EP0008060A1 - Utilisation d'alcools polyvalents, d'acides (hydroxy)carboxyliques et/ou de leurs esters avec des alcools polyvalents comme régulateurs de viscosité - Google Patents

Utilisation d'alcools polyvalents, d'acides (hydroxy)carboxyliques et/ou de leurs esters avec des alcools polyvalents comme régulateurs de viscosité Download PDF

Info

Publication number: EP0008060A1
Authority: EP; European Patent Office
Prior art keywords: alcohols; carboxylic acids; esters; hydroxy; acids
Prior art date: 1978-08-03
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Granted

Application number

EP79102709A

Other languages

German (de)

English (en)

Other versions

EP0008060B1 (fr

Inventor

Johannes Dr. Dipl.-Chem. Perner

Paul Ing.(Grad) Diessel

Dieter Ing.(Grad) Stoeckigt

Franz Dr. Dipl.-Chem. Merger

Juergen Dr. Dipl.-Chem. Paetsch

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

BASF SE

Original Assignee

BASF SE

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1978-08-03

Filing date

1979-07-30

Publication date

1980-02-20

1979-07-30 Application filed by BASF SE filed Critical BASF SE

1979-07-30 Priority to AT79102709T priority Critical patent/ATE30T1/de

1980-02-20 Publication of EP0008060A1 publication Critical patent/EP0008060A1/fr

1981-03-25 Application granted granted Critical

1981-03-25 Publication of EP0008060B1 publication Critical patent/EP0008060B1/fr

Status Expired legal-status Critical Current

Links

150000001298 alcohols Chemical class 0.000 title claims abstract description 18
150000002148 esters Chemical class 0.000 title claims abstract description 17
BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 title claims abstract description 14
239000002002 slurry Substances 0.000 claims abstract description 32
239000000203 mixture Substances 0.000 claims abstract description 18
239000003599 detergent Substances 0.000 claims abstract description 13
239000002253 acid Substances 0.000 claims abstract description 8
229910052799 carbon Inorganic materials 0.000 claims abstract description 8
-1 aliphatic alcohols Chemical class 0.000 claims abstract description 7
125000004432 carbon atom Chemical group C* 0.000 claims abstract description 7
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims abstract description 3
150000007933 aliphatic carboxylic acids Chemical class 0.000 claims abstract 2
SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 claims description 7
RDFQSFOGKVZWKF-UHFFFAOYSA-N 3-hydroxy-2,2-dimethylpropanoic acid Chemical compound OCC(C)(C)C(O)=O RDFQSFOGKVZWKF-UHFFFAOYSA-N 0.000 claims description 5
150000005846 sugar alcohols Polymers 0.000 claims description 5
IUGYQRQAERSCNH-UHFFFAOYSA-N pivalic acid Chemical compound CC(C)(C)C(O)=O IUGYQRQAERSCNH-UHFFFAOYSA-N 0.000 claims description 4
239000012459 cleaning agent Substances 0.000 claims description 3
ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims description 2
230000001476 alcoholic effect Effects 0.000 claims description 2
WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 2
150000001735 carboxylic acids Chemical class 0.000 abstract description 10
238000000034 method Methods 0.000 abstract description 5
150000007513 acids Chemical class 0.000 abstract description 4
150000001875 compounds Chemical class 0.000 abstract description 3
125000004429 atom Chemical group 0.000 abstract 1
125000000075 primary alcohol group Chemical group 0.000 abstract 1
230000001105 regulatory effect Effects 0.000 abstract 1
235000014113 dietary fatty acids Nutrition 0.000 description 10
239000000194 fatty acid Substances 0.000 description 10
229930195729 fatty acid Natural products 0.000 description 10
150000004665 fatty acids Chemical class 0.000 description 10
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
229910052708 sodium Inorganic materials 0.000 description 8
239000011734 sodium Substances 0.000 description 8
239000013543 active substance Substances 0.000 description 7
239000000843 powder Substances 0.000 description 7
229920002134 Carboxymethyl cellulose Polymers 0.000 description 6
239000001768 carboxy methyl cellulose Substances 0.000 description 6
235000010948 carboxy methyl cellulose Nutrition 0.000 description 6
239000008112 carboxymethyl-cellulose Substances 0.000 description 6
YRIUSKIDOIARQF-UHFFFAOYSA-N dodecyl benzenesulfonate Chemical compound CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 YRIUSKIDOIARQF-UHFFFAOYSA-N 0.000 description 6
229940117969 neopentyl glycol Drugs 0.000 description 6
239000000126 substance Substances 0.000 description 6
239000003760 tallow Substances 0.000 description 6
235000013162 Cocos nucifera Nutrition 0.000 description 5
244000060011 Cocos nucifera Species 0.000 description 5
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 5
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 5
229940071161 dodecylbenzenesulfonate Drugs 0.000 description 5
238000005259 measurement Methods 0.000 description 5
HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 5
150000003014 phosphoric acid esters Chemical class 0.000 description 5
239000000344 soap Substances 0.000 description 5
235000019832 sodium triphosphate Nutrition 0.000 description 5
RPACBEVZENYWOL-XFULWGLBSA-M sodium;(2r)-2-[6-(4-chlorophenoxy)hexyl]oxirane-2-carboxylate Chemical compound [Na+].C=1C=C(Cl)C=CC=1OCCCCCC[C@]1(C(=O)[O-])CO1 RPACBEVZENYWOL-XFULWGLBSA-M 0.000 description 5
239000001226 triphosphate Substances 0.000 description 5
239000004435 Oxo alcohol Substances 0.000 description 4
239000000047 product Substances 0.000 description 4
JSPLKZUTYZBBKA-UHFFFAOYSA-N trioxidane Chemical compound OOO JSPLKZUTYZBBKA-UHFFFAOYSA-N 0.000 description 4
238000005406 washing Methods 0.000 description 4
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 3
230000036571 hydration Effects 0.000 description 3
238000006703 hydration reaction Methods 0.000 description 3
239000007921 spray Substances 0.000 description 3
JBVOQKNLGSOPNZ-UHFFFAOYSA-N 2-propan-2-ylbenzenesulfonic acid Chemical compound CC(C)C1=CC=CC=C1S(O)(=O)=O JBVOQKNLGSOPNZ-UHFFFAOYSA-N 0.000 description 2
239000004115 Sodium Silicate Substances 0.000 description 2
229910021536 Zeolite Inorganic materials 0.000 description 2
230000002378 acidificating effect Effects 0.000 description 2
229940071118 cumenesulfonate Drugs 0.000 description 2
230000002349 favourable effect Effects 0.000 description 2
150000002334 glycols Chemical class 0.000 description 2
125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
239000002736 nonionic surfactant Substances 0.000 description 2
235000019795 sodium metasilicate Nutrition 0.000 description 2
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
229910052911 sodium silicate Inorganic materials 0.000 description 2
238000001694 spray drying Methods 0.000 description 2
239000003381 stabilizer Substances 0.000 description 2
239000004094 surface-active agent Substances 0.000 description 2
239000010457 zeolite Substances 0.000 description 2
SZCWBURCISJFEZ-UHFFFAOYSA-N (3-hydroxy-2,2-dimethylpropyl) 3-hydroxy-2,2-dimethylpropanoate Chemical compound OCC(C)(C)COC(=O)C(C)(C)CO SZCWBURCISJFEZ-UHFFFAOYSA-N 0.000 description 1
LBLYYCQCTBFVLH-UHFFFAOYSA-M 2-methylbenzenesulfonate Chemical compound CC1=CC=CC=C1S([O-])(=O)=O LBLYYCQCTBFVLH-UHFFFAOYSA-M 0.000 description 1
229910019142 PO4 Inorganic materials 0.000 description 1
ZZXDRXVIRVJQBT-UHFFFAOYSA-M Xylenesulfonate Chemical compound CC1=CC=CC(S([O-])(=O)=O)=C1C ZZXDRXVIRVJQBT-UHFFFAOYSA-M 0.000 description 1
238000010521 absorption reaction Methods 0.000 description 1
239000000654 additive Substances 0.000 description 1
239000012223 aqueous fraction Substances 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
230000000694 effects Effects 0.000 description 1
150000002191 fatty alcohols Chemical class 0.000 description 1
239000000835 fiber Substances 0.000 description 1
239000003752 hydrotrope Substances 0.000 description 1
230000003165 hydrotropic effect Effects 0.000 description 1
230000001771 impaired effect Effects 0.000 description 1
238000011835 investigation Methods 0.000 description 1
239000002245 particle Substances 0.000 description 1
235000021317 phosphate Nutrition 0.000 description 1
150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
159000000000 sodium salts Chemical class 0.000 description 1
239000007787 solid Substances 0.000 description 1
PBYVKELNSIHHMK-UHFFFAOYSA-K tetrasodium;2-[bis(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CC([O-])=O PBYVKELNSIHHMK-UHFFFAOYSA-K 0.000 description 1
229940071104 xylenesulfonate Drugs 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2093—Esters; Carbonates
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2044—Dihydric alcohols linear

Definitions

the invention relates to a new use of certain polyhydric aliphatic alcohols, carboxylic acids and / or esters from the two classes of compounds as viscosity regulators in aqueous detergent and cleaning agent slurries.
the detergent slurry is an aqueous slurry of inorganic and organic substances that is subject to unpredictable viscosity fluctuations.
the uniform quality and consistency of the type of powdered end product depends on the constant viscosity of the slurry. Viscosity fluctuations are generally caused by the surfactants contained in the slurry and especially by the hydration behavior of the phosphates contained in the detergent slurries and cause inconsistent dry products due to the different water content of the dried powder particles.
the viscosities have to be reduced because the slurry becomes too viscous due to the absorption of water, and on the other hand these viscosities have to be set to a constant value in order to ensure constant spray conditions and thus also uniform bulk weights of the finished powders to obtain.
hydrotropes such as cumene sulfonate, toluenesulfonate or xylene sulfonate have been used to reduce and keep the viscosity values constant, in amounts of 10 to 15% by weight.
DE-AS 16 17 160 discloses acidic phosphoric acid esters as homogenizing agents for slurries, which are present in amounts of preferably 5 to 25% by weight, based on surface-active agents.
the hydrotropic substances are present in such an amount that the detergent-active substances contained in the finished products are diluted too much, and thus the washing power of the products is impaired.
the acidic phosphoric acid esters which can be used in smaller quantities - based on the slurry - only work in detergent slurries that contain nonionic surfactants with which they apparently interact.
DE-AS 16 70 160 there is no indication in DE-AS 16 70 160 that the viscosity of the slurries described there can be reduced by the phosphoric acid esters described therein.
the aim of the invention was to find additives which, when used in the smallest possible amounts, are able are to reduce the viscosity of the slurries, to keep constant and the stability of the slurries to ver b es- fibers that is, they should as a viscosity, as a viscosity regulator and as stabilizers act without affecting the washing power of the finished products.
the aliphatic alcohols to be used according to the invention contain 5 to 9 carbon atoms, one of which is quaternary in nature, and 2 to 4 alcoholic hydroxyl groups, which are exclusively primary.
these alcohols e.g. Neopentylglycol, trimethylolpropane and pentaerythritol and mixtures thereof.
homologs of the alcohols mentioned are suitable which carry primary hydroxyethyl groups on the quaternary carbon atom instead of the methylol groups.
the carboxylic acids can be used. They too hold 5 to 9 aliphatic carbon atoms, one of which is quaternary in nature.
the carboxylic acids contain a carboxyl group which is bonded to the quaternary carbon atom and can furthermore contain primarily bonded hydroxyl groups.
esters of neopentyl glycol and hydroxypiralic acid preferably neopentyl glycol monohydroxypivalate.
the compounds themselves act as extreme viscosity improvers.
extreme viscosity improvers For some purposes, e.g. In order to obtain washing powder with a high content of detergent substance with little water of hydration after spray drying, medium viscosity ranges are required, i.e. Substances with an even better regulator function.
Particularly favorable mixtures are combinations of polyhydric alcohol, hydroxycarboxylic acid and hydroxycarboxylic acid esters, of which the mixture of neopentylglycol, hydroxypivalic acid and neopentyoglycol-hydroxypivalic acid ester is preferred.
This mixture is particularly easy to access technically.
the alcohols or mixtures of the alcohols with acids and / or esters are added to the slurries in an amount of 1 to 6% by weight, preferably 3 to 6% by weight, based on solid proportions. Larger amounts are also effective, but do not bring any additional benefits.
the viscosity measurements were carried out in a Brookfield viscometer and were carried out after 15, 30 and 60 minutes.
the percentages given in the individual examples relate to the total weight of the non-aqueous fractions.
the mixture was adjusted as an aqueous slurry containing 70% by weight of non-aqueous components.

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Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Emergency Medicine (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Detergent Compositions (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

EP79102709A 1978-08-03 1979-07-30 Utilisation d'alcools polyvalents, d'acides (hydroxy)carboxyliques et/ou de leurs esters avec des alcools polyvalents comme régulateurs de viscosité Expired EP0008060B1 (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
AT79102709T ATE30T1 (de)	1978-08-03	1979-07-30	Verwendung von mehrwertigen alkoholen, (hydroxy)carbonsaeuren und/oder deren estern mit den mehrwertigen alkoholen als viskositaetsregler

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
DE2834073		1978-08-03
DE19782834073 DE2834073A1 (de)	1978-08-03	1978-08-03	Verwendung von mehrwertigen alkoholen, (hydroxy)carbonsaeuren und/oder deren estern mit den mehrwertigen alkoholen als viskositaetsregler

Publications (2)

Publication Number	Publication Date
EP0008060A1 true EP0008060A1 (fr)	1980-02-20
EP0008060B1 EP0008060B1 (fr)	1981-03-25

Family

ID=6046129

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
EP79102709A Expired EP0008060B1 (fr)	1978-08-03	1979-07-30	Utilisation d'alcools polyvalents, d'acides (hydroxy)carboxyliques et/ou de leurs esters avec des alcools polyvalents comme régulateurs de viscosité

Country Status (4)

Country	Link
US (1)	US4239641A (fr)
EP (1)	EP0008060B1 (fr)
AT (1)	ATE30T1 (fr)
DE (2)	DE2834073A1 (fr)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP0126141A4 (fr) *	1982-11-15	1985-06-06	Louis J Jubanowsky	Additif accroissant la viscosite pour systemes fluides non aqueux.
US4532076A (en) *	1982-02-11	1985-07-30	Henkel Kommanditgesellschaft Auf Aktien	Aqueous anionic surfactant concentrates containing viscosity reducing agents
EP0116905A3 (en) *	1983-02-17	1985-08-28	Henkel Kommanditgesellschaft Auf Aktien	Use of alcohols and their derivatives as viscosity regulators for highly viscous concentrates of technical surfactants
EP0287514A1 (fr) *	1987-04-15	1988-10-19	Ciba-Geigy Ag	Détergent pour le postlavage de teintures réactives, son procédé de préparation et son emploi
WO1991019775A1 (fr) *	1990-06-15	1991-12-26	Henkel Kommanditgesellschaft Auf Aktien	Utilisation de sels des produits de sulfonation d'acides gras insatures comme reducteurs de viscosite
EP0425149A3 (en) *	1989-10-23	1992-03-25	Imperial Chemical Industries Plc	Detergent compositions and processes of making them
WO1993019146A1 (fr) *	1992-03-16	1993-09-30	The Procter & Gamble Company	Compositions fluides renfermant des amides d'acides gras polyhydroxy
US5304669A (en) *	1990-10-17	1994-04-19	Henkel Kommanditgesellschaft Auf Aktien	Process for the production of alkyl sulfate pastes having improved flow properties
WO2014072840A1 (fr)	2012-11-12	2014-05-15	Galaxy Surfactants Ltd.	Sulfates d'alkyle gras aqueux hautement actifs fluides

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4517025A (en) *	1982-05-17	1985-05-14	Amchem Products, Inc.	Method for removing sealant contamination
EP0166522B1 (fr) *	1984-05-24	1991-07-24	Pegel, Karl Heinrich	Composition cosmétique
DE3447859A1 (de) *	1984-12-31	1986-07-10	Henkel KGaA, 4000 Düsseldorf	Verwendung von alkansulfonaten als viskositaetsregler fuer hochviskose aniontensid-konzentrate
US5192462A (en) *	1989-03-21	1993-03-09	Croda Inc.	Thickening agents for topical preparations
US5024772A (en) *	1989-07-10	1991-06-18	Basf Corporation	Method of producing HPN and mixtures thereof
BR9306035A (pt) *	1992-03-06	1997-11-18	Unilever Nv	Composição de limpeza líquida aquosa de baixo espumamento e aditivo para uso como antiespumante em uma composição de limpeza
CA2120375A1 (fr) *	1993-04-02	1994-10-03	John Klier	Produit de pretraitement pour la lessive a proprietes nettoyantes ameliorees pour les souillures huileuses
US5597406A (en) *	1993-11-02	1997-01-28	Henkel Corporation	Method of thickening aqueous formulations
US5501813A (en) *	1993-11-02	1996-03-26	Henkel Corporation	Thickener for aqueous compositions

Citations (3)

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Publication number	Priority date	Publication date	Assignee	Title
DE1617160B2 (de) *	1966-06-23	1975-04-24	Mo Och Domsjoe Ab, Oernskoeldsvik (Schweden)	Verfahren zur Herstellung sprühgetrockneter Reinigungspräparate
US3893955A (en) *	1971-10-20	1975-07-08	Albright & Wilson	Aqueous concentrate detergent component
DE2531925A1 (de) *	1974-07-25	1976-02-05	Pierre Fusey	Verfahren zur herstellung eines basisdetergents fuer fluessige waschmittel

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DE1254798B (de) *	1964-06-26	1967-11-23	Henkel & Cie Gmbh	Fluessige oder pastenfoermige Waschmittelkonzentrate
US3554916A (en) *	1965-06-01	1971-01-12	Continental Oil Co	Viscosity modification of amine salts of linear alkylaryl sulfonates
SE352652B (fr) *	1969-10-01	1973-01-08	Hentschel V
CA995092A (en) *	1972-07-03	1976-08-17	Rodney M. Wise	Sulfated alkyl ethoxylate-containing detergent composition

1978
- 1978-08-03 DE DE19782834073 patent/DE2834073A1/de active Pending
1979
- 1979-07-23 US US06/059,777 patent/US4239641A/en not_active Expired - Lifetime
- 1979-07-30 DE DE7979102709T patent/DE2960214D1/de not_active Expired
- 1979-07-30 EP EP79102709A patent/EP0008060B1/fr not_active Expired
- 1979-07-30 AT AT79102709T patent/ATE30T1/de not_active IP Right Cessation

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE1617160B2 (de) *	1966-06-23	1975-04-24	Mo Och Domsjoe Ab, Oernskoeldsvik (Schweden)	Verfahren zur Herstellung sprühgetrockneter Reinigungspräparate
US3893955A (en) *	1971-10-20	1975-07-08	Albright & Wilson	Aqueous concentrate detergent component
DE2531925A1 (de) *	1974-07-25	1976-02-05	Pierre Fusey	Verfahren zur herstellung eines basisdetergents fuer fluessige waschmittel

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4532076A (en) *	1982-02-11	1985-07-30	Henkel Kommanditgesellschaft Auf Aktien	Aqueous anionic surfactant concentrates containing viscosity reducing agents
EP0126141A4 (fr) *	1982-11-15	1985-06-06	Louis J Jubanowsky	Additif accroissant la viscosite pour systemes fluides non aqueux.
EP0116905A3 (en) *	1983-02-17	1985-08-28	Henkel Kommanditgesellschaft Auf Aktien	Use of alcohols and their derivatives as viscosity regulators for highly viscous concentrates of technical surfactants
EP0287514A1 (fr) *	1987-04-15	1988-10-19	Ciba-Geigy Ag	Détergent pour le postlavage de teintures réactives, son procédé de préparation et son emploi
US4902439A (en) *	1987-04-15	1990-02-20	Ciba-Geigy Corporation	Detergent composition for washing off dyeings obtained with fibre-reactive dyes, process for the preparation thereof and use thereof
EP0425149A3 (en) *	1989-10-23	1992-03-25	Imperial Chemical Industries Plc	Detergent compositions and processes of making them
WO1991019775A1 (fr) *	1990-06-15	1991-12-26	Henkel Kommanditgesellschaft Auf Aktien	Utilisation de sels des produits de sulfonation d'acides gras insatures comme reducteurs de viscosite
US5304669A (en) *	1990-10-17	1994-04-19	Henkel Kommanditgesellschaft Auf Aktien	Process for the production of alkyl sulfate pastes having improved flow properties
WO1993019146A1 (fr) *	1992-03-16	1993-09-30	The Procter & Gamble Company	Compositions fluides renfermant des amides d'acides gras polyhydroxy
TR27593A (tr) *	1992-03-16	1995-06-13	Procter & Gamble	Polihidroksi yagli asit amidleri ihtiva eden akiskan bilesimleri.
WO2014072840A1 (fr)	2012-11-12	2014-05-15	Galaxy Surfactants Ltd.	Sulfates d'alkyle gras aqueux hautement actifs fluides

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DE2960214D1 (en)	1981-04-16
US4239641A (en)	1980-12-16
ATE30T1 (de)	1981-04-15
EP0008060B1 (fr)	1981-03-25

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Publication	Publication Date	Title
EP0008060B1 (fr)	1981-03-25	Utilisation d'alcools polyvalents, d'acides (hydroxy)carboxyliques et/ou de leurs esters avec des alcools polyvalents comme régulateurs de viscosité
EP0474915B2 (fr)	1998-06-10	Détergent
EP0116905B1 (fr)	1988-01-20	Utilisation de dérivés d'alcools comme régleurs de la viscosité pour des concentrés de tensio-actifs techniques hautement visqueux
DE1176307B (de)	1964-08-20	Schuett- und rieselfaehige, insbesondere pulver-foermige Wasch-, Netz- und Emulgiermittel
EP0185660B1 (fr)	1988-02-03	Suspension aqueuse, stabilisee a base de zeolithe
DE1916861C3 (de)	1978-05-11	Verfahren zur Herstellung von Wasch- und Reinigungsmitteln
EP0303187A2 (fr)	1989-02-15	Préparations aqueuses de tensio-actifsioniques, à viscosité augmentée
DE1170573C2 (de)	1973-07-19	Waschmittel
DE69203217T2 (de)	1995-11-30	Waschmittelzusammensetzungen und Verfahren zu deren Herstellung.
DE2326006A1 (de)	1973-12-13	Aus waessrigen konzentraten von alkoxylierten alkohol-sulfaten bestehende detergent-komponenten
DE1467615A1 (de)	1969-01-16	Waschmittel mit geringem Schaumvermoegen
DE2836277A1 (de)	1979-03-01	Verfahren zur herstellung eines fluessigwaschmittels auf waessriger basis
AT151676B (de)	1937-11-25	Kapillaraktive Mittel.
DE69332313T2 (de)	2003-07-31	Verfahren zur herstellung von tensidhaltigen mischungen
DE2161699B2 (de)	1979-10-11	Wasch- und Reinigungsmittel
EP0682691B1 (fr)	1997-04-09	Agents de lavage solides et anhydres
DE1135122B (de)	1962-08-23	Schaumarme Waschmittel
EP0848746B1 (fr)	1999-12-01	Nettoyant aqueux
DE3420334A1 (de)	1984-12-06	Koerniges wasch- und reinigungsmittel
DE3330220A1 (de)	1985-03-07	Stabilisierte, waessrige zeolith-suspension
EP0495176B1 (fr)	1995-06-21	Lessive en poudre
DE1281619B (de)	1969-04-03	Schuett- und rieselfaehige, insbesondere pulverfoermige Wasch-, Netz-und Emulgiermittel
DE4041172A1 (de)	1992-06-25	Fluessige seifenzubereitung
DE1162966B (de)	1964-02-13	Wasch-, Reinigungs-, Netz- und Schaummittel
AT246884B (de)	1966-05-10	Schütt- und rieselfähige, vorzugsweise pulverförmige Wasch-, Netz- und Emulgiermittel