DK3243807T3 - Anvendelse af vandige emulsioner på basis af propylethoxysilanoligomerer som tilsætning i hydraulisk afbindende cementblandinger til formindskelse af svind - Google Patents
Anvendelse af vandige emulsioner på basis af propylethoxysilanoligomerer som tilsætning i hydraulisk afbindende cementblandinger til formindskelse af svind Download PDFInfo
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- DK3243807T3 DK3243807T3 DK16169271.0T DK16169271T DK3243807T3 DK 3243807 T3 DK3243807 T3 DK 3243807T3 DK 16169271 T DK16169271 T DK 16169271T DK 3243807 T3 DK3243807 T3 DK 3243807T3
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- 239000000203 mixture Substances 0.000 title claims description 59
- 239000000839 emulsion Substances 0.000 title claims description 52
- 239000004568 cement Substances 0.000 title claims description 28
- 239000000654 additive Substances 0.000 title claims description 5
- 239000002699 waste material Substances 0.000 title 1
- 239000003995 emulsifying agent Substances 0.000 claims description 26
- 239000004570 mortar (masonry) Substances 0.000 claims description 26
- 239000004567 concrete Substances 0.000 claims description 23
- -1 alkaryl ether sulfates Chemical class 0.000 claims description 22
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 19
- MSRJTTSHWYDFIU-UHFFFAOYSA-N octyltriethoxysilane Chemical compound CCCCCCCC[Si](OCC)(OCC)OCC MSRJTTSHWYDFIU-UHFFFAOYSA-N 0.000 claims description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 18
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 14
- 238000004519 manufacturing process Methods 0.000 claims description 14
- 229960003493 octyltriethoxysilane Drugs 0.000 claims description 14
- 125000000217 alkyl group Chemical group 0.000 claims description 13
- BFSVOASYOCHEOV-UHFFFAOYSA-N 2-diethylaminoethanol Chemical compound CCN(CC)CCO BFSVOASYOCHEOV-UHFFFAOYSA-N 0.000 claims description 10
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 10
- 239000004094 surface-active agent Substances 0.000 claims description 10
- 125000004432 carbon atom Chemical group C* 0.000 claims description 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 8
- 239000003921 oil Substances 0.000 claims description 7
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 5
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 5
- 239000003755 preservative agent Substances 0.000 claims description 5
- 229910019142 PO4 Inorganic materials 0.000 claims description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
- 235000021317 phosphate Nutrition 0.000 claims description 4
- 239000010695 polyglycol Substances 0.000 claims description 4
- 229920000151 polyglycol Polymers 0.000 claims description 4
- 229920001296 polysiloxane Polymers 0.000 claims description 4
- 150000001298 alcohols Chemical class 0.000 claims description 3
- 125000003118 aryl group Chemical group 0.000 claims description 3
- 238000005260 corrosion Methods 0.000 claims description 3
- 238000000518 rheometry Methods 0.000 claims description 3
- 229920005682 EO-PO block copolymer Polymers 0.000 claims description 2
- 230000000996 additive effect Effects 0.000 claims description 2
- 150000003973 alkyl amines Chemical class 0.000 claims description 2
- 150000005215 alkyl ethers Chemical class 0.000 claims description 2
- 150000003863 ammonium salts Chemical class 0.000 claims description 2
- 150000001735 carboxylic acids Chemical class 0.000 claims description 2
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims description 2
- 150000002402 hexoses Chemical class 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 2
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 2
- 238000006384 oligomerization reaction Methods 0.000 claims description 2
- 150000002972 pentoses Chemical group 0.000 claims description 2
- 229920005989 resin Polymers 0.000 claims description 2
- 239000011347 resin Substances 0.000 claims description 2
- 229920006395 saturated elastomer Polymers 0.000 claims description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 1
- 239000003513 alkali Substances 0.000 claims 1
- 150000001447 alkali salts Chemical class 0.000 claims 1
- 125000000129 anionic group Chemical group 0.000 claims 1
- 125000003710 aryl alkyl group Chemical group 0.000 claims 1
- 239000001307 helium Substances 0.000 claims 1
- 229910052734 helium Inorganic materials 0.000 claims 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 claims 1
- 125000001165 hydrophobic group Chemical group 0.000 claims 1
- 239000012875 nonionic emulsifier Substances 0.000 claims 1
- 125000000962 organic group Chemical group 0.000 claims 1
- 229910052710 silicon Inorganic materials 0.000 claims 1
- 239000010703 silicon Substances 0.000 claims 1
- YAPKLBSSEAZLGL-UHFFFAOYSA-N ethoxy(propyl)silane Chemical compound CCC[SiH2]OCC YAPKLBSSEAZLGL-UHFFFAOYSA-N 0.000 description 19
- 238000007792 addition Methods 0.000 description 15
- 239000002585 base Substances 0.000 description 9
- 238000004945 emulsification Methods 0.000 description 7
- 239000004566 building material Substances 0.000 description 5
- 150000003254 radicals Chemical class 0.000 description 5
- 239000011150 reinforced concrete Substances 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000004753 textile Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- RUPBZQFQVRMKDG-UHFFFAOYSA-M Didecyldimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCC[N+](C)(C)CCCCCCCCCC RUPBZQFQVRMKDG-UHFFFAOYSA-M 0.000 description 3
- 240000002989 Euphorbia neriifolia Species 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000000470 constituent Substances 0.000 description 3
- 150000002169 ethanolamines Chemical class 0.000 description 3
- 150000002170 ethers Chemical class 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 229910000077 silane Inorganic materials 0.000 description 3
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
- 229940100555 2-methyl-4-isothiazolin-3-one Drugs 0.000 description 2
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 239000000872 buffer Substances 0.000 description 2
- DHNRXBZYEKSXIM-UHFFFAOYSA-N chloromethylisothiazolinone Chemical group CN1SC(Cl)=CC1=O DHNRXBZYEKSXIM-UHFFFAOYSA-N 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- BEGLCMHJXHIJLR-UHFFFAOYSA-N methylisothiazolinone Chemical group CN1SC=CC1=O BEGLCMHJXHIJLR-UHFFFAOYSA-N 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- ZWRUINPWMLAQRD-UHFFFAOYSA-N nonan-1-ol Chemical compound CCCCCCCCCO ZWRUINPWMLAQRD-UHFFFAOYSA-N 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 230000002335 preservative effect Effects 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- QDTDKYHPHANITQ-UHFFFAOYSA-N 7-methyloctan-1-ol Chemical compound CC(C)CCCCCCO QDTDKYHPHANITQ-UHFFFAOYSA-N 0.000 description 1
- 235000019738 Limestone Nutrition 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 239000004141 Sodium laurylsulphate Substances 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000002318 adhesion promoter Substances 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 239000003619 algicide Substances 0.000 description 1
- 229910000318 alkali metal phosphate Inorganic materials 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000001414 amino alcohols Chemical class 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 150000005840 aryl radicals Chemical class 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 235000012216 bentonite Nutrition 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- YHWCPXVTRSHPNY-UHFFFAOYSA-N butan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] YHWCPXVTRSHPNY-UHFFFAOYSA-N 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 239000012975 dibutyltin dilaurate Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical class CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 229920002313 fluoropolymer Polymers 0.000 description 1
- 239000004811 fluoropolymer Substances 0.000 description 1
- 239000010881 fly ash Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 229910021485 fumed silica Inorganic materials 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 230000003641 microbiacidal effect Effects 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 125000005375 organosiloxane group Chemical group 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 230000035899 viability Effects 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
- 150000003755 zirconium compounds Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
- C04B24/40—Compounds containing silicon, titanium or zirconium or other organo-metallic compounds; Organo-clays; Organo-inorganic complexes
- C04B24/42—Organo-silicon compounds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
- C04B40/0028—Aspects relating to the mixing step of the mortar preparation
- C04B40/0039—Premixtures of ingredients
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
- C04B24/16—Sulfur-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B7/00—Hydraulic cements
- C04B7/345—Hydraulic cements not provided for in one of the groups C04B7/02 - C04B7/34
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/0045—Polymers chosen for their physico-chemical characteristics
- C04B2103/0046—Polymers chosen for their physico-chemical characteristics added as monomers or as oligomers
- C04B2103/0048—Polymers chosen for their physico-chemical characteristics added as monomers or as oligomers as oligomers
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/56—Opacifiers
- C04B2103/58—Shrinkage reducing agents
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/60—Agents for protection against chemical, physical or biological attack
- C04B2103/67—Biocides
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/34—Non-shrinking or non-cracking materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/34—Non-shrinking or non-cracking materials
- C04B2111/346—Materials exhibiting reduced plastic shrinkage cracking
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/60—Flooring materials
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Civil Engineering (AREA)
- Dispersion Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Molecular Biology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Claims (11)
1. Anvendelse af en vandig emulsion, som indeholder en propylethoxysilanoligomer-blanding eller en blanding af en propylethoxysilanoligomer-blanding og octyltriethoxysilan i et vægtforhold på 3 til 1 til 1 til 3, i det mindste en emulgator eller et emulgatorsystem, i det mindste et indhold af en 2-aminoethanol og vand, som tilsætning ved fremstillingen af hydraulisk afbindende cementblandinger til formindskelse af svind.
2. Anvendelse ifølge krav 1, kendetegnet ved, at emulsionen har et indhold af propylethoxysilanoligomer-blanding på 20 til 85 vægt-%, baseret på den samlede vægt af emulsionen, idet oliefasen i summen udgør 40 til 85 vægt-%, fortrinsvis 41 til 82 vægt-%, baseret på den samlede vægt af emulsionen.
3. Anvendelse ifølge krav 1 eller 2, kendetegnet ved, at propylethoxysilanoligomer-blandingen indeholder oligomerer med formel (I)
og grupperne R1 uafhængigt af hinanden står for n- samt i-propyl, og grupperne R2 står for ethyl, og n bestemmer oligomeriseringsgraden som med 2 til 20.
4. Anvendelse ifølge et af kravene 1 til 3, kendetegnet ved, at emulsionen indeholder 0,1 til 1 vægt-%, fortrinsvis 0,25 til 0,75 vægt-%, baseret på den samlede vægt af emulsionen, i det mindste en 2-aminoethanol med den almene formel (II) ho-ch2-ch2-nr32 (II), hvori grupperne R3 er ens eller forskellige og uafhængigt af hinanden står for hydrogen, methyl samt ethyl.
5. Anvendelse ifølge et af kravene 1 til 4, kendetegnet ved, at 2-aminoethanolen i emulsionen er N,N-diethyl-2-aminoethanol.
6. Anvendelse ifølge et af kravene 1 til 5, kendetegnet ved, at emulsionen har en pH-værdi på 8 til 12.
7. Anvendelse ifølge et af kravene 1 til 6, kendetegnet ved, at emulsionen indeholder i det mindste et yderligere tilsætningsstof udvalgt af rækken af konserveringsmidler, såsom CIT eller MIT, antikorrosionshjælpemidler, afperlingshjælpemidler, såsom reaktivt siloxanharpiks eller organopolysiloxan, reologihjælpemidler, natriumhydrogencarbonat.
8. Anvendelse ifølge et af kravene 1 til 7, kendetegnet ved, at emulgatoren eller emulgatorsystemet, som baserer på i det mindste to af de følgende emulgatorer, er udvalgt af alkylsulfater med Cs-Cis-alkyl, alkyl- og alkarylethersulfater med Cs-Cis-alkyl i den hydrofobe gruppe og med 1 til 40 ethylenoxid (EO)- eller propylenoxid (PO)-enheder alkylsulfonater med Cs-Cis-alkyl, natriumlaurylsulfat (C12-C16) , alkarylsulfonater med Cs-Cis-alkyl, og halvestere af sulforavsyre med monovalente alkoholer eller alkylphenoler med 5 til 15 carbonatomer, alkali- og ammoniumsalte af carboxylsyrer med 8 til 20 carbonatomer i alkyl-, aryl-, alkaryl- eller aralkylgruppen, alkyl- og alkarylphosphater med 8 til 20 carbonatomer i den organiske gruppe, alkylether- eller alkaryletherphosphater med 8 til 20 carbonatomer i alkyl- eller alkarylgruppen og 1 til 40 EO-enheder, alkylpolyglykolether og alkarylpolyglykolether med 8 til 40 EO-enheder og C8-C20-carbonatomer i alkyl- eller arylgrupperne, ethylenoxid/propylenoxid (EO/PO)-blokcopolymerer med 8 til 40 EO- eller PO-enheder, additionsprodukter af alkylaminer med Cs- C22~alkylgrupper med ethylenoxid eller propylenoxid, alkylpolyglykosider med lineære eller forgrenede, mættede eller umættede Cs-C24-alkylgrupper og oligoglykosidgrupper med 1 til 10 hexose- eller pentoseenheder, siliciumfunktionelle tensider eller blandinger af to eller flere af disse emulgatorer.
9. Anvendelse ifølge et af kravene 1 til 8, kendetegnet ved, der i emulgatoren eller emulgatorsystemet findes en blanding af i det mindste en anionisk og en ikke-ionisk emulgator i en mængde på 0,02 til 3 vægt-%, baseret på den samlede vægt af emulsionen.
10. Anvendelse ifølge et af kravene 1 til 9, kendetegnet ved, at man anvender emulsionen med 0,1 til 5 vægt-%, baseret på den i cementblandingen indeholdte cementmængde.
11. Anvendelse ifølge et af kravene 1 til 10, kendetegnet ved, at den hydraulisk afbindende cementblanding er mørtel, afretningslag eller beton.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP16169271.0A EP3243807B1 (de) | 2016-05-12 | 2016-05-12 | Verwendung wässriger emulsionen auf basis von propylethoxysilanoligomeren als zusatz in hydraulisch abbindenden zementmischungen zur minderung des schwundverhaltens |
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| Publication Number | Publication Date |
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| DK3243807T3 true DK3243807T3 (da) | 2019-03-18 |
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| Application Number | Title | Priority Date | Filing Date |
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| DK16169271.0T DK3243807T3 (da) | 2016-05-12 | 2016-05-12 | Anvendelse af vandige emulsioner på basis af propylethoxysilanoligomerer som tilsætning i hydraulisk afbindende cementblandinger til formindskelse af svind |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US10259748B2 (da) |
| EP (1) | EP3243807B1 (da) |
| JP (1) | JP6895799B2 (da) |
| CN (1) | CN107365101B (da) |
| CA (1) | CA2966904C (da) |
| DK (1) | DK3243807T3 (da) |
| ES (1) | ES2711795T3 (da) |
| PL (1) | PL3243807T3 (da) |
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| WO2022073217A1 (en) * | 2020-10-10 | 2022-04-14 | Wacker Chemie Ag | Use of alkoxysilanes or alkoxysiloxanes or compositions containing the same as admixture for mass hydrophobization of cement-based materials |
| CN116601127A (zh) * | 2020-12-18 | 2023-08-15 | 赢创运营有限公司 | 用于无机建筑材料的本体疏水化的稀释稳定的水性组合物 |
| CN117120562A (zh) | 2021-02-02 | 2023-11-24 | 迈图高新材料公司 | 包含有机官能烷氧基硅烷的组合物和包含其的涂料组合物 |
| CN113321441B (zh) * | 2021-06-28 | 2022-06-14 | 青岛理工大学 | 硅烷复合乳液作为抗裂增强剂的应用 |
| CN113831839B (zh) * | 2021-10-15 | 2022-06-10 | 信和新材料（苏州）有限公司 | 一种混凝土浮浆增强物及其制备方法和应用 |
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| AU648002B2 (en) * | 1991-06-20 | 1994-03-31 | W.R. Grace & Co.-Conn. | Cement admixture and defoaming agent |
| DE4122263C1 (da) | 1991-07-05 | 1993-02-25 | Degussa Ag, 6000 Frankfurt, De | |
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| DE19830232A1 (de) | 1998-07-07 | 2000-01-13 | Abb Research Ltd | Stromkontaktanordnungen eines Stromschalters |
| US6074470A (en) | 1998-12-10 | 2000-06-13 | Dow Corning Corporation | Stable, constant particle size, aqueous emulsions of nonpolar silanes suitable for use in water repellence applications |
| DE19904496A1 (de) | 1999-02-04 | 2000-08-10 | Wacker Chemie Gmbh | Wäßrige Cremes von Organosiliciumverbindungen |
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| DE10056344A1 (de) | 2000-11-14 | 2002-05-16 | Degussa | n-Propylethoxysiloxane, Verfahren zu deren Herstellung und deren Verwendung |
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| DE102005004872A1 (de) | 2005-02-03 | 2006-08-10 | Degussa Ag | Wässrige Emulsionen von funktionellen Alkoxysilanen und deren kondensierten Oligomeren, deren Herstellung und Verwendung zur Oberflächenbehandlung |
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2016
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- 2016-05-12 EP EP16169271.0A patent/EP3243807B1/de active Active
- 2016-05-12 PL PL16169271T patent/PL3243807T3/pl unknown
- 2016-05-12 ES ES16169271T patent/ES2711795T3/es active Active
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2017
- 2017-05-11 CN CN201710329394.9A patent/CN107365101B/zh active Active
- 2017-05-11 CA CA2966904A patent/CA2966904C/en active Active
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Also Published As
| Publication number | Publication date |
|---|---|
| JP2017202973A (ja) | 2017-11-16 |
| CA2966904A1 (en) | 2017-11-12 |
| CN107365101B (zh) | 2021-10-08 |
| US20170327422A1 (en) | 2017-11-16 |
| CN107365101A (zh) | 2017-11-21 |
| EP3243807A1 (de) | 2017-11-15 |
| PL3243807T3 (pl) | 2019-05-31 |
| ES2711795T3 (es) | 2019-05-07 |
| US10259748B2 (en) | 2019-04-16 |
| EP3243807B1 (de) | 2018-11-14 |
| JP6895799B2 (ja) | 2021-06-30 |
| CA2966904C (en) | 2022-08-30 |
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