DK2792004T3 - Elektrisk genopladelig metalanodecelle og batterisystemer og fremgangsmåder - Google Patents

Elektrisk genopladelig metalanodecelle og batterisystemer og fremgangsmåder Download PDF

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DK2792004T3
DK2792004T3 DK12810495.7T DK12810495T DK2792004T3 DK 2792004 T3 DK2792004 T3 DK 2792004T3 DK 12810495 T DK12810495 T DK 12810495T DK 2792004 T3 DK2792004 T3 DK 2792004T3
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cell
electrolyte
air
electrode
metal
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DK12810495.7T
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Steven Amendola
Michael Binder
Phillip J Black
Stefanie Sharp-Goldman
Lois Johnson
Michael Kunz
Michael Oster
Tesia Chciuk
Regan Johnson
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Eos Energy Storage Llc
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Claims (14)

1. Elektrisk genopladelig metalanodecelle, der omfatter: en metalelektrode (102, 202); en i berøring med luft værende elektrode (104,204), der omfatter mindst én strømaftager med et korrosionsbestandigt udvendigt lag omfattende titancar-bid, et ledende indvendigt lag omfattende titanium og en luftgennemtrængelig hydrofob membran; en vandig elektrolyt (106, 206), der er anbragt mellem metalelektroden (102, 202) og den i berøring med luft værende elektrode (104, 204); og hvor metalelektroden (102, 202) er i direkte berøring med den vandige elektrolyt (106, 206), og uden et ionisk ledende og elektrisk isolerende materiale mellem den i berøring med luft værende elektrode (104, 204) og den vandige elektrolyt (106, 206), kendetegnet ved, at en ramme (100, 200), der understøtter både metalelektroden (102, 202) og den i berøring med luft værende elektrode, således at metalelektroden (102,202) og den i berøring med luft værende elektrode (104,204), befinder sig i en fast afstand fra hinanden til definering af et mellemrum, hvori den vandige elektrolyt (106, 206) er indeholdt, hvilken ramme omfatter et elektrolytstyresystem, der er integreret i rammen (100, 200), hvilket elektrolytstyresystem omfatter: en udløbs- eller påfyldningsåbning (J); en overløbskant (L), der er udformet til at opfange og indeholde den vandige elektrolyt (106, 206) inde i cellen, når den vandige elektrolyt (106, 206) løber over fra en af en øvre elektrolytbeholder (H) eller en overliggende celle, der er stablet vertikalt over cellens i berøring med luft værende elektrode (104, 204), hvor et overløb af den vandige elektrolyt (106, 206) inde i cellen løber over overløbskanten (L) og ind i udløbs- eller påfyldningsåbningen (J), idet udløbs- eller påfyldningsåbningen (J) tillader overløbet af den vandige elektrolyt (106, 206) at dryppe til en af en elektrolytopfangningsbeholder eller en underliggende celle, der er stablet vertikalt under cellens metalelektrode (102, 202).
2. Celle ifølge krav 1, hvor den i berøring med luft værende elektrode og metalelektroden er forbundet i en bipolær konfiguration.
3. Celle ifølge krav 1, hvor rammen er mindst delvist dannet af et polymermateriale eller af plast.
4. Celle ifølge krav 1, hvor den i berøring med luft værende elektrode er i en horisontal orientering og anbragt over metalelektroden.
5. Celle ifølge krav 1, hvor elektrolytten er en elektrolyt baseret på vandig chlorid med en pH-værdi i området 3 til 10.
6. Celle ifølge krav 1, hvor elektrolytten omfatter et additiv, der indbefatter et eller flere af følgende chloridsalte med høj hydrogenoverspænding: tinchlorid, blychlorid, mercurochlorid, cadmiumchlorid, indiumchlorid eller bismutchlorid.
7. Sekundær batterienhed, der omfatter: en første celle, der har en første metalelektrode (102, 202), en første i berøring med luft værende elektrode (104, 204), der omfatter mindst én strømaftager med et korrosionsbestandigt udvendigt lag omfattende titancarbid, et ledende indvendigt lag omfattende titanium og en luftgen-nemtrængelig hydrofob membran, elektrolyt (106, 206) derimellem og en første ramme (100, 200), der understøtter både den første metalelektrode (102, 202) og den første i berøring med luft værende elektrode (104, 204) med en fast afstand fra hinanden til definering af et første mellemrum, hvori elektrolytten er indeholdt, hvilken første ramme (100, 200) indbefatter en første overløbskant (L), der er udformet til at opretholde et konstant niveau af elektrolytten (106, 206) i den første celle; en anden celle, der har en anden metalelektrode (102, 202), en anden i berøring med luft værende elektrode (104, 204), der omfatter mindst én strømaftager med et korrosionsbestandigt udvendigt lag omfattende titancarbid, et ledende indvendigt lag omfattende titanium og en luftgen-nemtrængelig hydrofob membran, og en anden ramme (100, 200), der understøtter både den anden metalelektrode (102, 202) og den anden i berøring med luft værende elektrode (104, 204) med en fast afstand fra hinanden til definering af et andet mellemrum derimellem, hvilken anden ramme (100, 200) indbefatter en anden overløbskant (L), der er udformet til at opfange et overløb af elektrolytten (106, 206), der løber over den første overløbskant (L), og indeholde den opfangede elektrolyt (106, 206) i det andet mellemrum, hvor den første celles metalelektrode (102, 202) kommer i berøring med den anden celles i berøring med luft værende elektrode (104, 204), således at der dannes en lufttunnel (108, 208) mellem den første celles metalelektrode (102, 202) og den anden celles i berøring med luft værende elektrode (104, 204), og hvor både metalelektroden (102, 202) og den i berøring med luft værende elektrode (104, 204) af den første og anden celle er anbragt i en i det væsentlige horisontal orientering.
8. Batterienhed ifølge krav 7, hvor den første celles metalelektrode kommer i berøring med den anden celles i berøring med luft værende elektrode ved hjælp af en mekanisk indfalsning omkring kanterne af den første celles i berøring med luft værende elektrode, således at der dannes en centrode.
9. Batterienhed ifølge krav 7, hvor centroden tilvejebringer en serieforbindelse mellem den første celle og den anden celle.
10. Batterienhed ifølge krav 7, hvor gassen strømmer i en horisontal retning inde i lufttunnellen.
11. Batterienhed ifølge krav 7, yderligere omfattende: en tredje celle, der har en metalelektrode, en i berøring med luft værende elektrode, der omfatter mindst én strømaftager med et korrosionsbestandigt udvendigt lag omfattende titancarbid, et ledende indvendigt lag omfattende titanium og en luftgennemtrængelig hydrofob membran, og elektrolyt derimellem; og en fjerde celle, der har en metalelektrode, en i berøring med luft værende elektrode, der omfatter mindst én strømaftager med et korrosionsbestandigt udvendigt lag omfattende titancarbid, et ledende indvendigt lag omfattende titanium og en luftgennemtrængelig hydrofob membran, og elektrolyt derimellem, hvor den tredje celles metalelektrode er mekanisk indfalset omkring kanten af den fjerde celles i berøring med luft værende elektrode, således at der dannes en lufttunnel mellem den tredje celles metalelektrode og den fjerde celles i kontakt med luft værende elektrode, hvorved der dannes en anden centrode, og hvor den anden centrode er i elektrisk kontakt med den første centrode, hvorved der tilvejebringes elektrisk forbindelse mellem den første centrode og den anden centrode.
12. Batterienhed ifølge krav 7, yderligere omfattende en bakke til opsamling af flydende elektrolyt, som er anbragt under den anden celle.
13. Batterienhed ifølge krav 7, yderligere omfattende en tyngdekraftdrevet elektrolyttilførselsenhed, der tilvejebringer elektrolyt til den første og anden celle.
14. Batterienhed ifølge krav 13, hvor den første og anden celle er horisontalt orienterede og skråtstillede opad i nærheden af elektrolyttilførselsenheden i en vinkel på 1 til 5 grader fra horisontal.
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