DK2631269T3 - Fiberkvalitet med forbedret spindingsydeevne og mekaniske egenskaber - Google Patents
Fiberkvalitet med forbedret spindingsydeevne og mekaniske egenskaber Download PDFInfo
- Publication number
- DK2631269T3 DK2631269T3 DK12156791.1T DK12156791T DK2631269T3 DK 2631269 T3 DK2631269 T3 DK 2631269T3 DK 12156791 T DK12156791 T DK 12156791T DK 2631269 T3 DK2631269 T3 DK 2631269T3
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- DK
- Denmark
- Prior art keywords
- polypropylene
- polypropylene composition
- composition
- mfr2
- iso
- Prior art date
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- 239000000835 fiber Substances 0.000 title claims description 54
- 238000009987 spinning Methods 0.000 title claims description 20
- 229920001155 polypropylene Polymers 0.000 claims description 470
- 239000004743 Polypropylene Substances 0.000 claims description 350
- -1 polypropylene Polymers 0.000 claims description 337
- 239000000203 mixture Substances 0.000 claims description 162
- 101100023124 Schizosaccharomyces pombe (strain 972 / ATCC 24843) mfr2 gene Proteins 0.000 claims description 61
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 52
- 239000000155 melt Substances 0.000 claims description 51
- 229920001577 copolymer Polymers 0.000 claims description 49
- 238000000034 method Methods 0.000 claims description 35
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 30
- 239000005977 Ethylene Substances 0.000 claims description 30
- 229920001384 propylene homopolymer Polymers 0.000 claims description 29
- 239000004744 fabric Substances 0.000 claims description 28
- 238000002844 melting Methods 0.000 claims description 26
- 230000008018 melting Effects 0.000 claims description 26
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 18
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 12
- 239000008096 xylene Substances 0.000 claims description 12
- 206010021639 Incontinence Diseases 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 3
- 230000001681 protective effect Effects 0.000 claims description 3
- 238000003825 pressing Methods 0.000 claims description 2
- 208000012886 Vertigo Diseases 0.000 claims 5
- 229920001519 homopolymer Polymers 0.000 claims 2
- 150000001336 alkenes Chemical class 0.000 claims 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 1
- 238000010791 quenching Methods 0.000 claims 1
- 230000000171 quenching effect Effects 0.000 claims 1
- 229920000642 polymer Polymers 0.000 description 23
- 150000002978 peroxides Chemical class 0.000 description 10
- 239000003054 catalyst Substances 0.000 description 9
- 238000000113 differential scanning calorimetry Methods 0.000 description 9
- 238000002360 preparation method Methods 0.000 description 9
- 238000002156 mixing Methods 0.000 description 8
- 239000004711 α-olefin Substances 0.000 description 7
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 6
- 239000007789 gas Substances 0.000 description 6
- 239000008187 granular material Substances 0.000 description 6
- 239000008188 pellet Substances 0.000 description 6
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 5
- 239000011954 Ziegler–Natta catalyst Substances 0.000 description 5
- 238000009826 distribution Methods 0.000 description 5
- 238000006116 polymerization reaction Methods 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 4
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 4
- 238000002425 crystallisation Methods 0.000 description 4
- 230000008025 crystallization Effects 0.000 description 4
- 229920005629 polypropylene homopolymer Polymers 0.000 description 4
- DMWVYCCGCQPJEA-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhexane Chemical compound CC(C)(C)OOC(C)(C)CCC(C)(C)OOC(C)(C)C DMWVYCCGCQPJEA-UHFFFAOYSA-N 0.000 description 3
- BIISIZOQPWZPPS-UHFFFAOYSA-N 2-tert-butylperoxypropan-2-ylbenzene Chemical compound CC(C)(C)OOC(C)(C)C1=CC=CC=C1 BIISIZOQPWZPPS-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- 238000005481 NMR spectroscopy Methods 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 239000004745 nonwoven fabric Substances 0.000 description 3
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 2
- 238000012565 NMR experiment Methods 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 239000002216 antistatic agent Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 2
- 235000013539 calcium stearate Nutrition 0.000 description 2
- 239000008116 calcium stearate Substances 0.000 description 2
- 239000003426 co-catalyst Substances 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 239000010408 film Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000002667 nucleating agent Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000011002 quantification Methods 0.000 description 2
- 229920005604 random copolymer Polymers 0.000 description 2
- 238000000518 rheometry Methods 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- YWEWWNPYDDHZDI-JJKKTNRVSA-N (1r)-1-[(4r,4ar,8as)-2,6-bis(3,4-dimethylphenyl)-4,4a,8,8a-tetrahydro-[1,3]dioxino[5,4-d][1,3]dioxin-4-yl]ethane-1,2-diol Chemical compound C1=C(C)C(C)=CC=C1C1O[C@H]2[C@@H]([C@H](O)CO)OC(C=3C=C(C)C(C)=CC=3)O[C@H]2CO1 YWEWWNPYDDHZDI-JJKKTNRVSA-N 0.000 description 1
- VNQNXQYZMPJLQX-UHFFFAOYSA-N 1,3,5-tris[(3,5-ditert-butyl-4-hydroxyphenyl)methyl]-1,3,5-triazinane-2,4,6-trione Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CN2C(N(CC=3C=C(C(O)=C(C=3)C(C)(C)C)C(C)(C)C)C(=O)N(CC=3C=C(C(O)=C(C=3)C(C)(C)C)C(C)(C)C)C2=O)=O)=C1 VNQNXQYZMPJLQX-UHFFFAOYSA-N 0.000 description 1
- 238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 description 1
- ODBCKCWTWALFKM-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhex-3-yne Chemical compound CC(C)(C)OOC(C)(C)C#CC(C)(C)OOC(C)(C)C ODBCKCWTWALFKM-UHFFFAOYSA-N 0.000 description 1
- PSXUKPCAIKETHF-UHFFFAOYSA-N 2-[4-[3-[4-(4,5-dihydro-1h-imidazol-2-yl)phenoxy]propoxy]phenyl]-4,5-dihydro-1h-imidazole Chemical compound C=1C=C(C=2NCCN=2)C=CC=1OCCCOC(C=C1)=CC=C1C1=NCCN1 PSXUKPCAIKETHF-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical class OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- 102100029579 Diphosphoinositol polyphosphate phosphohydrolase 1 Human genes 0.000 description 1
- UAUDZVJPLUQNMU-UHFFFAOYSA-N Erucasaeureamid Natural products CCCCCCCCC=CCCCCCCCCCCCC(N)=O UAUDZVJPLUQNMU-UHFFFAOYSA-N 0.000 description 1
- 229920000181 Ethylene propylene rubber Polymers 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- SJJCABYOVIHNPZ-UHFFFAOYSA-N cyclohexyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C1CCCCC1 SJJCABYOVIHNPZ-UHFFFAOYSA-N 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 description 1
- JWCYDYZLEAQGJJ-UHFFFAOYSA-N dicyclopentyl(dimethoxy)silane Chemical compound C1CCCC1[Si](OC)(OC)C1CCCC1 JWCYDYZLEAQGJJ-UHFFFAOYSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- UAUDZVJPLUQNMU-KTKRTIGZSA-N erucamide Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(N)=O UAUDZVJPLUQNMU-KTKRTIGZSA-N 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
- YQEMORVAKMFKLG-UHFFFAOYSA-N glycerine monostearate Natural products CCCCCCCCCCCCCCCCCC(=O)OC(CO)CO YQEMORVAKMFKLG-UHFFFAOYSA-N 0.000 description 1
- SVUQHVRAGMNPLW-UHFFFAOYSA-N glycerol monostearate Natural products CCCCCCCCCCCCCCCCC(=O)OCC(O)CO SVUQHVRAGMNPLW-UHFFFAOYSA-N 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 229960001545 hydrotalcite Drugs 0.000 description 1
- 229910001701 hydrotalcite Inorganic materials 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 101710153356 mRNA-decapping protein g5R Proteins 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 1
- KOFGHHIZTRGVAF-UHFFFAOYSA-N n-ethyl-n-triethoxysilylethanamine Chemical compound CCO[Si](OCC)(OCC)N(CC)CC KOFGHHIZTRGVAF-UHFFFAOYSA-N 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- JGMMIGGLIIRHFV-UHFFFAOYSA-N nonane-1,2,3,4,5,6,7,8,9-nonol Chemical class OCC(O)C(O)C(O)C(O)C(O)C(O)C(O)CO JGMMIGGLIIRHFV-UHFFFAOYSA-N 0.000 description 1
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 description 1
- FATBGEAMYMYZAF-UHFFFAOYSA-N oleicacidamide-heptaglycolether Natural products CCCCCCCCC=CCCCCCCCC(N)=O FATBGEAMYMYZAF-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 230000003534 oscillatory effect Effects 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920005606 polypropylene copolymer Polymers 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 239000012748 slip agent Substances 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/44—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
- D01F6/46—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polyolefins
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/08—Melt spinning methods
- D01D5/098—Melt spinning methods with simultaneous stretching
- D01D5/0985—Melt spinning methods with simultaneous stretching by means of a flowing gas (e.g. melt-blowing)
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/12—Stretch-spinning methods
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
- D04H3/005—Synthetic yarns or filaments
- D04H3/007—Addition polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/12—Applications used for fibers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2321/00—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D10B2321/02—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins
- D10B2321/022—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins polypropylene
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2501/00—Wearing apparel
- D10B2501/04—Outerwear; Protective garments
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2505/00—Industrial
- D10B2505/04—Filters
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2509/00—Medical; Hygiene
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/298—Physical dimension
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/608—Including strand or fiber material which is of specific structural definition
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Mechanical Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Artificial Filaments (AREA)
- Nonwoven Fabrics (AREA)
Claims (15)
1. Polypropylensammensætning (PP-C), som omfatter a) mindst 80 vægt-%, baseret på den samlede vægt af polypropylensam-mensætningen (PP-C), af en polypropylen (L-PP) homo- eller copolymer med et smelteindeks i henhold til ISO 1133 (230 °C/2,16 kg) i området 0,1 g/10min til 15 g/10 min og et comonomerindhold på op til 5 vægt-%, idet comonomererne er udvalgt blandt ethylen og/eller C4- til Ci0-a-olefin, og b) mellem 2 vægt-% og 20 vægt-%, baseret på den samlede vægt af po-lypropylensammensætningen (PP-C), af en polypropylen (H-PP) homo- eller copolymer med et smelteindeks i henhold til ISO 1133 (230 °C/2,16 kg) i området 200 g/10 min til 2.500 g/10 min og et comonomerindhold på op til 5 vægt-%, idet comonomerne er udvalgt blandt ethylen og/eller C4- til C-m-a-olefin, hvor polypropylensammensætningen (PP-C) har et smelteindeks i henhold til ISO 1133 (230 °C/2,16 kg) i området 10 g/10 min til 60 g/10 min og et po-lydispersitetsindeks (PI) på ikke mere end 4,0.
2. Polypropylensammensætning (PP-C) ifølge krav 1, hvor polypropylen (L-PP) har a) et smelteindeks i henhold til ISO 1133 (230°C/2,16 kg) i området 0,5 g/10 min til 15 g/10 min, og/eller b) en smeltetemperatur Tm målt i henhold til ISO 11357-3 på mindst 150 °C, og/eller c) et kold xylen-opløseligt indhold (XCS) målt i henhold til ISO 6427 (23 °C) på ikke mere end 3,5 vægt-%.
3. Polypropylensammensætning (PP-C) ifølge krav 1 eller 2, hvor polypropylen (H-PP) har a) et smelteindeks i henhold til ISO 1133 (230 °C/2,16 kg) i området 400 g/10 min til 2.000 g/10 min, og/eller b) et kold xylen-opløseligt indhold (XCS) målt i henhold til ISO 6427 (23 °C) på ikke mere end 3,5 vægt-%.
4. Polypropylensammensætning (PP-C) ifølge et hvilket som helst af kravene 1 til 3, hvor a) polypropylen (L-PP) er et propylenhomopolymer (HL-PP), og/eller b) polypropylen (H-PP) er en propylenhomopolymer (HH-PP).
5. Polypropylensammensætning (PP-C) ifølge et hvilket som helst af kravene 1 til 4, hvor polypropylensammensætningen (PP-C) omfatter a) mindst 90 vægt-% polypropylen (L-PP) og b) mellem 3 vægt-% og 10 vægt-% polypropylen (H-PP), baseret på den samlede vægt af polypropylensammensætningen (PP-C), eventuelt baseret på den samlede mængde af polypropylen (L-PP) og polypropylen (H-PP) tilsammen.
6. Polypropylensammensætning (PP-C) ifølge et hvilket som helst af kravene 1 til 5, hvor forholdet af smelteindeks i henhold til ISO 1133 (230 °C/2,16 kg) mellem polypropylen (H-PP) og polypropylen (L-PP) [MFR2 (H-PP) / MFR2 (L-PP)] er mindst 10, hvor "MFR2 (H-PP)" er MFR2 (230°C) af polypropylen (H-PP) før visbreaking, og "MFR2 (L-PP)" er MFR2 (230 °C) af polypropylen (L-PP) før visbreaking.
7. Polypropylensammensætning (PP-C) ifølge et hvilket som helst af kravene 1 til 6, hvor polypropylensammensætningen (PP-C) a) har et smelteindeks i henhold til ISO 1133 (230 °C/2,16 kg) i området 25 g/10 min til 40 g/10 min, og/eller b) har et polydispersitetsindeks (PI) i området 2,0 til 4,0, og/eller c) er blevet udsat for visbreaking.
8. Polypropylensammensætning (PP-C) ifølge et hvilket som helst af kravene 1 til 7, hvor polypropylensammensætningen (PP-C), der omfatter polypropylen (L-PP) og polypropylen (H-PP), er blevet udsat for visbreaking med et visbreaking-forhold [endeligt MFR2 (230 °C) / indledende MFR2 (230 °C)] på 9 til 50, hvor "endeligt MFR2 (230 °C)" er MFR2 (230 °C) af propylensam- mensætningen (PP-C) efter visbreaking, og "indledende MFR2 (230 °C)" er MFR2 (230 °C) af polypropylensammensætningen (PP-C) før visbreaking.
9. Polypropylensammensætning (PP-C) ifølge et hvilket som helst af kravene 1 til 8, hvor polypropylensammensætningen (PP-C) har et polydispersitetsin-deks (Pl)-forhold [indledende PI / endeligt PI] på mindst 1,3, hvor "endeligt PI" er polydispersitetsindekset (PI) af polypropylensammensætningen (PP-C) efter visbreaking, og "indledende PI" er polydispersitetsindekset (PI) af polypropylensammensætningen (PP-C) før visbreaking.
10. Polypropylenfiber (PP-F) med en gennemsnitlig filamentfinhed på ikke mere end 1,50 denier, hvor fiberen (PP-F) omfatter mindst 95 vægt-%, baseret på den samlede vægt af polypropylenfiberen (PP-F), af en polypropylen-sammensætning (PP-C) ifølge et hvilket som helst af kravene 1 til 9.
11. Spunbonded stof omfattende polypropylenfibre (PP-F) ifølge krav 10 og/eller en polypropylensammensætning (PP-C) ifølge et hvilket som helst af kravene 1 til 9.
12. Artikel, omfattende en polypropylenfiber (PP-F) ifølge krav 10 og/eller spunbonded stof ifølge krav 11, hvor artiklen er udvalgt fra gruppen bestående af filtreringsmedium, ble, hygiejnebind, trusseindlæg, inkontinensprodukt til voksne, beskyttende tøj, afdækningsstykke, operationskittel og operationstøj.
13. Fremgangsmåde til fremstilling af spunbonded stof ifølge krav 11 eller en artikel ifølge krav 12, hvor en polypropylensammensætning (PP-C) ifølge et hvilket som helst af kravene 1 til 9 er blevet spunbonded under anvendelse af en fiberspindingslinje ved et maksimalt kabine-lufttryk på mindst of 3.000 Pa.
14. Fremgangsmåde ifølge krav 13, hvor fiberspindingslinjen omfatter følgende trin: a) at tilføre polypropylensammensætningen (PP-C) ind i en ekstruder til smeltning af polypropylensammensætningen (PP-C), b) at presse den smeltede polypropylensammensætning (PP-C) gennem en spindedyse, der har huller på 0,4 mm til 0,7 mm diameter og 65 til 75 huller pr. cm med 0,3 g til 1 g pr. hul pr. meter, til dannelse af polypropylenfibre (PP-F) og c) at quenche og trække polypropylenfibrene (PP-F) ved filament-hastigheder på mindst 3800 m/min.
15. Anvendelse af en polypropylensammensætning (PP-C) ifølge et hvilket som helst af kravene 1 til 9 til forbedring af spindingsstabiliteten af en fiber-spindingslinje, udtrykt ved det maksimale kabine-lufttryk under fiberspinding-behandlingen, hvor forbedringen er defineret ved formlen (I) (pp-c) / (pp-oc; >1,1 (i) hvor (PP-C) er det maksimale anvendelige kabine-lufttryk [Pa] for polypropylen-sammensætningen (PP-C) omfattende polypropylen (L-PP) og polypropylen (H-PP), (PP-OC) er det maksimale anvendelige kabine-lufttryk [Pa] for po-lypropylensammensætningen (PP-C) uden polypropylen (H-PP).
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| EP12156791.1A EP2631269B1 (en) | 2012-02-24 | 2012-02-24 | Fiber grade with improved spinning performance and mechanical properties |
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| USD732810S1 (en) | 2013-08-08 | 2015-06-30 | Tbl Licensing Llc | Footwear outsole |
| WO2015073855A1 (en) * | 2013-11-15 | 2015-05-21 | W.R. Grace & Co.-Conn | Propylene-based polymer with reduced high-molecular weight portion |
| BR112016011829B1 (pt) * | 2013-12-04 | 2022-01-18 | Borealis Ag | Composição de polipropileno, fibra e trama soprada em fusão, artigo e uso da composição de polipropileno |
| WO2016036466A2 (en) * | 2014-09-05 | 2016-03-10 | Exxomobil Chemical Patents Inc. | Polymer compositions and nonwoven materials prepared therefrom |
| US9879364B2 (en) | 2015-10-30 | 2018-01-30 | Exxonmobil Chemical Patents Inc. | Polymer compositions for staple and multifilament fibers |
| EP3400330B1 (en) | 2016-01-04 | 2021-11-17 | Borealis AG | Spunbonded nonwoven fabrics made of phthalate-free pp homopolymers |
| JP2019148032A (ja) * | 2018-02-27 | 2019-09-05 | 出光興産株式会社 | 繊維及び不織布 |
| WO2020011825A1 (en) * | 2018-07-13 | 2020-01-16 | Borealis Ag | Heterophasic polypropylene composition with improved balance of properties |
| USD912954S1 (en) | 2018-08-01 | 2021-03-16 | Tbl Licensing Llc | Footwear |
| USD905411S1 (en) | 2018-08-01 | 2020-12-22 | Tbl Licensing Llc | Footwear outsole |
| USD905408S1 (en) | 2018-08-01 | 2020-12-22 | Tbl Licensing Llc | Footwear outsole |
| USD905406S1 (en) | 2018-08-01 | 2020-12-22 | Tbl Licensing Llc | Footwear outsole |
| US20210324119A1 (en) * | 2018-09-21 | 2021-10-21 | Borealis Ag | Polypropylene composition for melt spun fiber applications |
| WO2020097183A1 (en) * | 2018-11-06 | 2020-05-14 | Kimberly-Clark Worldwide, Inc. | Method of making fine spunbond fiber nonwoven fabrics at high through-puts |
| EP3980588B1 (en) | 2019-06-07 | 2024-10-09 | Basell Poliolefine Italia S.r.l. | Propylene polymer fibers |
| CN112538213A (zh) * | 2020-08-20 | 2021-03-23 | 李野 | 一种pp专用纺粘料及其制作方法 |
| JP7882667B2 (ja) * | 2022-03-14 | 2026-06-30 | 株式会社プライムポリマー | ポリプロピレン繊維、および、その製造方法 |
| US20230399261A1 (en) * | 2022-06-10 | 2023-12-14 | Braskem S.A. | Polypropylene fiber for fiber cement-reinforced composites |
| EP4450685A1 (en) * | 2023-04-20 | 2024-10-23 | Basell Poliolefine Italia S.r.l. | Fiber comprising a propylene based polymers composition |
| WO2025131861A1 (en) | 2023-12-18 | 2025-06-26 | Sabic Global Technologies B.V. | Spun bond nonwoven fabric |
| WO2026042031A1 (en) * | 2024-08-22 | 2026-02-26 | 3M Innovative Properties Company | Polymer composition having a first and second polypropylene, fibers with such polymer composition, and nonwoven fabrics with such polymer composition |
| EP4759838A1 (en) | 2024-12-13 | 2026-06-17 | Abu Dhabi Polymers Co. Ltd (Borouge) - Sole Proprietorship L.L.C. | Polypropylene composition for fiber, molding or extrusion coating applications |
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| US5234879A (en) | 1990-12-19 | 1993-08-10 | Neste Oy | Method for the modification of catalysts intended for the polymerization of olefins |
| FI86867C (fi) | 1990-12-28 | 1992-10-26 | Neste Oy | Flerstegsprocess foer framstaellning av polyeten |
| FI88047C (fi) | 1991-05-09 | 1993-03-25 | Neste Oy | Pao tvenne elektrondonorer baserad katalysator foer polymerisation av olefiner |
| FI88048C (fi) | 1991-05-09 | 1993-03-25 | Neste Oy | Grovkornig polyolefin, dess framstaellningsmetod och en i metoden anvaend katalysator |
| DE69324280T2 (de) * | 1992-01-13 | 1999-08-12 | Hercules Inc., Wilmington, Del. | Wärmeverbindbare Fasern für wiederstandsfähige Vliesstoffe |
| US5529845A (en) | 1994-06-13 | 1996-06-25 | Montell North America Inc. | Fibers suitable for the production of nonwoven fabrics having improved strength and softness characteristics |
| US5549867A (en) * | 1994-11-03 | 1996-08-27 | Fiberweb North America, Inc. | Distribution enhanced polyolefin meltspinning process and product |
| US5820981A (en) * | 1996-04-02 | 1998-10-13 | Montell North America Inc. | Radiation visbroken polypropylene and fibers made therefrom |
| FI111848B (fi) | 1997-06-24 | 2003-09-30 | Borealis Tech Oy | Menetelmä ja laitteisto propeenin homo- ja kopolymeerien valmistamiseksi |
| DE69812710T2 (de) | 1997-12-23 | 2003-10-23 | Borealis Technology Oy, Porvoo | Löslicher magnesiumhalogenidkomplex, herstellung und verwendung |
| US6476135B1 (en) * | 2000-06-07 | 2002-11-05 | Basell Poliolefine Italia S.P.A. | Polyolefin composition containing low viscosity propylene homopolymer, fiber and extensible non-woven fabric prepared therefrom |
| WO2003035746A1 (en) * | 2001-10-25 | 2003-05-01 | Polypropylene Belgium (Naamloze Vennootschap) | Use of a polypropylene based composition for expanded beads |
| US7998579B2 (en) * | 2002-08-12 | 2011-08-16 | Exxonmobil Chemical Patents Inc. | Polypropylene based fibers and nonwovens |
| WO2005080497A1 (en) * | 2004-02-12 | 2005-09-01 | Exxonmobil Chemical Patents Inc. | Polypropylene resin suitable for fibers and nonwovens |
| JP4782800B2 (ja) * | 2004-12-17 | 2011-09-28 | エクソンモービル・ケミカル・パテンツ・インク | 均一ポリマー・ブレンドおよび該ブレンドからの製品 |
| PL2325248T3 (pl) * | 2009-11-16 | 2012-11-30 | Borealis Ag | Włókna pneumotermiczne typu melt blown z kompozycji polipropylenowych |
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- 2012-02-24 DK DK12156791.1T patent/DK2631269T3/da active
- 2012-02-24 ES ES12156791.1T patent/ES2634514T3/es active Active
- 2012-02-24 EP EP12156791.1A patent/EP2631269B1/en active Active
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2013
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- 2013-02-15 WO PCT/EP2013/053050 patent/WO2013124219A1/en not_active Ceased
- 2013-02-15 US US14/379,183 patent/US10519570B2/en active Active
- 2013-02-15 JP JP2014558072A patent/JP5885860B2/ja active Active
- 2013-02-15 CN CN201380009812.6A patent/CN104114634B/zh active Active
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Also Published As
| Publication number | Publication date |
|---|---|
| JP2015513578A (ja) | 2015-05-14 |
| KR20140119821A (ko) | 2014-10-10 |
| ES2634514T3 (es) | 2017-09-28 |
| JP5885860B2 (ja) | 2016-03-16 |
| CN104114634B (zh) | 2015-10-07 |
| US20150024650A1 (en) | 2015-01-22 |
| US10519570B2 (en) | 2019-12-31 |
| EP2631269A1 (en) | 2013-08-28 |
| EP2631269B1 (en) | 2017-05-10 |
| CN104114634A (zh) | 2014-10-22 |
| BR112014020379B1 (pt) | 2020-11-03 |
| WO2013124219A1 (en) | 2013-08-29 |
| KR101679943B1 (ko) | 2016-11-25 |
| PL2631269T3 (pl) | 2017-09-29 |
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