DK2652025T3 - Tørresammensætning og anvendelse deraf - Google Patents
Tørresammensætning og anvendelse deraf Download PDFInfo
- Publication number
- DK2652025T3 DK2652025T3 DK10794964.6T DK10794964T DK2652025T3 DK 2652025 T3 DK2652025 T3 DK 2652025T3 DK 10794964 T DK10794964 T DK 10794964T DK 2652025 T3 DK2652025 T3 DK 2652025T3
- Authority
- DK
- Denmark
- Prior art keywords
- acid
- group
- alkyl
- independently selected
- ioaryl
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims description 78
- 239000008199 coating composition Substances 0.000 claims description 72
- 229920000180 alkyd Polymers 0.000 claims description 61
- 238000001035 drying Methods 0.000 claims description 61
- 239000003446 ligand Substances 0.000 claims description 55
- 229910052751 metal Inorganic materials 0.000 claims description 55
- 239000002184 metal Substances 0.000 claims description 55
- 239000011230 binding agent Substances 0.000 claims description 54
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 52
- -1 alkylene ether Chemical compound 0.000 claims description 42
- 229910052757 nitrogen Inorganic materials 0.000 claims description 41
- 150000007524 organic acids Chemical class 0.000 claims description 34
- 150000003839 salts Chemical class 0.000 claims description 31
- 239000007787 solid Substances 0.000 claims description 27
- 125000000217 alkyl group Chemical group 0.000 claims description 21
- 229910052791 calcium Inorganic materials 0.000 claims description 20
- 239000003973 paint Substances 0.000 claims description 19
- 229910052739 hydrogen Inorganic materials 0.000 claims description 16
- 125000001072 heteroaryl group Chemical group 0.000 claims description 14
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 13
- 229910052748 manganese Inorganic materials 0.000 claims description 13
- 229910052726 zirconium Inorganic materials 0.000 claims description 13
- 229910052799 carbon Inorganic materials 0.000 claims description 12
- 150000004696 coordination complex Chemical class 0.000 claims description 12
- 229910052712 strontium Inorganic materials 0.000 claims description 12
- 239000000758 substrate Substances 0.000 claims description 12
- 125000001425 triazolyl group Chemical group 0.000 claims description 12
- 229910052742 iron Inorganic materials 0.000 claims description 11
- 125000004076 pyridyl group Chemical group 0.000 claims description 9
- 125000003785 benzimidazolyl group Chemical group N1=C(NC2=C1C=CC=C2)* 0.000 claims description 8
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 claims description 8
- 125000002883 imidazolyl group Chemical group 0.000 claims description 8
- 125000003373 pyrazinyl group Chemical group 0.000 claims description 8
- 125000003226 pyrazolyl group Chemical group 0.000 claims description 8
- 125000000714 pyrimidinyl group Chemical group 0.000 claims description 8
- 125000000168 pyrrolyl group Chemical group 0.000 claims description 8
- OAOABCKPVCUNKO-UHFFFAOYSA-N 8-methyl Nonanoic acid Chemical compound CC(C)CCCCCCC(O)=O OAOABCKPVCUNKO-UHFFFAOYSA-N 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 6
- 210000003298 dental enamel Anatomy 0.000 claims description 6
- 125000006514 pyridin-2-ylmethyl group Chemical group [H]C1=C([H])C([H])=C([H])C(=N1)C([H])([H])* 0.000 claims description 6
- 125000000335 thiazolyl group Chemical group 0.000 claims description 6
- 239000002966 varnish Substances 0.000 claims description 6
- 125000000882 C2-C6 alkenyl group Chemical group 0.000 claims description 5
- 150000007513 acids Chemical class 0.000 claims description 5
- OXQGTIUCKGYOAA-UHFFFAOYSA-N 2-Ethylbutanoic acid Chemical compound CCC(CC)C(O)=O OXQGTIUCKGYOAA-UHFFFAOYSA-N 0.000 claims description 4
- VZFUCHSFHOYXIS-UHFFFAOYSA-N Cycloheptanecarboxylic acid Chemical compound OC(=O)C1CCCCCC1 VZFUCHSFHOYXIS-UHFFFAOYSA-N 0.000 claims description 4
- 125000001931 aliphatic group Chemical group 0.000 claims description 4
- 150000001412 amines Chemical class 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- 150000003857 carboxamides Chemical class 0.000 claims description 4
- 150000001733 carboxylic acid esters Chemical class 0.000 claims description 4
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 claims description 4
- 125000000592 heterocycloalkyl group Chemical group 0.000 claims description 4
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 claims description 4
- SIOLDWZBFABPJU-UHFFFAOYSA-N isotridecanoic acid Chemical compound CC(C)CCCCCCCCCC(O)=O SIOLDWZBFABPJU-UHFFFAOYSA-N 0.000 claims description 4
- FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical compound CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 claims description 4
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 claims description 4
- QIIPQYDSKRYMFG-UHFFFAOYSA-N phenyl hydrogen carbonate Chemical compound OC(=O)OC1=CC=CC=C1 QIIPQYDSKRYMFG-UHFFFAOYSA-N 0.000 claims description 4
- 125000001424 substituent group Chemical group 0.000 claims description 4
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 4
- 229910052723 transition metal Inorganic materials 0.000 claims description 4
- 150000003624 transition metals Chemical class 0.000 claims description 4
- OBETXYAYXDNJHR-SSDOTTSWSA-M (2r)-2-ethylhexanoate Chemical compound CCCC[C@@H](CC)C([O-])=O OBETXYAYXDNJHR-SSDOTTSWSA-M 0.000 claims description 3
- XZOYHFBNQHPJRQ-UHFFFAOYSA-N 7-methyloctanoic acid Chemical compound CC(C)CCCCCC(O)=O XZOYHFBNQHPJRQ-UHFFFAOYSA-N 0.000 claims description 3
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 claims description 3
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 3
- 239000000194 fatty acid Substances 0.000 claims description 3
- 229930195729 fatty acid Natural products 0.000 claims description 3
- 150000004665 fatty acids Chemical class 0.000 claims description 3
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 3
- 239000003784 tall oil Substances 0.000 claims description 3
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 claims description 2
- 125000006590 (C2-C6) alkenylene group Chemical group 0.000 claims description 2
- 125000006552 (C3-C8) cycloalkyl group Chemical group 0.000 claims description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 2
- QZTPJIOXWNNJTE-UHFFFAOYSA-N 1,2-dimethylcyclohexane-1-carboxylic acid Chemical compound CC1CCCCC1(C)C(O)=O QZTPJIOXWNNJTE-UHFFFAOYSA-N 0.000 claims description 2
- REHQLKUNRPCYEW-UHFFFAOYSA-N 1-methylcyclohexane-1-carboxylic acid Chemical compound OC(=O)C1(C)CCCCC1 REHQLKUNRPCYEW-UHFFFAOYSA-N 0.000 claims description 2
- FEFCILUKYGHITK-UHFFFAOYSA-N 2-decoxycarbonylbenzoic acid Chemical compound CCCCCCCCCCOC(=O)C1=CC=CC=C1C(O)=O FEFCILUKYGHITK-UHFFFAOYSA-N 0.000 claims description 2
- XTCNGAJYWUIFFB-UHFFFAOYSA-N 2-ethyl-4-methylpentanoic acid Chemical compound CCC(C(O)=O)CC(C)C XTCNGAJYWUIFFB-UHFFFAOYSA-N 0.000 claims description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 2
- HNNQYHFROJDYHQ-UHFFFAOYSA-N 3-(4-ethylcyclohexyl)propanoic acid 3-(3-ethylcyclopentyl)propanoic acid Chemical compound CCC1CCC(CCC(O)=O)C1.CCC1CCC(CCC(O)=O)CC1 HNNQYHFROJDYHQ-UHFFFAOYSA-N 0.000 claims description 2
- KDVYCTOWXSLNNI-UHFFFAOYSA-N 4-t-Butylbenzoic acid Chemical compound CC(C)(C)C1=CC=C(C(O)=O)C=C1 KDVYCTOWXSLNNI-UHFFFAOYSA-N 0.000 claims description 2
- OEOIWYCWCDBOPA-UHFFFAOYSA-N 6-methyl-heptanoic acid Chemical compound CC(C)CCCCC(O)=O OEOIWYCWCDBOPA-UHFFFAOYSA-N 0.000 claims description 2
- YPIFGDQKSSMYHQ-UHFFFAOYSA-N 7,7-dimethyloctanoic acid Chemical compound CC(C)(C)CCCCCC(O)=O YPIFGDQKSSMYHQ-UHFFFAOYSA-N 0.000 claims description 2
- AAOISIQFPPAFQO-UHFFFAOYSA-N 7:0(6Me,6Me) Chemical compound CC(C)(C)CCCCC(O)=O AAOISIQFPPAFQO-UHFFFAOYSA-N 0.000 claims description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 2
- JIPTZBYHWFNYFB-UHFFFAOYSA-N Anteisomyristic acid Chemical compound CCC(C)CCCCCCCCCC(O)=O JIPTZBYHWFNYFB-UHFFFAOYSA-N 0.000 claims description 2
- DPUOLQHDNGRHBS-UHFFFAOYSA-N Brassidinsaeure Natural products CCCCCCCCC=CCCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-UHFFFAOYSA-N 0.000 claims description 2
- 125000003601 C2-C6 alkynyl group Chemical group 0.000 claims description 2
- URXZXNYJPAJJOQ-UHFFFAOYSA-N Erucic acid Natural products CCCCCCC=CCCCCCCCCCCCC(O)=O URXZXNYJPAJJOQ-UHFFFAOYSA-N 0.000 claims description 2
- 239000005642 Oleic acid Substances 0.000 claims description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 2
- 235000021355 Stearic acid Nutrition 0.000 claims description 2
- ZRYCZAWRXHAAPZ-UHFFFAOYSA-N alpha,alpha-dimethyl valeric acid Chemical compound CCCC(C)(C)C(O)=O ZRYCZAWRXHAAPZ-UHFFFAOYSA-N 0.000 claims description 2
- BAZMYXGARXYAEQ-UHFFFAOYSA-N alpha-ethyl valeric acid Chemical compound CCCC(CC)C(O)=O BAZMYXGARXYAEQ-UHFFFAOYSA-N 0.000 claims description 2
- 125000004103 aminoalkyl group Chemical class 0.000 claims description 2
- 125000003118 aryl group Chemical group 0.000 claims description 2
- UTOVMEACOLCUCK-PLNGDYQASA-N butyl maleate Chemical compound CCCCOC(=O)\C=C/C(O)=O UTOVMEACOLCUCK-PLNGDYQASA-N 0.000 claims description 2
- NZNMSOFKMUBTKW-UHFFFAOYSA-N cyclohexanecarboxylic acid Chemical compound OC(=O)C1CCCCC1 NZNMSOFKMUBTKW-UHFFFAOYSA-N 0.000 claims description 2
- DPUOLQHDNGRHBS-KTKRTIGZSA-N erucic acid Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-KTKRTIGZSA-N 0.000 claims description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 2
- 150000002763 monocarboxylic acids Chemical class 0.000 claims description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 2
- 235000021313 oleic acid Nutrition 0.000 claims description 2
- 229920006395 saturated elastomer Polymers 0.000 claims description 2
- 239000008117 stearic acid Substances 0.000 claims description 2
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 claims description 2
- 125000003545 alkoxy group Chemical group 0.000 claims 5
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims 3
- GBXQPDCOMJJCMJ-UHFFFAOYSA-M trimethyl-[6-(trimethylazaniumyl)hexyl]azanium;bromide Chemical compound [Br-].C[N+](C)(C)CCCCCC[N+](C)(C)C GBXQPDCOMJJCMJ-UHFFFAOYSA-M 0.000 claims 3
- 125000003320 C2-C6 alkenyloxy group Chemical group 0.000 claims 2
- 150000003973 alkyl amines Chemical class 0.000 claims 2
- YZXBAPSDXZZRGB-DOFZRALJSA-N arachidonic acid Chemical compound CCCCC\C=C/C\C=C/C\C=C/C\C=C/CCCC(O)=O YZXBAPSDXZZRGB-DOFZRALJSA-N 0.000 claims 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims 2
- 125000006273 (C1-C3) alkyl group Chemical group 0.000 claims 1
- 125000006720 (C1-C6) alkyl (C6-C10) aryl group Chemical group 0.000 claims 1
- 125000003161 (C1-C6) alkylene group Chemical group 0.000 claims 1
- 239000005711 Benzoic acid Substances 0.000 claims 1
- 125000002853 C1-C4 hydroxyalkyl group Chemical group 0.000 claims 1
- 125000006577 C1-C6 hydroxyalkyl group Chemical group 0.000 claims 1
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical compound NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 claims 1
- 125000003342 alkenyl group Chemical group 0.000 claims 1
- 150000005215 alkyl ethers Chemical class 0.000 claims 1
- 125000006294 amino alkylene group Chemical group 0.000 claims 1
- 229940114079 arachidonic acid Drugs 0.000 claims 1
- 235000021342 arachidonic acid Nutrition 0.000 claims 1
- 235000010233 benzoic acid Nutrition 0.000 claims 1
- 125000005702 oxyalkylene group Chemical group 0.000 claims 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 24
- 239000011575 calcium Substances 0.000 description 24
- 229910017052 cobalt Inorganic materials 0.000 description 22
- 239000010941 cobalt Substances 0.000 description 22
- 238000000576 coating method Methods 0.000 description 20
- 239000011572 manganese Substances 0.000 description 20
- 239000007983 Tris buffer Substances 0.000 description 18
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 18
- 239000011248 coating agent Substances 0.000 description 17
- 229910052700 potassium Inorganic materials 0.000 description 16
- 239000000049 pigment Substances 0.000 description 14
- MLCJWRIUYXIWNU-OWOJBTEDSA-N (e)-ethene-1,2-diamine Chemical compound N\C=C\N MLCJWRIUYXIWNU-OWOJBTEDSA-N 0.000 description 13
- 230000000052 comparative effect Effects 0.000 description 12
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 11
- 235000019198 oils Nutrition 0.000 description 11
- 239000003921 oil Substances 0.000 description 10
- 239000002904 solvent Substances 0.000 description 10
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 9
- 238000000034 method Methods 0.000 description 9
- 229920000642 polymer Polymers 0.000 description 9
- 239000011591 potassium Substances 0.000 description 9
- 239000000654 additive Substances 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 6
- 238000007605 air drying Methods 0.000 description 6
- 230000003197 catalytic effect Effects 0.000 description 6
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 6
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 6
- 150000004698 iron complex Chemical class 0.000 description 5
- 229910052744 lithium Inorganic materials 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 239000011368 organic material Substances 0.000 description 5
- 239000012071 phase Substances 0.000 description 5
- VSZWPYCFIRKVQL-UHFFFAOYSA-N selanylidenegallium;selenium Chemical compound [Se].[Se]=[Ga].[Se]=[Ga] VSZWPYCFIRKVQL-UHFFFAOYSA-N 0.000 description 5
- MDAXKAUIABOHTD-UHFFFAOYSA-N 1,4,8,11-tetraazacyclotetradecane Chemical compound C1CNCCNCCCNCCNC1 MDAXKAUIABOHTD-UHFFFAOYSA-N 0.000 description 4
- 125000004105 2-pyridyl group Chemical group N1=C([*])C([H])=C([H])C([H])=C1[H] 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
- 229910052779 Neodymium Inorganic materials 0.000 description 4
- 241001422033 Thestylus Species 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 238000006701 autoxidation reaction Methods 0.000 description 4
- 229910052788 barium Inorganic materials 0.000 description 4
- 229910052797 bismuth Inorganic materials 0.000 description 4
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 4
- 239000003086 colorant Substances 0.000 description 4
- 239000000470 constituent Substances 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- 125000000022 2-aminoethyl group Chemical group [H]C([*])([H])C([H])([H])N([H])[H] 0.000 description 3
- 229910052684 Cerium Inorganic materials 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 3
- 239000003963 antioxidant agent Substances 0.000 description 3
- 235000006708 antioxidants Nutrition 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 3
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 3
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 238000000227 grinding Methods 0.000 description 3
- 125000005842 heteroatom Chemical group 0.000 description 3
- 230000001965 increasing effect Effects 0.000 description 3
- 239000003112 inhibitor Substances 0.000 description 3
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 3
- 239000004922 lacquer Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 150000002696 manganese Chemical class 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229920001296 polysiloxane Polymers 0.000 description 3
- 229920002635 polyurethane Polymers 0.000 description 3
- 239000004814 polyurethane Substances 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000009736 wetting Methods 0.000 description 3
- QBPPRVHXOZRESW-UHFFFAOYSA-N 1,4,7,10-tetraazacyclododecane Chemical compound C1CNCCNCCNCCN1 QBPPRVHXOZRESW-UHFFFAOYSA-N 0.000 description 2
- ITWBWJFEJCHKSN-UHFFFAOYSA-N 1,4,7-triazonane Chemical group C1CNCCNCCN1 ITWBWJFEJCHKSN-UHFFFAOYSA-N 0.000 description 2
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 description 2
- SVONRAPFKPVNKG-UHFFFAOYSA-N 2-ethoxyethyl acetate Chemical compound CCOCCOC(C)=O SVONRAPFKPVNKG-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 2
- 239000004606 Fillers/Extenders Substances 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
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- WHIVNJATOVLWBW-UHFFFAOYSA-N n-butan-2-ylidenehydroxylamine Chemical compound CCC(C)=NO WHIVNJATOVLWBW-UHFFFAOYSA-N 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- BLPXLFREPYJZJC-UHFFFAOYSA-N n-hexyl-n,n',n'-tris(1h-imidazol-2-ylmethyl)ethane-1,2-diamine Chemical compound N=1C=CNC=1CN(CCCCCC)CCN(CC=1NC=CN=1)CC1=NC=CN1 BLPXLFREPYJZJC-UHFFFAOYSA-N 0.000 description 1
- DFMZGZYTSBUWAH-UHFFFAOYSA-N n-nonan-5-ylidenehydroxylamine Chemical compound CCCCC(=NO)CCCC DFMZGZYTSBUWAH-UHFFFAOYSA-N 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
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- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 150000007519 polyprotic acids Polymers 0.000 description 1
- ZUFQCVZBBNZMKD-UHFFFAOYSA-M potassium 2-ethylhexanoate Chemical compound [K+].CCCCC(CC)C([O-])=O ZUFQCVZBBNZMKD-UHFFFAOYSA-M 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- TVCBSVKTTHLKQC-UHFFFAOYSA-M propanoate;zirconium(4+) Chemical compound [Zr+4].CCC([O-])=O TVCBSVKTTHLKQC-UHFFFAOYSA-M 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000004353 pyrazol-1-yl group Chemical group [H]C1=NN(*)C([H])=C1[H] 0.000 description 1
- 150000003217 pyrazoles Chemical class 0.000 description 1
- FYNROBRQIVCIQF-UHFFFAOYSA-N pyrrolo[3,2-b]pyrrole-5,6-dione Chemical class C1=CN=C2C(=O)C(=O)N=C21 FYNROBRQIVCIQF-UHFFFAOYSA-N 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
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- 239000010959 steel Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- JBQYATWDVHIOAR-UHFFFAOYSA-N tellanylidenegermanium Chemical compound [Te]=[Ge] JBQYATWDVHIOAR-UHFFFAOYSA-N 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
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- 230000007704 transition Effects 0.000 description 1
- 239000002383 tung oil Substances 0.000 description 1
- 235000013799 ultramarine blue Nutrition 0.000 description 1
- LSGOVYNHVSXFFJ-UHFFFAOYSA-N vanadate(3-) Chemical compound [O-][V]([O-])([O-])=O LSGOVYNHVSXFFJ-UHFFFAOYSA-N 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3442—Heterocyclic compounds having nitrogen in the ring having two nitrogen atoms in the ring
- C08K5/3462—Six-membered rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3432—Six-membered rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/08—Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09F—NATURAL RESINS; FRENCH POLISH; DRYING-OILS; OIL DRYING AGENTS, i.e. SICCATIVES; TURPENTINE
- C09F9/00—Compounds to be used as driers, i.e. siccatives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0091—Complexes with metal-heteroatom-bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Paints Or Removers (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
- Pyridine Compounds (AREA)
Claims (14)
1. Tørresammensætning til autoxidiserbar alkydbaseret coatingsammensætning, omfattende: a) mindst et metalkompleks omfattende et metal og mindst en nitrogendonor-ligand, hvor metallet er udvalgt fra gruppen bestående af Fe og Mn, og hvor den mindst ene nitrogendonorligand er udvalgt fra gruppen omfattende mono-dentat, bidentat, tridentat, tetradentat, pentadentat og hexadentatnitrogen-do-norligander; og b) mindst et K-salt af en organisk syre.
2. Tørresammensætning ifølge krav 1, yderligere omfattende: c) mindst et andet metalsalt af en organisk syre, hvor metallet er udvalgt fra gruppen omfattende Co, Ca, Zr og Sr.
3. Tørresammensætning ifølge et af kravene 1 eller 2, hvor den mindst ene nitrogendonorligand er udvalgt fra gruppen omfattende forbindelserne med formel (I), (II), (III), (IV), (V), (VI), (VII), N-heterocykliske forbindelser og N-hetero-aromater,
hvor
R1 og R2 uafhængigt er udvalgt fra gruppen bestående af Ci-24alkyl, C6-ioaryl, heteroaryl, heteroarylCi-6alkyl, og -CH2-CH2-N(CH3)2, hvor heteroaryl er udvalgt fra gruppen bestående af pyridyl, pyrazinyl, pyrazolyl, pyrrolyl, imidazolyl, benzimidazolyl, pyrimidinyl, triazolyl og thiazolyl; R3 og R4 uafhængigt er udvalgt fra gruppen bestående af -H, Ci-salkyl, Ci-salkyl-O-Ci-salkyl, Ci-8alkyl-0-C6-ioaryl, C6-ioaryl, Ci-shydroxyalkyl og -(CH2)mC(O)OR5; R5 er udvalgt blandt -H eller Ci-4alkyl, m er et helt tal udvalgt blandt 0 til 4; hver R6 og R7 uafhængigt er udvalgt fra gruppen bestående af -H, -F, -Cl, -Br, -OH, Ci-4alkoxy, -NH-C(O)-H, -NH-C(O)-Ci-4alkyl, -NH2, -NH-Ci-4alkyl og Ci-4alkyl; og, X1 er udvalgt blandt -C(O)- eller -[C(R8)2]n-; hvor n er et helt tal udvalgt blandt 0 til 3, og hver R8 uafhængigt er udvalgt fra gruppen bestående af -H, -OH, Ci-4alkoxy og Ci-4alkyl; R11 og R12 hver især uafhængigt er en gruppe med formel -R14-R15; R13 er udvalgt fra gruppen bestående af -H, -R14-R15, og en eventuelt substitueret gruppe udvalgt fra gruppen bestående af Ci-6alkyl, C6-ioaryl og C6-ioaryl-Ci-6alkyl; hver R14 uafhængigt er udvalgt fra en enkelt kovalent binding eller en eventuelt substitueret gruppe udvalgt fra gruppen bestående af Ci-6alkylen, C2-6alkeny-len, Ci-6oxyalkylen, Ci-6aminoalkylen, C2-6alkylenether, carboxylester og car-boxylamid; og, hver R15 uafhængigt er udvalgt fra en eventuelt N-substitueret aminoalkyl-gruppe eller en eventuelt substitueret heteroarylgruppe udvalgt fra gruppen bestående af pyridyl, pyrazinyl, pyrazolyl, pyrrolyl, imidazolyl, benzimidazolyl, pyrimidinyl, triazolyl og thiazolyl; hver R20 uafhængigt er udvalgt fra gruppen bestående af Ci ealkyl, C3-8cycloal-kyl, heterocycloalkyl, heteroaryl, C6-ioaryl og C6-ioarylCi-6alkyl, eventuelt substitueret med en substituent udvalgt fra gruppen bestående af-OH, Ci-6alkoxy, phenoxy, carboxylat, carboxamid, carboxylester, sulfonat, amin, Ci-6alkylamin og -N+(R21)s; hver R21 er udvalgt blandt -H, Ci-6alkyl, C2-6alkenyl, C6-ioaryl-Ci-6alkyl, C6-ioaryl-C2-6alkenyl, Ci-6alkyloxy, C2-6alkenyloxy, aminoCi-6alkyl, aminoC2-6alkenyl, Ci-6alkylether, C2-6alkenylether og -CX22-R22; hver X2 er uafhængigt udvalgt blandt -H eller Ci-3alkyl, og hvor hver R22 er uafhængigt udvalgt fra en eventuelt substitueret heteroarylgruppe udvalgt fra gruppen bestående af pyridyl, pyrazinyl, pyrazolyl, pyrrolyl, imidazolyl, ben-zimidazolyl, pyrimidinyl, triazolyl og thiazolyl; og, mindst en af R21 er -CX22-R22; hver X3 er uafhængigt udvalgt blandt
9 p er 4; hver R37 uafhængigt er udvalgt fra gruppen bestående af -H, Ci-6alkyl, -CH2CH2OH, pyridin-2-ylmethyl og -CH2C(O)OH; og, hver R31, R32, R33, R34, R35 og R36 er uafhængigt udvalgt blandt: -H, -Ci-4alkyl og Ci-4-hydroxyalkyl; hvor hver R40 er uafhængigt udvalgt blandt -H eller en eventuelt substitueret gruppe udvalgt fra gruppen bestående af Ci-2oalkyl, Ci-6alkyl-C6-ioaryl, C2-6al-kenyl eller C2-6-alkynyl; og alle nitrogenatomer i de makropolycykliske ringe er koordineret med overgangsmetallet; X4 er udvalgt blandt -CH2CH2-, -CH2CH2CH2-, -CH2C(OH)HCH2-; hver R50 uafhængigt er udvalgt fra gruppen bestående af -H, Ci ealkyl, C3-scy-cloalkyl, heterocycloalkyl, heteroaryl, C6-ioaryl og C6-ioaryl-Ci-6alkyl, eventuelt substitueret med en substituent udvalgt blandt -OH, Ci-6alkoxy, phenoxy, car-boxylat, carboxamid, carboxylester, sulfonat, amin, Ci-6alkylamin og -N+(R51)3; hver R51 er udvalgt blandt -H, Ci ealkyl, C2-6alkenyl, C6-ioaryl-Ci-6alkyl, C6-ioaryl-C2-6alkenyl, Ci-6alkyloxy, C2-6alkenyloxy, aminoCi-6alkyl, aminoC2-6alke-nyl, Ci-6alkylether, C2-6alkenylether og -C(X5)2-R52; hver X5 er uafhængigt udvalgt blandt -H eller Ci-3alkyl, og hvor hver R52 er uafhængigt udvalgt blandt en eventuelt substitueret heteroarylgruppe udvalgt fra gruppen bestående af pyridyl, pyrazinyl, pyrazolyl, pyrrolyl, imidazolyl, ben-zimidazolyl, pyrimidinyl, triazolyl og thiazolyl; og, mindst to af R50 er -C(X5)2-R52; og hver R60 uafhængigt er udvalgt fra gruppen bestående af-H, C1 -6alkyl, C6-ioaryl, Ci-6alkyl-C6-ioaryl og C2-6alkenyl.
4. Tørresammensætning ifølge et af kravene 1 til 3, hvor den mindst ene nitro-gendonorligand er udvalgt fra gruppen omfattende forbindelserne med formel (XI), (XII), (XIII), (XIV), og (XV),
5. Tørresammensætning ifølge et af kravene 1 til 4, hvor den organiske syre af det mindst ene K-salt af en organisk syre er udvalgt blandt forgrenet-kæde eller lige-kæde mættede og umættede alifatiske, aromatiske og alicykliske mo-nocarboxylsyrer med 6 til 22 carbonatomer, cycloalifatiske monocarboxylsyrer med 6 til 10 carbonatomer, eller blandinger af disse syrer, fortrinsvis den organiske syre er udvalgt fra gruppen omfattende 2-ethylbutanoic acid, 2,2-di-methylpentansyre, 2-ethylpentansyre, 2-ethyl-4-methylpentansyre, 2-ethylhe-xansyre, isooctansyre, isononansyre, neononansyre, nonansyre, isodecan-syre, neodecansyre, 2-ethyldecansyre, isotridecansyre, isotetradecansyre, n-hexansyre, n-octansyre, n-decansyre, n-dodecansyre, cyclopentansyre, me-thylcyclopentansyre, cyclohexansyre, methylcyclohexansyre, 1,2-dimethyl-cy-clohexansyre, cycloheptansyre, myristinsyre, stearinsyre, arachidonsyre, be-hensyre, oliesyre, linolsyre, talloliefedtsyre, erucasyre, p-tert-butylbenzoesyre, monobutylmaleat, monodecylphthalat, naphthensyre og blandinger deraf.
6. Tørresammensætning ifølge et af kravene 1 til 5, hvor det mindst ene K-salt af en organisk syre er udvalgt fra gruppen omfattende K-octoat, K-naphthenat og K-neodecanoat, fortrinsvis K-octoat.
7. Coatingsammensætning, omfattende: a) mindst et autoxidiserbart alkydbaseret bindemiddel; og b) en tørresammensætning ifølge et af kravene 1 til 6.
8. Coatingsammensætning ifølge krav 8, omfattende fra 0,0001 vægt-% til 2 vægt-% metal, baseret på bindemiddelfaststoffer, af det mindst ene metalkompleks.
9. Coatingsammensætning ifølge claim 7 eller 8, omfattende fra 0,01 vægt-% til 2 vægt-% metal, baseret på bindemiddelfaststoffer, af det mindst ene K-salt af en organisk syre.
10. Coatingsammensætning ifølge et af kravene 7 til 9, hvor det mindst ene autoxidiserbare alkydbaserede bindemiddel er et medium eller langolieumodi-ficeret alkyd, et siliconemodificeret alkyd, et polyurethanmodificeret alkyd, eller en kombination deraf.
11. Coatingsammensætning ifølge et af kravene 7 til 10, hvor det mindst ene autoxidiserbare alkydbaserede bindemiddel foreligger i en mængde på fra 20 til 98 vægt-%, baseret på den samlede sammensætning.
12. Coatingsammensætning ifølge et af kravene 7 til 11, hvor sammensætningen er en opløsningsmiddelbåren sammensætning.
13. Anvendelse af coatingsammensætningen ifølge et af kravene 7 til 12 i en fernis, lak, maling, plet, emalje, tryksværte eller gulvbelægning.
14. Substrat, hvorpå der er påført en coatingsammensætning ifølge et af kravene 7 til 12.
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| PT2652025T (pt) * | 2010-12-15 | 2018-11-02 | Ppg Europe B V | Composição secante e a sua utilização |
| US8710043B2 (en) | 2011-06-24 | 2014-04-29 | Amgen Inc. | TRPM8 antagonists and their use in treatments |
| EP2723718A1 (en) | 2011-06-24 | 2014-04-30 | Amgen Inc. | Trpm8 antagonists and their use in treatments |
| US8952009B2 (en) | 2012-08-06 | 2015-02-10 | Amgen Inc. | Chroman derivatives as TRPM8 inhibitors |
| EP2912112B1 (en) | 2012-10-29 | 2019-12-18 | Ashland Licensing and Intellectual Property LLC | Resin compositions |
| MY173264A (en) * | 2012-12-07 | 2020-01-09 | Sicpa Holding Sa | Oxidatively drying ink compositions |
| GB201222908D0 (en) | 2012-12-19 | 2013-01-30 | Pq Silicas Uk Ltd | Curable liquid compositions |
| MX373424B (es) | 2013-01-29 | 2020-06-22 | Akzo Nobel Chemicals Int Bv | Proceso para preparar un material compuesto reforzado con fibra. |
| AU2014213761B2 (en) * | 2013-02-11 | 2017-03-16 | Catexel Limited | Oxidatively curable coating composition |
| WO2014122432A1 (en) * | 2013-02-11 | 2014-08-14 | Chemsenti Limited | Oxidatively curable coating composition |
| CA2900742C (en) * | 2013-02-11 | 2021-08-24 | Chemsenti Limited | Drier for alkyd-based coating |
| US20160304747A1 (en) | 2013-12-03 | 2016-10-20 | Ppg Europe B.V. | Drier Composition and Use Thereof |
| TW201708435A (zh) * | 2015-07-01 | 2017-03-01 | 西克帕控股有限公司 | 用於濕式平版印刷製程的環境友善油墨與潤版液以及濕式平版印刷製程 |
| AR107070A1 (es) | 2015-12-18 | 2018-03-14 | Catexel Ltd | Composición de recubrimiento oxidativamente curable |
| AR107530A1 (es) | 2016-02-05 | 2018-05-09 | Catexel Ltd | Método para preparar una formulación para un recubrimiento curable por oxidación |
| EP3272823A1 (en) * | 2016-07-19 | 2018-01-24 | ALLNEX AUSTRIA GmbH | Drier compositions for alkyd resins |
| EP3296372B1 (de) | 2016-09-19 | 2020-03-04 | Daw Se | Lösemittelhaltige beschichtungsmasse |
| PL3296353T3 (pl) | 2016-09-19 | 2022-05-30 | Daw Se | Masa powłokowa zawierająca rozpuszczalnik do powłok malarskich |
| US12570851B2 (en) * | 2018-07-05 | 2026-03-10 | Milliken Industrials Limited | Liquids |
| AU2019297084B2 (en) | 2018-07-05 | 2021-12-09 | Borchers Catalyst (UK) Limited | Oxidatively curable coating composition |
| EP3818116A1 (en) | 2018-07-05 | 2021-05-12 | Catexel Technologies Limited | Oxidatively curable coating composition |
| ES2914393T3 (es) | 2018-07-23 | 2022-06-10 | Akzo Nobel Coatings Int Bv | Composición de revestimiento de agua en aceite |
| EP3744800A1 (de) * | 2019-05-29 | 2020-12-02 | STO SE & Co. KGaA | Lösemittelhaltige emulgierte alkydharz-beschichtungsmasse für lasur- und lackbeschichtungen |
| EP3744799A1 (de) * | 2019-05-29 | 2020-12-02 | STO SE & Co. KGaA | Lösemittelhaltige beschichtungsmasse für lasur- und lackbeschichtungen |
| AR119275A1 (es) | 2019-07-04 | 2021-12-09 | Akzo Nobel Coatings Int Bv | Composición de revestimiento que comprende una resina auto-oxidable y un complejo de hierro con ligandos, sustrato recubierto con dicha composición, y dicho complejo de hierro con ligandos |
| EP3766914A1 (en) * | 2019-07-16 | 2021-01-20 | PPG Europe B.V. | A coating composition |
| US12466976B2 (en) | 2019-12-10 | 2025-11-11 | Akzo Nobel Coatings International B.V. | Two-component solvent-based coating composition |
| AR120995A1 (es) | 2020-01-17 | 2022-04-06 | Akzo Nobel Coatings Int Bv | Composición de revestimiento de agua en aceite y sustrato revestido con un revestimiento depositado a partir de dicha composición |
| BR112022026527A2 (pt) * | 2020-07-07 | 2023-01-31 | Swimc Llc | Composição de revestimento, e, métodos para preparar uma composição de revestimento e para aplicar uma composição de revestimento |
| CA3230619A1 (en) * | 2021-09-30 | 2023-04-06 | Neil J. Simpson | Process for improving resin performance using lewis acids |
| EP4414430A1 (en) * | 2023-02-09 | 2024-08-14 | PPG Europe B.V. | Drier and anti-skinning agent system for a coating composition |
| WO2026013020A1 (en) | 2024-07-08 | 2026-01-15 | Akzo Nobel Coatings International B.V. | Coating composition comprising an autoxidizable resin and drier comprising a transition metal and ligand |
Family Cites Families (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2565897A (en) | 1951-08-28 | Drier compositions | ||
| US2526718A (en) | 1950-10-24 | Coating compositions | ||
| US4331575A (en) | 1978-04-28 | 1982-05-25 | Tenneco Chemicals, Inc. | Drier systems and surface-coating compositions containing same |
| US4311625A (en) | 1980-11-10 | 1982-01-19 | Tenneco Chemicals, Inc. | Water-borne surface-coating compositions containing complexed cobalt driers |
| GB8334267D0 (en) | 1983-12-22 | 1984-02-01 | Turner New Technology Ltd John | Surface coating compositions |
| US5039740A (en) * | 1988-04-01 | 1991-08-13 | The Valspar Corporation | Fatty acid-modified polyester resin composition |
| US5154764A (en) * | 1990-04-10 | 1992-10-13 | Mooney Chemicals, Inc. | Neodymium carboxylates as driers in high-solids coating compositions |
| DE4032546A1 (de) | 1990-10-13 | 1992-04-16 | Link Guenter Ing Grad | Autoxidationskatalysator zur verbesserung der trocknung von oxidativ trocknenden ungesaettigten bindemitteln |
| ES2135068T3 (es) | 1994-06-13 | 1999-10-16 | Unilever Nv | Activacion de blanqueantes. |
| ZA981883B (en) | 1997-03-07 | 1998-09-01 | Univ Kansas | Catalysts and methods for catalytic oxidation |
| CA2248476A1 (en) | 1997-10-01 | 1999-04-01 | Unilever Plc | Bleach activation |
| GB0030673D0 (en) | 2000-12-15 | 2001-01-31 | Unilever Plc | Ligand and complex for catalytically bleaching a substrate |
| GB0102826D0 (en) | 2001-02-05 | 2001-03-21 | Unilever Plc | Composition and method for bleaching a substrate |
| WO2003093384A1 (en) * | 2002-05-03 | 2003-11-13 | Ato B.V. | Drier for air-drying coatings |
| GB0212991D0 (en) | 2002-06-06 | 2002-07-17 | Unilever Plc | Ligand and complex for catalytically bleaching a substrate |
| EP1382648A1 (en) | 2002-07-17 | 2004-01-21 | Universiteit Leiden | Drier for alkyd based coating |
| CN100545221C (zh) | 2002-08-30 | 2009-09-30 | 大日本油墨化学工业株式会社 | 印刷油墨用催干剂和含该催干剂的印刷油墨 |
| EP1772502A1 (en) | 2005-10-07 | 2007-04-11 | DSMIP Assets B.V. | Oxidatively drying composition to be employed in thin layers comprising 1,2 dioxo compounds |
| ES2644938T3 (es) * | 2006-07-06 | 2017-12-01 | Akzo Nobel Chemicals International B.V. | Composiciones de resina de éster de vinilo o de resina de poliéster insaturada |
| DE602007008423D1 (de) | 2006-07-07 | 2010-09-23 | Unilever Nv | Flüssigkeitshärtung |
| EP2014729A1 (en) | 2007-07-09 | 2009-01-14 | Sicpa Holding S.A. | Vanadium-drier intaglio ink |
| US8937119B2 (en) * | 2008-11-12 | 2015-01-20 | Lorama, Inc. | Stabilized drier for alkyd-based compositions |
| PT2652025T (pt) * | 2010-12-15 | 2018-11-02 | Ppg Europe B V | Composição secante e a sua utilização |
-
2010
- 2010-12-15 PT PT10794964T patent/PT2652025T/pt unknown
- 2010-12-15 DK DK10794964.6T patent/DK2652025T3/da active
- 2010-12-15 WO PCT/EP2010/069691 patent/WO2012079624A1/en not_active Ceased
- 2010-12-15 PL PL10794964T patent/PL2652025T3/pl unknown
- 2010-12-15 US US13/994,308 patent/US10077353B2/en active Active
- 2010-12-15 CA CA2820401A patent/CA2820401C/en active Active
- 2010-12-15 EP EP10794964.6A patent/EP2652025B1/en active Active
- 2010-12-15 AU AU2010365740A patent/AU2010365740B2/en not_active Ceased
- 2010-12-15 BR BR112013014385-1A patent/BR112013014385B1/pt not_active IP Right Cessation
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2018
- 2018-07-30 US US16/048,778 patent/US20180334549A1/en not_active Abandoned
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|---|---|
| BR112013014385B1 (pt) | 2019-08-20 |
| CA2820401C (en) | 2018-10-02 |
| WO2012079624A1 (en) | 2012-06-21 |
| PL2652025T3 (pl) | 2018-12-31 |
| CA2820401A1 (en) | 2012-06-21 |
| BR112013014385A2 (pt) | 2016-09-27 |
| PT2652025T (pt) | 2018-11-02 |
| AU2010365740A1 (en) | 2013-05-23 |
| AU2010365740B2 (en) | 2015-12-24 |
| US10077353B2 (en) | 2018-09-18 |
| EP2652025B1 (en) | 2018-08-22 |
| US20180334549A1 (en) | 2018-11-22 |
| US20130274386A1 (en) | 2013-10-17 |
| EP2652025A1 (en) | 2013-10-23 |
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