EP0030430A1 - Gazéification souterraine de charbon - Google Patents
Gazéification souterraine de charbon Download PDFInfo
- Publication number
- EP0030430A1 EP0030430A1 EP19800304267 EP80304267A EP0030430A1 EP 0030430 A1 EP0030430 A1 EP 0030430A1 EP 19800304267 EP19800304267 EP 19800304267 EP 80304267 A EP80304267 A EP 80304267A EP 0030430 A1 EP0030430 A1 EP 0030430A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- boreholes
- borehole
- coal
- water
- combustion zone
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 239000003245 coal Substances 0.000 title claims abstract description 34
- 238000002309 gasification Methods 0.000 title claims abstract description 17
- 239000007789 gas Substances 0.000 claims abstract description 37
- 238000002485 combustion reaction Methods 0.000 claims abstract description 29
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 27
- 238000000034 method Methods 0.000 claims abstract description 19
- 239000007800 oxidant agent Substances 0.000 claims abstract description 18
- 230000001590 oxidative effect Effects 0.000 claims abstract description 18
- 238000005553 drilling Methods 0.000 claims abstract description 10
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000001301 oxygen Substances 0.000 claims abstract description 7
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 7
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 7
- 238000002347 injection Methods 0.000 claims description 6
- 239000007924 injection Substances 0.000 claims description 6
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 4
- 238000010926 purge Methods 0.000 claims description 4
- 239000001569 carbon dioxide Substances 0.000 claims description 3
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 claims description 3
- 239000002351 wastewater Substances 0.000 claims description 3
- 241000237858 Gastropoda Species 0.000 claims description 2
- 238000004140 cleaning Methods 0.000 claims description 2
- 238000007598 dipping method Methods 0.000 claims description 2
- 239000011269 tar Substances 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000011800 void material Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 239000002802 bituminous coal Substances 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 230000000116 mitigating effect Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000011236 particulate material Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Images
Classifications
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/295—Gasification of minerals, e.g. for producing mixtures of combustible gases
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/16—Enhanced recovery methods for obtaining hydrocarbons
- E21B43/24—Enhanced recovery methods for obtaining hydrocarbons using heat, e.g. steam injection
- E21B43/243—Combustion in situ
- E21B43/247—Combustion in situ in association with fracturing processes or crevice forming processes
Definitions
- This invention relates to the underground gasification of coal and particularly to a method of gasifying coal which improves the efficiency and yield of the gasifying operation.
- Gasification is a method of partially burning coal underground under conditions such as to generate combustible gas (usually a mixture of CO, H 2 , CH 4 CO 2 and N 2 ).
- the raw coal behind the burning face is heated by conduction from the face; water vapour, tars and rich gas are discharged through the hot surfaces by which they may be partly cracked to hydrogen and carbon monoxide before mixing with the reacting gas stream.
- the combustion and gasification zones move forward into the virgin coal, "mining" the coal.
- boreholes have been drilled along the lower part of a seam, linked by various means at one end where air is introduced; gas is recovered from vertical boreholes intersecting the "in seam" holes.
- a real problem with this method is that eventually the unsupported roof of the void thus created, will cave in, blocking the passage of air to the burning face. At depths greater than about 600 metres subsidence of the ground above the cavity may completely seal the cavity.
- a method for the underground gasification of coal seams which comprises drilling two boreholes into and along the seam and linking the boreholes at one end, passing an oxidant blast of air or oxygen along one of the boreholes from the unlinked end and recovering gas from the other borehole at its unlinked end, and injecting water either continuously ⁇ or intermittently into said one borehole so as to minimise the combustion of coal within the borehole and to control the position of the combustion zone.
- boreholes may be arranged in pairs, respectively carrying oxidant blast and produced gas; alternatively boreholes may be provided in trios, oxidant being passed along one and gas recovered from the remaining two boreholes.
- Other arrangements may also be envisaged according to the size and character of the coal seam.
- the ratio of oxidant to gas boreholes is from 1:1 to 1:5.
- the role of the various boreholes may be reversed periodically, the oxidant blast channels being switched to conduct the gas produced and oxidant being forced down the previous gas-conducting channel.
- the boreholes may be drilled from an underground heading or by deviation drilling frcm the surface.
- the boreholes may be drilled from the surface along the base of the seam.
- control water injection may be introduced continuously, preferably some is injected as an intermittent "slug" of water in an amount computer from the extent of combustion which has taken place in the system, the blast rate and the temperature and analysis of the gas produced, in order to reduce the "burning back" effect.
- Waste water from the gas cleaning system used to clean the gas produced may be used as the control water.
- the control water may contain surplus tar byproduct, if desired. Thus dirty water may be used since the control water passes to the combustion zone.
- the water injection system eliminates the need for a large steam generator, which is very costly for high pressure operation.
- the system also permits re-injection to the combustion zone of particulate material recovered from the product gas.
- Carbon dioxide, water and/or additional oxidant may be introduced through vertical or other boreholes in the burned out zone in order to recover heat from the previously burned-out region and to purge that zone of combustible gases.
- the number, size and location of the boreholes is a matter which is determined by the size and character of the coal seam being worked, and by the operating pressure.
- the blast rate will depend upon the coal and seam properties and the pressure, but these are matters which can be readily and routinely optimised for any given coal seam by experiment.
- the linking of the boreholes at the intended initial combustion zone can be achieved in a number of ways, the preferred method again depending to some extent upon the character of the coal.
- linkage between boreholes may be achieved by air or oxygen injection, water injection, electrically or by drilling.
- Figure 1 shows air A being passed from the ground surface down through an oxidant borehole 1 to a coal seam 5 having a combustion zone 6.
- Combustible gas produced by partial combustion of coal passes along gasification bore 7 and is withdrawn along gas borehole 2.
- Reference numeral 3 indicates an initial oxidant blast borehole which has now been superseded as the combustion zone moves forward, and a further blast borehole 4 which will come into use when the combustion zone reaches it. In this way, the coal seam is progressively burnt out, usually at the rate of a few meters a day.
- the gasification bores 7 have been drilled horizontally from a heading 14 shown in dashed lines.
- the heading formed the initial ignition and blast zone.
- Figure 3 shows a first embodiment of the invention.
- a series of parallel boreholes 8, 9, 10 are drilled in the base of the coal seam 5 by drilling from a heading as before, cr by deviation drilling from the ground surface.
- the borehole 8 transmits blast air to the combustion zone 6 and boreholes 9 and 10 recover combustible gas from the combustion zone.
- Auxiliary gas if required, is introduced via a vertical bore hole 12 into the burnt out region 13 behind the combustion zone.
- coal there is a tendency for coal to burn backwards along the air blast borehole 8, rather than burning between the borehole 8 and the adjacent gas boreholes 9 and 10. This tendency is reduced by injecting water and/or steam into the borehole 8 along with air blast.
- the water may be injected continuously or intermittently.
- oxygen employed instead of air, water may be injected continuously with intermittent additions of slugs of water.
- This embodiment is particularly suitable for coals which shrink on drying (lower-rank coals).
- Figure 4 shows a similar arrangement to Figure 3 wherein the role of the parallel boreholes 8, 9 and 10 is cyclically varied according to arrangements 1, 2 and 3.
- Each borehole is fitted at the surface with a valve (not shown) to permit the connection of the borehole to either air, product gas, control water or to a purge mains for purging.
- the control water system may be combined with a conventional water quenching or washing system used to treat the gas exiting from the gas borehole.
- a conventional water quenching or washing system used to treat the gas exiting from the gas borehole.
- each borehole is used alternatively for air blast and for gas production.
- This embodiment allows any burn back which may occur on the air blast borehole to be equalised by switching the air blast between the various boreholes.
- Figure 5 shows a third embodiment wherein the linking of adjacent boreholes is achieved by drilling along the seam angled boreholes 11 which intersect. in the desired combustion zone 6. As before, air A is introduced along one borehole and gas G is recovered along the other borehole. This technique removes the need to create linking channels between the various bores before combustion is initiated, and may be particularly advantageous for deep seam operation.
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Geology (AREA)
- Mining & Mineral Resources (AREA)
- Physics & Mathematics (AREA)
- Environmental & Geological Engineering (AREA)
- Fluid Mechanics (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Air Supply (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AUPE150879 | 1979-11-28 | ||
| AU1508/79 | 1979-11-28 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP0030430A1 true EP0030430A1 (fr) | 1981-06-17 |
Family
ID=3768364
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP19800304267 Ceased EP0030430A1 (fr) | 1979-11-28 | 1980-11-27 | Gazéification souterraine de charbon |
Country Status (1)
| Country | Link |
|---|---|
| EP (1) | EP0030430A1 (fr) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0073576A1 (fr) * | 1981-08-18 | 1983-03-09 | Miron Tuval | Méthode de génération souterraine de chaleur |
| WO1996028638A1 (fr) * | 1995-03-15 | 1996-09-19 | Zhaoxi Chai | Procede de gazeification in situ du charbon |
| WO1999063200A1 (fr) * | 1998-05-29 | 1999-12-09 | Zhaoxi Chai | Mine de charbon produisant du gaz de houille a partir d'un gisement et procede de production de gaz de houille |
| RU2424429C1 (ru) * | 2009-12-02 | 2011-07-20 | Институт горного дела Севера им. Н.В. Черского Сибирского отделения Российской академии наук | Способ подземной газификации угля |
| CN103758501A (zh) * | 2014-01-28 | 2014-04-30 | 新奥气化采煤有限公司 | 煤炭地下气化方法 |
| CN115247552A (zh) * | 2021-04-27 | 2022-10-28 | 中国石油天然气集团有限公司 | 煤炭地下气化井筒的密封方法 |
| WO2023208248A1 (fr) * | 2022-10-17 | 2023-11-02 | 安徽理工大学 | Système de test et procédé de mesure de l'efficacité de gazéification souterraine de charbon |
| CN117823112A (zh) * | 2024-03-06 | 2024-04-05 | 太原理工大学 | 一种原位煤体超临界水气化制氢异层开采方法及装置 |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3196945A (en) * | 1962-10-08 | 1965-07-27 | Pan American Petroleum Company | Method of forward in situ combustion with water injection |
| US3221811A (en) * | 1963-03-11 | 1965-12-07 | Shell Oil Co | Mobile in-situ heating of formations |
| US4026357A (en) * | 1974-06-26 | 1977-05-31 | Texaco Exploration Canada Ltd. | In situ gasification of solid hydrocarbon materials in a subterranean formation |
| US4083402A (en) * | 1975-04-02 | 1978-04-11 | Roza Ivanovna Antonova | Method of underground gasification of a coal bed |
| FR2396792A1 (fr) * | 1977-07-06 | 1979-02-02 | Wenzel Werner | Procede et dispositif pour la gazeification souterraine de charbon |
| GB2004297A (en) * | 1977-09-16 | 1979-03-28 | Grupping Arnold | Underground gasification of coal |
-
1980
- 1980-11-27 EP EP19800304267 patent/EP0030430A1/fr not_active Ceased
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3196945A (en) * | 1962-10-08 | 1965-07-27 | Pan American Petroleum Company | Method of forward in situ combustion with water injection |
| US3221811A (en) * | 1963-03-11 | 1965-12-07 | Shell Oil Co | Mobile in-situ heating of formations |
| US4026357A (en) * | 1974-06-26 | 1977-05-31 | Texaco Exploration Canada Ltd. | In situ gasification of solid hydrocarbon materials in a subterranean formation |
| US4083402A (en) * | 1975-04-02 | 1978-04-11 | Roza Ivanovna Antonova | Method of underground gasification of a coal bed |
| FR2396792A1 (fr) * | 1977-07-06 | 1979-02-02 | Wenzel Werner | Procede et dispositif pour la gazeification souterraine de charbon |
| GB2004297A (en) * | 1977-09-16 | 1979-03-28 | Grupping Arnold | Underground gasification of coal |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0073576A1 (fr) * | 1981-08-18 | 1983-03-09 | Miron Tuval | Méthode de génération souterraine de chaleur |
| WO1996028638A1 (fr) * | 1995-03-15 | 1996-09-19 | Zhaoxi Chai | Procede de gazeification in situ du charbon |
| WO1999063200A1 (fr) * | 1998-05-29 | 1999-12-09 | Zhaoxi Chai | Mine de charbon produisant du gaz de houille a partir d'un gisement et procede de production de gaz de houille |
| RU2424429C1 (ru) * | 2009-12-02 | 2011-07-20 | Институт горного дела Севера им. Н.В. Черского Сибирского отделения Российской академии наук | Способ подземной газификации угля |
| CN103758501A (zh) * | 2014-01-28 | 2014-04-30 | 新奥气化采煤有限公司 | 煤炭地下气化方法 |
| CN103758501B (zh) * | 2014-01-28 | 2017-01-11 | 新奥气化采煤有限公司 | 煤炭地下气化方法 |
| CN115247552A (zh) * | 2021-04-27 | 2022-10-28 | 中国石油天然气集团有限公司 | 煤炭地下气化井筒的密封方法 |
| WO2023208248A1 (fr) * | 2022-10-17 | 2023-11-02 | 安徽理工大学 | Système de test et procédé de mesure de l'efficacité de gazéification souterraine de charbon |
| CN117823112A (zh) * | 2024-03-06 | 2024-04-05 | 太原理工大学 | 一种原位煤体超临界水气化制氢异层开采方法及装置 |
| CN117823112B (zh) * | 2024-03-06 | 2024-04-30 | 太原理工大学 | 一种原位煤体超临界水气化制氢异层开采方法及装置 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
| AK | Designated contracting states |
Designated state(s): BE DE FR GB NL |
|
| 17P | Request for examination filed |
Effective date: 19811125 |
|
| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION HAS BEEN REFUSED |
|
| 18R | Application refused |
Effective date: 19840605 |
|
| RIN1 | Information on inventor provided before grant (corrected) |
Inventor name: STEWART, IAN MCCOLL |