Classifications

• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M173/00—Lubricating compositions containing more than 10% water
  • C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
  • C10M2201/02—Water
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
  • C10M2205/18—Natural waxes, e.g. ceresin, ozocerite, bees wax, carnauba; Degras
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
  • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
  • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
  • C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
  • C10M2215/08—Amides [having hydrocarbon substituents containing less than thirty carbon atoms]
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
  • C10M2215/08—Amides [having hydrocarbon substituents containing less than thirty carbon atoms]
  • C10M2215/082—Amides [having hydrocarbon substituents containing less than thirty carbon atoms] containing hydroxyl groups; Alkoxylated derivatives
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
  • C10M2215/24—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions having hydrocarbon substituents containing thirty or more carbon atoms, e.g. nitrogen derivatives of substituted succinic acid
  • C10M2215/28—Amides; Imides
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
  • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
  • C10N2050/01—Emulsions, colloids, or micelles
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
  • C10N2070/00—Specific manufacturing methods for lubricant compositions
  • C10N2070/02—Concentrating of additives

Definitions

• Drilling, cutting and grinding emulsions are generally used for cooling saws, grinding machines, drilling machines and the like, in order to dissipate the heat occurring during the machining of workpieces and, as a result, increased wear on the tools, which occurs with excessive Avoid heating the same.
• So far so-called drilling oils have been used for this purpose, which were essentially water-solubilized mineral oils.
• the water solubility of the mineral oils is usually achieved by adding sodium hydroxide solution to a mixture of resin oil, olein or the like until the end product can be smoothly emulsified with water.
• sulfide leachate, tar oils and waste oils are also used, which are made water-soluble essentially using the same process.
• Such products are often mixed with disinfectant and rust-preventing components such as nitrite, chromium compounds or other substances.
• drilling oils are not biodegradable according to the prior art.
• the object is achieved according to the invention by a process in which a mixture of about 3 to 45% by weight of natural wax (s) of animal and / or vegetable origin, 0.1 to 0.45% by weight of a commercially available emulsifier, the rest about 50% by weight of water, about 37.5% by weight of di-ethanolamine (s) and about 12.5% by weight of tri-ethanolamine (s) aqueous di / tri-ethanol mixture , then the mixture is brought to a boil with stirring, after dissolution of the wax fraction is cooled to a reaction temperature with stirring and then, after amination of the wax fraction by the di / tri-ethanol mixture, it is cooled down to the use temperature.
• a mixture of about 3 to 45% by weight of natural wax (s) of animal and / or vegetable origin, 0.1 to 0.45% by weight of a commercially available emulsifier, the rest about 50% by weight of water, about 37.5% by weight of di-ethanolamine (s) and about 12.5% by weight of tri-ethanolamine (s)
• the cooling emulsion according to the invention also has better properties than previously known emulsions in its mode of action as drilling oil.
• the drilling, cutting and grinding emulsions have an above-average heat dissipation, so that a rapid cooling of the work place by heat dissipation to the total coolant in the reservoir causes.
• the cut surfaces in cast iron have smoother cut surfaces when using the cutting emulsion according to the invention than could previously be achieved with conventional ones, surprisingly less wear on the tools being observed. This could also be due to the excellent sliding properties of the emulsion according to the invention, since even when used in machine tools, the smooth running can improve the operation compared to that with known drilling oils.
• the emulsion according to the invention is anticorrosive and does not lead to the occurrence of oxidation in the processed objects.
• Another advantage of the drilling, cutting and grinding emulsions according to the invention is that they are completely biodegradable and therefore the previously necessary collection and destruction of the used drilling oils in a flaring system is no longer necessary. Instead, used drilling emulsions can simply be discharged into the sewage systems, in which they can be processed without affecting the receiving water of sewage systems.
• Organic and / or vegetable waxes preferably from plants of the Copernicia genus with an addition of a commercially available emulsifier, preferably a nonionic, are usually processed in the process according to the invention.
• About 1 to 3 parts by weight are used per 10 to 15 parts by weight of wax.
• 41 parts by weight of a di / tri-ethanol mixture and an anticorrosive metal-wetting disinfectant with bactericidal and fungicidal properties which prevent the growth of virus types, salmonella, adhesives and other problematic bacteria are added.
• About 1 to 2% by weight of preservative of the overall formulation is preferably used.
• a lemon peel extract with skin-protecting properties can be mixed in up to 1% of the total formulation.
• This emulsion thus obtained is diluted 20 to 30 times for use as a grinding, drilling or cutting aid.
• this dilution can only be carried out using water at the place of use.
• a commercially available mixture which consists of 75 parts of di- and 25 parts of tri-ethanolamine and is in 50% aqueous solution is usually used as the di-triethanol mixture.
• the wax content of the emulsion according to the invention should be between about 10 to 15%.
• the preferred preservative is an aqueous solution of dioctylaminoethylglycine lactate and alkylaminoethylglycine hydrochloride, as sold by Goldschmidt, Essen / Ruhr, Goldschmidtstrasse under the trademark "TEGO”.
• This emulsion can be used as a concentrate for the production of cutting, drilling or grinding emulsions.
• 15 parts by weight of a wax are mixed with 80 parts by weight of a mixture consisting of 50% by weight of H 2 O, 12.5% of tri-ethanolamine and 37.5% by weight of di-ethanolamine and 0.1% by weight of a commercially available , nonionic emulsifier boiled and cooled to a temperature of 50 ° C after complete amination.
• a commercially available preservative is then added with 1% of the total mixture.
• This emulsion can be diluted 35 times with water for use as a grinding, drilling or cutting emulsion, with a pH between 8 and 9.
• An emulsion is prepared as described in Example 1, 3 parts by weight of amino soap being added to the starting mixture with stirring.
• the emulsion made with amino acid was also suitable for use as a drilling, grinding or cutting aid.
• An emulsion was prepared as described in Example 2, except that 0.5-2% by weight sodium soap was added to the starting mixture.
• An emulsion was prepared as described in Example 1 or 2, with 0.5-2% by weight potassium soap being additionally added to the starting mixture.
• Example 1 The emulsion of Example 1 was diluted 35 times with water for use as a cutting oil, this diluted emulsion having a pH of 10. A circular saw with a circular saw blade of 15 mm in diameter was used. When using the emulsion according to the invention, the separating sheet had to be replaced after 2,800 separations.
• a comparison test with a conventional cutting oil showed that the circular saw blade had to be replaced after 1,200 separations. It was also observed that the machine ran less smoothly and smoothly than when using the emulsion according to the invention as cutting oil.
• Example 2 A 3% mixture of the emulsion of Example 1, diluted 35 times with water, was used in an MSO grinding machine.
• the emulsion according to the invention is suitable as a grinding emulsion.

Landscapes

• Chemical & Material Sciences (AREA)
• Chemical Kinetics & Catalysis (AREA)
• General Chemical & Material Sciences (AREA)
• Oil, Petroleum & Natural Gas (AREA)
• Organic Chemistry (AREA)
• Lubricants (AREA)
• Agricultural Chemicals And Associated Chemicals (AREA)

Priority Applications (1)

Applications Claiming Priority (4)

Publications (3)

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ID=25792471

Family Applications (1)

Country Status (6)

Cited By (1)

Families Citing this family (4)

Family Cites Families (15)

• 1982
  • 1982-03-31 DE DE8282102703T patent/DE3268625D1/de not_active Expired
  • 1982-03-31 EP EP82102703A patent/EP0062292B1/fr not_active Expired
  • 1982-04-01 US US06/364,505 patent/US4440654A/en not_active Expired - Fee Related
  • 1982-04-02 BR BR8201867A patent/BR8201867A/pt unknown
  • 1982-04-02 ES ES511120A patent/ES8307283A1/es not_active Expired
  • 1982-04-05 CA CA000400477A patent/CA1181735A/fr not_active Expired

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