DK2635541T3 - Bindemiddel til måtter af fibre, navnlig af mineralske fibre, og opnåede produkter - Google Patents

Bindemiddel til måtter af fibre, navnlig af mineralske fibre, og opnåede produkter Download PDF

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Publication number
DK2635541T3
DK2635541T3 DK11799744.5T DK11799744T DK2635541T3 DK 2635541 T3 DK2635541 T3 DK 2635541T3 DK 11799744 T DK11799744 T DK 11799744T DK 2635541 T3 DK2635541 T3 DK 2635541T3
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fibers
weight
binder according
binder
polysaccharide
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DK11799744.5T
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Matthieu Varagnat
Boris Jaffrennou
Katarzyna Chuda
Said Lamou
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Saint Gobain Isover
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D131/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Coating compositions based on derivatives of such polymers
    • C09D131/02—Homopolymers or copolymers of esters of monocarboxylic acids
    • C09D131/04—Homopolymers or copolymers of vinyl acetate
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
    • C03C25/10—Coating
    • C03C25/24—Coatings containing organic materials
    • C03C25/26—Macromolecular compounds or prepolymers
    • C03C25/32—Macromolecular compounds or prepolymers obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
    • C03C25/321—Starch; Starch derivatives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C08J5/241—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres
    • C08J5/244—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres using glass fibres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C08J5/249—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs characterised by the additives used in the prepolymer mixture
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C08K5/092—Polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L29/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers
    • C08L29/02—Homopolymers or copolymers of unsaturated alcohols
    • C08L29/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L3/00—Compositions of starch, amylose or amylopectin or of their derivatives or degradation products
    • C08L3/02—Starch; Degradation products thereof, e.g. dextrin
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L31/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid; Compositions of derivatives of such polymers
    • C08L31/02—Homopolymers or copolymers of esters of monocarboxylic acids
    • C08L31/04—Homopolymers or copolymers of vinyl acetate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J103/00—Adhesives based on starch, amylose or amylopectin or on their derivatives or degradation products
    • C09J103/02—Starch; Degradation products thereof, e.g. dextrin
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4209—Inorganic fibres
    • D04H1/4218—Glass fibres
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
    • D04H1/587—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives characterised by the bonding agents used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2303/00—Characterised by the use of starch, amylose or amylopectin or of their derivatives or degradation products
    • C08J2303/02—Starch; Degradation products thereof, e.g. dextrin
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2305/00—Characterised by the use of polysaccharides or of their derivatives not provided for in groups C08J2301/00 or C08J2303/00
    • C08J2305/02—Dextran; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2431/00—Characterised by the use of copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, or carbonic acid, or of a haloformic acid
    • C08J2431/02—Characterised by the use of omopolymers or copolymers of esters of monocarboxylic acids
    • C08J2431/04—Homopolymers or copolymers of vinyl acetate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/608—Including strand or fiber material which is of specific structural definition
    • Y10T442/627—Strand or fiber material is specified as non-linear [e.g., crimped, coiled, etc.]
    • Y10T442/631—Glass strand or fiber material

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Textile Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Wood Science & Technology (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Nonwoven Fabrics (AREA)
  • Reinforced Plastic Materials (AREA)
  • Paper (AREA)

Claims (23)

  1. BINDEMIDDEL TIL MÅTTER AF FIBRE, NAVNLIG AF MINERALSKE FIBRE, OG OPNÅEDE PRODUKTER
    1. Bindemiddel til fibre, navnlig mineralske fibre, særligt af glas eller sten, kendetegnet ved, at det omfatter - mindst et monosaccharid og/eller mindst et polysaccharid, - mindst en organisk polycarboxylsyre, der har en molvægt, som er mindre end eller lig med 1000, og - mindst en vinylacetat-homopolymer eller -copolymer.
  2. 2. Bindemiddel ifølge krav 1, kendetegnet ved, at monosaccharidet er valgt blandt monosaccharider, der indeholder 3 til 8 carbonatomer, fortrinsvis 5 til 7.
  3. 3. Bindemiddel ifølge krav 2, kendetegnet ved, at monosaccharidet er en hexose såsom glucose, mannose og galactose.
  4. 4. Bindemiddel ifølge krav 1, kendetegnet ved, at polysaccharidet er udgjort af over 50 % glucosegentagelsesgrupper.
  5. 5. Bindemiddel ifølge krav 4, kendetegnet ved, at polysaccharidet omfatter dextriner og stivelser, navnlig stivelser med en molvægt på mindst 105 g/mol og på op til 109 g/mol.
  6. 6. Bindemiddel ifølge et af kravene 1 til 5, kendetegnet ved, at det omfatter en blanding af monosaccharid(er) og/eller polysaccharid(er), særligt et dextrin, en melasse eller en blanding indeholdende fra 20 til 80 vægt-% stivelse(r).
  7. 7. Bindemiddel ifølge krav 6, kendetegnet ved, at dextrinet har en dextroseækvivalent, der varierer fra 5 til 100, fortrinsvis fra 15 til 100, og med fordel fra 15 til 50.
  8. 8. Bindemiddel ifølge et af kravene 1 til 7, kendetegnet ved, at den organiske polycarboxylsyre omfatter mindst to carboxylsyrefunktioner, fortrinsvis højst 4, og med fordel højst 3 carboxylsyrefunktioner.
  9. 9. Bindemiddel ifølge krav 8, kendetegnet ved, at syren har en molvægt, som er mindre end eller lig med 750 og fortrinsvis mindre end eller lig med 500.
  10. 10. Bindemiddel ifølge et af kravene 1 til 9, kendetegnet ved, at den organiske polycarboxylsyre er malonsyre, vinsyre eller citronsyre, fortrinsvis citronsyre.
  11. 11. Bindemiddel ifølge et af kravene 1 til 10, kendetegnet ved, at vinylacetatcopolymeren er en copolymer af vinylacetat og mindst en hydrofob monomer, såsom ethylen, propylen, butylen, styren og vinylchlorid, fortrinsvis en copolymer af ethylen og vinylacetat (EVA).
  12. 12. Bindemiddel ifølge et af kravene 1 til 11, kendetegnet ved, at monosaccharidet og/eller polysaccharidet udgør 10 til 90 vægt-% af blandingen, der udgøres af monosaccharidet og/eller polysaccharidet og den organiske polycarboxylsyre, fortrinsvis 20 til 85 %, og med fordel 30 til 80 %.
  13. 13. Bindemiddel ifølge et af kravene 1 til 12, kendetegnet ved, at vinylacetatpolymeren er til stede i en mængde på 1 til 15 dele for 100 vægtdele af blandingen, der udgøres af monosaccharidet og/eller polysaccharidet og den organiske polycarboxylsyre, fortrinsvis 2 til 8 vægtdele.
  14. 14. Bindemiddel ifølge et af kravene 1 til 13, kendetegnet ved, at det desuden omfatter en katalysator valgt blandt Lewis-syrer og -baser, phosphorholdige forbindelser og fluor- og borholdige forbindelser.
  15. 15. Bindemiddel ifølge et af kravene 1 til 14, kendetegnet ved, at katalysatoren udgør op til 20 vægt-% af blandingen, der udgøres af monosaccharidet og/eller polysaccharidet og den organiske polycarboxylsyre, fortrinsvis op til 10 %, og med fordel mindst 1 %.
  16. 16. Bindemiddel ifølge et af kravene 1 til 15, kendetegnet ved, at det desuden omfatter de nedenstående additiver i følgende forhold beregnet på basis af 100 vægtdele af monosaccharid og/eller polysaccharid og organisk polycarboxylsyre: - 0 til 1 del silan, særligt en aminosilan, fortrinsvis 0,1 til 0,5 del, og - 0 til 5 dele af en silicone, en vegetabilsk olie eller en fluoreret forbindelse, fortrinsvis 0,1 til 1 del.
  17. 17. Måtte på basis af fibre omfattende et bindemiddel ifølge et af kravene 1 til 16.
  18. 18. Måtte ifølge krav 17, kendetegnet ved, at fibrene er mineralske fibre, navnlig af glas eller sten, særligt af basalt, eller organiske syntetiske eller naturlige fibre.
  19. 19. Måtte ifølge krav 17 eller 18, kendetegnet ved, at fibrene er i form af afbrudte mineralske filamenter, mineralske tråde sammensat af en flerhed af mineralske filamenter (basistråde) eller samlinger af disse basistråde til forgarn.
  20. 20. Måtte ifølge et af kravene 17 til 19, kendetegnet ved, at den har en gramvægt, der varierer fra 10 til 1100 g/m2, fortrinsvis fra 30 til 350 g/m2, med fordel fra 35 til 60 g/m2.
  21. 21. Måtte ifølge et af kravene 17 til 19, kendetegnet ved, at bindemidlet udgør 10 til 35 vægt-% af måtten af fibre, navnlig af mineralske fibre, fortrinsvis 13 til 25 %.
  22. 22. Måtte ifølge et af kravene 17 til 20, kendetegnet ved, at fibrene er udgjort af mere end 50 vægt-% mineralske fibre, fortrinsvis mere end 75 % og med fordel 100 %.
  23. 23. Måtte ifølge krav 22, kendetegnet ved, at fibrene er af glas.
DK11799744.5T 2010-11-02 2011-11-02 Bindemiddel til måtter af fibre, navnlig af mineralske fibre, og opnåede produkter DK2635541T3 (da)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1058992A FR2966822B1 (fr) 2010-11-02 2010-11-02 Liant pour mat de fibres, notamment minerales, et produits obtenus
PCT/FR2011/052557 WO2012059687A1 (fr) 2010-11-02 2011-11-02 Liant pour mat de fibres, notamment minerales, et produits obtenus.

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DK2635541T3 true DK2635541T3 (da) 2018-06-06

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Country Link
US (1) US9453140B2 (da)
EP (1) EP2635541B1 (da)
CN (1) CN103269992A (da)
DK (1) DK2635541T3 (da)
FR (1) FR2966822B1 (da)
NO (1) NO2635541T3 (da)
PL (1) PL2635541T3 (da)
RU (1) RU2013125455A (da)
SI (1) SI2635541T1 (da)
WO (1) WO2012059687A1 (da)

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EP2635541A1 (fr) 2013-09-11
SI2635541T1 (en) 2018-06-29
PL2635541T3 (pl) 2018-08-31
FR2966822A1 (fr) 2012-05-04
EP2635541B1 (fr) 2018-03-07
FR2966822B1 (fr) 2017-12-22
NO2635541T3 (da) 2018-08-04
CN103269992A (zh) 2013-08-28
RU2013125455A (ru) 2014-12-10
US20130295361A1 (en) 2013-11-07
US9453140B2 (en) 2016-09-27
WO2012059687A1 (fr) 2012-05-10

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