DK3046995T3 - Raffinering af brugte olier - Google Patents
Raffinering af brugte olier Download PDFInfo
- Publication number
- DK3046995T3 DK3046995T3 DK14808474.2T DK14808474T DK3046995T3 DK 3046995 T3 DK3046995 T3 DK 3046995T3 DK 14808474 T DK14808474 T DK 14808474T DK 3046995 T3 DK3046995 T3 DK 3046995T3
- Authority
- DK
- Denmark
- Prior art keywords
- oil
- hydrogen
- pressure
- liquid
- outlet
- Prior art date
Links
- 238000007670 refining Methods 0.000 title claims description 21
- 239000010913 used oil Substances 0.000 title 1
- 229910052739 hydrogen Inorganic materials 0.000 claims description 81
- 239000001257 hydrogen Substances 0.000 claims description 81
- 239000007788 liquid Substances 0.000 claims description 81
- 238000000034 method Methods 0.000 claims description 72
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 62
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 50
- 230000008569 process Effects 0.000 claims description 48
- 239000007789 gas Substances 0.000 claims description 43
- 238000007872 degassing Methods 0.000 claims description 37
- 229930195733 hydrocarbon Natural products 0.000 claims description 20
- 150000002430 hydrocarbons Chemical class 0.000 claims description 20
- 150000002431 hydrogen Chemical class 0.000 claims description 20
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 18
- 239000003054 catalyst Substances 0.000 claims description 17
- 239000000356 contaminant Substances 0.000 claims description 16
- 239000012433 hydrogen halide Substances 0.000 claims description 14
- 229910000039 hydrogen halide Inorganic materials 0.000 claims description 14
- 229910021529 ammonia Inorganic materials 0.000 claims description 9
- 230000001590 oxidative effect Effects 0.000 claims description 9
- 238000000605 extraction Methods 0.000 claims description 8
- 230000003134 recirculating effect Effects 0.000 claims description 7
- -1 halogen organic compound Chemical class 0.000 claims description 6
- 238000004064 recycling Methods 0.000 claims description 5
- 229910052736 halogen Inorganic materials 0.000 claims description 3
- 239000003921 oil Substances 0.000 description 165
- 239000000047 product Substances 0.000 description 47
- 239000010735 electrical insulating oil Substances 0.000 description 23
- 239000000463 material Substances 0.000 description 17
- 238000006722 reduction reaction Methods 0.000 description 17
- 239000002199 base oil Substances 0.000 description 16
- 230000003647 oxidation Effects 0.000 description 16
- 238000007254 oxidation reaction Methods 0.000 description 16
- 238000004519 manufacturing process Methods 0.000 description 13
- 239000002516 radical scavenger Substances 0.000 description 13
- 230000009467 reduction Effects 0.000 description 13
- 150000001875 compounds Chemical class 0.000 description 12
- 238000012545 processing Methods 0.000 description 11
- 238000006243 chemical reaction Methods 0.000 description 9
- 150000004820 halides Chemical class 0.000 description 9
- 238000005984 hydrogenation reaction Methods 0.000 description 9
- 150000003839 salts Chemical class 0.000 description 7
- 238000009849 vacuum degassing Methods 0.000 description 7
- 239000004215 Carbon black (E152) Substances 0.000 description 6
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 5
- 230000006872 improvement Effects 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 239000003039 volatile agent Substances 0.000 description 5
- 239000000341 volatile oil Substances 0.000 description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 238000009835 boiling Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
- 150000003071 polychlorinated biphenyls Chemical class 0.000 description 4
- 238000005201 scrubbing Methods 0.000 description 4
- 150000004763 sulfides Chemical class 0.000 description 4
- 125000003118 aryl group Chemical group 0.000 description 3
- 239000006227 byproduct Substances 0.000 description 3
- 238000010924 continuous production Methods 0.000 description 3
- 239000010696 ester oil Substances 0.000 description 3
- 239000012467 final product Substances 0.000 description 3
- 239000007800 oxidant agent Substances 0.000 description 3
- 238000010791 quenching Methods 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- 230000002000 scavenging effect Effects 0.000 description 3
- 238000012546 transfer Methods 0.000 description 3
- 238000003809 water extraction Methods 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000005864 Sulphur Substances 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 238000011021 bench scale process Methods 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 239000003518 caustics Substances 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- 239000010779 crude oil Substances 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000010408 film Substances 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 230000009972 noncorrosive effect Effects 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 229910052763 palladium Inorganic materials 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 230000000171 quenching effect Effects 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 239000010802 sludge Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 150000003464 sulfur compounds Chemical class 0.000 description 2
- 239000010409 thin film Substances 0.000 description 2
- 150000003573 thiols Chemical class 0.000 description 2
- 238000013022 venting Methods 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 229910003296 Ni-Mo Inorganic materials 0.000 description 1
- 229910003294 NiMo Inorganic materials 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- HIVLDXAAFGCOFU-UHFFFAOYSA-N ammonium hydrosulfide Chemical compound [NH4+].[SH-] HIVLDXAAFGCOFU-UHFFFAOYSA-N 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 150000001728 carbonyl compounds Chemical class 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000004517 catalytic hydrocracking Methods 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000004939 coking Methods 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000011437 continuous method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000010730 cutting oil Substances 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 150000002440 hydroxy compounds Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- DDTIGTPWGISMKL-UHFFFAOYSA-N molybdenum nickel Chemical compound [Ni].[Mo] DDTIGTPWGISMKL-UHFFFAOYSA-N 0.000 description 1
- 230000001473 noxious effect Effects 0.000 description 1
- 229910052762 osmium Inorganic materials 0.000 description 1
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000002085 persistent effect Effects 0.000 description 1
- 238000005373 pervaporation Methods 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000012958 reprocessing Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 229910052702 rhenium Inorganic materials 0.000 description 1
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000012163 sequencing technique Methods 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000002195 soluble material Substances 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 238000007655 standard test method Methods 0.000 description 1
- 229910052713 technetium Inorganic materials 0.000 description 1
- GKLVYJBZJHMRIY-UHFFFAOYSA-N technetium atom Chemical compound [Tc] GKLVYJBZJHMRIY-UHFFFAOYSA-N 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G67/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only
- C10G67/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only
- C10G67/14—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only including at least two different refining steps in the absence of hydrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D11/00—Solvent extraction
- B01D11/04—Solvent extraction of solutions which are liquid
- B01D11/0492—Applications, solvents used
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D19/00—Degasification of liquids
- B01D19/0036—Flash degasification
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G19/00—Refining hydrocarbon oils in the absence of hydrogen, by alkaline treatment
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G19/00—Refining hydrocarbon oils in the absence of hydrogen, by alkaline treatment
- C10G19/02—Refining hydrocarbon oils in the absence of hydrogen, by alkaline treatment with aqueous alkaline solutions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G31/00—Refining of hydrocarbon oils, in the absence of hydrogen, by methods not otherwise provided for
- C10G31/08—Refining of hydrocarbon oils, in the absence of hydrogen, by methods not otherwise provided for by treating with water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G53/00—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes
- C10G53/02—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes plural serial stages only
- C10G53/04—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes plural serial stages only including at least one extraction step
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G67/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only
- C10G67/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only
- C10G67/04—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only including solvent extraction as the refining step in the absence of hydrogen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/201—Impurities
- C10G2300/202—Heteroatoms content, i.e. S, N, O, P
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Lubricants (AREA)
- Organic Insulating Materials (AREA)
Claims (14)
1. Fremgangsmåde til raffinering af en tilførselsolie, der indeholder kontaminanter, hvilken fremgangsmåde omfatter: i) eksponering af tilførselsolien for reducerende betingelser ved en temperatur på 200 til 600 °C og et tryk på 1 til 50 MPa, især i nærvær af en katalysator til reducering af mindst nogle af kontaminanterne; ii) afgasning af den resulterende olie ved et absolut tryk på under 90 kPa under ikke-oxiderende betingelser; og iii) ekstraktion af den resulterende olie med vand til frembringelse af en raffineret olie.
2. Fremgangsmåde ifølge krav 1, hvor tilførselsolien indeholder en halogenorganisk forbindelse og de reducerende betingelser i trin i) omfatter elementært hydrogen og et hydrogenhalidrensemiddel, hvor hydrogenhalidrensemidlet fortrinsvis omfatter ammoniak.
3. Fremgangsmåde ifølge krav 1 eller krav 2, der yderligere omfatter trin ia) mellem trin i) og ii), hvor trin ia) separerer gasformigt hydrogen fra den resulterende olie ved opretholdelse af trykket, der er anvendt i trin i).
4. Fremgangsmåde ifølge krav 3, hvor det fraseparerede gasformige hydrogen indeholder carbonhydrider, og trin ia) yderligere omfatter trinene: • eksponering af det gasformige hydrogen og carbonhydrider for vand til reducering af temperaturen af det gasformige hydrogen; og • separering af en væskestrøm fra det gasformige hydrogen, hvilken væskestrøm omfatter vandet og carbonhydriderne; og • fortrinsvis separering af carbonhydriderne fra væskestrømmen og kombinering af carbonhydriderne med olien.
5. Fremgangsmåde ifølge krav 3 eller krav 4, der omfatter trinet recirkulering af det fraseparerede hydrogen til anvendelse i trin i).
6. Fremgangsmåde ifølge et hvilket som helst af kravene 3 til 5, der yderligere omfatter trin ib) mellem trin ia) og ii) , hvilket trin ib) reducerer trykket i den resulterende olie til omtrent atmosfærisk tryk, hvor trin ib) fortrinsvis yderligere omfatter passage af den resulterende olie gennem en gas-væske-separator ved omgivelsestryk til fjernelse af en opløst gas derfra.
7. Fremgangsmåde ifølge et hvilket som helst af kravene 1 til 6, hvor trin ii) udføres ved et absolut tryk på mindre end ca. 10 kPa og/eller fortrinsvis ved en temperatur på mellem 30 og 80 °C.
8. Apparat til raffinering af en tilførselsolie, hvilket apparat omfatter: • en højtryksreaktor med et reaktorindløb og et reaktorudløb; • en afgasningsenhed, der er koblet til reaktorudløbet, til afgasning ved et absolut tryk på mindre end 90 kPa; • en ekstraktionsenhed, der er koblet til afgasningsenheden, til ekstraktion af raffineret olie med vand; og • en højtryks-gas-væske-separator mellem reaktorudløbet og afgasningsenheden, hvor separatoren har et separatorindløb, der er koblet til reaktorudløbet, et olieudløb, der er koblet til afgasningsenheden, og et gasudløb.
9. Apparat ifølge krav 8, der yderligere omfatter et vandindløb, der er disponeret til kombinering af en hydrogenholdig gas, der strømmer ud af gasudløbet, med vand.
10. Apparat ifølge krav 9, der omfatter en hydrogenseparator til separering af en væske fra den hydrogenholdige gas.
11. Apparat ifølge krav 10, hvor hydrogenseparatoren er koblet til reaktorindløbet til muliggørelse af recirkulering af hydrogen i den hydrogenholdige gas til højtryksreaktoren.
12. Apparat ifølge krav 10 eller krav 11, hvor hydrogenseparatoren har et væskeudløb, der er koblet til en væske-væske-separator til separering af en vandig væske fra en ikke-vandig væske, hvilken væske-væske-separator har et vandigt udløb og et ikke-vandigt udløb, hvor det ikke-vandige udløb fortrinsvis er koblet til olieudløbet på højtryks-gas-væske-separatoren til kombinering af den ikke-vandige væske med olie, der strømmer ud af olieudløbet.
13. Apparat ifølge et hvilket som helst af kravene 8 til 12, hvor olieudløbet på højtryks-gas-væske-separatoren er koblet til en lavtryks-gas-væske-separator, der har et lavtryksseparatorudløb, hvilket lavtryksseparatorudløb er koblet til afgasningsenheden.
14. Apparat ifølge et hvilket som helst af kravene 8 til 13, hvor ekstraktionsenheden omfatter et vandindløb, der er disponeret til kombinering af olie, der strømmer ud af afgasningsenheden, med vand, og en vandseparator til separering af vand fra olien, efter at den er blevet kombineret med vand.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AU2014900905A AU2014900905A0 (en) | 2014-03-17 | Refining of used oils | |
| PCT/AU2014/000687 WO2015139068A1 (en) | 2014-03-17 | 2014-07-02 | Refining of used oils |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DK3046995T3 true DK3046995T3 (da) | 2018-12-10 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DK14808474.2T DK3046995T3 (da) | 2014-03-17 | 2014-07-02 | Raffinering af brugte olier |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US9828558B2 (da) |
| EP (1) | EP3046995B1 (da) |
| JP (1) | JP6498270B2 (da) |
| AU (1) | AU2014259565B8 (da) |
| DK (1) | DK3046995T3 (da) |
| ES (1) | ES2694004T3 (da) |
| MX (1) | MX360259B (da) |
| PL (1) | PL3046995T3 (da) |
| PT (1) | PT3046995T (da) |
| TR (1) | TR201816563T4 (da) |
| WO (1) | WO2015139068A1 (da) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| GB2544715A (en) * | 2015-09-15 | 2017-05-31 | Statoil Petroleum As | Method and system for processing a fluid produced from a well |
| US10053369B2 (en) * | 2016-04-11 | 2018-08-21 | The Research Foundation For The State University Of New York | Production of ammonium sulfate using a vacuum absorption process |
| JP2018063218A (ja) * | 2016-10-14 | 2018-04-19 | 日本特殊陶業株式会社 | 油状態制御装置 |
| CN108251202A (zh) * | 2017-12-31 | 2018-07-06 | 安徽凯奥新能源股份有限公司 | 一种从变压器油中分离出水分与溶解性气体的制备方法 |
| CN115820333B (zh) * | 2021-09-17 | 2024-01-26 | 山东大学 | 一种废润滑油泥的资源化回收利用方法 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4414194A (en) | 1981-05-26 | 1983-11-08 | Shell Oil Company | Extraction process |
| NL8402837A (nl) | 1984-09-14 | 1986-04-01 | Kinetics Technology | Werkwijze voor het zuiveren en/of onschadelijk maken van een door halogeen-, stikstof- en/of zwavel (verbindingen) verontreinigde vloeibare koolwaterstofstroom. |
| US4623448A (en) | 1985-03-12 | 1986-11-18 | Moreco Energy, Inc. | Removing halogenated polyphenyl materials from used oil products |
| DE3723607A1 (de) * | 1987-07-17 | 1989-01-26 | Ruhrkohle Ag | Verfahren zum hydrierenden aufarbeiten von altoelen |
| US5013424A (en) * | 1990-07-30 | 1991-05-07 | Uop | Process for the simultaneous hydrogenation of a first feedstock comprising hydrocarbonaceous compounds and having a non-distillable component and a second feedstock comprising halogenated organic compounds |
| JP3404042B2 (ja) * | 1992-12-23 | 2003-05-06 | コモンウェルス・サイエンティフィック・アンド・インダストリアル・リサーチ・オーガニゼイション | ハライド含有有機物の分解および溶媒精製 |
| US5951852A (en) * | 1993-12-23 | 1999-09-14 | Commonwealth Scientific And Industrial Research Organisation Et Al. | Destruction of halide containing organics and solvent purification |
| JP2005270388A (ja) * | 2004-03-25 | 2005-10-06 | Tokyo Electric Power Co Inc:The | 有機ハロゲン化合物の分解処理方法 |
| WO2007136340A1 (en) * | 2006-05-18 | 2007-11-29 | Nynas Ab | Process for the regeneration of a used oil |
-
2014
- 2014-07-02 PT PT14808474T patent/PT3046995T/pt unknown
- 2014-07-02 ES ES14808474.2T patent/ES2694004T3/es active Active
- 2014-07-02 AU AU2014259565A patent/AU2014259565B8/en not_active Ceased
- 2014-07-02 MX MX2014013398A patent/MX360259B/es active IP Right Grant
- 2014-07-02 PL PL14808474T patent/PL3046995T3/pl unknown
- 2014-07-02 DK DK14808474.2T patent/DK3046995T3/da active
- 2014-07-02 JP JP2017500098A patent/JP6498270B2/ja not_active Expired - Fee Related
- 2014-07-02 WO PCT/AU2014/000687 patent/WO2015139068A1/en not_active Ceased
- 2014-07-02 EP EP14808474.2A patent/EP3046995B1/en not_active Not-in-force
- 2014-07-02 TR TR2018/16563T patent/TR201816563T4/tr unknown
- 2014-07-02 US US14/399,297 patent/US9828558B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| JP6498270B2 (ja) | 2019-04-10 |
| WO2015139068A1 (en) | 2015-09-24 |
| AU2014259565B2 (en) | 2018-10-18 |
| US20160208178A1 (en) | 2016-07-21 |
| ES2694004T3 (es) | 2018-12-17 |
| MX360259B (es) | 2018-10-26 |
| TR201816563T4 (tr) | 2018-11-21 |
| EP3046995A4 (en) | 2016-11-23 |
| AU2014259565A1 (en) | 2015-10-01 |
| AU2014259565B8 (en) | 2018-10-25 |
| MX2014013398A (es) | 2016-03-08 |
| PL3046995T3 (pl) | 2019-02-28 |
| EP3046995A1 (en) | 2016-07-27 |
| PT3046995T (pt) | 2018-11-23 |
| US9828558B2 (en) | 2017-11-28 |
| EP3046995B1 (en) | 2018-08-22 |
| JP2017519090A (ja) | 2017-07-13 |
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