ECSP055872A - PROCESS FOR THE CONVERSION OF HEAVY LOADS, SUCH AS HEAVY CRUDE OILS AND DISTILLATION WASTE - Google Patents

PROCESS FOR THE CONVERSION OF HEAVY LOADS, SUCH AS HEAVY CRUDE OILS AND DISTILLATION WASTE

Info

Publication number
ECSP055872A
ECSP055872A EC2005005872A ECSP055872A ECSP055872A EC SP055872 A ECSP055872 A EC SP055872A EC 2005005872 A EC2005005872 A EC 2005005872A EC SP055872 A ECSP055872 A EC SP055872A EC SP055872 A ECSP055872 A EC SP055872A
Authority
EC
Ecuador
Prior art keywords
heavy
distillation
hydrotreatment
flash
load
Prior art date
Application number
EC2005005872A
Other languages
Spanish (es)
Inventor
Alberto Delbianco
Nicoletta Panariti
Sebastiano Correra
Montanari
Sergio Rosi
Mario Marchionna
Original Assignee
Eni Spa
Snam Progetti
Enitecnologie Spa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eni Spa, Snam Progetti, Enitecnologie Spa filed Critical Eni Spa
Publication of ECSP055872A publication Critical patent/ECSP055872A/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G67/00Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only
    • C10G67/02Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only
    • C10G67/04Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only including solvent extraction as the refining step in the absence of hydrogen
    • C10G67/0454Solvent desasphalting

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Working-Up Tar And Pitch (AREA)

Abstract

Un proceso para la conversión de materias primas pesadas, tales como petróleos crudos pesados, alquitranes de arenas petrolíferas y residuos de destilación, por medio del uso combinado de las siguientes tres unidades de proceso: hidroconversión con catalizadores en fase de mortero (HT), destilación o flash (D), desasfaltado (SDA), caracterizado por que las tres unidades operan en corrientes combinadas conformadas por carga fresca y corrientes recicladas, por medio del uso de las siguientes etapas: enviar al menos una fracción de la materia prima pesada a una sección de desasfaltado (SDA) en presencia de solventes de hidrocarburo, obteniendo dos corrientes, la una conformada por aceite desasfaltado (DAO) y la otra conformada por asfaltos; mezclar el asfalto con un catalizador de hidrogenación adecuado y, opcionalmente, con la fracción remanente de carga pesada no enviada a la sección de desasfaltado y enviar la mezcla obtenida a un reactor de hidrotratamiento (HT) dentro del cual se carga hidrógeno o una mezcla de hidrógeno y H2S; enviar la corriente que contiene el producto de reacción de hidrotratamiento y el catalizador en fase dispersa a una o más etapas de destilación o flash (D), por medio de las cuales se separan las fracciones más volátiles, entre ellas los gases producidos en la reacción de hidrotratamiento; reciclar hacia la zona de desasfaltado al menos 60% en peso, de preferencia al menos 80% y más preferentemente al menos 95% del residuo de destilación (alquitrán) o del líquido que sale de la unidad de flash, que contiene el catalizador en fase dispersa, rico en sulfuros metálicos producidos por la desmetalización de la carga y posiblemente coque.A process for the conversion of heavy raw materials, such as heavy crude oils, oil sands tars and distillation residues, through the combined use of the following three process units: hydroconversion with mortar phase catalysts (HT), distillation or flash (D), desasfaltado (SDA), characterized in that the three units operate in combined currents formed by fresh load and recycled currents, through the use of the following stages: send at least a fraction of the heavy raw material to a deasphalting section (SDA) in the presence of hydrocarbon solvents, obtaining two streams, one formed by deasphalted oil (DAO) and the other formed by asphalts; mixing the asphalt with a suitable hydrogenation catalyst and, optionally, with the remaining heavy load fraction not sent to the de-asphalting section and sending the obtained mixture to a hydrotreatment reactor (HT) into which hydrogen or a mixture of hydrogen and H2S; send the stream containing the hydrotreatment reaction product and the dispersed phase catalyst to one or more distillation or flash stages (D), by means of which the most volatile fractions are separated, including the gases produced in the reaction hydrotreatment; recycle to the deasphalting zone at least 60% by weight, preferably at least 80% and more preferably at least 95% of the distillation residue (tar) or liquid leaving the flash unit, which contains the catalyst in phase dispersed, rich in metal sulphides produced by the demetalization of the load and possibly coke.

EC2005005872A 2002-12-30 2005-06-20 PROCESS FOR THE CONVERSION OF HEAVY LOADS, SUCH AS HEAVY CRUDE OILS AND DISTILLATION WASTE ECSP055872A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/EP2002/014847 WO2004058922A1 (en) 2002-12-30 2002-12-30 Process for the conversion of heavy charges such as heavy crude oils and distillation residues

Publications (1)

Publication Number Publication Date
ECSP055872A true ECSP055872A (en) 2005-09-20

Family

ID=32668704

Family Applications (1)

Application Number Title Priority Date Filing Date
EC2005005872A ECSP055872A (en) 2002-12-30 2005-06-20 PROCESS FOR THE CONVERSION OF HEAVY LOADS, SUCH AS HEAVY CRUDE OILS AND DISTILLATION WASTE

Country Status (7)

Country Link
EP (1) EP1578891B1 (en)
JP (1) JP4498929B2 (en)
AU (1) AU2002358182B8 (en)
EC (1) ECSP055872A (en)
ES (1) ES2679629T3 (en)
NO (1) NO20052951L (en)
WO (1) WO2004058922A1 (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ITMI20042445A1 (en) * 2004-12-22 2005-03-22 Eni Spa PROCEDURE FOR THE CONVERSION OF HEAVY CHARGES WHICH WEIGHING AND DISTILLATION WASTE
US9284499B2 (en) 2009-06-30 2016-03-15 Uop Llc Process and apparatus for integrating slurry hydrocracking and deasphalting
US9074143B2 (en) 2009-12-11 2015-07-07 Uop Llc Process for producing hydrocarbon fuel
US8193401B2 (en) 2009-12-11 2012-06-05 Uop Llc Composition of hydrocarbon fuel
US8133446B2 (en) 2009-12-11 2012-03-13 Uop Llc Apparatus for producing hydrocarbon fuel
CN103773433B (en) * 2012-10-23 2016-12-21 中国石油天然气股份有限公司 A kind of inferior oil product hydrogenation processing method

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3723294A (en) * 1971-10-18 1973-03-27 Universal Oil Prod Co Conversion of asphaltene-containing hydrocarbonaceous charge stocks
NL7510465A (en) * 1975-09-05 1977-03-08 Shell Int Research PROCESS FOR CONVERTING HYDROCARBONS.
NL8201119A (en) * 1982-03-18 1983-10-17 Shell Int Research PROCESS FOR PREPARING HYDROCARBON OIL DISTILLATES
US4686028A (en) * 1985-04-05 1987-08-11 Driesen Roger P Van Upgrading of high boiling hydrocarbons
US5242578A (en) * 1989-07-18 1993-09-07 Amoco Corporation Means for and methods of deasphalting low sulfur and hydrotreated resids
IT1275447B (en) * 1995-05-26 1997-08-07 Snam Progetti PROCEDURE FOR THE CONVERSION OF HEAVY CRUDE AND DISTILLATION DISTILLATION RESIDUES
AU2001238235A1 (en) * 2000-02-15 2001-08-27 Exxonmobil Research And Engineering Company Heavy feed upgrading based on solvent deasphalting followed by slurry hydroprocessing of asphalt from solvent deasphalting

Also Published As

Publication number Publication date
EP1578891A1 (en) 2005-09-28
EP1578891B1 (en) 2018-04-25
AU2002358182B2 (en) 2009-04-02
ES2679629T3 (en) 2018-08-29
AU2002358182B8 (en) 2009-04-23
WO2004058922A1 (en) 2004-07-15
NO20052951L (en) 2005-09-30
AU2002358182A1 (en) 2004-07-22
NO20052951D0 (en) 2005-06-16
JP2006510781A (en) 2006-03-30
AU2002358182A8 (en) 2004-07-22
JP4498929B2 (en) 2010-07-07

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