EP0026422A1 - Agent de nettoyage aérosol pour le traitement des textiles - Google Patents

Agent de nettoyage aérosol pour le traitement des textiles Download PDF

Info

Publication number
EP0026422A1
EP0026422A1 EP80105681A EP80105681A EP0026422A1 EP 0026422 A1 EP0026422 A1 EP 0026422A1 EP 80105681 A EP80105681 A EP 80105681A EP 80105681 A EP80105681 A EP 80105681A EP 0026422 A1 EP0026422 A1 EP 0026422A1
Authority
EP
European Patent Office
Prior art keywords
weight
percent
average
ethylene glycol
glycol ether
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP80105681A
Other languages
German (de)
English (en)
Other versions
EP0026422B1 (fr
Inventor
Manfred Wilsberg
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Priority to AT80105681T priority Critical patent/ATE8662T1/de
Publication of EP0026422A1 publication Critical patent/EP0026422A1/fr
Application granted granted Critical
Publication of EP0026422B1 publication Critical patent/EP0026422B1/fr
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0043For use with aerosol devices
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/825Mixtures of compounds all of which are non-ionic
    • C11D1/8255Mixtures of compounds all of which are non-ionic containing a combination of compounds differently alcoxylised or with differently alkylated chains
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/43Solvents
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/72Ethers of polyoxyalkylene glycols

Definitions

  • the present invention relates to a cleaning agent which is suitable for the treatment of heavily soiled areas, such as collars and cuffs, of items of laundry which are subsequently washed in the customary manner.
  • a cleaning agent which is suitable for the treatment of heavily soiled areas, such as collars and cuffs, of items of laundry which are subsequently washed in the customary manner.
  • Such agents enhance the effect of the detergent against stubborn dirt, generally in a so-called “fine linen” at 30 ° to 40 ° C, and carried out at 50 ° to 60 0 C wash for "easy-care textiles" can not be sufficiently removed.
  • Corresponding pretreatment agents are known as paste-like or liquid concentrates or as viscous masses shaped into application pens and also as a spray.
  • sprayable agents are particularly valued by consumers, since on the one hand they can be conveniently distributed evenly on the soiled areas without the aid of fingers or a spatula and, on the other hand, in the case of coarsely knit textiles, they penetrate into the deeper fibers and consequently on the surface applied application pen are superior in terms of their cleaning effect.
  • the alcohols on which the nonionic surfactant constituents listed under (a) to (c) are based can be straight-chain or methyl-branched in the 2-position, saturated or simply olefinically unsaturated. They can be of natural or synthetic origin, for example obtained by ethylene polymerization or oxo synthesis, or they can be present as mixtures of such alcohols.
  • the constituent listed under (a) preferably consists of at least 75 percent by weight of an average of 5 to 7 saturated C 8 alcohols containing ethylene glycol ether groups.
  • the component listed under (b) is preferably a mixture of two nonionic compounds (b 1 ) and (b 2 ), which are present in a weight ratio of 1: 4 to 4: 1.
  • Component (b 1 ) preferably consists of saturated averages of 2 to 4 ethylene glycol ether groups C 12 -C 14 alcohols.
  • the component (b 2 ) preferably consists of an average of 2 to 3 ethylene glycol ether groups, saturated or monounsaturated C 16 -C 18 alcohols, the proportion of saturated C 16 -C 18 alcohols not more than 65 percent by weight and in particular not more than Is 50 percent by weight.
  • oleyl alcohol can be used as monounsaturated alcohol.
  • the component listed under (c) preferably has an average of 11 to 13 ethylene glycol ether groups and is preferably derived from mono-olefinically unsaturated or saturated C 16 -C 18 alcohols or mixtures thereof. If alcohol mixtures are used as the starting base, these can be 50 to 100% saturated and consist, for example, of mixtures of cetyl, stearyl and optionally oleyl alcohol, such as those obtainable from tallow fatty alcohols.
  • the component (d) consists of a high-boiling gasoline fraction, which preferably has a boiling range from 205 to 245 ° C. and is present in particular in an amount of 35 to 45 percent by weight, based on the mixture free of blowing agent.
  • the amount of the hydrocarbon is such that the agent is non-combustible in interaction with the other components and can therefore be handled safely in the household.
  • the lower chlorinated hydrocarbons according to component (s), which can also be present in a mixture, are preferably present in an amount of 20 to 32 percent by weight, based on the propellant-free components.
  • the preferred chlorinated hydrocarbon is methylene chloride. The amount of chlorinated hydrocarbons is so limited that there are no health hazards for humans and pets to fear even when accidentally inhaled.
  • the selection and the amount of solvents (d) and (e) guarantees that even wax-like impurities, for example those from candle wax, are sufficiently pre-dissolved so that they can be washed out during the subsequent washing treatment.
  • the solvents in the selected composition do not lead to the formation of a ring.
  • the agents can also contain fragrances, in particular those which mask the inherent odor of the solvents and the detergent ingredients. In general, amounts of 0.1 to 1 percent by weight of perfume oil are sufficient for this.
  • Suitable propellants are conventional propellant gases used for the production of aerosols and low-boiling solvents which are gaseous at room temperature.
  • blowing agents for example combustible hydrocarbons such as propane or butane, or fluorine-containing blowing agents, which are considered to be of concern for environmental reasons, can be dispensed with.
  • Carbon dioxide is preferably used as the blowing agent, with 2 to 3 parts by weight of carbon dioxide accounting for 98 to 97 parts by weight of blowing agent-free components.
  • E0 stands for attached ethylene oxide.
  • the percentages mean percent by weight.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
EP80105681A 1979-10-01 1980-09-22 Agent de nettoyage aérosol pour le traitement des textiles Expired EP0026422B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT80105681T ATE8662T1 (de) 1979-10-01 1980-09-22 Zur textilbehandlung geeignetes spruehreinigungsmittel.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19792939810 DE2939810A1 (de) 1979-10-01 1979-10-01 Zur textilbehandlung geeignetes spruehreinigungsmittel
DE2939810 1979-10-01

Publications (2)

Publication Number Publication Date
EP0026422A1 true EP0026422A1 (fr) 1981-04-08
EP0026422B1 EP0026422B1 (fr) 1984-07-25

Family

ID=6082421

Family Applications (1)

Application Number Title Priority Date Filing Date
EP80105681A Expired EP0026422B1 (fr) 1979-10-01 1980-09-22 Agent de nettoyage aérosol pour le traitement des textiles

Country Status (5)

Country Link
US (1) US4288339A (fr)
EP (1) EP0026422B1 (fr)
AT (1) ATE8662T1 (fr)
BR (1) BR8006289A (fr)
DE (2) DE2939810A1 (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0871808A4 (fr) * 1995-11-27 1999-04-28 Procter & Gamble Composition pour traiter des taches sur des textiles a laver et procede de traitement
EP1149945A1 (fr) * 2000-04-29 2001-10-31 Ciba Spezialitätenchemie Pfersee GmbH Composition pour le prétraitement de matériaux fibreux
WO2013107579A1 (fr) * 2012-01-18 2013-07-25 Henkel Ag & Co. Kgaa Détergent, produit de nettoyage ou agent de prétraitement présentant une force de nettoyage augmentée

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4438009A (en) 1981-08-14 1984-03-20 S. C. Johnson & Son, Inc. Low solvent laundry pre-spotting composition
DE3514364A1 (de) * 1985-04-20 1986-10-23 Henkel KGaA, 4000 Düsseldorf Koerniges waschmittel mit verbessertem reinigungsvermoegen
US4820436A (en) * 1985-06-22 1989-04-11 Henkel Kommanditgesellschaft Auf Aktien Detergents for low laundering temperatures
US4810411A (en) * 1986-04-16 1989-03-07 E. I. Du Pont De Nemours And Company Solvent-based fabric protector
DE3626224A1 (de) * 1986-08-02 1988-02-04 Henkel Kgaa Reinigungsmittel
DE3730179A1 (de) * 1987-09-09 1989-03-23 Henkel Kgaa Verdickte waessrige tensidloesungen, insbesondere fuer deren einsatz auf dem gebiet kosmetischer praeparate
US4954286A (en) * 1988-04-14 1990-09-04 Lever Brothers Company Fabric pretreatment cleaning compositions
DE59303668D1 (de) * 1992-03-12 1996-10-10 Henkel Kgaa Entfettungsmittel
EP0616028A1 (fr) * 1993-03-19 1994-09-21 The Procter & Gamble Company Compositions de nettoyage comprenant des agents tensioactifs non-ioniques à chaînes courtes
US5981455A (en) * 1993-03-19 1999-11-09 The Procter & Gamble Company Cleaning compositions with short chain nonionic surfactants
US5435936A (en) * 1993-09-01 1995-07-25 Colgate Palmolive Co. Nonaqueous liquid microemulsion compositions
US6021926A (en) * 1995-07-13 2000-02-08 The Procter & Gamble Company Packaged foaming composition
DE69531936T2 (de) * 1995-07-13 2004-08-12 The Procter & Gamble Company, Cincinnati Verpackte schäumende Zusammensetzung
US5968202A (en) * 1995-07-13 1999-10-19 The Procter & Gamble Company Method of cleaning textile fabrics
US5925608A (en) * 1995-07-13 1999-07-20 The Procter & Gamble Company Packaged foaming composition
EP0753558A1 (fr) * 1995-07-13 1997-01-15 The Procter & Gamble Company Composition moussante emballée
US20040214737A1 (en) * 2003-04-25 2004-10-28 John Billman Foamy composition for pretreatment of stains on fabrics
WO2007096292A1 (fr) * 2006-02-22 2007-08-30 Basf Se Melange de tensioactifs comprenant des composants a chaine courte et des composants a chaine longue

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1279273B (de) * 1965-03-30 1968-10-03 Henkel & Cie Gmbh Fluessige Fleckenbehandlungskonzentrate zur lokalen Direktbehandlung verschmutzter Textilteile
FR2013197A6 (en) * 1968-07-18 1970-03-27 Henkel & Cie Gmbh Low foaming textile detergents
AU429637B2 (en) * 1970-08-24 1972-10-30 R & C Products Pty Limited An improved method of and preparation forthe removal of soils from textile articles and materials
DE2323605A1 (de) * 1972-03-27 1974-11-21 Minnesota Mining & Mfg Schmutz- und fleckenentfernungsmittel
DE2628480A1 (de) * 1976-06-25 1978-01-05 Oreal Fleckenentfernungsmittel fuer gewebe und ihre herstellung
GB1518676A (en) * 1975-10-30 1978-07-19 Procter & Gamble Ltd Detergent compositions
GB2011944A (en) * 1978-01-09 1979-07-18 Unilever Ltd Liquid nonionic detergent composition

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1617119A1 (de) * 1966-11-18 1971-02-18 Henkel & Cie Gmbh Schaumarmes Fleckenbehandlungsmittel fuer Textilien
US3707506A (en) * 1968-08-19 1972-12-26 Basf Wyandotte Corp Nonionic detergent compositions for cleaning polyester fabrics
US3741902A (en) * 1971-05-24 1973-06-26 Purex Corp Laundry prespotter composition
US3870647A (en) * 1972-06-05 1975-03-11 Seneca Chemicals Inc Liquid cleaning agent
DE2362114C2 (de) * 1973-12-14 1984-07-05 Henkel KGaA, 4000 Düsseldorf Flüssiges schaumreguliertes Wasch- und Reinigungsmittel
US4093417A (en) * 1974-06-01 1978-06-06 Karl Hans Heinlein Method for processing textile material
GB1497747A (en) * 1975-03-04 1978-01-12 Shell Int Research Detergent composition
DE2703998C3 (de) * 1977-02-01 1981-10-01 Henkel KGaA, 4000 Düsseldorf Flüssiges Waschmittelkonzentrat mit geringem Schaumvermögen
US4178262A (en) * 1977-03-23 1979-12-11 Basf Wyandotte Corporation Spotting-agent composition
US4199482A (en) * 1977-03-31 1980-04-22 Colgate-Palmolive Company Laundry pre-spotter composition and method of using same
US4161458A (en) * 1977-08-29 1979-07-17 Scott's Liquid Gold Incorporated Stable aqueous aerosol system with carbon dioxide propellant
GR67588B (fr) * 1978-01-09 1981-08-31 Unilever Nv

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1279273B (de) * 1965-03-30 1968-10-03 Henkel & Cie Gmbh Fluessige Fleckenbehandlungskonzentrate zur lokalen Direktbehandlung verschmutzter Textilteile
FR2013197A6 (en) * 1968-07-18 1970-03-27 Henkel & Cie Gmbh Low foaming textile detergents
AU429637B2 (en) * 1970-08-24 1972-10-30 R & C Products Pty Limited An improved method of and preparation forthe removal of soils from textile articles and materials
DE2323605A1 (de) * 1972-03-27 1974-11-21 Minnesota Mining & Mfg Schmutz- und fleckenentfernungsmittel
GB1518676A (en) * 1975-10-30 1978-07-19 Procter & Gamble Ltd Detergent compositions
DE2628480A1 (de) * 1976-06-25 1978-01-05 Oreal Fleckenentfernungsmittel fuer gewebe und ihre herstellung
GB2011944A (en) * 1978-01-09 1979-07-18 Unilever Ltd Liquid nonionic detergent composition

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0871808A4 (fr) * 1995-11-27 1999-04-28 Procter & Gamble Composition pour traiter des taches sur des textiles a laver et procede de traitement
EP1149945A1 (fr) * 2000-04-29 2001-10-31 Ciba Spezialitätenchemie Pfersee GmbH Composition pour le prétraitement de matériaux fibreux
WO2001083879A1 (fr) * 2000-04-29 2001-11-08 Ciba Spezialitätenchemie Pfersee GmbH Composition pour le pretraitement de materiaux fibreux
WO2013107579A1 (fr) * 2012-01-18 2013-07-25 Henkel Ag & Co. Kgaa Détergent, produit de nettoyage ou agent de prétraitement présentant une force de nettoyage augmentée

Also Published As

Publication number Publication date
EP0026422B1 (fr) 1984-07-25
BR8006289A (pt) 1981-04-07
DE3068694D1 (en) 1984-08-30
ATE8662T1 (de) 1984-08-15
DE2939810A1 (de) 1981-04-16
US4288339A (en) 1981-09-08

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