EP0045457A1 - Procédé de teinture en continu ou en semi-continu de matières constituées de fibres cellulosiques, tricotées sur métiers circulaires, utilisant des colorants de développement azoiques - Google Patents
Procédé de teinture en continu ou en semi-continu de matières constituées de fibres cellulosiques, tricotées sur métiers circulaires, utilisant des colorants de développement azoiques Download PDFInfo
- Publication number
- EP0045457A1 EP0045457A1 EP81105850A EP81105850A EP0045457A1 EP 0045457 A1 EP0045457 A1 EP 0045457A1 EP 81105850 A EP81105850 A EP 81105850A EP 81105850 A EP81105850 A EP 81105850A EP 0045457 A1 EP0045457 A1 EP 0045457A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- liquor
- acrylic acid
- acid amide
- wet
- padding
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000975 dye Substances 0.000 title claims abstract description 23
- 238000004043 dyeing Methods 0.000 title claims abstract description 18
- 238000009940 knitting Methods 0.000 title 2
- 238000010924 continuous production Methods 0.000 title 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims abstract description 29
- 238000000034 method Methods 0.000 claims abstract description 28
- 230000008878 coupling Effects 0.000 claims abstract description 25
- 238000010168 coupling process Methods 0.000 claims abstract description 25
- 238000005859 coupling reaction Methods 0.000 claims abstract description 25
- 238000011161 development Methods 0.000 claims abstract description 18
- 239000004744 fabric Substances 0.000 claims abstract description 17
- 229920001577 copolymer Polymers 0.000 claims abstract description 15
- 230000008569 process Effects 0.000 claims abstract description 15
- 239000000080 wetting agent Substances 0.000 claims abstract description 14
- 230000037452 priming Effects 0.000 claims abstract description 10
- 239000000835 fiber Substances 0.000 claims abstract description 8
- 239000000987 azo dye Substances 0.000 claims abstract description 5
- 229920000642 polymer Polymers 0.000 claims description 20
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 claims description 15
- 239000002253 acid Substances 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 11
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 claims description 8
- 230000002378 acidificating effect Effects 0.000 claims description 5
- 150000001412 amines Chemical class 0.000 claims description 4
- 125000000129 anionic group Chemical group 0.000 claims description 4
- 150000002191 fatty alcohols Chemical class 0.000 claims description 4
- 230000004048 modification Effects 0.000 claims description 4
- 238000012986 modification Methods 0.000 claims description 4
- 235000010288 sodium nitrite Nutrition 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 4
- 229920003043 Cellulose fiber Polymers 0.000 claims description 3
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 claims description 3
- PNLUGRYDUHRLOF-UHFFFAOYSA-N n-ethenyl-n-methylacetamide Chemical compound C=CN(C)C(C)=O PNLUGRYDUHRLOF-UHFFFAOYSA-N 0.000 claims description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 150000002170 ethers Chemical class 0.000 claims description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 2
- 239000011976 maleic acid Substances 0.000 claims description 2
- 229920000151 polyglycol Polymers 0.000 claims description 2
- 239000010695 polyglycol Substances 0.000 claims description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 2
- 238000011437 continuous method Methods 0.000 claims 1
- 229920002401 polyacrylamide Polymers 0.000 claims 1
- 239000004753 textile Substances 0.000 abstract description 21
- 238000010521 absorption reaction Methods 0.000 abstract description 19
- 238000001035 drying Methods 0.000 abstract description 6
- 230000015572 biosynthetic process Effects 0.000 abstract description 5
- 238000010014 continuous dyeing Methods 0.000 abstract description 2
- 230000035515 penetration Effects 0.000 abstract description 2
- 229920002678 cellulose Polymers 0.000 abstract 1
- 239000001913 cellulose Substances 0.000 abstract 1
- 239000002657 fibrous material Substances 0.000 abstract 1
- 229920001519 homopolymer Polymers 0.000 abstract 1
- 239000000463 material Substances 0.000 description 15
- 229920000742 Cotton Polymers 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 150000001989 diazonium salts Chemical class 0.000 description 5
- 239000007864 aqueous solution Substances 0.000 description 4
- 239000011230 binding agent Substances 0.000 description 3
- 239000003513 alkali Substances 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 238000006193 diazotization reaction Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000006386 neutralization reaction Methods 0.000 description 2
- ZPFAVCIQZKRBGF-UHFFFAOYSA-N 1,3,2-dioxathiolane 2,2-dioxide Chemical compound O=S1(=O)OCCO1 ZPFAVCIQZKRBGF-UHFFFAOYSA-N 0.000 description 1
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 1
- 244000046052 Phaseolus vulgaris Species 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- POJOORKDYOPQLS-UHFFFAOYSA-L barium(2+) 5-chloro-2-[(2-hydroxynaphthalen-1-yl)diazenyl]-4-methylbenzenesulfonate Chemical compound [Ba+2].C1=C(Cl)C(C)=CC(N=NC=2C3=CC=CC=C3C=CC=2O)=C1S([O-])(=O)=O.C1=C(Cl)C(C)=CC(N=NC=2C3=CC=CC=C3C=CC=2O)=C1S([O-])(=O)=O POJOORKDYOPQLS-UHFFFAOYSA-L 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 235000015111 chews Nutrition 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000000986 disperse dye Substances 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- SWGJCIMEBVHMTA-UHFFFAOYSA-K trisodium;6-oxido-4-sulfo-5-[(4-sulfonatonaphthalen-1-yl)diazenyl]naphthalene-2-sulfonate Chemical compound [Na+].[Na+].[Na+].C1=CC=C2C(N=NC3=C4C(=CC(=CC4=CC=C3O)S([O-])(=O)=O)S([O-])(=O)=O)=CC=C(S([O-])(=O)=O)C2=C1 SWGJCIMEBVHMTA-UHFFFAOYSA-K 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- D06P1/525—Polymers of unsaturated carboxylic acids or functional derivatives thereof
- D06P1/5257—(Meth)acrylic acid
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/58—Material containing hydroxyl groups
- D06P3/60—Natural or regenerated cellulose
- D06P3/68—Preparing azo dyes on the material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
- Y10S8/916—Natural fiber dyeing
- Y10S8/918—Cellulose textile
Definitions
- the described invention as hereinafter relates to the uniform dyeing present in tubular form Rundstuhl- knitwear of cellulose fibers, especially cotton, with generated on the fiber water-insoluble azo dyestuffs according to a continuous or semi-continuous M ethosulfate de, wherein the primer by Vorklotzen with a coupling component under alkaline conditions and the subsequent dye development is carried out wet-on-wet by padding with a diazo component in the presence of acid or acid-providing substances.
- a stabilized but non-coupling-capable diazo component is simultaneously applied to the textile material as part of the priming block. Thereafter, wet-in-wet padding with acid causes the release of the diazonium compound together with the dye coupling.
- this process can only be carried out on non-voluminous, smooth textile webs, because in the case of voluminous textiles, the neutralization of the alkaline primer inside the product proceeds faster than the formation of the coupling-capable diazonium compound, which ultimately gives the picture of poor coloration due to uneven dye coupling between the outside of the product and Inside the goods.
- the concentration of alkali binders to adjust the low clutch pH range is again so high that takes place during the first contact of the primed, alkaline goods with the developing liquor a local "over neutralization" and the already on g around the higher Density of the slower coupling of the dye additionally disrupts.
- the object of the present invention was therefore to eliminate the disadvantages described above in the two-bath dyeing of round chair knitted fabrics in tubular form wet-on-wet with the components for forming azo dyes on the fiber.
- the main problem here was by which means or in which way a higher liquor absorption by the textile material can be achieved in the second padding with the diazo component or only with acid.
- the polymers of acrylic acid amide used or their copolymers with the other monomers mentioned above under a) to e) have a molecular weight of 1.0 ⁇ 10 6 to 2.5'106, preferably 1.5 ⁇ 10 6 to 2 , 0 ⁇ 10 6 .
- padding with the priming liquor results in a liquor absorption of 70 to 120% (on the weight of the dry goods) ) and - what that bean
- the above-mentioned process made it possible - in the second padding with the development fleet, fleet intake values of an additional 90 to 130% by weight, ie in the end a total liquor intake of 180 to 250% by weight when padding twice. This is the only way to dissolve the necessary amount of diazo component in this additional amount of liquor.
- the alkaline binder concentration is brought to normal levels in this way, thereby not affecting the coupling conditions more ver - is ursacht.
- the wetting agent in turn causes a rapid, uniform penetration of the fabric hose with both padding liquors and thus contributes to the good and, above all, uniform coloring of the same.
- the increased absorption of the liquor also means that irregularities which the textile material exhibits immediately after leaving the foulard are compensated for by diffusion, so that there is no marking of the squeezed edges of the knitted tube. Another deficiency that has occurred in previous attempts is also eliminated.
- the use of the padding aids according to the method according to the invention makes it possible for the first time to dye even bulky tubular material with the components for forming water-insoluble azo dyes on the fiber properly and without intermediate drying. This means technical progress, because until now it was only possible to apply developing dyes in a wet-on-wet process on smooth and thin goods. Apart from the fact that the new process does not offer any advantage on this type of smooth product, it is surprising that the higher liquor uptake required by the invention cannot be achieved there either by adding the acrylic acid amide polymers and the wetting agent.
- the chemical compounds listed in the Color Index, 3rd edition 1971, which are customary for producing developing dyes are suitable as “Azoic Coupling Component” (coupling component) and as “Azoic Diazo Component” (diazo component).
- Some of the polymerization products of acrylic acid amide used according to the invention are known (DE-OS 2 542 051, CASSELLA AKTIENGESELLSCHAFT), but they are used for a completely different purpose, namely to suppress the "frosting effect" when dyeing polyester fibers with disperse dyes.
- a modification of the claimed process offers the following procedure, the textile material in the first padding process consisting of an alkaline liquor, which at the same time forms the coupling component together with a non-coupling-capable diazo component, either in the form of a diazonium compound which is not coupling-capable under the above conditions or in the form of a suitably prepared (finely dispersed or dissolved in organic solvents), diazotizable amine with the sodium nitrite necessary for diazotization, in addition to the auxiliary mixture according to the invention, is pre-padded for priming, after which only the acid which triggers the coupling or the diazotization and coupling is added in the second padding process applies to the goods together with the polyacrylic acid amide / wetting agent combination.
- This modified method can be further modified by applying the coupling component and sodium nitrite together with the auxiliary mixture in the first padding process and then in the second phase by dipping a diazotizable amine, acid and the auxiliary mixture to develop the dye.
- the primer is padded wet-on-wet at 20 ° C. using an aqueous liquor containing:
- liquor images of 90% are obtained with the first padding and only 20% with the second padding, and an irregular, partially not completely colored, i.e. in places still white, goods hose.
- concentration of the diazonium compound to 270 g / l, as would be necessary with an additional liquor uptake of only 20%, fails because of the insufficient solubility thereof.
- the primer thus prepared is padded wet-on-wet on the padder with an aqueous liquor at 80 ° C. containing:
- Cotton interlock goods should be bleached and dyed at the same time. To do this, block the fabric hose on the foulard with a liquor absorption of 100% with an aqueous block liquor at 20 ° C containing:
- the primer prepared in this way is rolled up for 1 hour and then padded with an aqueous liquor at 80 ° C., which contains the following additives, without intermediate drying on the padder:
- the goods are then rolled up again and held for 3 hours at 85 ° C. for dye coupling.
- the additional liquor absorption in the second padding is 100%, so that the goods hose now contains 200% "moisture.
- the dyeing is rinsed and post-treated as usual. A shell-free, brilliantly red-colored goods tube is obtained; Color and levelness are flawless.
- the second stage of the treatment of the fabric tube can also be carried out continuously with a similar result, by steaming at 103 ° C. for 3 minutes instead of staying for three hours to complete the dye development.
- 250 kg of raw cotton interlock fabric are to be dyed in the form of a tube.
- the textile material is placed on the padder with a liquor containing an aqueous solution of: shows, cold (20 ° C) padded with a liquor absorption of 120% and this primer is then rolled up for 1 hour.
- the dye formation is now obtained by padding the wet fabric hose on the padder with an aqueous liquor: at 20 ° C and an additional liquor intake of 100% (the total liquor intake is therefore 220%) and completed by an air passage of 20 seconds and a hot water passage at 80 ° C.
- the dye formation is then ver by an air passage of 60 seconds and a hot water passage at 80 ° C. completed. After the usual post-treatment of the dyeing, a dull red interlock tube of any color is obtained with good coloration.
- the pad liquor for priming contains as an aqueous solution:
- the liquor absorption of the hose in this second block is 90%. Now there is an air passage of 40 seconds and a hot water passage at 80 ° C to complete the dye coupling.
- This dyeing is then aftertreated, as is usual with dyeings with development dyes. In this way, a brilliant orange-colored product hose is obtained; Equality and color are good.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Coloring (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE3028844 | 1980-07-30 | ||
| DE19803028844 DE3028844A1 (de) | 1980-07-30 | 1980-07-30 | Verfahren zum kontinuierlichen oder halbkontinuierlichen faerben von rundstuhl-wirkwaren aus cellulosefasern mit azo-entwicklungsfarbstoffen |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0045457A1 true EP0045457A1 (fr) | 1982-02-10 |
| EP0045457B1 EP0045457B1 (fr) | 1984-11-14 |
Family
ID=6108448
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP81105850A Expired EP0045457B1 (fr) | 1980-07-30 | 1981-07-24 | Procédé de teinture en continu ou en semi-continu de matières constituées de fibres cellulosiques, tricotées sur métiers circulaires, utilisant des colorants de développement azoiques |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US4420309A (fr) |
| EP (1) | EP0045457B1 (fr) |
| JP (1) | JPS5751882A (fr) |
| DE (2) | DE3028844A1 (fr) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0109609A1 (fr) * | 1982-11-13 | 1984-05-30 | Hoechst Aktiengesellschaft | Procédé de teinture égale de tissus tubulaires tricotés constitués de fibres cellulosiques avec des colorants azoiques insolubles dans l'eau produits sur la fibre |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR66672E (fr) * | 1953-07-15 | 1957-08-16 | Basf Ag | Produits auxiliaires pour textiles et pour la teinture |
| JPS5188480A (en) * | 1975-01-07 | 1976-08-03 | Jukibutsuganjuekino shorihoho | |
| JPS5238175A (en) * | 1975-09-20 | 1977-03-24 | Matsushita Electric Works Ltd | Magnetic sensing switch |
| DE2542051A1 (de) * | 1975-09-20 | 1977-03-31 | Cassella Farbwerke Mainkur Ag | Verfahren zum kontinuierlichen faerben von polyestermischgeweben |
| CH594727A5 (en) * | 1976-04-08 | 1978-01-31 | Rohner Ag | Stable printing ink or concentrate for transfer printing |
| DE2836289A1 (de) * | 1977-08-19 | 1979-03-01 | Allied Colloids Ltd | Verdickungsmittel fuer teppich-siebdruckpasten |
| DE2738497A1 (de) * | 1977-08-26 | 1979-03-01 | Pfersee Chem Fab | Verwendung von wasserloeslichen polymeren als migrationsinhibitoren |
| DE2815511A1 (de) * | 1978-04-10 | 1979-10-18 | Cassella Ag | Verfahren zum faerben und bedrucken von textilmaterialien aus zellulose/polyesterfaser-mischungen |
| EP0019188A1 (fr) * | 1979-05-09 | 1980-11-26 | Hoechst Aktiengesellschaft | Procédé de teinture par foulardage de matières textiles cellulosiques en forme de bandes |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3957427A (en) * | 1973-12-03 | 1976-05-18 | Gaf Corporation | Control of dye migration by treating textile with aqueous dye bath containing an amide derivative of polyvinyl methyl ether/maleic anhydride |
| NL7610147A (nl) * | 1975-09-18 | 1977-03-22 | Cassella Farbwerke Mainkur Ag | Werkwijze ter bereiding van in koud water oplosbare copolymeren. |
| DE2709623C2 (de) * | 1977-03-05 | 1986-02-20 | Hoechst Ag, 6230 Frankfurt | Verfahren zur Erzeugung von wasserunlöslichen Azofarbstoffen auf der Faser |
| DE2808909C2 (de) | 1978-03-02 | 1980-05-08 | Hoechst Ag, 6000 Frankfurt | Verfahren zum einbadigen Färben von strangförmigen Textilmaterialien aus Cellulosefasern auf Haspelkufen oder Jet-Färbeanlagen mit auf der Faser erzeugten wasserunlöslichen Azofarbstoffen |
-
1980
- 1980-07-30 DE DE19803028844 patent/DE3028844A1/de not_active Withdrawn
-
1981
- 1981-07-24 DE DE8181105850T patent/DE3167191D1/de not_active Expired
- 1981-07-24 EP EP81105850A patent/EP0045457B1/fr not_active Expired
- 1981-07-29 JP JP56117876A patent/JPS5751882A/ja active Pending
-
1982
- 1982-07-22 US US06/401,015 patent/US4420309A/en not_active Expired - Fee Related
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR66672E (fr) * | 1953-07-15 | 1957-08-16 | Basf Ag | Produits auxiliaires pour textiles et pour la teinture |
| JPS5188480A (en) * | 1975-01-07 | 1976-08-03 | Jukibutsuganjuekino shorihoho | |
| JPS5238175A (en) * | 1975-09-20 | 1977-03-24 | Matsushita Electric Works Ltd | Magnetic sensing switch |
| DE2542051A1 (de) * | 1975-09-20 | 1977-03-31 | Cassella Farbwerke Mainkur Ag | Verfahren zum kontinuierlichen faerben von polyestermischgeweben |
| CH594727A5 (en) * | 1976-04-08 | 1978-01-31 | Rohner Ag | Stable printing ink or concentrate for transfer printing |
| DE2836289A1 (de) * | 1977-08-19 | 1979-03-01 | Allied Colloids Ltd | Verdickungsmittel fuer teppich-siebdruckpasten |
| DE2738497A1 (de) * | 1977-08-26 | 1979-03-01 | Pfersee Chem Fab | Verwendung von wasserloeslichen polymeren als migrationsinhibitoren |
| DE2815511A1 (de) * | 1978-04-10 | 1979-10-18 | Cassella Ag | Verfahren zum faerben und bedrucken von textilmaterialien aus zellulose/polyesterfaser-mischungen |
| EP0019188A1 (fr) * | 1979-05-09 | 1980-11-26 | Hoechst Aktiengesellschaft | Procédé de teinture par foulardage de matières textiles cellulosiques en forme de bandes |
Non-Patent Citations (2)
| Title |
|---|
| CHEMICAL ABSTRACTS, Band 83, Nr. 16, 20. Oktober 1975, seite 96, Nr. 133261w Columbus, Ohio, U.S.A. & JP - A - 75 52381 (Shikishima Spinning Co., Ltd.) 09-05-1975 * Zusammenfassung * * |
| CHEMICAL ABSTRACTS, Band 93, Nr. 8, August 1980, Seite 96, Nr. 73688k Columbus, Ohio, U.S.A. & JP - A - 80 51884 (Fukui, Kiyoshi) 15-04-1980 * Zusammenfassung * * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0109609A1 (fr) * | 1982-11-13 | 1984-05-30 | Hoechst Aktiengesellschaft | Procédé de teinture égale de tissus tubulaires tricotés constitués de fibres cellulosiques avec des colorants azoiques insolubles dans l'eau produits sur la fibre |
Also Published As
| Publication number | Publication date |
|---|---|
| DE3028844A1 (de) | 1982-02-25 |
| DE3167191D1 (en) | 1984-12-20 |
| JPS5751882A (en) | 1982-03-26 |
| US4420309A (en) | 1983-12-13 |
| EP0045457B1 (fr) | 1984-11-14 |
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