DK2641925T3 - Addukter af isocyanatoalkyl-trialkoxysilaner og alifatiske, alkylforgrenede dioler eller polyoler - Google Patents
Addukter af isocyanatoalkyl-trialkoxysilaner og alifatiske, alkylforgrenede dioler eller polyoler Download PDFInfo
- Publication number
- DK2641925T3 DK2641925T3 DK13158701.6T DK13158701T DK2641925T3 DK 2641925 T3 DK2641925 T3 DK 2641925T3 DK 13158701 T DK13158701 T DK 13158701T DK 2641925 T3 DK2641925 T3 DK 2641925T3
- Authority
- DK
- Denmark
- Prior art keywords
- adducts
- tetrabutylammonium
- compounds
- formula
- coating compositions
- Prior art date
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- 125000000217 alkyl group Chemical group 0.000 title claims description 6
- 150000002009 diols Chemical class 0.000 title description 11
- 229920005862 polyol Polymers 0.000 title description 10
- 150000003077 polyols Chemical class 0.000 title description 10
- 125000001931 aliphatic group Chemical group 0.000 title description 4
- 239000008199 coating composition Substances 0.000 claims description 42
- 150000001875 compounds Chemical class 0.000 claims description 29
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 17
- 239000011230 binding agent Substances 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 16
- -1 methoxy, ethoxy, propoxy Chemical group 0.000 claims description 15
- 239000003054 catalyst Substances 0.000 claims description 14
- 238000006243 chemical reaction Methods 0.000 claims description 12
- 125000002947 alkylene group Chemical group 0.000 claims description 9
- 239000011248 coating agent Substances 0.000 claims description 8
- 125000003545 alkoxy group Chemical group 0.000 claims description 6
- 229920000058 polyacrylate Polymers 0.000 claims description 6
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- 229920000728 polyester Polymers 0.000 claims description 5
- 239000002904 solvent Substances 0.000 claims description 5
- 125000004106 butoxy group Chemical group [*]OC([H])([H])C([H])([H])C(C([H])([H])[H])([H])[H] 0.000 claims description 4
- 238000002844 melting Methods 0.000 claims description 4
- 230000008018 melting Effects 0.000 claims description 4
- 239000004814 polyurethane Substances 0.000 claims description 4
- 239000000654 additive Substances 0.000 claims description 3
- 239000011521 glass Substances 0.000 claims description 3
- 239000003960 organic solvent Substances 0.000 claims description 3
- 229920000515 polycarbonate Polymers 0.000 claims description 3
- 239000004417 polycarbonate Substances 0.000 claims description 3
- 229920000570 polyether Polymers 0.000 claims description 3
- WGYONVRJGWHMKV-UHFFFAOYSA-M tetrabutylazanium;benzoate Chemical compound [O-]C(=O)C1=CC=CC=C1.CCCC[N+](CCCC)(CCCC)CCCC WGYONVRJGWHMKV-UHFFFAOYSA-M 0.000 claims description 3
- CBXCPBUEXACCNR-UHFFFAOYSA-N tetraethylammonium Chemical compound CC[N+](CC)(CC)CC CBXCPBUEXACCNR-UHFFFAOYSA-N 0.000 claims description 3
- SMKNBYSXDYPBME-UHFFFAOYSA-M butanoate;tetrabutylazanium Chemical compound CCCC([O-])=O.CCCC[N+](CCCC)(CCCC)CCCC SMKNBYSXDYPBME-UHFFFAOYSA-M 0.000 claims description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 2
- 239000004033 plastic Substances 0.000 claims description 2
- 229920003023 plastic Polymers 0.000 claims description 2
- 229920002635 polyurethane Polymers 0.000 claims description 2
- AOLHFTSRLXHBNU-UHFFFAOYSA-M propanoate;tetrabutylazanium Chemical compound CCC([O-])=O.CCCC[N+](CCCC)(CCCC)CCCC AOLHFTSRLXHBNU-UHFFFAOYSA-M 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims 2
- 125000002993 cycloalkylene group Chemical group 0.000 claims 1
- MCZDHTKJGDCTAE-UHFFFAOYSA-M tetrabutylazanium;acetate Chemical compound CC([O-])=O.CCCC[N+](CCCC)(CCCC)CCCC MCZDHTKJGDCTAE-UHFFFAOYSA-M 0.000 claims 1
- SNMZANHSFVMKKA-UHFFFAOYSA-M tetrabutylazanium;formate Chemical compound [O-]C=O.CCCC[N+](CCCC)(CCCC)CCCC SNMZANHSFVMKKA-UHFFFAOYSA-M 0.000 claims 1
- MRYQZMHVZZSQRT-UHFFFAOYSA-M tetramethylazanium;acetate Chemical compound CC([O-])=O.C[N+](C)(C)C MRYQZMHVZZSQRT-UHFFFAOYSA-M 0.000 claims 1
- WWIYWFVQZQOECA-UHFFFAOYSA-M tetramethylazanium;formate Chemical compound [O-]C=O.C[N+](C)(C)C WWIYWFVQZQOECA-UHFFFAOYSA-M 0.000 claims 1
- 238000000576 coating method Methods 0.000 description 22
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 9
- 239000007788 liquid Substances 0.000 description 8
- 125000004429 atom Chemical group 0.000 description 7
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 6
- 238000004132 cross linking Methods 0.000 description 5
- 239000000178 monomer Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 229920006243 acrylic copolymer Polymers 0.000 description 4
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 4
- 150000007942 carboxylates Chemical class 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000012975 dibutyltin dilaurate Substances 0.000 description 4
- 125000000524 functional group Chemical group 0.000 description 4
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 4
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 4
- 230000003678 scratch resistant effect Effects 0.000 description 4
- FMGBDYLOANULLW-UHFFFAOYSA-N 3-isocyanatopropyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)CCCN=C=O FMGBDYLOANULLW-UHFFFAOYSA-N 0.000 description 3
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 150000001735 carboxylic acids Chemical class 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 238000002425 crystallisation Methods 0.000 description 3
- 230000008025 crystallization Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000005227 gel permeation chromatography Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000006120 scratch resistant coating Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- CIFIGXMZHITUAZ-UHFFFAOYSA-M tetraethylazanium;benzoate Chemical compound CC[N+](CC)(CC)CC.[O-]C(=O)C1=CC=CC=C1 CIFIGXMZHITUAZ-UHFFFAOYSA-M 0.000 description 3
- 229910052723 transition metal Inorganic materials 0.000 description 3
- 150000003624 transition metals Chemical class 0.000 description 3
- VZXPHDGHQXLXJC-UHFFFAOYSA-N 1,6-diisocyanato-5,6-dimethylheptane Chemical compound O=C=NC(C)(C)C(C)CCCCN=C=O VZXPHDGHQXLXJC-UHFFFAOYSA-N 0.000 description 2
- ICCGPSONZQYELI-UHFFFAOYSA-N 2,4,4-trimethylhexane-1,1-diol Chemical compound CCC(C)(C)CC(C)C(O)O ICCGPSONZQYELI-UHFFFAOYSA-N 0.000 description 2
- XACKQJURAZIUES-UHFFFAOYSA-N 2,4,4-trimethylhexane-1,6-diol Chemical compound OCC(C)CC(C)(C)CCO XACKQJURAZIUES-UHFFFAOYSA-N 0.000 description 2
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 2
- VHYFNPMBLIVWCW-UHFFFAOYSA-N 4-Dimethylaminopyridine Chemical compound CN(C)C1=CC=NC=C1 VHYFNPMBLIVWCW-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000005711 Benzoic acid Substances 0.000 description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical class [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 150000001398 aluminium Chemical class 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 235000010233 benzoic acid Nutrition 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- GHLKSLMMWAKNBM-UHFFFAOYSA-N dodecane-1,12-diol Chemical compound OCCCCCCCCCCCCO GHLKSLMMWAKNBM-UHFFFAOYSA-N 0.000 description 2
- 125000004185 ester group Chemical group 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 2
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical class OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 229920005906 polyester polyol Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 229960004889 salicylic acid Drugs 0.000 description 2
- 229910000077 silane Inorganic materials 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 150000003460 sulfonic acids Chemical class 0.000 description 2
- DZLFLBLQUQXARW-UHFFFAOYSA-N tetrabutylammonium Chemical compound CCCC[N+](CCCC)(CCCC)CCCC DZLFLBLQUQXARW-UHFFFAOYSA-N 0.000 description 2
- QEMXHQIAXOOASZ-UHFFFAOYSA-N tetramethylammonium Chemical compound C[N+](C)(C)C QEMXHQIAXOOASZ-UHFFFAOYSA-N 0.000 description 2
- OSBSFAARYOCBHB-UHFFFAOYSA-N tetrapropylammonium Chemical compound CCC[N+](CCC)(CCC)CCC OSBSFAARYOCBHB-UHFFFAOYSA-N 0.000 description 2
- 150000003608 titanium Chemical class 0.000 description 2
- FRGPKMWIYVTFIQ-UHFFFAOYSA-N triethoxy(3-isocyanatopropyl)silane Chemical compound CCO[Si](OCC)(OCC)CCCN=C=O FRGPKMWIYVTFIQ-UHFFFAOYSA-N 0.000 description 2
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- 150000003754 zirconium Chemical class 0.000 description 2
- GZZLQUBMUXEOBE-UHFFFAOYSA-N 2,2,4-trimethylhexane-1,6-diol Chemical compound OCCC(C)CC(C)(C)CO GZZLQUBMUXEOBE-UHFFFAOYSA-N 0.000 description 1
- QXKKYNIWAYERHT-UHFFFAOYSA-N 2,2-dimethylbutane-1,3-diol Chemical compound CC(O)C(C)(C)CO QXKKYNIWAYERHT-UHFFFAOYSA-N 0.000 description 1
- BGQUJDPWPVVEGV-UHFFFAOYSA-N 2,2-dimethylhexane-1,3-diol Chemical compound CCCC(O)C(C)(C)CO BGQUJDPWPVVEGV-UHFFFAOYSA-N 0.000 description 1
- IHZHYITXFSSZIZ-UHFFFAOYSA-N 2-isocyanatoethyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)CCN=C=O IHZHYITXFSSZIZ-UHFFFAOYSA-N 0.000 description 1
- CTRNPTLUEVNRNH-UHFFFAOYSA-N 2-isocyanatoethyl-tri(propan-2-yloxy)silane Chemical compound CC(C)O[Si](OC(C)C)(OC(C)C)CCN=C=O CTRNPTLUEVNRNH-UHFFFAOYSA-N 0.000 description 1
- 108010048295 2-isopropylmalate synthase Proteins 0.000 description 1
- AAAWJUMVTPNRDT-UHFFFAOYSA-N 2-methylpentane-1,5-diol Chemical compound OCC(C)CCCO AAAWJUMVTPNRDT-UHFFFAOYSA-N 0.000 description 1
- JQKBYCKXGRPGAV-UHFFFAOYSA-N 3-isocyanatopropyl-tri(propan-2-yloxy)silane Chemical compound CC(C)O[Si](OC(C)C)(OC(C)C)CCCN=C=O JQKBYCKXGRPGAV-UHFFFAOYSA-N 0.000 description 1
- SXFJDZNJHVPHPH-UHFFFAOYSA-N 3-methylpentane-1,5-diol Chemical compound OCCC(C)CCO SXFJDZNJHVPHPH-UHFFFAOYSA-N 0.000 description 1
- RBQLGIKHSXQZTB-UHFFFAOYSA-N 3-methylpentane-2,4-diol Chemical compound CC(O)C(C)C(C)O RBQLGIKHSXQZTB-UHFFFAOYSA-N 0.000 description 1
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 description 1
- CDBAMNGURPMUTG-UHFFFAOYSA-N 4-[2-(4-hydroxycyclohexyl)propan-2-yl]cyclohexan-1-ol Chemical compound C1CC(O)CCC1C(C)(C)C1CCC(O)CC1 CDBAMNGURPMUTG-UHFFFAOYSA-N 0.000 description 1
- AONXMESMHBIONB-UHFFFAOYSA-N 4-isocyanatobutyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)CCCCN=C=O AONXMESMHBIONB-UHFFFAOYSA-N 0.000 description 1
- FVMPSSZYZUMFDB-UHFFFAOYSA-N 4-isocyanatobutyl-tri(propan-2-yloxy)silane Chemical compound CC(C)O[Si](OC(C)C)(OC(C)C)CCCCN=C=O FVMPSSZYZUMFDB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 239000004971 Cross linker Substances 0.000 description 1
- 239000005058 Isophorone diisocyanate Substances 0.000 description 1
- 239000002841 Lewis acid Substances 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- BLWUXYZPUFJVSE-UHFFFAOYSA-M butanoate;tetraethylazanium Chemical compound CCCC([O-])=O.CC[N+](CC)(CC)CC BLWUXYZPUFJVSE-UHFFFAOYSA-M 0.000 description 1
- OYGSFKZFXQKZDS-UHFFFAOYSA-M butanoate;tetramethylazanium Chemical compound C[N+](C)(C)C.CCCC([O-])=O OYGSFKZFXQKZDS-UHFFFAOYSA-M 0.000 description 1
- KWAJGRXLJIZCBX-UHFFFAOYSA-M butanoate;tetrapropylazanium Chemical compound CCCC([O-])=O.CCC[N+](CCC)(CCC)CCC KWAJGRXLJIZCBX-UHFFFAOYSA-M 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 238000012936 correction and preventive action Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000001212 derivatisation Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003480 eluent Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 229910021485 fumed silica Inorganic materials 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- 238000012001 immunoprecipitation mass spectrometry Methods 0.000 description 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 1
- QRFPECUQGPJPMV-UHFFFAOYSA-N isocyanatomethyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)CN=C=O QRFPECUQGPJPMV-UHFFFAOYSA-N 0.000 description 1
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 150000007517 lewis acids Chemical class 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000037361 pathway Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- ZEKIXPPWVVMOMQ-UHFFFAOYSA-M propanoate;tetraethylazanium Chemical compound CCC([O-])=O.CC[N+](CC)(CC)CC ZEKIXPPWVVMOMQ-UHFFFAOYSA-M 0.000 description 1
- XNWSMNKRGNKRKP-UHFFFAOYSA-M propanoate;tetramethylazanium Chemical compound CCC([O-])=O.C[N+](C)(C)C XNWSMNKRGNKRKP-UHFFFAOYSA-M 0.000 description 1
- VTIZRIDYIWLCRE-UHFFFAOYSA-M propanoate;tetrapropylazanium Chemical compound CCC([O-])=O.CCC[N+](CCC)(CCC)CCC VTIZRIDYIWLCRE-UHFFFAOYSA-M 0.000 description 1
- 239000003586 protic polar solvent Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000006748 scratching Methods 0.000 description 1
- 230000002393 scratching effect Effects 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- HWCKGOZZJDHMNC-UHFFFAOYSA-M tetraethylammonium bromide Chemical compound [Br-].CC[N+](CC)(CC)CC HWCKGOZZJDHMNC-UHFFFAOYSA-M 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- IEVVGBFMAHJELO-UHFFFAOYSA-M tetramethylazanium;benzoate Chemical compound C[N+](C)(C)C.[O-]C(=O)C1=CC=CC=C1 IEVVGBFMAHJELO-UHFFFAOYSA-M 0.000 description 1
- QOHLYFXRPYZSJX-UHFFFAOYSA-M tetrapropylazanium;benzoate Chemical compound [O-]C(=O)C1=CC=CC=C1.CCC[N+](CCC)(CCC)CCC QOHLYFXRPYZSJX-UHFFFAOYSA-M 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- KEIBTGABMNALIT-UHFFFAOYSA-N triethoxy(2-isocyanatoethyl)silane Chemical compound CCO[Si](OCC)(OCC)CCN=C=O KEIBTGABMNALIT-UHFFFAOYSA-N 0.000 description 1
- ASUUSZXVXTVKDD-UHFFFAOYSA-N triethoxy(4-isocyanatobutyl)silane Chemical compound CCO[Si](OCC)(OCC)CCCCN=C=O ASUUSZXVXTVKDD-UHFFFAOYSA-N 0.000 description 1
- BOTMPGMIDPRZGP-UHFFFAOYSA-N triethoxy(isocyanatomethyl)silane Chemical compound CCO[Si](OCC)(OCC)CN=C=O BOTMPGMIDPRZGP-UHFFFAOYSA-N 0.000 description 1
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 1
- 150000004072 triols Chemical class 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/10—Compounds having one or more C—Si linkages containing nitrogen having a Si-N linkage
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3203—Polyhydroxy compounds
- C08G18/3206—Polyhydroxy compounds aliphatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3203—Polyhydroxy compounds
- C08G18/3221—Polyhydroxy compounds hydroxylated esters of carboxylic acids other than higher fatty acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/71—Monoisocyanates or monoisothiocyanates
- C08G18/718—Monoisocyanates or monoisothiocyanates containing silicon
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/02—Polysilicates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
- Y10T428/31609—Particulate metal or metal compound-containing
- Y10T428/31612—As silicone, silane or siloxane
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31652—Of asbestos
- Y10T428/31663—As siloxane, silicone or silane
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Paints Or Removers (AREA)
- Polyurethanes Or Polyureas (AREA)
- Silicon Polymers (AREA)
Claims (5)
1. Belaegningsmidler indeholdende A) addukter if0lge den foreliggende opfindelse af omsaetningen af forbindelser med formel (I) OCN-(alkyl)-Si(alkoxy)3 (I) med forbindelser med formel (II) H0-(R)-OH (II) hvor alkyl betegner lineare eller forgrenede alkylenkasder med 1-4 carbonatomer, alkoxy samtidigt eller uafhangigt af hinanden betegner methoxy-, ethoxy-, propoxy- eller butoxy-grupper, og R betegner en forgrenet alkylen- eller cycloalkylengruppe med ikke mere end 20 carbonatomer, idet R kan vasre hydroxy-substitueret, B) en eller flere bindemiddelbestanddele, C) 0,1 til 4 vasgt-% baseret pá alie ándele af bestanddelene A) til E) af i det mindste en katalysator, idet katalysatoren Cl) er i det mindste en organisk carboxylsyre med et smeltepunkt over 60 °C, og eller C2) er i det mindste et tetraalkylammoniumcarboxylat, D) valgfrit hjselpe- og tilsastningsstoffer, E) valgfrit organiske opl0sningsmidler.
2. Belaegningsmidler if0lge krav 1, kendetegnet ved, at de kan hasrdes ved temperaturer fra 20 til 100 °C.
3. Belaegningsmidler if0lge krav 1 eller 2, kendetegnet ved, at der som bestanddel B) anvendes hydroxylgruppeholdige polyestere, polyethere, polyacrylater, polycarbonater og polyurethaner med et OH-tal fra 20 til 500 mg KOH/g bestemt i henhold til DIN 53240-2 og en gennemsnitlig molarmasse pá 250 til 6.000 g/mol.
4. Belaegningsmidler if0lge et af de foregáende krav, kendetegnet ved, at bestanddel C2) er udvalgt af tetramethylammoniumformiat, tetramethylammoniumacetat, tetramethylammoniumpropionat, tetramethylammoniumbutyrat, tetramethylammoniumbenzoat, tetraethylammoniumformiat, tetraethylammoniumacetat, tetraethylammoniumpropionat, tetraethylammoniumbutyrat, tetraethylammoniumbenzoat, tetrapropylammoniumformiat, tetrapropylammoniumacetat, tetrapropylammoniumpropionat, tetrapropylammoniumbutyrat, tetrapropylammoniumbenzoat, tetrabutylammoniumformiat, tetrabutylammoniumacetat, tetrabutylammoniumpropionat, tetrabutylammoniumbutyrat og/eller tetrabutylammoniumbenzoat.
5. Metalbelasgningssammensastninger og belasgningssammensaetninger til glas-, kunststof- eller trasbelasgninger indeholdende belasgningsmidler if0lge et eller flere af kravene 1 til 4.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE201210204290 DE102012204290A1 (de) | 2012-03-19 | 2012-03-19 | Addukte aus Isocyanatoalkyl-trialkoxysilanen und aliphatischen, alkyl-verzweigten Diolen oder Polyolen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DK2641925T3 true DK2641925T3 (da) | 2017-05-01 |
Family
ID=47900730
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DK13158701.6T DK2641925T3 (da) | 2012-03-19 | 2013-03-12 | Addukter af isocyanatoalkyl-trialkoxysilaner og alifatiske, alkylforgrenede dioler eller polyoler |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US20130244043A1 (da) |
| EP (1) | EP2641925B1 (da) |
| JP (1) | JP2013194055A (da) |
| KR (1) | KR20130106309A (da) |
| CN (1) | CN103319684A (da) |
| BR (1) | BR102013007461A2 (da) |
| CA (1) | CA2809720A1 (da) |
| DE (1) | DE102012204290A1 (da) |
| DK (1) | DK2641925T3 (da) |
| ES (1) | ES2623261T3 (da) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102010041247A1 (de) | 2010-09-23 | 2012-03-29 | Evonik Degussa Gmbh | Verfahren zur Herstellung von lagerstabilen Polyurethan-Prepregs und daraus hergestellte Formkörper aus Polyurethanzusammensetzung in Lösung |
| WO2013189882A2 (de) | 2012-06-20 | 2013-12-27 | Evonik Industries Ag | Beschichtungsmittel mit hoher kratzbeständigkeit |
| EP2905296B1 (de) * | 2014-02-10 | 2015-12-23 | Evonik Degussa GmbH | Copolymere aus Isocyanatoalkyltrialkoxysilanen und Urethandiolen |
| DE102014203865A1 (de) * | 2014-03-04 | 2015-09-10 | Henkel Ag & Co. Kgaa | Rohstoff und seine Verwendung |
| ES2707979T3 (es) | 2015-04-09 | 2019-04-08 | Evonik Degussa Gmbh | Aductos de isocianatoalquiltrimetoxisilanos y agentes ignífugos reactivos con éstos |
| DK3356444T3 (da) * | 2015-09-30 | 2020-11-16 | Evonik Operations Gmbh | Med silikoneharpiks modificerede isocyanatoalkylalkoxysilan-addukter og deres anvendelse |
| EP3263616B8 (de) | 2016-06-27 | 2020-01-15 | Evonik Operations GmbH | Alkoxysilan-funktionalisierte allophanat-haltige beschichtungsmittel |
| ES2927985T3 (es) | 2016-08-09 | 2022-11-14 | Covestro Intellectual Property Gmbh & Co Kg | Poliuretanos poliméricos con funcionalidad silano |
| EP3404073B1 (de) * | 2017-05-19 | 2021-09-22 | Evonik Operations GmbH | Hydrophile, alkoxysilanhaltige isocyanurate |
| CN108504318B (zh) * | 2018-03-13 | 2021-02-09 | 广东省石油与精细化工研究院 | 一种高透明度和高强度的硅烷改性聚醚弹性密封胶及其制备方法 |
| US11326017B2 (en) | 2018-09-10 | 2022-05-10 | Evonik Operations Gmbh | Tin-free catalysis of silane-functional polyurethane crosslinkers |
| WO2020089019A1 (de) | 2018-10-30 | 2020-05-07 | Covestro Deutschland Ag | Verfahren zur herstellung eines mehrschicht-lackaufbaus mit einer deckschicht aus silangruppen-enthaltenden prepolymeren |
| EP3873959B1 (de) | 2018-10-30 | 2024-09-11 | Covestro Deutschland AG | Mehrschicht-lackaufbau mit verbesserter schichthaftung |
| EP3722346A1 (de) | 2019-04-09 | 2020-10-14 | Covestro Deutschland AG | 2-komponenten-polyurethanbeschichtungen mit verbesserter topfzeit ohne einbusse in der witterungsstabilität |
| CA3136562A1 (en) | 2019-05-06 | 2020-11-12 | Basf Coatings Gmbh | Silane-based coating composition |
| AU2020384713A1 (en) | 2019-11-15 | 2022-05-26 | Basf Coatings Gmbh | Silane-based coating compositions comprising a metal alkoxide catalyst |
| US20230159790A1 (en) | 2020-04-02 | 2023-05-25 | Basf Coatings Gmbh | Silane-based coating compositions comprising a metal alkoxide catalyst and an acid-functional polymer |
| JP7444282B2 (ja) * | 2020-11-13 | 2024-03-06 | 信越化学工業株式会社 | コーティング剤組成物、該組成物を含む表面処理剤、及び該表面処理剤で表面処理された物品 |
| KR20240033019A (ko) | 2021-07-13 | 2024-03-12 | 에보니크 오퍼레이션즈 게엠베하 | 실란 개질된 지방족 폴리우레아 |
| TW202528481A (zh) * | 2023-09-11 | 2025-07-16 | 日商富士軟片股份有限公司 | 樹脂組成物、硬化物、積層體、硬化物之製造方法、積層體之製造方法、半導體元件之製造方法及半導體元件、以及化合物 |
| KR102804536B1 (ko) * | 2024-04-02 | 2025-05-12 | 주식회사 엔케이이노텍 | 도막식 방수 및 이를 이용한 복합식 방수공법 |
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| DE2906136C2 (de) * | 1979-02-17 | 1983-12-08 | Fa. Carl Freudenberg, 6940 Weinheim | Verfahren zur Herstellung von niedrigschmelzenden Polyurethanen |
| US4540766A (en) | 1983-10-03 | 1985-09-10 | Ppg Industries, Inc. | Thermosetting high solids solvent-based polyester-urethane one-component coating compositions |
| JPH0232186A (ja) * | 1988-07-21 | 1990-02-01 | Kuraray Co Ltd | 接着剤 |
| WO1992011328A1 (en) | 1990-12-17 | 1992-07-09 | E.I. Du Pont De Nemours And Company | Automotive coating composition comprising an organosilane polymer |
| DE4204518A1 (de) | 1992-02-15 | 1993-08-19 | Basf Lacke & Farben | Verfahren zur herstellung einer zweischichtigen lackierung und fuer dieses verfahren geeignete nicht-waessrige lacke |
| GB9210653D0 (en) * | 1992-05-19 | 1992-07-01 | Ici Plc | Silane functional oligomer |
| JPH0911406A (ja) * | 1995-06-29 | 1997-01-14 | Teijin Ltd | 表面を保護されたプラスチック成形体及びその製造方法 |
| DE19529124C1 (de) | 1995-08-08 | 1996-11-21 | Herberts Gmbh | Überzugsmittel und deren Verwendung in Verfahren zur Herstellung von Mehrschichtüberzügen |
| DE19714320A1 (de) * | 1997-03-25 | 1998-10-01 | Ivoclar Ag | Hydrolysierbare und polymerisierbare Vinylcyclopropansilane |
| CN1235931C (zh) * | 1998-04-24 | 2006-01-11 | Ck威特科有限公司 | 使用硅烷或硅烷处理的填料的粉末涂料或粘合剂 |
| DE10132938A1 (de) | 2001-07-06 | 2003-01-16 | Degussa | Nichtwässriges, wärmehärtendes Zweikomponenten-Beschichtungsmittel |
| JP2003089723A (ja) * | 2001-09-18 | 2003-03-28 | Kansai Paint Co Ltd | 硬化性組成物及びその被膜形成方法 |
| JP2004035612A (ja) * | 2002-06-28 | 2004-02-05 | Teijin Chem Ltd | 表面を保護された透明プラスチック成形体およびオルガノシロキサン樹脂組成物用下塗り塗料組成物 |
| DE10346958A1 (de) * | 2003-10-09 | 2005-05-12 | Degussa | Uretdiongruppenhaltige Polyurethanzusammensetzungen, welche bei niedriger Temperatur härtbar sind |
| JP2005128304A (ja) * | 2003-10-24 | 2005-05-19 | Dainippon Ink & Chem Inc | 光ファイバー被覆用樹脂組成物及びそれを用いた光ファイバー素線 |
| DE602005017638D1 (de) * | 2004-08-26 | 2009-12-24 | Idemitsu Kosan Co | Beschichtungszusammensetzung und harzmehrschichtkörper |
| DE102004050747A1 (de) | 2004-10-19 | 2006-04-27 | Basf Coatings Ag | Beschichtungsmittel enthaltend Addukte mit Alkoxysilanfunktionalität |
| DE102004050748A1 (de) | 2004-10-19 | 2006-04-20 | Basf Coatings Aktiengesellschaft | Hochkratzfeste und hochelastische Beschichtungsmittel auf Basis von Alkoxysilanen |
| DE102006044310A1 (de) | 2006-09-18 | 2008-03-27 | Nano-X Gmbh | Silanbeschichtungsmaterial und Verfahren zur Herstellung eines Silanbeschichtungsmaterials |
| DE102007020404A1 (de) | 2006-09-18 | 2008-10-30 | Nano-X Gmbh | Verfahren zur Herstellung eines Beschichtungsmaterials |
| BRPI0721288A2 (pt) | 2006-12-19 | 2014-03-25 | Basf Coatings Ag | Agente de revestimento com resistência a arranhões e estabilidade ao intemperismo elevadas |
| DE102007013262A1 (de) | 2007-03-15 | 2008-09-18 | Basf Coatings Ag | Beschichtungsmittel enthaltend Addukte mit Silanfunktionalität und daraus hergestellte hochkratzfeste Beschichtungen mit verbesserter Rissbeständigkeit |
| DE102007013242A1 (de) | 2007-03-15 | 2008-09-18 | Basf Coatings Ag | Hochkratzfeste Beschichtung mit guter Witterungs- und Rissbeständigkeit |
| US8147974B2 (en) * | 2007-12-18 | 2012-04-03 | Dow Global Technologies Llc | Protective coating for window glass having enhanced adhesion to glass bonding adhesives |
| CA2718967A1 (en) * | 2008-03-18 | 2009-09-24 | Nano-X Gmbh | Method for the production of a highly abrasion-resistant vehicle paint, vehicle paint, and the use thereof |
| JP5316300B2 (ja) * | 2009-08-07 | 2013-10-16 | 信越化学工業株式会社 | 耐摩耗性シリコーンコーティング組成物並びに被覆物品及びその製造方法 |
-
2012
- 2012-03-19 DE DE201210204290 patent/DE102012204290A1/de not_active Withdrawn
-
2013
- 2013-03-12 DK DK13158701.6T patent/DK2641925T3/da active
- 2013-03-12 EP EP13158701.6A patent/EP2641925B1/de active Active
- 2013-03-12 ES ES13158701.6T patent/ES2623261T3/es active Active
- 2013-03-13 US US13/799,626 patent/US20130244043A1/en not_active Abandoned
- 2013-03-15 CA CA 2809720 patent/CA2809720A1/en not_active Abandoned
- 2013-03-18 KR KR1020130028426A patent/KR20130106309A/ko not_active Ceased
- 2013-03-18 CN CN2013100857585A patent/CN103319684A/zh active Pending
- 2013-03-19 JP JP2013056814A patent/JP2013194055A/ja active Pending
- 2013-03-19 BR BRBR102013007461-6A patent/BR102013007461A2/pt not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| JP2013194055A (ja) | 2013-09-30 |
| CA2809720A1 (en) | 2013-09-19 |
| EP2641925B1 (de) | 2017-02-01 |
| US20130244043A1 (en) | 2013-09-19 |
| DE102012204290A1 (de) | 2013-09-19 |
| KR20130106309A (ko) | 2013-09-27 |
| BR102013007461A2 (pt) | 2015-06-16 |
| ES2623261T3 (es) | 2017-07-10 |
| EP2641925A1 (de) | 2013-09-25 |
| CN103319684A (zh) | 2013-09-25 |
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