DK2448670T3 - Fremgangsmåde til fremstilling af en multimetallisk katalysator med en optimeret nærhed af sites - Google Patents

Fremgangsmåde til fremstilling af en multimetallisk katalysator med en optimeret nærhed af sites Download PDF

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Publication number
DK2448670T3
DK2448670T3 DK10734170.3T DK10734170T DK2448670T3 DK 2448670 T3 DK2448670 T3 DK 2448670T3 DK 10734170 T DK10734170 T DK 10734170T DK 2448670 T3 DK2448670 T3 DK 2448670T3
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weight
tin
catalyst
support
preparing
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DK10734170.3T
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English (en)
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Priscilla Avenier
Sylvie Lacombe
HERVé CAUFFRIEZ
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IFP Energies Nouvelles
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/128—Halogens; Compounds thereof with iron group metals or platinum group metals
    • B01J27/13—Platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B01J23/622—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
    • B01J23/626—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead with tin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/644—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/644—Arsenic, antimony or bismuth
    • B01J23/6445—Antimony
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/185—Phosphorus; Compounds thereof with iron group metals or platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/185—Phosphorus; Compounds thereof with iron group metals or platinum group metals
    • B01J27/1856—Phosphorus; Compounds thereof with iron group metals or platinum group metals with platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0205—Impregnation in several steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0207—Pretreatment of the support
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/22—Halogenating
    • B01J37/24—Chlorinating
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G35/00—Reforming naphtha
    • C10G35/04—Catalytic reforming
    • C10G35/06—Catalytic reforming characterised by the catalyst used
    • C10G35/085—Catalytic reforming characterised by the catalyst used containing platinum group metals or compounds thereof
    • C10G35/09—Bimetallic catalysts in which at least one of the metals is a platinum group metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/05—Nuclear magnetic resonance [NMR]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/10—Infrared [IR]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/28—Phosphorising
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/70—Catalyst aspects

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Claims (10)

1. Fremgangsmåde til fremstilling af en katalysator, som omfatter mindst ét metal M fra platingruppen, tin, en phosphorpromotor, en halogenforbindelse, en porøs bærer af alumina og mindst én promotor XI valgt fra gruppen bestående af gallium, indium, antimon, hvilken fremgangsmåde omfatter følgende trin: a) indføring af promotoren eller promotorerne XI og phosphor i en foruddannet sol af aluminaprecursor og derpå formning af bæreren, b) indføring af tin under indføringen af promotoren eller promotorerne XI og phosphor i trin a) og før formningen af bæreren, idet trin a) og b) er samtidige, c) tørring af det ved afslutningen af trin b) opnåede produkt, d) kalcinering af det i trin c) opnåede produkt ved en temperatur på mellem 350 og 650°C, e) deponering af mindst ét metal M fra platingruppen, f) tørring under en strøm af neutral gas eller en oxygenholdig gasstrøm ved en moderat temperatur, som ikke overstiger 150°C, g) kalcinering af det i trin f) opnåede produkt ved en temperatur på mellem 350 og 650°C.
2. Fremgangsmåde til fremstilling af en katalysator ifølge krav 1, hvor atomforholdet Sn/M er på mellem 0,5 og 4,0.
3. Fremgangsmåde til fremstilling af en katalysator ifølge et hvilket som helst af kravene 1-2, hvor forholdet Xl/M er på mellem 0,1 og 5,0.
4. Fremgangsmåde til fremstilling af en katalysator ifølge et hvilket som helst af kravene 1-3, hvor forholdet P/M er på mellem 0,2 og 30,0.
5. Fremgangsmåde til fremstilling af en katalysator ifølge et hvilket som helst af kravene 1-4, hvor indholdet af metallet M er på mellem 0,01 og 5 vægtprocent.
6. Fremgangsmåde til fremstilling af en katalysator ifølge et hvilket som helst af kravene 1-5, hvor metallet M er platin eller palladium.
7. Fremgangsmåde til fremstilling af en katalysator ifølge et hvilket som helst af kravene 1-6, hvor halogenforbindelsen er valgt fra gruppen bestående af fluor, chlor, brom og iod.
8. Fremgangsmåde til fremstilling af en katalysator ifølge et hvilket som helst af kravene 1-7, hvor indholdet af halogenforbindelsen er på mellem 0,1 og 15,0 vægtprocent.
9. Fremgangsmåde til fremstilling af en katalysator ifølge et hvilket som helst af kravene 1-8, hvor halogenforbindelsen er chlor, og indholdet af chlor er på mellem 0,1 og 5,0 vægtprocent.
10. Fremgangsmåde til fremstilling af en katalysator ifølge et hvilket som helst af kravene 1-9, hvor tinnet kun delvist kan indføres i trin b) , hvilken fremgangsmåde så omfatter et supplerende trin til deponering af en yderligere fraktion af tinnet på bæreren, enten mellem trin d) og e), eventuelt efterfulgt af en tørring og en kalcinering, eller mellem trin e) og f) , eller efter trin g), efterfulgt af en tørring og en kalcinering.
DK10734170.3T 2009-07-01 2010-06-15 Fremgangsmåde til fremstilling af en multimetallisk katalysator med en optimeret nærhed af sites DK2448670T3 (da)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0903226A FR2947465B1 (fr) 2009-07-01 2009-07-01 Catalyseur multi-metallique presentant une proximite de sites optimisee
PCT/FR2010/000443 WO2011012776A2 (fr) 2009-07-01 2010-06-15 Procede de preparation d'un catalyseur multi-métallique présentant une proximité de sites optimisée

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DK2448670T3 true DK2448670T3 (da) 2016-01-11

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US (2) US20120178979A1 (da)
EP (1) EP2448670B1 (da)
JP (1) JP5615917B2 (da)
CN (2) CN102665897A (da)
DK (1) DK2448670T3 (da)
FR (1) FR2947465B1 (da)
RU (1) RU2535206C2 (da)
WO (1) WO2011012776A2 (da)

Families Citing this family (7)

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Publication number Priority date Publication date Assignee Title
US20150133291A1 (en) * 2012-05-08 2015-05-14 Stc.Unm Hydrothermal Stability of Oxides With Carbon Coatings
CN104841425A (zh) * 2014-02-18 2015-08-19 中国石油化工股份有限公司 一种半再生催化重整催化剂及其制备方法
FR3039082B1 (fr) * 2015-07-24 2017-07-21 Ifp Energies Now Catalyseur multi-metallique dope par du phosphore et un lanthanide
FR3074063B1 (fr) * 2017-11-30 2019-11-01 IFP Energies Nouvelles Catalyseur multi-metallique dope par du phosphore et de l'ytterbium
FR3120076A1 (fr) 2021-02-22 2022-08-26 IFP Energies Nouvelles Procédé de production de composés aromatiques et/ou d’essences à partir d’une charge hydrocarbonée de type naphta
FR3123230A1 (fr) 2021-05-28 2022-12-02 IFP Energies Nouvelles Procédé de traitement à régénération continue de catalyseur d’une charge hydrocarbonée
FR3156335A1 (fr) * 2023-12-06 2025-06-13 Axens Catalyseur de reformage catalytique ayant une acidite optimisee

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Publication number Publication date
JP5615917B2 (ja) 2014-10-29
RU2535206C2 (ru) 2014-12-10
FR2947465A1 (fr) 2011-01-07
EP2448670A2 (fr) 2012-05-09
CN106423226B (zh) 2022-09-27
CN102665897A (zh) 2012-09-12
WO2011012776A3 (fr) 2011-11-17
US20120178979A1 (en) 2012-07-12
JP2012531306A (ja) 2012-12-10
CN106423226A (zh) 2017-02-22
US20170252726A1 (en) 2017-09-07
FR2947465B1 (fr) 2012-05-11
EP2448670B1 (fr) 2015-09-23
WO2011012776A2 (fr) 2011-02-03
RU2012103328A (ru) 2013-08-10

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