DK3079795T3 - Sekvestrering af kuldioxid ved binding som alkalicarbonat - Google Patents
Sekvestrering af kuldioxid ved binding som alkalicarbonat Download PDFInfo
- Publication number
- DK3079795T3 DK3079795T3 DK14808945.1T DK14808945T DK3079795T3 DK 3079795 T3 DK3079795 T3 DK 3079795T3 DK 14808945 T DK14808945 T DK 14808945T DK 3079795 T3 DK3079795 T3 DK 3079795T3
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- DK
- Denmark
- Prior art keywords
- optionally
- carbon dioxide
- electrolysis
- designed
- hydrogen
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- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 title claims description 102
- 229910002092 carbon dioxide Inorganic materials 0.000 title claims description 53
- 239000001569 carbon dioxide Substances 0.000 title claims description 51
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 title description 7
- 239000003513 alkali Substances 0.000 title description 3
- 230000009919 sequestration Effects 0.000 title description 3
- 238000005868 electrolysis reaction Methods 0.000 claims description 68
- 238000000034 method Methods 0.000 claims description 41
- 239000001257 hydrogen Substances 0.000 claims description 38
- 229910052739 hydrogen Inorganic materials 0.000 claims description 38
- 238000006243 chemical reaction Methods 0.000 claims description 33
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 31
- 239000000460 chlorine Substances 0.000 claims description 29
- 239000000126 substance Substances 0.000 claims description 21
- 150000001875 compounds Chemical class 0.000 claims description 20
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 19
- 229910052801 chlorine Inorganic materials 0.000 claims description 19
- 239000000203 mixture Substances 0.000 claims description 18
- 230000008569 process Effects 0.000 claims description 16
- 238000002485 combustion reaction Methods 0.000 claims description 14
- 229910052708 sodium Inorganic materials 0.000 claims description 14
- 238000003860 storage Methods 0.000 claims description 14
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 11
- 229910052700 potassium Inorganic materials 0.000 claims description 11
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 10
- 239000007864 aqueous solution Substances 0.000 claims description 7
- 150000002431 hydrogen Chemical class 0.000 claims description 7
- 239000002699 waste material Substances 0.000 claims description 7
- 229910001868 water Inorganic materials 0.000 description 31
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 23
- 150000003839 salts Chemical class 0.000 description 20
- 238000004519 manufacturing process Methods 0.000 description 13
- 239000011734 sodium Substances 0.000 description 13
- 229910052751 metal Inorganic materials 0.000 description 11
- 239000002184 metal Substances 0.000 description 11
- 239000011780 sodium chloride Substances 0.000 description 11
- 229910052783 alkali metal Inorganic materials 0.000 description 10
- 150000001340 alkali metals Chemical class 0.000 description 9
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 8
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 8
- 150000001298 alcohols Chemical class 0.000 description 8
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 7
- 150000001335 aliphatic alkanes Chemical class 0.000 description 7
- 150000001336 alkenes Chemical class 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000003570 air Substances 0.000 description 5
- 230000008901 benefit Effects 0.000 description 5
- 239000000543 intermediate Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- 238000007792 addition Methods 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 4
- 239000001103 potassium chloride Substances 0.000 description 4
- 235000011164 potassium chloride Nutrition 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 229910000029 sodium carbonate Inorganic materials 0.000 description 4
- 235000017550 sodium carbonate Nutrition 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 238000012261 overproduction Methods 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- 239000002028 Biomass Substances 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- -1 alkali metal salts Chemical class 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 229910000069 nitrogen hydride Inorganic materials 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 229960003975 potassium Drugs 0.000 description 2
- 229910000027 potassium carbonate Inorganic materials 0.000 description 2
- 235000011181 potassium carbonates Nutrition 0.000 description 2
- 230000001932 seasonal effect Effects 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- OYPRJOBELJOOCE-IGMARMGPSA-N Calcium-40 Chemical compound [40Ca] OYPRJOBELJOOCE-IGMARMGPSA-N 0.000 description 1
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 229910001854 alkali hydroxide Inorganic materials 0.000 description 1
- 229910001514 alkali metal chloride Inorganic materials 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000012080 ambient air Substances 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- WDIHJSXYQDMJHN-UHFFFAOYSA-L barium chloride Chemical compound [Cl-].[Cl-].[Ba+2] WDIHJSXYQDMJHN-UHFFFAOYSA-L 0.000 description 1
- 229910001626 barium chloride Inorganic materials 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000010891 electric arc Methods 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 230000005496 eutectics Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 239000005431 greenhouse gas Substances 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910001510 metal chloride Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 150000002828 nitro derivatives Chemical class 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000010587 phase diagram Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000011736 potassium bicarbonate Substances 0.000 description 1
- 235000015497 potassium bicarbonate Nutrition 0.000 description 1
- 229910000028 potassium bicarbonate Inorganic materials 0.000 description 1
- 229940086066 potassium hydrogencarbonate Drugs 0.000 description 1
- BUKHSQBUKZIMLB-UHFFFAOYSA-L potassium;sodium;dichloride Chemical compound [Na+].[Cl-].[Cl-].[K+] BUKHSQBUKZIMLB-UHFFFAOYSA-L 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000009420 retrofitting Methods 0.000 description 1
- 239000011833 salt mixture Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/32—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by electrical effects other than those provided for in group B01D61/00
- B01D53/326—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by electrical effects other than those provided for in group B01D61/00 in electrochemical cells
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/62—Carbon oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/81—Solid phase processes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
- C07C1/0485—Set-up of reactors or accessories; Multi-step processes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
- C07C29/1516—Multisteps
- C07C29/1518—Multisteps one step being the formation of initial mixture of carbon oxides and hydrogen for synthesis
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/24—Halogens or compounds thereof
- C25B1/26—Chlorine; Compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B15/00—Operating or servicing cells
- C25B15/02—Process control or regulation
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B15/00—Operating or servicing cells
- C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
- C25C3/02—Electrolytic production, recovery or refining of metals by electrolysis of melts of alkali or alkaline earth metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/30—Alkali metal compounds
- B01D2251/304—Alkali metal compounds of sodium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/30—Alkali metal compounds
- B01D2251/306—Alkali metal compounds of potassium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/60—Inorganic bases or salts
- B01D2251/606—Carbonates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/50—Carbon oxides
- B01D2257/504—Carbon dioxide
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/40—Capture or disposal of greenhouse gases of CO2
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/133—Renewable energy sources, e.g. sunlight
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/151—Reduction of greenhouse gas [GHG] emissions, e.g. CO2
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Environmental & Geological Engineering (AREA)
- Analytical Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Inorganic Chemistry (AREA)
- Automation & Control Theory (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Claims (12)
1. Fremgangsmåde til fremstilling af chlor og lagring af kuldioxid, hvor a) en forbindelse med formel M+Cl· reageres elektrolytisk til M og CI2, hvor M+ = Na, K eller en blanding deraf; b) M reageres med kuldioxid og eventuelt H2O til M2CO3 og/eller eventuelt til MHCO3; og c) M2CO3 og/eller eventuelt MHCO3 lagres, hvor reaktionen af M med kuldioxid og eventuelt H2O i trin b) foregår ved forbrænding af M i en atmosfære, omfattende kuldioxid og eventuelt H2O.
2. Fremgangsmåde ifølge krav 1, hvor energien til den elektrolytiske reaktion af ΜΌ’ til M og CI2 i det væsentlige består af overskudsenergi fra vedvarende energier.
3. Fremgangsmåde ifølge et af de foregående krav, hvor forbindelsen med formel M+CI’ udvindes af affaldsprodukter fra den kemiske industri.
4. Fremgangsmåde ifølge et af de foregående krav, hvor elektrolysen i trin a) foregår ved saltsmelte-elektrolyse af en blanding, omfattende en forbindelse med formel M+Cl·.
5. Fremgangsmåde ifølge krav 4, hvor der ved reaktionen i trin b) også genereres kulstofmonoxid, som eventuelt reageres til yderligere kemiske produkter.
6. Fremgangsmåde ifølge et af kravene 1 til 4, hvor der afvekslingsvis foregår en elektrolyse af en vandig opløsning af forbindelsen med formel M+Cl·, idet der opstår hydrogen.
7. Fremgangsmåde ifølge krav 6, hvor der ved reaktionen i trin b) også genereres kulstofmonoxid, som reageres sammen med hydrogenet til yderligere kemiske produkter.
8. Indretning til fremstilling af chlor og lagring af kuldioxid, omfattende en elektrolyseindretning (E), som er udformet til at reagere en forbindelse med formel M+Cl· elektrolytisk til M og CI2, hvor M+ = Na, K eller en blanding deraf; en første tilførselsindretning (1) til M+Cl·, som er udformet til at tilføre M+Cl· til elektrolyseindretningen (E); en første bortledningsindretning (1') til CI2, som er udformet til at fjerne CI2 fra elektrolyseindretningen (E); en anden bortledningsindretning (2') til M, som er udformet til at fjerne M fra elektrolyseindretningen (E); en første reaktor (R) til reaktion af kuldioxid med M, der er udformet til at reagere M med kuldioxid og eventuelt H2O til M2CO3 og/eller eventuelt til MHCO3; en anden tilførselsindretning (2) til M, som er forbundet med den anden bortledningsindretning (2') til M og er udformet til at tilføre M til den første reaktor (R); en tredje tilførselsindretning (3) til kuldioxid og eventuelt H2O, der er udformet til at tilføre kuldioxid og eventuelt H2O til den første reaktor (R); en tredje bortledningsindretning (3') til M2CO3 og/eller eventuelt MHCO3, som er udformet til at fjerne M2CO3 og/eller eventuelt MHCO3 fra den første reaktor (R); og en lagringsindretning (S) til lagring af M2CO3 og/eller eventuelt MHCO3, som er udformet til at lagre M2CO3 og/eller eventuelt MHCO3, som kommer fra den tredje bortledningsindretning (3'), hvor den første reaktor (R) har en brænder til forbrænding af M med kuldioxid og eventuelt H2O.
9. Indretning ifølge krav 8, yderligere omfattende en indretning til vedvarende energi, som er udformet til at forsyne elektrolyseindretningen (E) med elektrisk energi.
10. Indretning ifølge et af de foregående indretningsrelevante krav, hvor elektrolyseindretningen (E) er en saltsmelte-elektrolyseindretning.
11. Indretning ifølge et af kravene 8 og 9, hvor elektrolyseindretningen (E) er udformet på en sådan måde, at der afvekslingsvis elektrolyseres en vandig opløsning af M+Cl·, yderligere omfattende en fjerde bortledningsindretning (4') til hydrogen, som er udformet til at fjerne hydrogen fra elektrolyseindretningen (E).
12. Indretning ifølge krav 11, yderligere omfattende en fjerde tilførselsindretning (4) til hydrogen, som er forbundet med den fjerde bortledningsindretning (4') til hydrogen og er udformet til at tilføre hydrogen til den første reaktor (R).
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102013225419.9A DE102013225419A1 (de) | 2013-12-10 | 2013-12-10 | Sequestrierung von Kohlendioxid durch Bindung als Alkalicarbonat |
| PCT/EP2014/076389 WO2015086394A1 (de) | 2013-12-10 | 2014-12-03 | Sequestrierung von kohlendioxid durch bindung als alkalicarbonat |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DK3079795T3 true DK3079795T3 (da) | 2018-10-22 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DK14808945.1T DK3079795T3 (da) | 2013-12-10 | 2014-12-03 | Sekvestrering af kuldioxid ved binding som alkalicarbonat |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US20160319443A1 (da) |
| EP (1) | EP3079795B1 (da) |
| KR (1) | KR101831589B1 (da) |
| CN (1) | CN106413855A (da) |
| DE (1) | DE102013225419A1 (da) |
| DK (1) | DK3079795T3 (da) |
| ES (1) | ES2692796T3 (da) |
| HR (1) | HRP20181581T1 (da) |
| PL (1) | PL3079795T3 (da) |
| PT (1) | PT3079795T (da) |
| RS (1) | RS57726B1 (da) |
| WO (1) | WO2015086394A1 (da) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| KR102004690B1 (ko) * | 2017-12-11 | 2019-07-29 | 한국에너지기술연구원 | 무기질 폐기물을 이용한 이산화탄소 고정화 방법 |
| CN110983357A (zh) * | 2019-12-04 | 2020-04-10 | 昆明理工大学 | 一种电解二氧化碳制一氧化碳同时副产氯气、碳酸氢盐的三室隔膜电解方法 |
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| US3051635A (en) * | 1959-06-17 | 1962-08-28 | Solvay | Process for the manufacture of sodium by electrolysis of fused salt baths |
| JP2002014195A (ja) * | 2000-06-29 | 2002-01-18 | Japan Nuclear Cycle Development Inst States Of Projects | ナトリウム精製電解槽およびこれを用いた放射性ナトリウム廃棄物の処理方法 |
| CN101068610A (zh) * | 2004-09-23 | 2007-11-07 | 乔·大卫·琼斯 | 通过碳酸盐和/或碳酸氢盐无机物的共同产生从废弃流中除去二氧化碳 |
| JP2006137620A (ja) * | 2004-11-10 | 2006-06-01 | Toshiba Corp | 排ガス中の二酸化炭素の回収システムおよび回収方法 |
| US8549857B2 (en) * | 2006-12-16 | 2013-10-08 | Christopher J. Papile | Methods and/or systems for magnetobaric assisted generation of power from low temperature heat |
| DE102008031437A1 (de) | 2008-07-04 | 2010-01-07 | Siemens Aktiengesellschaft | Mobiler Energieträger und Energiespeicher |
| JP2010087275A (ja) * | 2008-09-30 | 2010-04-15 | Panasonic Corp | 半導体集積回路および電子機器 |
| DE102009007755A1 (de) * | 2009-02-05 | 2010-08-12 | Martin Vogelmann | Verfahren zur Speicherung von elektrischer Energie und von Kohlenstoffdioxid |
| AU2010282714B2 (en) * | 2009-08-10 | 2013-11-14 | David Randolph Smith | Method and apparatus to sequester CO2 gas |
| KR20120112570A (ko) * | 2009-12-18 | 2012-10-11 | 스카이오닉 코퍼레이션 | 2족 탄산염 및 이산화규소의 형성을 통한 이산화탄소 격리 방법 |
| GB201015223D0 (en) * | 2010-09-13 | 2010-10-27 | Sec Dep For Environment Food A | Vaccines |
| DE102010041033A1 (de) | 2010-09-20 | 2012-03-22 | Siemens Aktiengesellschaft | Stoffverwertung mit elektropositivem Metall |
| DE102011077819A1 (de) * | 2011-06-20 | 2012-12-20 | Siemens Aktiengesellschaft | Kohlendioxidreduktion in Stahlwerken |
| US8728425B2 (en) | 2012-04-17 | 2014-05-20 | Siemens Aktiengesellschaft | Method and an apparatus for performing an energy efficient desulphurization and decarbonisation of a flue gas |
| US10221491B2 (en) * | 2012-06-29 | 2019-03-05 | Australian Biorefining Pty Ltd | Process and apparatus for generating or recovering hydrochloric acid from metal salt solutions |
-
2013
- 2013-12-10 DE DE102013225419.9A patent/DE102013225419A1/de not_active Withdrawn
-
2014
- 2014-12-03 KR KR1020167018536A patent/KR101831589B1/ko not_active Expired - Fee Related
- 2014-12-03 PT PT14808945T patent/PT3079795T/pt unknown
- 2014-12-03 US US15/102,604 patent/US20160319443A1/en not_active Abandoned
- 2014-12-03 PL PL14808945T patent/PL3079795T3/pl unknown
- 2014-12-03 DK DK14808945.1T patent/DK3079795T3/da active
- 2014-12-03 RS RS20181116A patent/RS57726B1/sr unknown
- 2014-12-03 WO PCT/EP2014/076389 patent/WO2015086394A1/de not_active Ceased
- 2014-12-03 EP EP14808945.1A patent/EP3079795B1/de not_active Not-in-force
- 2014-12-03 HR HRP20181581TT patent/HRP20181581T1/hr unknown
- 2014-12-03 ES ES14808945.1T patent/ES2692796T3/es active Active
- 2014-12-03 CN CN201480073475.1A patent/CN106413855A/zh active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| EP3079795A1 (de) | 2016-10-19 |
| ES2692796T3 (es) | 2018-12-05 |
| HRP20181581T1 (hr) | 2018-11-30 |
| DE102013225419A1 (de) | 2015-06-11 |
| KR20160096182A (ko) | 2016-08-12 |
| WO2015086394A1 (de) | 2015-06-18 |
| KR101831589B1 (ko) | 2018-02-23 |
| CN106413855A (zh) | 2017-02-15 |
| RS57726B1 (sr) | 2018-12-31 |
| PL3079795T3 (pl) | 2019-02-28 |
| US20160319443A1 (en) | 2016-11-03 |
| EP3079795B1 (de) | 2018-07-25 |
| PT3079795T (pt) | 2018-11-12 |
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