EP0026422A1 - Agent de nettoyage aérosol pour le traitement des textiles - Google Patents
Agent de nettoyage aérosol pour le traitement des textiles Download PDFInfo
- Publication number
- EP0026422A1 EP0026422A1 EP80105681A EP80105681A EP0026422A1 EP 0026422 A1 EP0026422 A1 EP 0026422A1 EP 80105681 A EP80105681 A EP 80105681A EP 80105681 A EP80105681 A EP 80105681A EP 0026422 A1 EP0026422 A1 EP 0026422A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- weight
- percent
- average
- ethylene glycol
- glycol ether
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004753 textile Substances 0.000 title claims abstract description 12
- 239000007921 spray Substances 0.000 title claims abstract description 7
- 239000012459 cleaning agent Substances 0.000 title claims description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 34
- 239000000203 mixture Substances 0.000 claims abstract description 24
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229920006395 saturated elastomer Polymers 0.000 claims abstract description 17
- 238000009835 boiling Methods 0.000 claims abstract description 7
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 claims abstract description 4
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 claims abstract description 4
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims abstract description 3
- 150000001298 alcohols Chemical class 0.000 claims description 20
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 16
- 239000003795 chemical substances by application Substances 0.000 claims description 16
- 239000004604 Blowing Agent Substances 0.000 claims description 8
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 8
- 239000001569 carbon dioxide Substances 0.000 claims description 8
- 239000002904 solvent Substances 0.000 claims description 6
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 claims description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- 238000007664 blowing Methods 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 3
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 claims description 2
- 229950011008 tetrachloroethylene Drugs 0.000 claims description 2
- 238000005406 washing Methods 0.000 abstract description 8
- 239000003380 propellant Substances 0.000 abstract description 4
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 abstract 2
- VHHHONWQHHHLTI-UHFFFAOYSA-N hexachloroethane Chemical compound ClC(Cl)(Cl)C(Cl)(Cl)Cl VHHHONWQHHHLTI-UHFFFAOYSA-N 0.000 abstract 1
- 239000000443 aerosol Substances 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 239000003599 detergent Substances 0.000 description 4
- 239000000470 constituent Substances 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 239000001993 wax Substances 0.000 description 3
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 2
- 241000282412 Homo Species 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000004519 grease Substances 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 229940055577 oleyl alcohol Drugs 0.000 description 2
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 241000282414 Homo sapiens Species 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000000383 hazardous chemical Substances 0.000 description 1
- 231100000206 health hazard Toxicity 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 235000014666 liquid concentrate Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 231100000956 nontoxicity Toxicity 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- -1 propane or butane Chemical class 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0043—For use with aerosol devices
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
- C11D1/8255—Mixtures of compounds all of which are non-ionic containing a combination of compounds differently alcoxylised or with differently alkylated chains
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
Definitions
- the present invention relates to a cleaning agent which is suitable for the treatment of heavily soiled areas, such as collars and cuffs, of items of laundry which are subsequently washed in the customary manner.
- a cleaning agent which is suitable for the treatment of heavily soiled areas, such as collars and cuffs, of items of laundry which are subsequently washed in the customary manner.
- Such agents enhance the effect of the detergent against stubborn dirt, generally in a so-called “fine linen” at 30 ° to 40 ° C, and carried out at 50 ° to 60 0 C wash for "easy-care textiles" can not be sufficiently removed.
- Corresponding pretreatment agents are known as paste-like or liquid concentrates or as viscous masses shaped into application pens and also as a spray.
- sprayable agents are particularly valued by consumers, since on the one hand they can be conveniently distributed evenly on the soiled areas without the aid of fingers or a spatula and, on the other hand, in the case of coarsely knit textiles, they penetrate into the deeper fibers and consequently on the surface applied application pen are superior in terms of their cleaning effect.
- the alcohols on which the nonionic surfactant constituents listed under (a) to (c) are based can be straight-chain or methyl-branched in the 2-position, saturated or simply olefinically unsaturated. They can be of natural or synthetic origin, for example obtained by ethylene polymerization or oxo synthesis, or they can be present as mixtures of such alcohols.
- the constituent listed under (a) preferably consists of at least 75 percent by weight of an average of 5 to 7 saturated C 8 alcohols containing ethylene glycol ether groups.
- the component listed under (b) is preferably a mixture of two nonionic compounds (b 1 ) and (b 2 ), which are present in a weight ratio of 1: 4 to 4: 1.
- Component (b 1 ) preferably consists of saturated averages of 2 to 4 ethylene glycol ether groups C 12 -C 14 alcohols.
- the component (b 2 ) preferably consists of an average of 2 to 3 ethylene glycol ether groups, saturated or monounsaturated C 16 -C 18 alcohols, the proportion of saturated C 16 -C 18 alcohols not more than 65 percent by weight and in particular not more than Is 50 percent by weight.
- oleyl alcohol can be used as monounsaturated alcohol.
- the component listed under (c) preferably has an average of 11 to 13 ethylene glycol ether groups and is preferably derived from mono-olefinically unsaturated or saturated C 16 -C 18 alcohols or mixtures thereof. If alcohol mixtures are used as the starting base, these can be 50 to 100% saturated and consist, for example, of mixtures of cetyl, stearyl and optionally oleyl alcohol, such as those obtainable from tallow fatty alcohols.
- the component (d) consists of a high-boiling gasoline fraction, which preferably has a boiling range from 205 to 245 ° C. and is present in particular in an amount of 35 to 45 percent by weight, based on the mixture free of blowing agent.
- the amount of the hydrocarbon is such that the agent is non-combustible in interaction with the other components and can therefore be handled safely in the household.
- the lower chlorinated hydrocarbons according to component (s), which can also be present in a mixture, are preferably present in an amount of 20 to 32 percent by weight, based on the propellant-free components.
- the preferred chlorinated hydrocarbon is methylene chloride. The amount of chlorinated hydrocarbons is so limited that there are no health hazards for humans and pets to fear even when accidentally inhaled.
- the selection and the amount of solvents (d) and (e) guarantees that even wax-like impurities, for example those from candle wax, are sufficiently pre-dissolved so that they can be washed out during the subsequent washing treatment.
- the solvents in the selected composition do not lead to the formation of a ring.
- the agents can also contain fragrances, in particular those which mask the inherent odor of the solvents and the detergent ingredients. In general, amounts of 0.1 to 1 percent by weight of perfume oil are sufficient for this.
- Suitable propellants are conventional propellant gases used for the production of aerosols and low-boiling solvents which are gaseous at room temperature.
- blowing agents for example combustible hydrocarbons such as propane or butane, or fluorine-containing blowing agents, which are considered to be of concern for environmental reasons, can be dispensed with.
- Carbon dioxide is preferably used as the blowing agent, with 2 to 3 parts by weight of carbon dioxide accounting for 98 to 97 parts by weight of blowing agent-free components.
- E0 stands for attached ethylene oxide.
- the percentages mean percent by weight.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT80105681T ATE8662T1 (de) | 1979-10-01 | 1980-09-22 | Zur textilbehandlung geeignetes spruehreinigungsmittel. |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19792939810 DE2939810A1 (de) | 1979-10-01 | 1979-10-01 | Zur textilbehandlung geeignetes spruehreinigungsmittel |
| DE2939810 | 1979-10-01 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0026422A1 true EP0026422A1 (fr) | 1981-04-08 |
| EP0026422B1 EP0026422B1 (fr) | 1984-07-25 |
Family
ID=6082421
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP80105681A Expired EP0026422B1 (fr) | 1979-10-01 | 1980-09-22 | Agent de nettoyage aérosol pour le traitement des textiles |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US4288339A (fr) |
| EP (1) | EP0026422B1 (fr) |
| AT (1) | ATE8662T1 (fr) |
| BR (1) | BR8006289A (fr) |
| DE (2) | DE2939810A1 (fr) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0871808A4 (fr) * | 1995-11-27 | 1999-04-28 | Procter & Gamble | Composition pour traiter des taches sur des textiles a laver et procede de traitement |
| EP1149945A1 (fr) * | 2000-04-29 | 2001-10-31 | Ciba Spezialitätenchemie Pfersee GmbH | Composition pour le prétraitement de matériaux fibreux |
| WO2013107579A1 (fr) * | 2012-01-18 | 2013-07-25 | Henkel Ag & Co. Kgaa | Détergent, produit de nettoyage ou agent de prétraitement présentant une force de nettoyage augmentée |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4438009A (en) | 1981-08-14 | 1984-03-20 | S. C. Johnson & Son, Inc. | Low solvent laundry pre-spotting composition |
| DE3514364A1 (de) * | 1985-04-20 | 1986-10-23 | Henkel KGaA, 4000 Düsseldorf | Koerniges waschmittel mit verbessertem reinigungsvermoegen |
| US4820436A (en) * | 1985-06-22 | 1989-04-11 | Henkel Kommanditgesellschaft Auf Aktien | Detergents for low laundering temperatures |
| US4810411A (en) * | 1986-04-16 | 1989-03-07 | E. I. Du Pont De Nemours And Company | Solvent-based fabric protector |
| DE3626224A1 (de) * | 1986-08-02 | 1988-02-04 | Henkel Kgaa | Reinigungsmittel |
| DE3730179A1 (de) * | 1987-09-09 | 1989-03-23 | Henkel Kgaa | Verdickte waessrige tensidloesungen, insbesondere fuer deren einsatz auf dem gebiet kosmetischer praeparate |
| US4954286A (en) * | 1988-04-14 | 1990-09-04 | Lever Brothers Company | Fabric pretreatment cleaning compositions |
| DE59303668D1 (de) * | 1992-03-12 | 1996-10-10 | Henkel Kgaa | Entfettungsmittel |
| EP0616028A1 (fr) * | 1993-03-19 | 1994-09-21 | The Procter & Gamble Company | Compositions de nettoyage comprenant des agents tensioactifs non-ioniques à chaînes courtes |
| US5981455A (en) * | 1993-03-19 | 1999-11-09 | The Procter & Gamble Company | Cleaning compositions with short chain nonionic surfactants |
| US5435936A (en) * | 1993-09-01 | 1995-07-25 | Colgate Palmolive Co. | Nonaqueous liquid microemulsion compositions |
| US6021926A (en) * | 1995-07-13 | 2000-02-08 | The Procter & Gamble Company | Packaged foaming composition |
| DE69531936T2 (de) * | 1995-07-13 | 2004-08-12 | The Procter & Gamble Company, Cincinnati | Verpackte schäumende Zusammensetzung |
| US5968202A (en) * | 1995-07-13 | 1999-10-19 | The Procter & Gamble Company | Method of cleaning textile fabrics |
| US5925608A (en) * | 1995-07-13 | 1999-07-20 | The Procter & Gamble Company | Packaged foaming composition |
| EP0753558A1 (fr) * | 1995-07-13 | 1997-01-15 | The Procter & Gamble Company | Composition moussante emballée |
| US20040214737A1 (en) * | 2003-04-25 | 2004-10-28 | John Billman | Foamy composition for pretreatment of stains on fabrics |
| WO2007096292A1 (fr) * | 2006-02-22 | 2007-08-30 | Basf Se | Melange de tensioactifs comprenant des composants a chaine courte et des composants a chaine longue |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1279273B (de) * | 1965-03-30 | 1968-10-03 | Henkel & Cie Gmbh | Fluessige Fleckenbehandlungskonzentrate zur lokalen Direktbehandlung verschmutzter Textilteile |
| FR2013197A6 (en) * | 1968-07-18 | 1970-03-27 | Henkel & Cie Gmbh | Low foaming textile detergents |
| AU429637B2 (en) * | 1970-08-24 | 1972-10-30 | R & C Products Pty Limited | An improved method of and preparation forthe removal of soils from textile articles and materials |
| DE2323605A1 (de) * | 1972-03-27 | 1974-11-21 | Minnesota Mining & Mfg | Schmutz- und fleckenentfernungsmittel |
| DE2628480A1 (de) * | 1976-06-25 | 1978-01-05 | Oreal | Fleckenentfernungsmittel fuer gewebe und ihre herstellung |
| GB1518676A (en) * | 1975-10-30 | 1978-07-19 | Procter & Gamble Ltd | Detergent compositions |
| GB2011944A (en) * | 1978-01-09 | 1979-07-18 | Unilever Ltd | Liquid nonionic detergent composition |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1617119A1 (de) * | 1966-11-18 | 1971-02-18 | Henkel & Cie Gmbh | Schaumarmes Fleckenbehandlungsmittel fuer Textilien |
| US3707506A (en) * | 1968-08-19 | 1972-12-26 | Basf Wyandotte Corp | Nonionic detergent compositions for cleaning polyester fabrics |
| US3741902A (en) * | 1971-05-24 | 1973-06-26 | Purex Corp | Laundry prespotter composition |
| US3870647A (en) * | 1972-06-05 | 1975-03-11 | Seneca Chemicals Inc | Liquid cleaning agent |
| DE2362114C2 (de) * | 1973-12-14 | 1984-07-05 | Henkel KGaA, 4000 Düsseldorf | Flüssiges schaumreguliertes Wasch- und Reinigungsmittel |
| US4093417A (en) * | 1974-06-01 | 1978-06-06 | Karl Hans Heinlein | Method for processing textile material |
| GB1497747A (en) * | 1975-03-04 | 1978-01-12 | Shell Int Research | Detergent composition |
| DE2703998C3 (de) * | 1977-02-01 | 1981-10-01 | Henkel KGaA, 4000 Düsseldorf | Flüssiges Waschmittelkonzentrat mit geringem Schaumvermögen |
| US4178262A (en) * | 1977-03-23 | 1979-12-11 | Basf Wyandotte Corporation | Spotting-agent composition |
| US4199482A (en) * | 1977-03-31 | 1980-04-22 | Colgate-Palmolive Company | Laundry pre-spotter composition and method of using same |
| US4161458A (en) * | 1977-08-29 | 1979-07-17 | Scott's Liquid Gold Incorporated | Stable aqueous aerosol system with carbon dioxide propellant |
| GR67588B (fr) * | 1978-01-09 | 1981-08-31 | Unilever Nv |
-
1979
- 1979-10-01 DE DE19792939810 patent/DE2939810A1/de not_active Withdrawn
-
1980
- 1980-09-15 US US06/187,521 patent/US4288339A/en not_active Expired - Lifetime
- 1980-09-22 DE DE8080105681T patent/DE3068694D1/de not_active Expired
- 1980-09-22 AT AT80105681T patent/ATE8662T1/de not_active IP Right Cessation
- 1980-09-22 EP EP80105681A patent/EP0026422B1/fr not_active Expired
- 1980-09-30 BR BR8006289A patent/BR8006289A/pt unknown
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1279273B (de) * | 1965-03-30 | 1968-10-03 | Henkel & Cie Gmbh | Fluessige Fleckenbehandlungskonzentrate zur lokalen Direktbehandlung verschmutzter Textilteile |
| FR2013197A6 (en) * | 1968-07-18 | 1970-03-27 | Henkel & Cie Gmbh | Low foaming textile detergents |
| AU429637B2 (en) * | 1970-08-24 | 1972-10-30 | R & C Products Pty Limited | An improved method of and preparation forthe removal of soils from textile articles and materials |
| DE2323605A1 (de) * | 1972-03-27 | 1974-11-21 | Minnesota Mining & Mfg | Schmutz- und fleckenentfernungsmittel |
| GB1518676A (en) * | 1975-10-30 | 1978-07-19 | Procter & Gamble Ltd | Detergent compositions |
| DE2628480A1 (de) * | 1976-06-25 | 1978-01-05 | Oreal | Fleckenentfernungsmittel fuer gewebe und ihre herstellung |
| GB2011944A (en) * | 1978-01-09 | 1979-07-18 | Unilever Ltd | Liquid nonionic detergent composition |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0871808A4 (fr) * | 1995-11-27 | 1999-04-28 | Procter & Gamble | Composition pour traiter des taches sur des textiles a laver et procede de traitement |
| EP1149945A1 (fr) * | 2000-04-29 | 2001-10-31 | Ciba Spezialitätenchemie Pfersee GmbH | Composition pour le prétraitement de matériaux fibreux |
| WO2001083879A1 (fr) * | 2000-04-29 | 2001-11-08 | Ciba Spezialitätenchemie Pfersee GmbH | Composition pour le pretraitement de materiaux fibreux |
| WO2013107579A1 (fr) * | 2012-01-18 | 2013-07-25 | Henkel Ag & Co. Kgaa | Détergent, produit de nettoyage ou agent de prétraitement présentant une force de nettoyage augmentée |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0026422B1 (fr) | 1984-07-25 |
| BR8006289A (pt) | 1981-04-07 |
| DE3068694D1 (en) | 1984-08-30 |
| ATE8662T1 (de) | 1984-08-15 |
| DE2939810A1 (de) | 1981-04-16 |
| US4288339A (en) | 1981-09-08 |
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