EG24986A - Process for contacting a hydrocarbon and an oxygen-containing gas with a catalyst bed. - Google Patents

Process for contacting a hydrocarbon and an oxygen-containing gas with a catalyst bed.

Info

Publication number
EG24986A
EG24986A EG2008071187A EG2008071187A EG24986A EG 24986 A EG24986 A EG 24986A EG 2008071187 A EG2008071187 A EG 2008071187A EG 2008071187 A EG2008071187 A EG 2008071187A EG 24986 A EG24986 A EG 24986A
Authority
EG
Egypt
Prior art keywords
catalyst bed
tiles
hydrocarbon
contacting
oxygen
Prior art date
Application number
EG2008071187A
Other languages
English (en)
Inventor
Vaughan Clifford Williams
Original Assignee
Ineos Europe Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ineos Europe Ltd filed Critical Ineos Europe Ltd
Application granted granted Critical
Publication of EG24986A publication Critical patent/EG24986A/xx

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24Stationary reactors without moving elements inside
    • B01J19/248Reactors comprising multiple separated flow channels
    • B01J19/2485Monolithic reactors
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24Stationary reactors without moving elements inside
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/30Loose or shaped packing elements, e.g. Raschig rings or Berl saddles, for pouring into the apparatus for mass or heat transfer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/825Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with gallium, indium or thallium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/835Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with germanium, tin or lead
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8926Copper and noble metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/008Details of the reactor or of the particulate material; Processes to increase or to retard the rate of reaction
    • B01J8/0085Details of the reactor or of the particulate material; Processes to increase or to retard the rate of reaction promoting uninterrupted fluid flow, e.g. by filtering out particles in front of the catalyst layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/008Details of the reactor or of the particulate material; Processes to increase or to retard the rate of reaction
    • B01J8/009Membranes, e.g. feeding or removing reactants or products to or from the catalyst bed through a membrane
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00017Controlling the temperature
    • B01J2208/00327Controlling the temperature by direct heat exchange
    • B01J2208/00336Controlling the temperature by direct heat exchange adding a temperature modifying medium to the reactants
    • B01J2208/00353Non-cryogenic fluids
    • B01J2208/00362Liquid
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00548Flow
    • B01J2208/00557Flow controlling the residence time inside the reactor vessel
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00796Details of the reactor or of the particulate material
    • B01J2208/00805Details of the particulate material
    • B01J2208/00814Details of the particulate material the particulate material being provides in prefilled containers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00796Details of the reactor or of the particulate material
    • B01J2208/00823Mixing elements
    • B01J2208/00831Stationary elements
    • B01J2208/00849Stationary elements outside the bed, e.g. baffles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00796Details of the reactor or of the particulate material
    • B01J2208/00884Means for supporting the bed of particles, e.g. grids, bars, perforated plates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/02Processes carried out in the presence of solid particles; Reactors therefor with stationary particles
    • B01J2208/021Processes carried out in the presence of solid particles; Reactors therefor with stationary particles comprising a plurality of beds with flow of reactants in parallel
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/02Processes carried out in the presence of solid particles; Reactors therefor with stationary particles
    • B01J2208/023Details
    • B01J2208/024Particulate material
    • B01J2208/025Two or more types of catalyst
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00051Controlling the temperature
    • B01J2219/00121Controlling the temperature by direct heating or cooling
    • B01J2219/00123Controlling the temperature by direct heating or cooling adding a temperature modifying medium to the reactants
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00164Controlling or regulating processes controlling the flow
    • B01J2219/00166Controlling or regulating processes controlling the flow controlling the residence time inside the reactor vessel
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/19Details relating to the geometry of the reactor
    • B01J2219/192Details relating to the geometry of the reactor polygonal
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/19Details relating to the geometry of the reactor
    • B01J2219/192Details relating to the geometry of the reactor polygonal
    • B01J2219/1928Details relating to the geometry of the reactor polygonal hexagonal
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/30Details relating to random packing elements
    • B01J2219/302Basic shape of the elements
    • B01J2219/3023Triangle
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/30Details relating to random packing elements
    • B01J2219/302Basic shape of the elements
    • B01J2219/3023Triangle
    • B01J2219/30234Hexagon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/30Details relating to random packing elements
    • B01J2219/302Basic shape of the elements
    • B01J2219/30246Square or square-derived
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/30Details relating to random packing elements
    • B01J2219/302Basic shape of the elements
    • B01J2219/30246Square or square-derived
    • B01J2219/30249Cube
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/30Details relating to random packing elements
    • B01J2219/304Composition or microstructure of the elements
    • B01J2219/30416Ceramic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/30Details relating to random packing elements
    • B01J2219/304Composition or microstructure of the elements
    • B01J2219/30475Composition or microstructure of the elements comprising catalytically active material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/30Details relating to random packing elements
    • B01J2219/308Details relating to random packing elements filling or discharging the elements into or from packed columns
    • B01J2219/3081Orientation of the packing elements within the column or vessel
    • B01J2219/3085Ordered or stacked packing elements

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Fluid Mechanics (AREA)
  • Catalysts (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
EG2008071187A 2006-01-20 2008-07-15 Process for contacting a hydrocarbon and an oxygen-containing gas with a catalyst bed. EG24986A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP06250307A EP1820569A1 (de) 2006-01-20 2006-01-20 Verfahren zum Kontaktieren von Kohlenwasserstoffen und einem sauerstoffhaltigen Gas mit einem Katalysatorbett
PCT/GB2006/004825 WO2007083077A1 (en) 2006-01-20 2006-12-20 Process for contacting a hydrocarbon and an oxygen- containing gas with a catalyst bed

Publications (1)

Publication Number Publication Date
EG24986A true EG24986A (en) 2011-04-11

Family

ID=36463332

Family Applications (1)

Application Number Title Priority Date Filing Date
EG2008071187A EG24986A (en) 2006-01-20 2008-07-15 Process for contacting a hydrocarbon and an oxygen-containing gas with a catalyst bed.

Country Status (10)

Country Link
US (1) US8002856B2 (de)
EP (2) EP1820569A1 (de)
JP (1) JP5296552B2 (de)
CN (1) CN101360557B (de)
AT (1) ATE434487T1 (de)
CA (1) CA2636158C (de)
DE (1) DE602006007492D1 (de)
EA (1) EA013706B1 (de)
EG (1) EG24986A (de)
WO (1) WO2007083077A1 (de)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1820569A1 (de) * 2006-01-20 2007-08-22 Ineos Europe Limited Verfahren zum Kontaktieren von Kohlenwasserstoffen und einem sauerstoffhaltigen Gas mit einem Katalysatorbett
EP2506963B1 (de) * 2009-12-01 2014-11-05 Basf Se Reaktor zur durchführung von autothermen gasphasendehydrierungen
US20140272068A1 (en) * 2013-03-14 2014-09-18 Indra Prakash Beverages containing rare sugars
EP3263211B1 (de) * 2016-06-27 2022-09-21 Alantum Europe GmbH Plattenfoermigekatalysatorfüllung
CN110325270B (zh) * 2017-02-27 2022-06-17 托普索公司 带有催化剂支承系统的化学反应器

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US3959401A (en) * 1973-05-14 1976-05-25 Union Carbide Corporation Process for cracking
JPS5794341A (en) * 1980-12-04 1982-06-11 Babcock Hitachi Kk Block catalytic device
GB8528031D0 (en) * 1985-11-13 1985-12-18 Ici Plc Ceramic structures
US4927607A (en) 1988-01-11 1990-05-22 Columbian Chemicals Company Non-cylindrical reactor for carbon black production
EP0396650B2 (de) * 1988-09-02 1995-04-12 GebràœDer Sulzer Aktiengesellschaft Vorrichtung zur durchführung katalysierter reaktionen
DZ1444A1 (fr) * 1989-09-12 2004-09-13 Inst Francais Du Petrole Procédé et réacteur d'oxydation à differentiel de perte de charge et son utilisation.
US6119481A (en) * 1998-01-19 2000-09-19 Air Products And Chemicals, Inc. Horizontal structured packing
DE19813053C2 (de) * 1998-03-25 2001-10-18 Xcellsis Gmbh Reaktoreinheit für eine katalytische chemische Reaktion, insbesondere zur katalytischen Methanolreformierung
JPH11333235A (ja) * 1998-03-25 1999-12-07 Daikin Ind Ltd 脱臭デバイスとこれを備えた脱臭機及び空気調和機
ES2192075T5 (es) * 1998-09-03 2008-02-01 Dow Global Technologies Inc. Procedimiento autotermico para la produccion de olefinas.
BR0016603A (pt) * 1999-12-23 2003-06-10 Bp Chem Int Ltd Processo para a produção de olefinas
JP2001190956A (ja) * 2000-01-12 2001-07-17 Nikki Universal Co Ltd メタン改質触媒とそれを用いた合成ガスの製法
GB0010693D0 (en) * 2000-05-03 2000-06-28 Bp Chem Int Ltd Process for the production of olefins
US6447745B1 (en) * 2000-08-01 2002-09-10 Exxonmobil Research And Engineering Company Catalytic oxidation process
JP2002095957A (ja) * 2000-09-21 2002-04-02 Ngk Insulators Ltd 異種気体接触反応装置
GB0124172D0 (en) 2001-10-09 2001-11-28 Ici Plc Reactor
DE10158160A1 (de) * 2001-11-28 2003-06-12 Basf Ag Herstellung von Isocyanaten in der Gasphase
EP1386664B1 (de) 2002-07-31 2016-05-11 Ineos Technologies (Vinyls) Limited Hohlquader geeignet als Katalysatorträger für selektive exotherme Reaktionen
US7090826B2 (en) * 2002-12-23 2006-08-15 The Boc Group, Inc. Monolith based catalytic partial oxidation process for syngas production
GB0312966D0 (en) 2003-06-05 2003-07-09 Bp Chem Int Ltd Process for the production of olefins
US7410622B2 (en) * 2003-07-24 2008-08-12 Basf Aktiengesellschaft Reactor for partial oxidations having thermoplate modules
EP1820569A1 (de) * 2006-01-20 2007-08-22 Ineos Europe Limited Verfahren zum Kontaktieren von Kohlenwasserstoffen und einem sauerstoffhaltigen Gas mit einem Katalysatorbett

Also Published As

Publication number Publication date
JP5296552B2 (ja) 2013-09-25
WO2007083077A1 (en) 2007-07-26
DE602006007492D1 (de) 2009-08-06
US8002856B2 (en) 2011-08-23
US20090094891A1 (en) 2009-04-16
EA200801683A1 (ru) 2009-02-27
CN101360557A (zh) 2009-02-04
EP1820569A1 (de) 2007-08-22
CN101360557B (zh) 2011-12-14
EP1973649A1 (de) 2008-10-01
ATE434487T1 (de) 2009-07-15
EP1973649B1 (de) 2009-06-24
JP2009523688A (ja) 2009-06-25
CA2636158C (en) 2014-02-11
EA013706B1 (ru) 2010-06-30
CA2636158A1 (en) 2007-07-26

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