en) | 2013-06-26 | 2017-02-08 | Ensyn Renewables, Inc. | Systems and methods for renewable fuel |
| AU2016286296B2 (en) | 2015-07-02 | 2021-12-09 | Haldor Topsøe A/S | Demetallization of hydrocarbons |
| AU2017268727B2 (en) | 2016-05-26 | 2021-06-03 | Ensyn Renewables, Inc. | Integrated process for the pre-treatment of biomass and production of bio-oil |
| BR112019001194A2 (pt) * | 2016-07-20 | 2019-04-30 | Ensyn Renewables Inc | sistemas e métodos para preparar e coprocessar óleo biocru |
| BR112019013387B1 (pt) | 2016-12-29 | 2023-03-28 | Ensyn Renewables, Inc | Desmetalização de biomassa |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4260473A (en) * | 1979-05-03 | 1981-04-07 | Occidental Research Corporation | Removal of particulates from pyrolytic oil |
| US5064527A (en) | 1984-05-08 | 1991-11-12 | Exxon Research & Engineering Company | Catalytic process for hydroconversion of carbonaceous materials |
| US5115084A (en) * | 1989-07-19 | 1992-05-19 | Biocarbons Corporation | Method for controlling oil reservoir permeability using biomass oil |
| US6022419A (en) | 1996-09-30 | 2000-02-08 | Midwest Research Institute | Hydrolysis and fractionation of lignocellulosic biomass |
| US6048374A (en) * | 1997-08-18 | 2000-04-11 | Green; Alex E. S. | Process and device for pyrolysis of feedstock |
| US6419788B1 (en) | 2000-08-16 | 2002-07-16 | Purevision Technology, Inc. | Method of treating lignocellulosic biomass to produce cellulose |
| CN1180866C (zh) | 2003-04-15 | 2004-12-22 | 黄铭 | 多溶剂萃取方法 |
| US7503981B2 (en) | 2004-12-02 | 2009-03-17 | The Trustees Of Dartmouth College | Removal of minerals from cellulosic biomass |
| WO2006117005A1 (en) * | 2005-05-03 | 2006-11-09 | Danmarks Tekniske Universitet | Pyrolysis method and apparatus |
| US20080009055A1 (en) * | 2006-07-10 | 2008-01-10 | Greenfuel Technologies Corp. | Integrated photobioreactor-based pollution mitigation and oil extraction processes and systems |
| US20080029233A1 (en) | 2006-08-03 | 2008-02-07 | Purevision Technology, Inc. | Moving bed biomass fractionation system and method |
-
2009
- 2009-12-22 CN CN2009801529575A patent/CN102300958A/zh active Pending
- 2009-12-22 DK DK09835786.6T patent/DK2376599T3/da active
- 2009-12-22 CA CA2747512A patent/CA2747512C/en not_active Expired - Fee Related
- 2009-12-22 WO PCT/US2009/069264 patent/WO2010075429A1/en not_active Ceased
- 2009-12-22 BR BRPI0922426A patent/BRPI0922426A2/pt not_active IP Right Cessation
- 2009-12-22 EP EP09835786.6A patent/EP2376599B1/en not_active Not-in-force
- 2009-12-22 US US13/139,954 patent/US8876925B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN102300958A (zh) | 2011-12-28 |
| CA2747512C (en) | 2017-04-04 |
| EP2376599B1 (en) | 2017-06-28 |
| US20120137571A1 (en) | 2012-06-07 |
| CA2747512A1 (en) | 2010-07-01 |
| EP2376599A4 (en) | 2014-03-19 |
| BRPI0922426A2 (pt) | 2015-12-15 |
| WO2010075429A1 (en) | 2010-07-01 |
| US8876925B2 (en) | 2014-11-04 |
| EP2376599A1 (en) | 2011-10-19 |
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