DK2652064T3 - ANVENDELSE TIL OPVARMNING AF KOMBINATIONER AF E-1,3,3,3-TETRAFLUORPROPEN og CHF2CHF2 - Google Patents
ANVENDELSE TIL OPVARMNING AF KOMBINATIONER AF E-1,3,3,3-TETRAFLUORPROPEN og CHF2CHF2 Download PDFInfo
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- DK2652064T3 DK2652064T3 DK11807811.2T DK11807811T DK2652064T3 DK 2652064 T3 DK2652064 T3 DK 2652064T3 DK 11807811 T DK11807811 T DK 11807811T DK 2652064 T3 DK2652064 T3 DK 2652064T3
- Authority
- DK
- Denmark
- Prior art keywords
- chf
- cf3ch
- working fluid
- chf2chf2
- heat pump
- Prior art date
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- KDTSHFARGAKYJN-UHFFFAOYSA-N dephosphocoenzyme A Natural products OC1C(O)C(COP(O)(=O)OP(O)(=O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCS)OC1N1C2=NC=NC(N)=C2N=C1 KDTSHFARGAKYJN-UHFFFAOYSA-N 0.000 description 1
- 229940043279 diisopropylamine Drugs 0.000 description 1
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- XMQYIPNJVLNWOE-UHFFFAOYSA-N dioctyl hydrogen phosphite Chemical compound CCCCCCCCOP(O)OCCCCCCCC XMQYIPNJVLNWOE-UHFFFAOYSA-N 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
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- 150000002148 esters Chemical class 0.000 description 1
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- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 description 1
- 238000003682 fluorination reaction Methods 0.000 description 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
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- ZCQWOFVYLHDMMC-UHFFFAOYSA-O hydron;1,3-oxazole Chemical compound C1=COC=[NH+]1 ZCQWOFVYLHDMMC-UHFFFAOYSA-O 0.000 description 1
- CZPWVGJYEJSRLH-UHFFFAOYSA-O hydron;pyrimidine Chemical compound C1=CN=C[NH+]=C1 CZPWVGJYEJSRLH-UHFFFAOYSA-O 0.000 description 1
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- OAIJSZIZWZSQBC-GYZMGTAESA-N lycopene Chemical compound CC(C)=CCC\C(C)=C\C=C\C(\C)=C\C=C\C(\C)=C\C=C\C=C(/C)\C=C\C=C(/C)\C=C\C=C(/C)CCC=C(C)C OAIJSZIZWZSQBC-GYZMGTAESA-N 0.000 description 1
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- UZKWTJUDCOPSNM-UHFFFAOYSA-N methoxybenzene Substances CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- VBYLGQXERITIBP-UHFFFAOYSA-N n-[dimethylamino(methyl)silyl]-n-methylmethanamine Chemical compound CN(C)[SiH](C)N(C)C VBYLGQXERITIBP-UHFFFAOYSA-N 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- 238000006384 oligomerization reaction Methods 0.000 description 1
- 150000002921 oxetanes Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 125000006340 pentafluoro ethyl group Chemical group FC(F)(F)C(F)(F)* 0.000 description 1
- 125000005010 perfluoroalkyl group Chemical group 0.000 description 1
- 239000010701 perfluoropolyalkylether Substances 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
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- 238000007539 photo-oxidation reaction Methods 0.000 description 1
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- 239000001294 propane Substances 0.000 description 1
- PBMFSQRYOILNGV-UHFFFAOYSA-N pyridazine Chemical compound C1=CC=NN=C1 PBMFSQRYOILNGV-UHFFFAOYSA-N 0.000 description 1
- JUJWROOIHBZHMG-UHFFFAOYSA-O pyridinium Chemical compound C1=CC=[NH+]C=C1 JUJWROOIHBZHMG-UHFFFAOYSA-O 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
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- 230000002207 retinal effect Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
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- 239000000741 silica gel Substances 0.000 description 1
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- 239000002904 solvent Substances 0.000 description 1
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- 239000005437 stratosphere Substances 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- 229930006978 terpinene Natural products 0.000 description 1
- 150000003507 terpinene derivatives Chemical class 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 235000010384 tocopherol Nutrition 0.000 description 1
- 229960001295 tocopherol Drugs 0.000 description 1
- 229930003799 tocopherol Natural products 0.000 description 1
- 239000011732 tocopherol Substances 0.000 description 1
- ZCIHMQAPACOQHT-ZGMPDRQDSA-N trans-isorenieratene Natural products CC(=C/C=C/C=C(C)/C=C/C=C(C)/C=C/c1c(C)ccc(C)c1C)C=CC=C(/C)C=Cc2c(C)ccc(C)c2C ZCIHMQAPACOQHT-ZGMPDRQDSA-N 0.000 description 1
- 125000001425 triazolyl group Chemical group 0.000 description 1
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical class C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
- 235000019155 vitamin A Nutrition 0.000 description 1
- 239000011719 vitamin A Substances 0.000 description 1
- NCYCYZXNIZJOKI-UHFFFAOYSA-N vitamin A aldehyde Natural products O=CC=C(C)C=CC=C(C)C=CC1=C(C)CCCC1(C)C NCYCYZXNIZJOKI-UHFFFAOYSA-N 0.000 description 1
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- GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 description 1
- OENHQHLEOONYIE-JLTXGRSLSA-N β-Carotene Chemical compound CC=1CCCC(C)(C)C=1\C=C\C(\C)=C\C=C\C(\C)=C\C=C\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C OENHQHLEOONYIE-JLTXGRSLSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/02—Materials undergoing a change of physical state when used
- C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/02—Materials undergoing a change of physical state when used
- C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
- C09K5/041—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems
- C09K5/044—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds
- C09K5/045—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds containing only fluorine as halogen
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24H—FLUID HEATERS, e.g. WATER OR AIR HEATERS, HAVING HEAT-GENERATING MEANS, e.g. HEAT PUMPS, IN GENERAL
- F24H4/00—Fluid heaters characterised by the use of heat pumps
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B45/00—Arrangements for charging or discharging refrigerant
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
- C09K2205/10—Components
- C09K2205/12—Hydrocarbons
- C09K2205/126—Unsaturated fluorinated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
- C09K2205/22—All components of a mixture being fluoro compounds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Claims (12)
- ANVENDELSE TIL OPVARMNING AF KOMBINATIONER AF E-l,3,3,3-TETRAFLUORPROPEN og CHF2CHF21. Fremgangsmåde til produktion af varme, hvilken fremgangsmåde omfatter kondensering af et damparbejdsfluid omfattende (a) fs-CF3CH=CFIF og (b) CHF2CHF2, i en kondensator, hvorved der produceres et flydende arbejdsfluid; forudsat at vægtforholdet mellem £-CF3CH=CHF og den totale mængde afii-CF3CH=CHF og CHF2CHF2 i arbejdsfluidet er fra 0,05 til 0,99; hvor opvarmningen sker i en højtemperaturvarmepumpe omfattende kondensatoren, hvor den maksimale kondensatordriftstemperatur for højtemperaturvarmepumpen er større end 55 °C, hvilken fremgangsmåde endvidere omfatter (i) passage af et overføringsmedium gennem kondensatoren, hvorved kondenseringen af arbejdsfluid opvarmer varmeoverføringsmediet, og passage af det opvarmede varmeoverføringsmedium fra kondensatoren til et legeme, der skal opvarmes, eller (ii) passage af et fluid, der skal opvarmes, gennem kondensatoren, hvorved fluidet opvarmes, hvor fluidet er luft, vand eller en del af en industriel proces.
- 2. Fremgangsmåde ifølge krav 1, hvor varmeoverføringsmediet er vand og det legeme, der skal opvarmes, er vand, eller hvor varmeoverføringsmediet er vand, og det legeme, der skal opvarmes, er luft til rumopvarmning, eller hvor varmeoverføringsmediet er en industriel varmeoverføringsvæske og det legeme, der skal opvarmes, er en kemisk procesdamp.
- 3. Fremgangsmåde ifølge et hvilket som helst af kravene 1 til 2, hvilken fremgangsmåde endvidere omfatter komprimering af arbejdsfluiddampen i en centrifugal kompressor.
- 4. Fremgangsmåde ifølge krav 1 eller 3, hvor fluidet er luft, og den opvarmede luft fra kondensatoren overføres til et rum, der skal opvarmes, eller hvor fluidet er en del af en procesdamp, og den opvarmede del returneres til processen.
- 5. Fremgangsmåde ifølge et hvilket som helst af kravene 1 til 4, hvor vægtforholdet mellem E-CF3CH=CHF og den totale mængde af E-CF3CH=CHF og CHF2CHF2 er mindre end 0,70, fortrinsvis fra 0,05 til 0,53.
- 6. Varmepumpeanordning indeholdende et arbejdsfluid omfattende (a) fs-CF3CH=CHF og (b) CHF2CHF2; forudsat at vægtforholdet mellem fs-CF3CI I=CHF og den totale mængde af /1-CF3CH=CHF og CHF2CHF2 i arbejdsfluidet er fra 0,05 til 0,99; hvor varmepumpeanordningen er en højtemperaturvarmepumpeanordning, der kan producere maksimale kondensatordriftstemperaturer på mere end 55 °C.
- 7. Anordning ifølge krav 6, hvor vægtforholdet mellem .Zi-CF3CH=CHF og den totale mængde af E-CF3CH=CHF og CHF2CHF2 er fra 0,05 til 0,69, fortrinsvis fra 0,05 til 0,53.
- 8. Varmepumpeanordning ifølge krav 6, hvilken varmepumpe anordning omfatter en centrifugal kompressor.
- 9. Fremgangsmåde til at hæve den maksimalt mulige kondensatordriftstemperatur i en varmepumpeanordning, der er egnet til anvendelse med HFC-134a arbejdsfluid i forhold til den maksimalt mulige kondensatordriftstemperatur, når HFC-134a anvendes som varmepumpens arbejdsfluid, omfattende påfyldning på varmepumpen som defineret i krav 1 af et arbejdsfluid som defineret i krav 1.
- 10. Fremgangsmåde ifølge krav 9, hvor varmepumpen er flydt med et arbejdsfluid omfattende E-CF3CH=CHF og CHF2CHF2 og den maksimalt mulige kondensatordriftstemperatur er hævet mindst 5 °C, fortrinsvist mindst 10 °C, sammenlignet med den maksimalt mulige kondensatordriftstemperatur, når 134a anvendes som varmepumpens arbejdsfluid.
- 11. Fremgangsmåde ifølge et hvilket som helst af kravene 9 til 10, hvor vægtforholdet mellem E-CF3CF1=CHF og den totale mængde af /i-CF,CH=CIIF og CHF2CHF2 er mindre end 0,70, fortrinsvis fra 0,05 til 0,53,
- 12. Fremgangsmåde til udskiftning af HFC-134a kølemiddel i en varmepumpe, der er designet til HFC-134a, hvilken fremgangsmåde omfatter tilvejebringelse af et udskiftningsarbejdsfluid som defineret i krav 1; hvor varmepumpen omfatter en centrifugalkompressor, hvor den maksimale kondensatordriftstemperatur for højtemperaturvarmepumpen er højere end 55 °C.
Applications Claiming Priority (2)
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| US42293510P | 2010-12-14 | 2010-12-14 | |
| PCT/US2011/064974 WO2012082939A1 (en) | 2010-12-14 | 2011-12-14 | Combinations of e-1,3,3,3-tetrafluoropropene and at least one tetrafluoroethane and their use for heating |
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| DK2652064T3 true DK2652064T3 (da) | 2016-11-07 |
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| DK11807811.2T DK2652064T3 (da) | 2010-12-14 | 2011-12-14 | ANVENDELSE TIL OPVARMNING AF KOMBINATIONER AF E-1,3,3,3-TETRAFLUORPROPEN og CHF2CHF2 |
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| US (1) | US9828536B2 (da) |
| EP (1) | EP2652064B1 (da) |
| JP (2) | JP2014504323A (da) |
| KR (1) | KR101908151B1 (da) |
| CN (1) | CN103261360B (da) |
| AU (1) | AU2011343819B2 (da) |
| BR (1) | BR112013012043A2 (da) |
| CA (1) | CA2820077C (da) |
| DK (1) | DK2652064T3 (da) |
| ES (1) | ES2595387T3 (da) |
| MX (1) | MX372901B (da) |
| MY (1) | MY161767A (da) |
| SG (1) | SG190193A1 (da) |
| WO (1) | WO2012082939A1 (da) |
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|---|---|---|---|---|
| US8463441B2 (en) | 2002-12-09 | 2013-06-11 | Hudson Technologies, Inc. | Method and apparatus for optimizing refrigeration systems |
| US8747691B2 (en) * | 2010-05-06 | 2014-06-10 | Honeywell International Inc. | Azeotrope-like compositions of tetrafluoropropene and water |
| FR2979419B1 (fr) * | 2011-08-30 | 2018-03-30 | Arkema France | Fluides de transfert de chaleur supercritiques a base de tetrafluoropropene |
| TW201411068A (zh) * | 2012-08-01 | 2014-03-16 | Du Pont | 於級聯熱泵中在最終級聯階段使用包含ｚ－１，１，１，４，４，４－六氟－２－丁烯之工作流體製造加熱 |
| WO2015022958A1 (ja) | 2013-08-14 | 2015-02-19 | セントラル硝子株式会社 | 熱伝達方法及び高温ヒートポンプ装置 |
| KR102382714B1 (ko) | 2013-10-10 | 2022-04-06 | 더 케무어스 컴퍼니 에프씨, 엘엘씨 | 다이플루오로메탄, 펜타플루오로에탄, 테트라플루오로에탄, 및 테트라플루오로프로펜을 포함하는 조성물 및 그의 용도 |
| EP3071664B1 (en) * | 2013-11-22 | 2022-08-03 | The Chemours Company FC, LLC | Use of compositions comprising tetrafluoropropene and tetrafluoroethane in power cycles; and power cycle apparatus |
| WO2017027716A1 (en) * | 2015-08-11 | 2017-02-16 | Trane International Inc. | Refrigerant recovery and repurposing |
| JP6938273B2 (ja) * | 2017-08-10 | 2021-09-22 | 三菱重工サーマルシステムズ株式会社 | ヒートポンプおよびその設計方法 |
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| EP2171012A1 (en) * | 2007-07-27 | 2010-04-07 | E. I. du Pont de Nemours and Company | Compositions comprising fluoroolefins and uses thereof |
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| GB201002619D0 (en) | 2010-02-16 | 2010-03-31 | Ineos Fluor Holdings Ltd | Heat transfer compositions |
| GB201002617D0 (en) | 2010-02-16 | 2010-03-31 | Ineos Fluor Holdings Ltd | Heat transfer compositions |
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| EP2652064A1 (en) | 2013-10-23 |
| EP2652064B1 (en) | 2016-07-20 |
| JP2014504323A (ja) | 2014-02-20 |
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| CN103261360A (zh) | 2013-08-21 |
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| MX372901B (es) | 2020-04-07 |
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| KR20140036133A (ko) | 2014-03-25 |
| AU2011343819B2 (en) | 2016-01-14 |
| AU2011343819A2 (en) | 2013-06-06 |
| MY161767A (en) | 2017-05-15 |
| KR101908151B1 (ko) | 2018-10-15 |
| JP2017071792A (ja) | 2017-04-13 |
| CA2820077C (en) | 2019-10-08 |
| ES2595387T3 (es) | 2016-12-29 |
| BR112013012043A2 (pt) | 2017-10-10 |
| MX2013006600A (es) | 2013-07-15 |
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