EP0063565A1 - Utilisation de l'ethanol dans le pulpage alcalin - Google Patents
Utilisation de l'ethanol dans le pulpage alcalinInfo
- Publication number
- EP0063565A1 EP0063565A1 EP19810901196 EP81901196A EP0063565A1 EP 0063565 A1 EP0063565 A1 EP 0063565A1 EP 19810901196 EP19810901196 EP 19810901196 EP 81901196 A EP81901196 A EP 81901196A EP 0063565 A1 EP0063565 A1 EP 0063565A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- ethanol
- pulping
- wood
- pulp
- naoh
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 title claims abstract description 28
- 238000004537 pulping Methods 0.000 title claims description 20
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 56
- 238000000034 method Methods 0.000 claims abstract description 14
- 229920001131 Pulp (paper) Polymers 0.000 claims abstract description 13
- 238000004519 manufacturing process Methods 0.000 claims abstract description 4
- 239000000203 mixture Substances 0.000 claims abstract description 4
- 239000002023 wood Substances 0.000 claims description 10
- 241000218657 Picea Species 0.000 claims description 5
- 235000011121 sodium hydroxide Nutrition 0.000 description 13
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical group [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 238000010411 cooking Methods 0.000 description 2
- 238000007670 refining Methods 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 235000014633 carbohydrates Nutrition 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000003911 water pollution Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C3/00—Pulping cellulose-containing materials
- D21C3/20—Pulping cellulose-containing materials with organic solvents or in solvent environment
Definitions
- This invention relates to wood pulping using chemical pulping media and more particularly relates to such media which result in superior wood pulps with a lower refining energy requirement.
- a method for manufacturing wood pulp which comprises pulping wood with a mixture of ethanol and sodium hydroxide.
- the invention also includes wood pulp manufactured in accordance with the method. DETAILED DESCRIPTION OF THE INVENTION
- the pulping time in accordance with the preferred embodiment, is from about 1/2 to about 4 hours and the pulping temperature is from about 100 to about 200°C.
- any wood can be pulped in accordance with the method of the invention to obtain a superior wood pulp than was obtained by commercially usuable prior arti chemical wood pulping methods.
- Spruce chips are cooked in an electrically heated digester with mixtures of water and ethanol (1 :1 by volume), at a 5:1 liquor to wood ratio, 170°C for 2-1/2 hr.
- cooks under the same conditions were carried out with the addition of 20% NaOH (calculated on wood), and with alkali alone.
- Table 1 shows that ethanol plus NaOH (column 1) is more effective than either ingredient alone
- the ethanol-NaOH process is especially significant in the area of high-yield pulping, because it allows a greater preservation of carbohydrates than NaOH alone. So, e.g., an ethanol-NaOH pulp of 81.6% yield (obtained with 5% NaOH, 170°C, 45 min.) has a Kappa number of 157, while a soda pulp (obtained with 20% NaOH) of 66% yield has a very similar (147) Kappa number. This is because in soda pulping only limited delignif ication can occur, thus low Kappa number pulps are obtained.
Landscapes
- Paper (AREA)
Abstract
Procede de fabrication de pulpe de bois comprenant la reduction en pulpe du bois au moyen d'un melange d'ethanol et d'hydroxyde de sodium et pulpe de bois obtenue conformement a ce procede.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/US1980/001451 WO1982001568A1 (fr) | 1980-10-29 | 1980-10-29 | Utilisation de l'ethanol dans le pulpage alcalin |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP0063565A1 true EP0063565A1 (fr) | 1982-11-03 |
Family
ID=22154626
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP19810901196 Withdrawn EP0063565A1 (fr) | 1980-10-29 | 1980-10-29 | Utilisation de l'ethanol dans le pulpage alcalin |
Country Status (2)
| Country | Link |
|---|---|
| EP (1) | EP0063565A1 (fr) |
| WO (1) | WO1982001568A1 (fr) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3212767A1 (de) * | 1982-04-06 | 1983-10-06 | Nicolaus Md Verwaltungsges | Verfahren und reaktor zum kontinuierlichen aufschliessen von pflanzenfasermaterial |
| AT510346A1 (de) | 2010-09-02 | 2012-03-15 | Annikki Gmbh | Ligningewinnung |
| AR091998A1 (es) | 2012-05-03 | 2015-03-18 | Annikki Gmbh | Procedimiento de preparacion de celulosa con baja concentracion de lignina |
| HUE041549T2 (hu) | 2013-11-20 | 2019-05-28 | Annikki Gmbh | Eljárás lignocellulózok frakcionálására |
| EP4722446A1 (fr) | 2024-10-01 | 2026-04-08 | Annikki GmbH | Procédé de production de pâte à papier |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2166540A (en) * | 1937-12-17 | 1939-07-18 | Univ Minnesota | Alcoholic treatment of ligneous cellulosic material |
| JP3093387B2 (ja) * | 1991-12-02 | 2000-10-03 | キヤノン株式会社 | 測定装置 |
-
1980
- 1980-10-29 EP EP19810901196 patent/EP0063565A1/fr not_active Withdrawn
- 1980-10-29 WO PCT/US1980/001451 patent/WO1982001568A1/fr not_active Ceased
Non-Patent Citations (1)
| Title |
|---|
| See references of WO8201568A1 * |
Also Published As
| Publication number | Publication date |
|---|---|
| WO1982001568A1 (fr) | 1982-05-13 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
| AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AT CH DE FR GB LU NL SE |
|
| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN |
|
| 18D | Application deemed to be withdrawn |
Effective date: 19821227 |