DK2493938T3 - POLYETHYLEN MANUFACTURED WITH CHILDREN LATE TRANSITION METAL CATALYST SYSTEMS - Google Patents

POLYETHYLEN MANUFACTURED WITH CHILDREN LATE TRANSITION METAL CATALYST SYSTEMS Download PDF

Info

Publication number: DK2493938T3
Authority: DK; Denmark
Prior art keywords: polyethylene; transition metal; late transition; silica; metal catalyst
Prior art date: 2009-10-29

Application number

DK10778604.8T

Other languages

Danish (da)

English (en)

Inventor

Sabine Sirol

Olivier Lhost

Original Assignee

Total Res & Technology Feluy

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2009-10-29

Filing date

2010-10-28

Publication date

2019-04-01

2010-10-28 Application filed by Total Res & Technology Feluy filed Critical Total Res & Technology Feluy

2019-04-01 Application granted granted Critical

2019-04-01 Publication of DK2493938T3 publication Critical patent/DK2493938T3/en

Links

-1 POLYETHYLEN Polymers 0.000 title claims description 27
239000003054 catalyst Substances 0.000 title claims description 25
229920000573 polyethylene Polymers 0.000 title claims description 23
229910052723 transition metal Inorganic materials 0.000 title claims description 8
150000003624 transition metals Chemical class 0.000 title claims description 8
101100020619 Arabidopsis thaliana LATE gene Proteins 0.000 title claims 2
239000004698 Polyethylene Substances 0.000 claims description 23
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 20
230000004913 activation Effects 0.000 claims description 16
238000000034 method Methods 0.000 claims description 13
230000003213 activating effect Effects 0.000 claims description 12
239000000377 silicon dioxide Substances 0.000 claims description 10
229910052782 aluminium Inorganic materials 0.000 claims description 8
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 7
239000005977 Ethylene Substances 0.000 claims description 7
239000002516 radical scavenger Substances 0.000 claims description 7
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 6
239000003795 chemical substances by application Substances 0.000 claims description 6
MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 claims description 6
125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 claims description 5
230000008569 process Effects 0.000 claims description 5
229910021585 Nickel(II) bromide Inorganic materials 0.000 claims description 4
IPLJNQFXJUCRNH-UHFFFAOYSA-L nickel(2+);dibromide Chemical compound [Ni+2].[Br-].[Br-] IPLJNQFXJUCRNH-UHFFFAOYSA-L 0.000 claims description 4
239000000178 monomer Substances 0.000 claims description 2
238000006116 polymerization reaction Methods 0.000 claims 3
229920000642 polymer Polymers 0.000 description 17
238000005259 measurement Methods 0.000 description 14
238000001542 size-exclusion chromatography Methods 0.000 description 11
239000011148 porous material Substances 0.000 description 10
238000005227 gel permeation chromatography Methods 0.000 description 9
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Natural products CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 8
230000000694 effects Effects 0.000 description 8
NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 8
239000002904 solvent Substances 0.000 description 7
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 6
CPOFMOWDMVWCLF-UHFFFAOYSA-N methyl(oxo)alumane Chemical group C[Al]=O CPOFMOWDMVWCLF-UHFFFAOYSA-N 0.000 description 6
PBKONEOXTCPAFI-UHFFFAOYSA-N 1,2,4-trichlorobenzene Chemical compound ClC1=CC=C(Cl)C(Cl)=C1 PBKONEOXTCPAFI-UHFFFAOYSA-N 0.000 description 5
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 5
150000001335 aliphatic alkanes Chemical class 0.000 description 5
239000004411 aluminium Substances 0.000 description 5
125000004432 carbon atom Chemical group C* 0.000 description 5
239000000126 substance Substances 0.000 description 5
150000001875 compounds Chemical class 0.000 description 4
FFUAGWLWBBFQJT-UHFFFAOYSA-N hexamethyldisilazane Chemical compound C[Si](C)(C)N[Si](C)(C)C FFUAGWLWBBFQJT-UHFFFAOYSA-N 0.000 description 4
239000001282 iso-butane Substances 0.000 description 4
239000003446 ligand Substances 0.000 description 4
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
230000000052 comparative effect Effects 0.000 description 3
229910000071 diazene Inorganic materials 0.000 description 3
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 3
239000002245 particle Substances 0.000 description 3
238000002360 preparation method Methods 0.000 description 3
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
238000001228 spectrum Methods 0.000 description 3
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
239000004793 Polystyrene Substances 0.000 description 2
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
239000012190 activator Substances 0.000 description 2
238000004458 analytical method Methods 0.000 description 2
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
230000003197 catalytic effect Effects 0.000 description 2
239000003085 diluting agent Substances 0.000 description 2
229910052742 iron Inorganic materials 0.000 description 2
229910052751 metal Inorganic materials 0.000 description 2
239000002184 metal Substances 0.000 description 2
125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
229910052759 nickel Inorganic materials 0.000 description 2
229920002223 polystyrene Polymers 0.000 description 2
238000000926 separation method Methods 0.000 description 2
239000002002 slurry Substances 0.000 description 2
230000007704 transition Effects 0.000 description 2
150000003623 transition metal compounds Chemical class 0.000 description 2
JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 2
RELMFMZEBKVZJC-UHFFFAOYSA-N 1,2,3-trichlorobenzene Chemical compound ClC1=CC=CC(Cl)=C1Cl RELMFMZEBKVZJC-UHFFFAOYSA-N 0.000 description 1
238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 description 1
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical group [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
NHTMVDHEPJAVLT-UHFFFAOYSA-N Isooctane Chemical compound CC(C)CC(C)(C)C NHTMVDHEPJAVLT-UHFFFAOYSA-N 0.000 description 1
238000005481 NMR spectroscopy Methods 0.000 description 1
239000004743 Polypropylene Substances 0.000 description 1
239000000853 adhesive Substances 0.000 description 1
230000001070 adhesive effect Effects 0.000 description 1
239000002156 adsorbate Substances 0.000 description 1
238000013019 agitation Methods 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
230000004888 barrier function Effects 0.000 description 1
239000011324 bead Substances 0.000 description 1
230000009286 beneficial effect Effects 0.000 description 1
230000008901 benefit Effects 0.000 description 1
UHOVQNZJYSORNB-MZWXYZOWSA-N benzene-d6 Chemical compound [2H]C1=C([2H])C([2H])=C([2H])C([2H])=C1[2H] UHOVQNZJYSORNB-MZWXYZOWSA-N 0.000 description 1
229910052796 boron Inorganic materials 0.000 description 1
239000001273 butane Substances 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
150000001735 carboxylic acids Chemical class 0.000 description 1
238000010516 chain-walking reaction Methods 0.000 description 1
238000012512 characterization method Methods 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
238000002425 crystallisation Methods 0.000 description 1
230000007423 decrease Effects 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
238000003795 desorption Methods 0.000 description 1
230000001627 detrimental effect Effects 0.000 description 1
RAABOESOVLLHRU-UHFFFAOYSA-N diazene Chemical compound N=N RAABOESOVLLHRU-UHFFFAOYSA-N 0.000 description 1
JVSWJIKNEAIKJW-UHFFFAOYSA-N dimethyl-hexane Natural products CCCCCC(C)C JVSWJIKNEAIKJW-UHFFFAOYSA-N 0.000 description 1
229920001971 elastomer Polymers 0.000 description 1
239000000806 elastomer Substances 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
230000002349 favourable effect Effects 0.000 description 1
238000001595 flow curve Methods 0.000 description 1
239000007789 gas Substances 0.000 description 1
229910052736 halogen Inorganic materials 0.000 description 1
150000002367 halogens Chemical class 0.000 description 1
DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 1
UQEAIHBTYFGYIE-UHFFFAOYSA-N hexamethyldisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)C UQEAIHBTYFGYIE-UHFFFAOYSA-N 0.000 description 1
125000001183 hydrocarbyl group Chemical group 0.000 description 1
230000006872 improvement Effects 0.000 description 1
238000002347 injection Methods 0.000 description 1
239000007924 injection Substances 0.000 description 1
230000007774 longterm Effects 0.000 description 1
230000007246 mechanism Effects 0.000 description 1
238000000465 moulding Methods 0.000 description 1
IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
230000007935 neutral effect Effects 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
230000003534 oscillatory effect Effects 0.000 description 1
229910052763 palladium Inorganic materials 0.000 description 1
KDLHZDBZIXYQEI-UHFFFAOYSA-N palladium Substances [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 1
125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
230000000737 periodic effect Effects 0.000 description 1
239000002685 polymerization catalyst Substances 0.000 description 1
229920001155 polypropylene Polymers 0.000 description 1
239000001294 propane Substances 0.000 description 1
230000008707 rearrangement Effects 0.000 description 1
229920005989 resin Polymers 0.000 description 1
239000011347 resin Substances 0.000 description 1
238000000974 shear rheometry Methods 0.000 description 1
239000007787 solid Substances 0.000 description 1
238000001179 sorption measurement Methods 0.000 description 1
230000003595 spectral effect Effects 0.000 description 1
238000010998 test method Methods 0.000 description 1
125000003944 tolyl group Chemical group 0.000 description 1
VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 1
239000003643 water by type Substances 0.000 description 1
239000004711 α-olefin Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/02—Carriers therefor
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/70—Iron group metals, platinum group metals or compounds thereof

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

DK10778604.8T 2009-10-29 2010-10-28 POLYETHYLEN MANUFACTURED WITH CHILDREN LATE TRANSITION METAL CATALYST SYSTEMS DK2493938T3 (en)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
EP09174498A EP2316864A1 (en)	2009-10-29	2009-10-29	Polyethylene prepared with supported late transition metal catalyst system.
PCT/EP2010/066320 WO2011051371A1 (en)	2009-10-29	2010-10-28	Polyethylene prepared with supported late transition metal catalyst systems

Publications (1)

Publication Number	Publication Date
DK2493938T3 true DK2493938T3 (en)	2019-04-01

Family

ID=41818604

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DK10778604.8T DK2493938T3 (en)	2009-10-29	2010-10-28	POLYETHYLEN MANUFACTURED WITH CHILDREN LATE TRANSITION METAL CATALYST SYSTEMS

Country Status (11)

Country	Link
US (2)	US8822612B2 (2)
EP (2)	EP2316864A1 (2)
KR (1)	KR101472643B1 (2)
CN (1)	CN102597019A (2)
BR (1)	BR112012010048A2 (2)
DK (1)	DK2493938T3 (2)
EA (1)	EA201270593A1 (2)
ES (1)	ES2715080T3 (2)
IN (1)	IN2012DN01557A (2)
MX (1)	MX2012004950A (2)
WO (1)	WO2011051371A1 (2)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US11332552B2 (en) *	2016-05-20	2022-05-17	Chevron Phillips Chemical Company Lp	Low pressure process for preparing low-density polyethylene
KR101958015B1 (ko)	2016-11-08	2019-07-04	주식회사 엘지화학	에틸렌/알파-올레핀 공중합체
CN107118288B (zh) *	2017-05-25	2019-10-18	江苏奥克化学有限公司	一种负载型后过渡金属催化剂及其制备方法
KR20260021818A (ko) *	2018-09-17	2026-02-13	셰브론 필립스 케미컬 컴퍼니 엘피	크롬 촉매의 광 처리, 관련 촉매 제조 시스템 및 중합 공정

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US5700895A (en) *	1993-08-23	1997-12-23	Sumitomo Chemical Company, Limited	Ethylene-α-olefin copolymer and molded article thereof
US5880241A (en) *	1995-01-24	1999-03-09	E. I. Du Pont De Nemours And Company	Olefin polymers
JP3847783B2 (ja)	1995-01-24	2006-11-22	イー・アイ・デュポン・ドゥ・ヌムール・アンド・カンパニー	オレフィンの重合方法
JPH08306233A (ja) *	1995-05-08	1996-11-22	Fujikura Ltd	電力ケーブル用絶縁体組成物
IL129929A0 (en)	1996-12-17	2000-02-29	Du Pont	Polymerization of ethylene with specific iron or cobalt complexes novel pyridinebis (imines) and novel complexes of pyridinebis(imines) with iron and cobalt
US5865677A (en)	1997-01-03	1999-02-02	Tiger Electronics, Ltd.	Hand-held electronic game
JP2001512522A (ja)	1997-02-25	2001-08-21	イーストマンケミカルカンパニー	官能化オレフィンモノマーを含有するポリマー
US6103658A (en) *	1997-03-10	2000-08-15	Eastman Chemical Company	Olefin polymerization catalysts containing group 8-10 transition metals, processes employing such catalysts and polymers obtained therefrom
US6822062B2 (en) *	1997-03-10	2004-11-23	Eastman Chemical Company	Supported group 8-10 transition metal olefin polymerization catalysts
CA2210131C (en) *	1997-07-09	2005-08-02	Douglas W. Stephan	Supported phosphinimine-cp catalysts
US6255414B1 (en) *	1998-09-01	2001-07-03	E. I. Du Pont De Nemours And Company	Polymerization of olefins
JP2000080125A (ja) *	1998-09-08	2000-03-21	Idemitsu Petrochem Co Ltd	エチレン単独重合体及びそれを成形してなる成形体
WO2000022007A1 (en) *	1998-10-14	2000-04-20	E.I. Du Pont De Nemours And Company	Polymerization of olefins
US6531424B2 (en) *	1999-12-17	2003-03-11	E. I. Du Pont De Nemours And Company	Polymerization of olefins
DE60211305T2 (de) *	2001-01-12	2007-03-29	Total Petrochemicals Research Feluy, Seneffe	Metallocen-filmharz
EP1674523A1 (en) *	2004-12-22	2006-06-28	Total Petrochemicals Research Feluy	Caps and closures
US20060199727A1 (en)	2005-03-04	2006-09-07	Brookhart Maurice S	Supported olefin polymerization catalysts
JP2007177183A (ja) *	2005-12-28	2007-07-12	Nippon Polyethylene Kk	電線・ケーブル被覆用樹脂材料及びそれを用いた被覆電線・ケーブル
JP5414971B2 (ja) *	2005-12-28	2014-02-12	日本ポリエチレン株式会社	エチレン系樹脂組成物によるフィルム
EP1972642A1 (en)	2007-03-19	2008-09-24	Total Petrochemicals Research Feluy	Homo-or co-polymers of ethylene with combination of processability and toughness properties
WO2009069823A1 (ja) *	2007-11-30	2009-06-04	Sumitomo Chemical Company, Limited	エチレン－α－オレフィン共重合体および成形体
JP2011099092A (ja) *	2009-09-30	2011-05-19	Sumitomo Chemical Co Ltd	エチレン系重合体

2009
- 2009-10-29 EP EP09174498A patent/EP2316864A1/en not_active Withdrawn
2010
- 2010-10-28 WO PCT/EP2010/066320 patent/WO2011051371A1/en not_active Ceased
- 2010-10-28 EA EA201270593A patent/EA201270593A1/ru unknown
- 2010-10-28 KR KR1020127009942A patent/KR101472643B1/ko not_active Expired - Fee Related
- 2010-10-28 MX MX2012004950A patent/MX2012004950A/es not_active Application Discontinuation
- 2010-10-28 IN IN1557DEN2012 patent/IN2012DN01557A/en unknown
- 2010-10-28 US US13/502,158 patent/US8822612B2/en not_active Expired - Fee Related
- 2010-10-28 BR BR112012010048A patent/BR112012010048A2/pt not_active IP Right Cessation
- 2010-10-28 EP EP10778604.8A patent/EP2493938B1/en not_active Not-in-force
- 2010-10-28 DK DK10778604.8T patent/DK2493938T3/en active
- 2010-10-28 ES ES10778604T patent/ES2715080T3/es active Active
- 2010-10-28 CN CN2010800490091A patent/CN102597019A/zh active Pending
2014
- 2014-07-07 US US14/324,402 patent/US9181366B2/en not_active Expired - Fee Related

Also Published As

Publication number	Publication date
CN102597019A (zh)	2012-07-18
IN2012DN01557A (2)	2015-06-05
BR112012010048A2 (pt)	2016-05-24
EA201270593A1 (ru)	2012-09-28
MX2012004950A (es)	2012-06-12
US8822612B2 (en)	2014-09-02
ES2715080T3 (es)	2019-05-31
US20120277388A1 (en)	2012-11-01
WO2011051371A1 (en)	2011-05-05
KR20120068925A (ko)	2012-06-27
EP2493938A1 (en)	2012-09-05
EP2316864A1 (en)	2011-05-04
KR101472643B1 (ko)	2014-12-15
US20140323675A1 (en)	2014-10-30
US9181366B2 (en)	2015-11-10
EP2493938B1 (en)	2018-12-12

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