ECSP12012240A - Tensioactivos de alcohol de guerbet alcoxilado y su uso en las aplicaciones de recuperación mejorada de petróleo - Google Patents
Tensioactivos de alcohol de guerbet alcoxilado y su uso en las aplicaciones de recuperación mejorada de petróleoInfo
- Publication number
- ECSP12012240A ECSP12012240A ECSP12012240A ECSP12012240A EC SP12012240 A ECSP12012240 A EC SP12012240A EC SP12012240 A ECSP12012240 A EC SP12012240A EC SP12012240 A ECSP12012240 A EC SP12012240A
- Authority
- EC
- Ecuador
- Prior art keywords
- alcoxilado
- tensioactive
- oil recovery
- improved oil
- guerbet alcohol
- Prior art date
Links
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 title abstract 2
- 238000011084 recovery Methods 0.000 title abstract 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- 125000000129 anionic group Chemical group 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- 230000002209 hydrophobic effect Effects 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 abstract 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 abstract 1
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- 239000003945 anionic surfactant Substances 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 238000004140 cleaning Methods 0.000 abstract 1
- 238000006471 dimerization reaction Methods 0.000 abstract 1
- 230000007613 environmental effect Effects 0.000 abstract 1
- 238000010348 incorporation Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000002736 nonionic surfactant Substances 0.000 abstract 1
- 239000003208 petroleum Substances 0.000 abstract 1
- 230000007928 solubilization Effects 0.000 abstract 1
- 238000005063 solubilization Methods 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
- 238000003786 synthesis reaction Methods 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/58—Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids
- C09K8/584—Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids characterised by the use of specific surfactants
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C305/00—Esters of sulfuric acids
- C07C305/02—Esters of sulfuric acids having oxygen atoms of sulfate groups bound to acyclic carbon atoms of a carbon skeleton
- C07C305/04—Esters of sulfuric acids having oxygen atoms of sulfate groups bound to acyclic carbon atoms of a carbon skeleton being acyclic and saturated
- C07C305/10—Esters of sulfuric acids having oxygen atoms of sulfate groups bound to acyclic carbon atoms of a carbon skeleton being acyclic and saturated being further substituted by singly-bound oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
- C07C309/01—Sulfonic acids
- C07C309/02—Sulfonic acids having sulfo groups bound to acyclic carbon atoms
- C07C309/03—Sulfonic acids having sulfo groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
- C07C309/07—Sulfonic acids having sulfo groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton containing oxygen atoms bound to the carbon skeleton
- C07C309/09—Sulfonic acids having sulfo groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton containing oxygen atoms bound to the carbon skeleton containing etherified hydroxy groups bound to the carbon skeleton
- C07C309/10—Sulfonic acids having sulfo groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton containing oxygen atoms bound to the carbon skeleton containing etherified hydroxy groups bound to the carbon skeleton with the oxygen atom of at least one of the etherified hydroxy groups further bound to an acyclic carbon atom
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2603—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen
- C08G65/2606—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen containing hydroxyl groups
- C08G65/2609—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen containing hydroxyl groups containing aliphatic hydroxyl groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/32—Polymers modified by chemical after-treatment
- C08G65/329—Polymers modified by chemical after-treatment with organic compounds
- C08G65/334—Polymers modified by chemical after-treatment with organic compounds containing sulfur
- C08G65/3344—Polymers modified by chemical after-treatment with organic compounds containing sulfur containing oxygen in addition to sulfur
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/16—Enhanced recovery methods for obtaining hydrocarbons
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Mining & Mineral Resources (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Fluid Mechanics (AREA)
- Environmental & Geological Engineering (AREA)
- Geochemistry & Mineralogy (AREA)
- Detergent Compositions (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Cosmetics (AREA)
- Media Introduction/Drainage Providing Device (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
Abstract
Se describen composiciones y métodos de síntesis de tensioactivos aniónicos mediante la alcoxilación de un alcohol de Guerbet (GA) que tiene de 12 a 36 átomos de carbono utilizando óxido de butileno, y opcionalmente oxido de propileno y/u óxido de etileno, seguida por la incorporación de un grupo aniónico terminal como se describe en este documento. El GA de la presente invención es preparado por un método fácil y económico que involucra una dimerización de alcoholes con 6 a 18 átomos de carbono catalizada por una base, a alta temperatura. Los tensioactivos éter hidrófobos grandes de la presente invención encuentran usos en las aplicaciones de recuperación mejorada de petróleo (EOR) en donde se utiliza para la solubilización y movilización del petróleo y para la limpieza ambiental. Además, el GA alcoxilado hidrófobo sin grupo aniónico terminal se puede usar como un tensioactivo no iónico de ultra alto peso molecular.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US32501510P | 2010-04-16 | 2010-04-16 | |
| US13/085,248 US8841241B2 (en) | 2010-04-16 | 2011-04-12 | Anionic polyalkoxy group comprising surfactants on basis of guerbet-alcohols, method of manufacture and use in enhanced oil recovery (EOR) applications |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ECSP12012240A true ECSP12012240A (es) | 2012-11-30 |
Family
ID=44798996
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ECSP12012240 ECSP12012240A (es) | 2010-04-16 | 2012-10-09 | Tensioactivos de alcohol de guerbet alcoxilado y su uso en las aplicaciones de recuperación mejorada de petróleo |
Country Status (11)
| Country | Link |
|---|---|
| US (2) | US8841241B2 (es) |
| EP (2) | EP2738236B1 (es) |
| CN (1) | CN103003385B (es) |
| AU (1) | AU2011240606B2 (es) |
| CA (1) | CA2793499C (es) |
| EA (1) | EA022635B1 (es) |
| EC (1) | ECSP12012240A (es) |
| MX (1) | MX2012011796A (es) |
| MY (1) | MY150849A (es) |
| WO (1) | WO2011130310A1 (es) |
| ZA (1) | ZA201207053B (es) |
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| US7985718B2 (en) | 2008-04-21 | 2011-07-26 | Basf Se | Use of surfactant mixtures for tertiary mineral oil extraction |
| MX2010004526A (es) | 2009-04-30 | 2010-11-01 | Basf Se | Agente de dispersion. |
| BR112012005744A2 (pt) | 2009-09-22 | 2019-09-24 | Board Of Regente The Univ Of Texas System | método, composição, e, método para usar uma formulação de tensoativo aniônico de éter-sulfato para recuperação melhorada de petróleo de uma formação possuindo hidrocarboneto |
| US20110220364A1 (en) | 2010-03-10 | 2011-09-15 | Basf Se | Process for mineral oil production using cationic surfactants having a hydrophobic block with a chain length of 6 to 10 carbon atoms |
| US8596367B2 (en) | 2010-03-10 | 2013-12-03 | Basf Se | Process for producing mineral oil using surfactants based on C16C18-containing alkyl propoxy surfactants |
| US8607865B2 (en) | 2010-03-10 | 2013-12-17 | Basf Se | Process for extracting mineral oil using surfactants based on butylene oxide-containing alkyl alkoxylates |
| EP2545138A1 (de) | 2010-03-10 | 2013-01-16 | Basf Se | Verwendung von tensidmischungen von polycarboxylaten zum mikroemulsionsfluten |
| CN103003385B (zh) | 2010-04-16 | 2015-06-03 | 德克萨斯州立大学董事会 | Guerbet醇烷氧基化物表面活性剂及其在提高油采收率应用中的用途 |
-
2011
- 2011-04-12 CN CN201180019219.0A patent/CN103003385B/zh not_active Expired - Fee Related
- 2011-04-12 EP EP13199022.8A patent/EP2738236B1/en not_active Not-in-force
- 2011-04-12 US US13/085,248 patent/US8841241B2/en not_active Expired - Fee Related
- 2011-04-12 EA EA201270743A patent/EA022635B1/ru not_active IP Right Cessation
- 2011-04-12 MX MX2012011796A patent/MX2012011796A/es active IP Right Grant
- 2011-04-12 MY MYPI2012004060 patent/MY150849A/en unknown
- 2011-04-12 AU AU2011240606A patent/AU2011240606B2/en not_active Ceased
- 2011-04-12 CA CA2793499A patent/CA2793499C/en not_active Expired - Fee Related
- 2011-04-12 WO PCT/US2011/032166 patent/WO2011130310A1/en not_active Ceased
- 2011-04-12 EP EP11769466.1A patent/EP2558546A4/en not_active Withdrawn
-
2012
- 2012-09-19 ZA ZA2012/07053A patent/ZA201207053B/en unknown
- 2012-10-09 EC ECSP12012240 patent/ECSP12012240A/es unknown
-
2014
- 2014-03-07 US US14/201,323 patent/US9296942B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| EA022635B1 (ru) | 2016-02-29 |
| US20110281779A1 (en) | 2011-11-17 |
| US9296942B2 (en) | 2016-03-29 |
| CN103003385A (zh) | 2013-03-27 |
| EP2558546A1 (en) | 2013-02-20 |
| WO2011130310A1 (en) | 2011-10-20 |
| MY150849A (en) | 2014-03-14 |
| AU2011240606A1 (en) | 2012-09-27 |
| EP2738236B1 (en) | 2016-04-06 |
| ZA201207053B (en) | 2013-05-29 |
| EA201270743A1 (ru) | 2013-02-28 |
| US20140182851A1 (en) | 2014-07-03 |
| MX2012011796A (es) | 2013-02-07 |
| US8841241B2 (en) | 2014-09-23 |
| EP2558546A4 (en) | 2013-09-18 |
| CA2793499C (en) | 2014-12-30 |
| CN103003385B (zh) | 2015-06-03 |
| EP2738236A1 (en) | 2014-06-04 |
| AU2011240606B2 (en) | 2013-07-18 |
| CA2793499A1 (en) | 2011-10-20 |
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