EP0013541A1 - Procédé pour la fabrication de fibres de polymères thermoplastiques d'acrylonitrile - Google Patents

Procédé pour la fabrication de fibres de polymères thermoplastiques d'acrylonitrile Download PDF

Info

Publication number: EP0013541A1
Authority: EP; European Patent Office
Prior art keywords: acrylonitrile; polymer; acrylic; polymerisate; fibers
Prior art date: 1979-01-04
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Granted

Application number

EP79810189A

Other languages

German (de)

English (en)

Other versions

EP0013541B1 (fr

Inventor

Guido Dr.-Chem. Stampa

Gero Dr. Dipl.-Ing. Büttiker

Peter Dr.-Chem Meier

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Amrotex AG

Original Assignee

Amrotex AG

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1979-01-04

Filing date

1979-12-28

Publication date

1980-07-23

1979-12-28 Application filed by Amrotex AG filed Critical Amrotex AG

1979-12-28 Priority to AT79810189T priority Critical patent/ATE1956T1/de

1980-07-23 Publication of EP0013541A1 publication Critical patent/EP0013541A1/fr

1982-12-08 Application granted granted Critical

1982-12-08 Publication of EP0013541B1 publication Critical patent/EP0013541B1/fr

Status Expired legal-status Critical Current

Links

238000004519 manufacturing process Methods 0.000 title claims abstract description 5
229920001169 thermoplastic Polymers 0.000 title claims abstract description 4
238000000034 method Methods 0.000 title claims description 6
239000004416 thermosoftening plastic Substances 0.000 title abstract description 3
229920002239 polyacrylonitrile Polymers 0.000 title 1
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims abstract description 16
239000000835 fiber Substances 0.000 claims abstract description 16
229920000642 polymer Polymers 0.000 claims abstract description 9
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims abstract description 7
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims abstract description 6
150000002148 esters Chemical class 0.000 claims abstract description 5
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 3
238000001816 cooling Methods 0.000 claims abstract 2
RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims description 4
229920001577 copolymer Polymers 0.000 claims description 4
229920000578 graft copolymer Polymers 0.000 claims description 2
125000005396 acrylic acid ester group Chemical group 0.000 claims 1
NTXGQCSETZTARF-UHFFFAOYSA-N buta-1,3-diene;prop-2-enenitrile Chemical compound C=CC=C.C=CC#N NTXGQCSETZTARF-UHFFFAOYSA-N 0.000 claims 1
150000002825 nitriles Chemical group 0.000 claims 1
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract description 6
125000005397 methacrylic acid ester group Chemical group 0.000 abstract 1
239000010425 asbestos Substances 0.000 description 4
239000011230 binding agent Substances 0.000 description 4
229910052895 riebeckite Inorganic materials 0.000 description 4
239000004743 Polypropylene Substances 0.000 description 3
239000004568 cement Substances 0.000 description 3
-1 polypropylene Polymers 0.000 description 3
229920001155 polypropylene Polymers 0.000 description 3
239000004952 Polyamide Substances 0.000 description 2
230000001070 adhesive effect Effects 0.000 description 2
125000005250 alkyl acrylate group Chemical group 0.000 description 2
239000002657 fibrous material Substances 0.000 description 2
239000004033 plastic Substances 0.000 description 2
229920003023 plastic Polymers 0.000 description 2
229920002647 polyamide Polymers 0.000 description 2
239000012779 reinforcing material Substances 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
229920001824 Barex® Polymers 0.000 description 1
206010013786 Dry skin Diseases 0.000 description 1
229910010413 TiO 2 Inorganic materials 0.000 description 1
239000000853 adhesive Substances 0.000 description 1
239000003513 alkali Substances 0.000 description 1
125000005907 alkyl ester group Chemical group 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
239000006229 carbon black Substances 0.000 description 1
239000001913 cellulose Substances 0.000 description 1
229920002678 cellulose Polymers 0.000 description 1
238000001035 drying Methods 0.000 description 1
239000000945 filler Substances 0.000 description 1
239000000463 material Substances 0.000 description 1
238000002156 mixing Methods 0.000 description 1
229930014626 natural product Natural products 0.000 description 1
239000004745 nonwoven fabric Substances 0.000 description 1
239000000049 pigment Substances 0.000 description 1
229920000728 polyester Polymers 0.000 description 1
229920006149 polyester-amide block copolymer Polymers 0.000 description 1
238000003825 pressing Methods 0.000 description 1
230000003014 reinforcing effect Effects 0.000 description 1
239000012763 reinforcing filler Substances 0.000 description 1
238000005096 rolling process Methods 0.000 description 1
238000007873 sieving Methods 0.000 description 1
239000002893 slag Substances 0.000 description 1
239000000126 substance Substances 0.000 description 1

Classifications

- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/42—Formation of filaments, threads, or the like by cutting films into narrow ribbons or filaments or by fibrillation of films or filaments
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/28—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D01F6/38—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds comprising unsaturated nitriles as the major constituent

Definitions

the invention relates to a process for producing fibers from a polymer of acrylonitrile with esters of acrylic and / or methacrylic acid, which has a molar concentration of the acrylonitrile units in the range from 50 to 96%.
asbestos fibers are used as reinforcing material and / or filler for the production of components, such as pipes, plates, plant boxes, etc. It is also known that asbestos will not be available in unlimited quantities and must be counted among those natural products whose stocks may soon run out. For this reason, the relevant industry repeatedly tries to replace the asbestos fibers with other fiber material, including fibers made of plastics, such as polypropylene, polyester, polyamide, etc. Polypropylene fibers have the disadvantage that the adhesion with the hydraulic binders or . whose hardening products are bad; therefore, attempts are known to process polypropylene fibers connected in a network.
Polyester and polyamide products that can be spliced into fibers also unsuitable because they are not alkali-resistant.
Other plastics such as PVC, which, from a chemical point of view, can be suitable for processing together with hydraulic binders, prove to be difficult to split.
extruded, stretched and spliced hoses or tapes can be used as continuous fibers or as a reinforcing material cut in a stack from 1 to 10 mm inge.
the polymer can also be a graft polymer of acrylonitrile / alkyl ester of acrylic acid and / or methacrylic acid on a copolymer of acrylonitrile / butadiene and / or isoprene or of alkyl acrylates.
the polymer can contain fillers and pigments such as carbon black, TiO 2 , circles, blast furnace slag etc.
the mixing ratio between fibers and cement is depending on the fiber length, respectively. depending on the requirements placed on the finished product, between 1: 3 and 1: 15.
the cut pieces of tubing can only be spliced into the individual fibers when they are mixed with the hydraulic binders.

Landscapes

Engineering & Computer Science (AREA)
Textile Engineering (AREA)
Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
General Chemical & Material Sciences (AREA)
Mechanical Engineering (AREA)
Artificial Filaments (AREA)
Reinforced Plastic Materials (AREA)
Polymerisation Methods In General (AREA)

EP79810189A 1979-01-04 1979-12-28 Procédé pour la fabrication de fibres de polymères thermoplastiques d'acrylonitrile Expired EP0013541B1 (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
AT79810189T ATE1956T1 (de)	1979-01-04	1979-12-28	Verfahren zur herstellung von fasern aus thermoplastischen polymerisaten des acrylnitrils.

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
CH41/79		1979-01-04
CH4179		1979-01-04

Publications (2)

Publication Number	Publication Date
EP0013541A1 true EP0013541A1 (fr)	1980-07-23
EP0013541B1 EP0013541B1 (fr)	1982-12-08

Family

ID=4177986

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
EP79810189A Expired EP0013541B1 (fr)	1979-01-04	1979-12-28	Procédé pour la fabrication de fibres de polymères thermoplastiques d'acrylonitrile

Country Status (4)

Country	Link
EP (1)	EP0013541B1 (fr)
AT (1)	ATE1956T1 (fr)
DE (1)	DE2964235D1 (fr)
DK (1)	DK4080A (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP0780498A1 (fr) *	1995-12-18	1997-06-25	The Standard Oil Company	Fibres d'acrylonitrile et composés à insaturation oléfinique filées au fondu et procédé de fabrication

Citations (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR1208402A (fr) *	1957-06-11	1960-02-23	Du Pont	Structures filamenteuses et procédé pour les fabriquer
FR1428992A (fr) *	1965-03-29	1966-02-18	Polymer Proc Res Inst	Procédé et dispositif pour la fabrication continue de fibrilles
US3364102A (en) *	1964-07-27	1968-01-16	Dow Chemical Co	Method for making paper-like and related non-woven products from acrylonitrile polymer fibers
CH450894A (fr) *	1964-06-03	1968-05-15	Chemstrand Ltd	Procédé de fabrication de papier à partir de fibres de polymères d'acrylonitrile et papiers obtenus par ce procédé
DE1469160A1 (de) *	1961-08-29	1968-12-05	Schweizerische Viscose	Verfahren zum Herstellen kuenstlicher und synthetischer Fasern
FR1559289A (fr) *	1967-09-20	1969-03-07

1979
- 1979-12-28 EP EP79810189A patent/EP0013541B1/fr not_active Expired
- 1979-12-28 DE DE7979810189T patent/DE2964235D1/de not_active Expired
- 1979-12-28 AT AT79810189T patent/ATE1956T1/de not_active IP Right Cessation
1980
- 1980-01-03 DK DK4080A patent/DK4080A/da not_active Application Discontinuation

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR1208402A (fr) *	1957-06-11	1960-02-23	Du Pont	Structures filamenteuses et procédé pour les fabriquer
DE1469160A1 (de) *	1961-08-29	1968-12-05	Schweizerische Viscose	Verfahren zum Herstellen kuenstlicher und synthetischer Fasern
CH450894A (fr) *	1964-06-03	1968-05-15	Chemstrand Ltd	Procédé de fabrication de papier à partir de fibres de polymères d'acrylonitrile et papiers obtenus par ce procédé
US3364102A (en) *	1964-07-27	1968-01-16	Dow Chemical Co	Method for making paper-like and related non-woven products from acrylonitrile polymer fibers
FR1428992A (fr) *	1965-03-29	1966-02-18	Polymer Proc Res Inst	Procédé et dispositif pour la fabrication continue de fibrilles
FR1559289A (fr) *	1967-09-20	1969-03-07

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP0780498A1 (fr) *	1995-12-18	1997-06-25	The Standard Oil Company	Fibres d'acrylonitrile et composés à insaturation oléfinique filées au fondu et procédé de fabrication

Also Published As

Publication number	Publication date
EP0013541B1 (fr)	1982-12-08
DK4080A (da)	1980-07-05
ATE1956T1 (de)	1982-12-15
DE2964235D1 (en)	1983-01-13

Legal Events

Date	Code	Title	Description
1980-05-28	PUAI	Public reference made under article 153(3) epc to a published international application that has entered the european phase	Free format text: ORIGINAL CODE: 0009012
1980-07-23	AK	Designated contracting states	Designated state(s): AT BE DE FR GB LU NL SE
1980-10-29	17P	Request for examination filed
1982-10-08	GRAA	(expected) grant	Free format text: ORIGINAL CODE: 0009210
1982-12-08	AK	Designated contracting states	Designated state(s): AT BE DE FR GB LU NL SE
1982-12-08	PG25	Lapsed in a contracting state [announced via postgrant information from national office to epo]	Ref country code: SE Effective date: 19821208 Ref country code: NL Effective date: 19821208 Ref country code: FR Free format text: THE PATENT HAS BEEN ANNULLED BY A DECISION OF A NATIONAL AUTHORITY Effective date: 19821208 Ref country code: BE Effective date: 19821208
1982-12-08	REF	Corresponds to:	Ref document number: 1956 Country of ref document: AT Date of ref document: 19821215 Kind code of ref document: T
1982-12-28	PG25	Lapsed in a contracting state [announced via postgrant information from national office to epo]	Ref country code: AT Effective date: 19821228
1982-12-31	PG25	Lapsed in a contracting state [announced via postgrant information from national office to epo]	Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 19821231
1983-01-13	REF	Corresponds to:	Ref document number: 2964235 Country of ref document: DE Date of ref document: 19830113
1983-05-16	NLV1	Nl: lapsed or annulled due to failure to fulfill the requirements of art. 29p and 29m of the patents act
1983-09-30	EN	Fr: translation not filed
1984-06-25	PGFP	Annual fee paid to national office [announced via postgrant information from national office to epo]	Ref country code: DE Payment date: 19840625 Year of fee payment: 5
1984-08-01	GBPC	Gb: european patent ceased through non-payment of renewal fee
1985-09-03	PG25	Lapsed in a contracting state [announced via postgrant information from national office to epo]	Ref country code: DE Effective date: 19850903
1988-11-18	PG25	Lapsed in a contracting state [announced via postgrant information from national office to epo]	Ref country code: GB Effective date: 19881118
2016-09-14	PLBE	No opposition filed within time limit	Free format text: ORIGINAL CODE: 0009261
2016-09-14	STAA	Information on the status of an ep patent application or granted ep patent	Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

Publication	Publication Date	Title
DE2907729C2 (de)	1982-08-26	Verstärkungs- oder Füllstoffmaterial enthaltende Polyäthylenterephthalat-Zusammensetzung
DE1914370A1 (de)	1969-10-09	Glasfaserverstaerktes,thermoplastisches Harzpraeparat
DE2742177A1 (de)	1979-03-29	Polyamidlegierungen
DE2635957C2 (fr)	1988-03-31
DE2458912A1 (de)	1975-07-10	Verfahren zur herstellung von fasern und anderen gegenstaenden aus acrylnitrilpolymeren
DE2926778A1 (de)	1981-01-15	Mit fasern verstaerkte polyamid-formmassen
DE102007031467A1 (de)	2009-01-08	Verfahren zur Herstellung eines faserverstärkten Verbundstoffs und Verbundstoff
DE1161019B (de)	1964-01-09	Verfahren zum Herstellen von faserverstaerkten Formteilen aus Polyester-Formmassen
DE2352903A1 (de)	1974-04-25	Verfahren zur herstellung von mit kohlenstoffasern verstaerkten polyamidharzen
EP0013541B1 (fr)	1982-12-08	Procédé pour la fabrication de fibres de polymères thermoplastiques d'acrylonitrile
EP0000783A2 (fr)	1979-02-21	Article conformé à base de polypropylène
EP0725091B1 (fr)	1999-09-08	Masses à mouler à ténacité à basse température améliorée
DE1934541A1 (de)	1971-01-14	Verfahren und Vorrichtung zur Herstellung von Stapelfasern aus thermoplastischen Kunststoffen
DE3686369T2 (de)	1993-03-25	Verlaengerte formgranulate und ihre verwendung beim spritzgiessverfahren.
DE4015182A1 (de)	1991-11-14	Homogene polymermischung aus polymethacrylimid-polymeren
EP0154217B1 (fr)	1989-09-20	Monofilament et brasses d'homo ou copolymérisats d'acrylonitrile et méthode de fabrication
DE2063933A1 (de)	1971-07-01	Fullstoffhaltige Faden oder Fasern und Verfahren zu ihrer Herstellung
DE669793C (de)	1939-01-04	Verfahren zur Herstellung geformter Gegenstaende aus Polymerisationsprodukten von Koerpern mit einer olefinischen Doppelbindung
DE959409C (de)	1957-03-07	Verfahren zur Herstellung von Formkoerpern aus einer thermoplastischen polyurethanhaltigen Kunststoffmasse
DE1298282B (de)	1969-06-26	Mischungen auf der Basis von Bitumen zur Herstellung von Formkoerpern
DE2027070A1 (de)	1970-12-10	Härtbares Kunststoffpulvergemisch
DE1132088B (de)	1962-06-28	Verfahren zur Herstellung eines Vlieses
DE2633310A1 (de)	1977-02-03	Herstellung von faserhaltigen gegenstaenden
DE960504C (de)	1957-03-21	Bindemittel fuer faserverstaerkte Formkoerper
DE1222461B (de)	1966-08-11	Faserschichtstoffe aus synthetischen Fasern oder Faeden

EP0013541A1 - Procédé pour la fabrication de fibres de polymères thermoplastiques d'acrylonitrile - Google Patents

Info

Links

Classifications

Definitions

Landscapes

Priority Applications (1)

Applications Claiming Priority (2)

Publications (2)

Family

ID=4177986

Family Applications (1)

Country Status (4)

Cited By (1)

Citations (6)

Patent Citations (6)

Cited By (1)

Also Published As

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