EP0000564B1 - Catalyseurs contenant du fer et du molybdène et utilisation de ces catalyseurs pour la préparation d'acrylonitrile ou de méthacrylonitrile - Google Patents

Catalyseurs contenant du fer et du molybdène et utilisation de ces catalyseurs pour la préparation d'acrylonitrile ou de méthacrylonitrile Download PDF

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Publication number
EP0000564B1
EP0000564B1 EP78100469A EP78100469A EP0000564B1 EP 0000564 B1 EP0000564 B1 EP 0000564B1 EP 78100469 A EP78100469 A EP 78100469A EP 78100469 A EP78100469 A EP 78100469A EP 0000564 B1 EP0000564 B1 EP 0000564B1
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EP
European Patent Office
Prior art keywords
catalysts
mixtures
catalyst
acrylonitrile
methacrylonitrile
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
EP78100469A
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German (de)
English (en)
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EP0000564A1 (fr
Inventor
Robert Karl Grasselli
Dev Dhanaraj Suresh
Maria Strada Friedrich
David Allan Orndoff
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Standard Oil Co
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Standard Oil Co
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Publication of EP0000564A1 publication Critical patent/EP0000564A1/fr
Application granted granted Critical
Publication of EP0000564B1 publication Critical patent/EP0000564B1/fr
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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8872—Alkali or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8875—Germanium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8876—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8993—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/057—Selenium or tellurium; Compounds thereof
    • B01J27/0576—Tellurium; Compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
    • C07C253/26—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons containing carbon-to-carbon multiple bonds, e.g. unsaturated aldehydes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Definitions

  • the catalysts of the present invention may be used unsupported or supported on various conventional carriers such as Si0 2 , AI 2 0 3 , Zr0 2 , Ti0 2 , BP0 4 , SbP0 4 , MgO, montmorillonite, or the like. They may be used in fixed-bed or fluid-bed reactors as desired. When using these catalysts, they are simply substituted for the catalysts previously employed, and the reaction is conducted under substantially the same conditions.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Claims (7)

1. Catalysateurs d'oxidation caracterisés par la formule générale ci-après:
Figure imgb0009
dans laquelle
J est un métal alcalin, du thallium, de l'argent ou leurs mélanges;
Q est du Co, Ni, Zn, Cd, Be, Mg, Ca, Sr, Ba, Ra ou leurs mélanges;
Z est un système a deux ou plusieurs éléments comprenant du Cu+W, Cu+Sn, Ce+W, Pr+Mn, Mn+W, W+Sb, Cr+Sn, W+Sn,Ge+Sn, Sb+Sn, Cr+Cu, Sb+Cu ou leurs mélanges;
D représente du Bi ou Te; et

dans laquelle
a est un nombre de 0,01 à 0,5;
b est un nombre de 0,1 à 20;
c est un nombre de 0,1 à 9;
d est un nombre de 0,1 à 20;
e est un nombre de 0.1 à 20; et
x représente une valeur satisfaisant les exigences de valence des éléments compris dans le catalysateur pour l'oxygène;

chacun des éléments du système à deux ou plusieur éléments étant présent en une quantité d'au moins 1 pourcent atomique par rapport au nombre d'atomes compris dans le système.
2. Les catalysateurs de la revendication 1, caractérisés en ce que D représente du Bi.
3. Les catalysateurs de la revendication 2, caractérisés en ce que Z représente ou bien du Cu+W, Cu+Sn, Ce+W, Pr+Mn, W+Sb, Cr+Sn, W+Sn, Ge+Sn, Sb+Sn, Cr+Cu, Sb+Cu, ou du Mn+W.
4. Les catalysateurs de la revendication 2, caractérisés en ce que ces catalysateurs comprennent au moins un des éléments K, Rb et Cs et au moins un des éléments Co et Ni.
5. Procédé pour la préparation d'acrylonitril ou du methacrylonitril par réaction de propylène ou d'isobutylène, d'oxygène moléculaire et d'ammonium à une température variant de 200°C à 600°C et en présence d'un catalysateur, caractérisé en ce qu'il est utilisé un catalysateur de la formule générale suivante
Figure imgb0010
dans laquelle
J est un métal alcalin, du thallium, de l'argent ou leurs mélanges;
Q est du Co, Ni, Zn, Cd, Be, Mg, Ca, Sr, Ba, Ra ou leurs mélanges;
Z est un système à deux ou plusieurs éléments comprenant du Ge+Sb, Cu+W, Cu+Sn, Ce+W, Pr+Mn, Sn+Mn, Mn+W, W+Sb, Cr+Sn, W+Sn, Ge+Sn, Sb+Sn, Sb+P, Cr+Cu, Sb+Cu, Mn+P ou leurs mélanges, il étant entendu que le dit catalysateur ne contiendra pas de TI lorsque Z représente du Mn+P;
D est du Bi ou du Te; et

dans laquelle
a est un nombre de 0,01 à 0,5;
b est un nombre de 0,1 à 20;
c est un nombre de 0,1 à 9;
d est un nombre de 0,1 à 20;
e est un nombre de 0,1 à 20; et
x représente une valeurs satisfaisant les exigences de valence des éléments compris dans le catalysateur pour l'oxygène;

chacun des éléments du système à deux ou plusieurs éléments étant présent en une quantité d'au moins 1 pourcent atomique par rapport au nombre d'atomes compris dans le système.
6. Procédé suivant la revendication 5 dans lequel D représente du Bi.
7. Procédé suivant la revendication 6 dans lequel J représente au moins un des éléments K, Rb et Cs et Q représente au moins un des éléments Co et Ni.
EP78100469A 1977-07-28 1978-07-21 Catalyseurs contenant du fer et du molybdène et utilisation de ces catalyseurs pour la préparation d'acrylonitrile ou de méthacrylonitrile Expired EP0000564B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US81973277A 1977-07-28 1977-07-28
US819732 1977-07-28

Publications (2)

Publication Number Publication Date
EP0000564A1 EP0000564A1 (fr) 1979-02-07
EP0000564B1 true EP0000564B1 (fr) 1982-05-19

Family

ID=25228901

Family Applications (1)

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EP78100469A Expired EP0000564B1 (fr) 1977-07-28 1978-07-21 Catalyseurs contenant du fer et du molybdène et utilisation de ces catalyseurs pour la préparation d'acrylonitrile ou de méthacrylonitrile

Country Status (20)

Country Link
EP (1) EP0000564B1 (fr)
AT (1) AT363911B (fr)
AU (1) AU525163B2 (fr)
BR (1) BR7804847A (fr)
CA (1) CA1132124A (fr)
DD (1) DD137532A5 (fr)
DE (1) DE2861849D1 (fr)
DK (1) DK333778A (fr)
EG (1) EG13970A (fr)
ES (1) ES471682A1 (fr)
FI (1) FI66129C (fr)
GR (1) GR66444B (fr)
IE (1) IE47301B1 (fr)
IL (1) IL55073A (fr)
IN (1) IN148019B (fr)
IT (1) IT1196394B (fr)
NO (1) NO150345C (fr)
PT (1) PT68312A (fr)
RO (1) RO77761A (fr)
ZA (1) ZA783914B (fr)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1127137A (fr) * 1977-12-20 1982-07-06 Dev D. Suresh Ammoxydation d'olefines sur de nouveaux catalyseurs a l'antimonate
US4316855A (en) * 1979-12-28 1982-02-23 The Standard Oil Co. Multiply promoted Sn-Sb oxide catalysts
EP0044875B1 (fr) * 1980-07-18 1984-06-13 Mitsubishi Kasei Corporation Composition catalytique, procédé pour sa préparation et son utilisation
ATE34090T1 (de) * 1982-09-30 1988-05-15 Monsanto Co Katalysatoren zur oxydierung und ammoxydation von alkoholen.
US4469810A (en) * 1983-01-11 1984-09-04 Mitsubishi Rayon Company Limited Process for the calcination of phosphorus-molybdenum catalyst
GB2221852A (en) * 1988-08-18 1990-02-21 Ti Corporate Services Vehicle exhaust gas catalysts
US5093299A (en) * 1990-01-09 1992-03-03 The Standard Oil Company Catalyst for process for the manufacture of acrylonitrile and methacrylonitrile

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5112603B1 (fr) * 1971-05-26 1976-04-21
CA1004232A (en) * 1971-12-30 1977-01-25 The Standard Oil Company Coproduction of methacrylonitrile and butadiene
CA1049553A (fr) * 1973-04-30 1979-02-27 The Standard Oil Company Synthese d'acide acrylique ou methacrylique a partir de propylene ou d'isobutylene
GB1456752A (en) * 1973-05-10 1976-11-24 Japan Synthetic Rubber Co Ltd Catalyst and process for the production of unsaturated carbonyl compounds
DE2424934A1 (de) * 1973-06-04 1975-01-02 Standard Oil Co Ohio Verfahren zur katalytischen herstellung ungesaettigter nitrile
US3972920A (en) * 1973-06-11 1976-08-03 Mitsubishi Rayon Co., Ltd. Process for producing unsaturated aldehydes, unsaturated fatty acids or conjugated dienes
CH569926A5 (fr) * 1973-06-15 1975-11-28 Bartolomeis Spa Forni Ed Impia
US3883573A (en) * 1973-06-15 1975-05-13 Standard Oil Co Commercial fixed-bed acrylonitrile or methacrylonitrile
US3932551A (en) * 1973-10-12 1976-01-13 The Standard Oil Company Process for the preparation of diolefins from olefins
GB1523772A (en) * 1974-07-22 1978-09-06 Standard Oil Co Oxidation catalysts
US4001317A (en) * 1974-07-22 1977-01-04 Standard Oil Company Process for the oxidation of olefins using catalysts containing various promoter elements
GB1489559A (en) * 1975-03-03 1977-10-19 Mitsubishi Rayon Co Catalytic process for the preparation of acrylic acid or methacrylic acid
GB1490683A (en) * 1975-03-12 1977-11-02 Mitsubishi Rayon Co Process and a catalyst for producing unsaturated aldehydes unsaturated carboxylic acids or conjugated diene
IN142430B (fr) * 1975-04-21 1977-07-09 Standard Oil Co
US4118419A (en) * 1975-12-03 1978-10-03 Mitsubishi Rayon Company, Ltd. Catalytic process for the preparation of an unsaturated carboxylic acid
DE2626887B2 (de) * 1976-06-16 1978-06-29 Basf Ag, 6700 Ludwigshafen Katalysator für die Oxadation von (Methacrolein zu (Meth)Acrylsäure
US4335264A (en) * 1976-07-07 1982-06-15 E. I. Du Pont De Nemours And Company High yield, low byproduct α, β-unsaturated aldehydes from olefins
US4065507A (en) * 1976-08-02 1977-12-27 Standard Oil Company Preparation of methacrylic derivatives from tertiary butyl-containing compounds

Also Published As

Publication number Publication date
GR66444B (fr) 1981-03-23
AT363911B (de) 1981-09-10
FI66129C (fi) 1984-09-10
IE47301B1 (en) 1984-02-22
DE2861849D1 (en) 1982-07-08
NO150345C (no) 1984-10-03
CA1132124A (fr) 1982-09-21
AU3793078A (en) 1980-01-17
ZA783914B (en) 1979-08-29
NO150345B (no) 1984-06-25
ATA547778A (de) 1981-02-15
EG13970A (en) 1983-03-31
FI782285A7 (fi) 1979-01-29
DK333778A (da) 1979-01-29
NO782582L (no) 1979-01-30
DD137532A5 (de) 1979-09-12
ES471682A1 (es) 1979-10-01
BR7804847A (pt) 1979-04-10
RO77761A (fr) 1981-11-24
EP0000564A1 (fr) 1979-02-07
IL55073A (en) 1982-01-31
IT7826142A0 (it) 1978-07-26
PT68312A (en) 1978-08-01
IN148019B (fr) 1980-09-27
IE781523L (en) 1979-01-28
FI66129B (fi) 1984-05-31
IT1196394B (it) 1988-11-16
AU525163B2 (en) 1982-10-21

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