ECSP045272A - Un proceso de destilación reactiva para alquilación que incluye la regeneración del catalizador en el sitio - Google Patents

Un proceso de destilación reactiva para alquilación que incluye la regeneración del catalizador en el sitio

Info

Publication number
ECSP045272A
ECSP045272A EC2004005272A ECSP045272A ECSP045272A EC SP045272 A ECSP045272 A EC SP045272A EC 2004005272 A EC2004005272 A EC 2004005272A EC SP045272 A ECSP045272 A EC SP045272A EC SP045272 A ECSP045272 A EC SP045272A
Authority
EC
Ecuador
Prior art keywords
sub
catalyst
aromatic
column
zone
Prior art date
Application number
EC2004005272A
Other languages
English (en)
Inventor
J Barry Winder
Donald L Wharry
John R Schell
Mary J Brown
Joy L Murray
Richard C Howe
Wayne L Sorenson
Daniel P Szura
Frank Gates
Original Assignee
Sasol North America Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sasol North America Inc filed Critical Sasol North America Inc
Publication of ECSP045272A publication Critical patent/ECSP045272A/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/90—Regeneration or reactivation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • B01J38/50—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using organic liquids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/009—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping in combination with chemical reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/12—Treating with free oxygen-containing gas
    • B01J38/38—Treating with free oxygen-containing gas and adding heat by solid heat carrier
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • B01J38/50—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using organic liquids
    • B01J38/56—Hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

Un proceso unificado que combina un proceso único de regeneración del catalizador en el sitio con una destilación reactiva continua bajo presión para la alquilación de hidrocarburos aromáticos livianos, tales como benceno con olefinas C2-C30, usando un catalizador de ácido sólido para alquilación sostenido en la zona de reflujo (21) de una columna de destilación (Sección A). La regeneración periódica del catalizador (Secciones E, F y G) se lleva a cabo con una inyección contracorriente de una parafina C4-C16 (35) por debajo de la zona de rectificación de benceno en la parte superior de la columna, pero por encima de la zona del catalizador, mientras se inyecta la carga de hidrocarburo aromático para reacción (17) de manera continua en un punto por encima de una zona de rectificación en la base de la columna donde el compuesto aromático es separado de la parafina y los subproductos son lavados para retirarlos del catalizador. El uso de parafina C4-C16 con el hidrocarburo aromático en un porcentaje molar en el rango de 40 a 90% permite una temperatura de regeneración de alrededor de 175-250°C, que se logra y se mantiene regulando la presión de la columna y la tasa de reflujo del hidrocarburo aromático. Se necesitan presiones significativamente más bajas, del orden de 125 a 370 psig, para lograr la temperatura de regeneración que las que se requerirían con el uso solamente del hidrocarburo aromático para diluir y lavar los subproductos de las superficies del catalizador.
EC2004005272A 2002-03-05 2004-09-02 Un proceso de destilación reactiva para alquilación que incluye la regeneración del catalizador en el sitio ECSP045272A (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US10/090,859 US7199068B2 (en) 2002-03-05 2002-03-05 Reactive distillation alkylation process including in situ catalyst regeneration

Publications (1)

Publication Number Publication Date
ECSP045272A true ECSP045272A (es) 2005-01-28

Family

ID=27804071

Family Applications (1)

Application Number Title Priority Date Filing Date
EC2004005272A ECSP045272A (es) 2002-03-05 2004-09-02 Un proceso de destilación reactiva para alquilación que incluye la regeneración del catalizador en el sitio

Country Status (20)

Country Link
US (1) US7199068B2 (es)
EP (1) EP1480746B1 (es)
JP (1) JP4526267B2 (es)
KR (1) KR100944565B1 (es)
CN (1) CN100418631C (es)
AT (1) ATE485253T1 (es)
AU (1) AU2003205189B2 (es)
BR (1) BR0308241A (es)
CA (1) CA2477127A1 (es)
CO (1) CO5631414A2 (es)
DE (1) DE60334606D1 (es)
EA (1) EA006786B1 (es)
EC (1) ECSP045272A (es)
EG (1) EG23500A (es)
HN (1) HN2004000357A (es)
IL (2) IL163618A0 (es)
MX (1) MXPA04008562A (es)
NO (1) NO327663B1 (es)
WO (1) WO2003076074A1 (es)
ZA (1) ZA200406622B (es)

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TWI335239B (en) * 2003-03-21 2011-01-01 Stone & Webster Inc Production of alkyl aromatic compounds with catalyst reactivation
US7498474B2 (en) 2005-02-28 2009-03-03 Exxonmobil Research And Engineering Company Vapor phase aromatics alkylation process
US7525002B2 (en) 2005-02-28 2009-04-28 Exxonmobil Research And Engineering Company Gasoline production by olefin polymerization with aromatics alkylation
US7476774B2 (en) 2005-02-28 2009-01-13 Exxonmobil Research And Engineering Company Liquid phase aromatics alkylation process
US20080029435A1 (en) * 2006-08-02 2008-02-07 Exxonmobil Research And Engineering Company Rejuvenation process for olefin polymerization and alkylation catalyst
US7981256B2 (en) * 2007-11-09 2011-07-19 Uop Llc Splitter with multi-stage heat pump compressor and inter-reboiler
WO2010011451A1 (en) * 2008-07-22 2010-01-28 Exxonmobil Chemical Patents Inc. Preparation of molecular sieve containing catalyst and its use in the production of alkylaromatic hydrocarbons
US8395006B2 (en) 2009-03-13 2013-03-12 Exxonmobil Research And Engineering Company Process for making high octane gasoline with reduced benzene content by benzene alkylation at high benzene conversion
CN102355948B (zh) 2009-03-16 2013-11-20 沙特基础工业公司 用于生产合成气的镍/氧化镧催化剂
US8935847B2 (en) * 2009-09-17 2015-01-20 Lester F. Ludwig Modular reactive distillation emulation elements integrated with instrumentation, control, and simulation algorithms
WO2012084160A1 (en) 2010-12-22 2012-06-28 Saudi Basic Industries Corporation Catalyst useful in fisher-tropsch synthesis
CN103648639B (zh) 2011-04-19 2016-10-12 沙特基础工业公司 碳负载的钴和钼催化剂
WO2013007345A1 (en) 2011-07-08 2013-01-17 Saudi Basic Industries Corporation Improved carbon supported cobalt and molybdenum catalyst and use thereof for producing lower alcohols
EP2679568A1 (en) 2012-06-25 2014-01-01 Saudi Basic Industries Corporation Process for production ethylene and propylene from syngas
WO2014001354A1 (en) 2012-06-27 2014-01-03 Saudi Basic Industries Corporation Catalyst and process for the selective production of lower hydrocarbons c1-c5 from syngass with low methane and co2 production
CN105636691A (zh) 2013-07-31 2016-06-01 沙特基础工业公司 用于转化合成气的催化剂
BR102014002154A2 (pt) * 2014-01-28 2015-10-27 Whirlpool Sa processo de produção de composto alquilaromático, processo de transalquilação de polialquilaromáticos para produção seletiva de composto monoalquilaromático, e, processo de alquilação e transalquilação de compostos aromáticos e/ou poliaromáticos
US9751817B2 (en) 2014-03-07 2017-09-05 Uop Llc Combined reactor effluent and regenerant recirculation for detergent alkylation process
US9732014B2 (en) 2014-03-07 2017-08-15 Uop Llc Method of producing alkylaromatic compounds using aromatic compound from catalyst regeneration
JP6228246B2 (ja) 2015-03-03 2017-11-08 エボニック デグサ ゲーエムベーハーＥｖｏｎｉｋ Ｄｅｇｕｓｓａ ＧｍｂＨ エテンのオリゴマー化に使用される不均一系触媒の再生
CN111203287A (zh) * 2018-11-21 2020-05-29 内蒙古伊泰煤基新材料研究院有限公司 一种苯烷基化固体酸催化剂的再生方法
CN112642476B (zh) * 2019-10-09 2023-04-07 中国石油化工股份有限公司 芳烃脱烯烃催化剂原位脱结焦物的活性控制方法及其应用
CN111763130B (zh) 2020-06-22 2023-01-03 南京克米斯璀新能源科技有限公司 一种用于生产长链烷基苯的方法
CN116262881B (zh) * 2021-12-14 2025-12-30 中国石油化工股份有限公司 一种选择性脱除重整生成油中烯烃杂质的方法
CN120132389B (zh) * 2025-04-03 2025-12-23 广东百宏裕能新材料科技有限公司 从nmp再生液中回收nmp的精馏提纯方法

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ES2007545A6 (es) * 1988-08-03 1989-06-16 Petroquimica Espanola S A Petr Proceso de alquilacion catalitica en lecho fijo de hidrocarburos aromaticos.
US5082990A (en) 1988-10-28 1992-01-21 Chevron Research And Technology Company Alkylation of aromatics-containing refinery streams
US5019669A (en) 1989-03-10 1991-05-28 Chemical Research & Licensing Company Alkylation of organic aromatic compounds
US5326923A (en) * 1990-09-26 1994-07-05 Catalytica, Inc. Method for regenerating certain acidic hydrocarbon conversion catalysts by solvent extraction
US5258560A (en) 1992-06-22 1993-11-02 Uop Etherification of C5 -plus olefins by catalytic distillation
US5648579A (en) * 1993-09-27 1997-07-15 Uop Continuous alkylation of aromatics using solid catalysts; prevention of catalyst deactivation using a pulsed feed reactor
FR2721603B1 (fr) * 1994-06-22 1996-09-20 Inst Francais Du Petrole Procédé de réjuvénation d'un catalyseur solide d'alkylation.
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Also Published As

Publication number Publication date
IL163618A0 (en) 2005-12-18
MXPA04008562A (es) 2005-05-05
US7199068B2 (en) 2007-04-03
BR0308241A (pt) 2005-05-24
NO327663B1 (no) 2009-09-07
ZA200406622B (en) 2006-06-28
EP1480746A4 (en) 2005-07-27
EG23500A (en) 2006-01-17
ATE485253T1 (de) 2010-11-15
CO5631414A2 (es) 2006-04-28
EP1480746B1 (en) 2010-10-20
WO2003076074A1 (en) 2003-09-18
IL163618A (en) 2008-04-13
CN100418631C (zh) 2008-09-17
HN2004000357A (es) 2008-10-07
JP2005518939A (ja) 2005-06-30
EA006786B1 (ru) 2006-04-28
CN1638870A (zh) 2005-07-13
EP1480746A1 (en) 2004-12-01
EA200401155A1 (ru) 2005-02-24
DE60334606D1 (de) 2010-12-02
KR20040095261A (ko) 2004-11-12
US20030171204A1 (en) 2003-09-11
CA2477127A1 (en) 2003-09-18
JP4526267B2 (ja) 2010-08-18
KR100944565B1 (ko) 2010-02-25
AU2003205189B2 (en) 2008-04-10
AU2003205189A1 (en) 2003-09-22
NO20044083L (no) 2004-10-01

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