EP0070852A1 - Pestizide formulierungen - Google Patents
Pestizide formulierungenInfo
- Publication number
- EP0070852A1 EP0070852A1 EP82900377A EP82900377A EP0070852A1 EP 0070852 A1 EP0070852 A1 EP 0070852A1 EP 82900377 A EP82900377 A EP 82900377A EP 82900377 A EP82900377 A EP 82900377A EP 0070852 A1 EP0070852 A1 EP 0070852A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- composition
- active compound
- water
- insecticidally active
- insecticide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 22
- 238000009472 formulation Methods 0.000 title description 3
- 230000000361 pesticidal effect Effects 0.000 title description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000005892 Deltamethrin Substances 0.000 claims abstract description 9
- 229960002483 decamethrin Drugs 0.000 claims abstract description 9
- OWZREIFADZCYQD-NSHGMRRFSA-N deltamethrin Chemical compound CC1(C)[C@@H](C=C(Br)Br)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 OWZREIFADZCYQD-NSHGMRRFSA-N 0.000 claims abstract description 9
- 239000002917 insecticide Substances 0.000 claims description 21
- 241001465754 Metazoa Species 0.000 claims description 10
- 238000007598 dipping method Methods 0.000 claims description 9
- 241000283690 Bos taurus Species 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 6
- 239000000080 wetting agent Substances 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 239000002270 dispersing agent Substances 0.000 claims description 5
- 239000002775 capsule Substances 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 239000002728 pyrethroid Substances 0.000 abstract description 3
- 239000004480 active ingredient Substances 0.000 abstract description 2
- 239000007787 solid Substances 0.000 abstract description 2
- 230000000749 insecticidal effect Effects 0.000 abstract 2
- 238000004806 packaging method and process Methods 0.000 abstract 1
- 239000000843 powder Substances 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 241001494479 Pecora Species 0.000 description 3
- 241000238876 Acari Species 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 201000002266 mite infestation Diseases 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- DYBIGIADVHIODH-UHFFFAOYSA-N 2-nonylphenol;oxirane Chemical compound C1CO1.CCCCCCCCCC1=CC=CC=C1O DYBIGIADVHIODH-UHFFFAOYSA-N 0.000 description 1
- 241000283707 Capra Species 0.000 description 1
- 241000255925 Diptera Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- PNKUSGQVOMIXLU-UHFFFAOYSA-N Formamidine Chemical class NC=N PNKUSGQVOMIXLU-UHFFFAOYSA-N 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 206010067482 No adverse event Diseases 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 241001674048 Phthiraptera Species 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 206010039509 Scab Diseases 0.000 description 1
- 241000258242 Siphonaptera Species 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- VEMKTZHHVJILDY-UXHICEINSA-N bioresmethrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCC1=COC(CC=2C=CC=CC=2)=C1 VEMKTZHHVJILDY-UXHICEINSA-N 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 239000004495 emulsifiable concentrate Substances 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 239000002085 irritant Substances 0.000 description 1
- 231100000021 irritant Toxicity 0.000 description 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 1
- 150000004045 organic chlorine compounds Chemical class 0.000 description 1
- 244000045947 parasite Species 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 229920001983 poloxamer Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- HIEHAIZHJZLEPQ-UHFFFAOYSA-M sodium;naphthalene-1-sulfonate Chemical compound [Na+].C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 HIEHAIZHJZLEPQ-UHFFFAOYSA-M 0.000 description 1
- 239000004546 suspension concentrate Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 230000003442 weekly effect Effects 0.000 description 1
- 239000004563 wettable powder Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/34—Shaped forms, e.g. sheets, not provided for in any other sub-group of this main group
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
Definitions
- THIS INVENTION relates to insecticides, particularly pesticides for the treatment of animals.
- insects When dipping animals, such as cattle and sheep, the animals are dipped in an aqueous dip emulsion or suspension containing insecticides. As each animal passes through the dip, it removes a portion of the wash containing the insecticide. The amount removed by each animal varies generally between 0,05 gram and 7,5 grams.
- the insecticides used are generally organo-chlorine compounds, organo-phosphates, formamidines and pyrethroids. These insecticides are generally formulated as emulsifiable concentrates, wettable powders or suspension concentrates. These formulations are usually measured out in the field by the farmer and diluted with water before dipping or spraying.
- the invention concerns a suitable form of such insecticides, and which avoids handling by the farmer of highly toxic insecticides.
- the present invention provides a new composition of matter comprising a predetermined amount of a multiple unit dose of an insecticidally active compound in a package form, said package form being soluble in water.
- the insecticide conveniently may be a solid insecticide.
- a multiple unit dose is an amount of insecticide which is calculated to be used for treating a multiple number of animals.
- the package form may be a water-soluble sachet, tablet, capsule, or the like.
- Gelatin or polyvinyl alcohol may be used for forming a capsule or sachet.
- the insecticide may be present in the package as a finely milled dispersible powder (eg of a size below 10 ⁇ ), a wettable powder, or the like.
- Any suitable insecticide can be used, particularly a pyrethroid insecticide.
- An example is DELTAMETHRIN.
- Some of these pyrethroid insecticides are highly active and dipping or spraying at 0,0025% or less has been found to be sufficient for providing protection for many types of animals against external parasites, such as insects, ticks, flies, fleas, cattle mange mites, lice, sheep scab, goat mange, or the like.
- the composition may contain sufficient multiple dose for dipping from about 50 to 120 cattle, eg for dipping about 100 cattle of average size.
- the insecticide may also be mixed with a dispersing agent (for example the sodium salt of oxylignin, or a sodium naphthalene sulphonate/formaldehyde condensation product), a wetting agent and/or an anti-frothing agent.
- a dispersing agent for example the sodium salt of oxylignin, or a sodium naphthalene sulphonate/formaldehyde condensation product
- wetting agents are nonylphenol ethylene oxide/propylene oxide condensates and/or sodium diiscpropyl naphthalene sulphonate.
- a suitable anti-frothing agent is a silicone/water emulsion.
- the insecticide may make up from 10 to 90%, more usually about 30 to 60% of the composition.
- the dispersing agent can be present in amounts varying from less than that of the insecticide to more than that of the insecticide. Amounts of from 10 to 60% of dispersing agent have been found to be suitable.
- Anti-frothing agents may be present in amounts of up to 1%, and wetting agents in amounts of up to 7% by weight of the composition.
- the package form of the invention may be sold in any suitable size.
- the invention also provides a method of making up an animal dip, particularly a dip for cattle or sheep, which comprises dissolving or suspending the composition of matter, as provided by the invention, in a predetermined amount of water.
- Dispersing agent 47 7 % ('TAMOL NNO)
- Anti-frothing agent 0 , 12 % ('SILCOLAPSE 5000A')
- wetting agent (2) 0 , 90 % (Aerosol 'OS')
- the above mixture was milled with water to a very fine particle size (1-5 u) and dried. It was then packed into a watersoluble sachet.
- the sachets were made by heat-sealing together two layers of water-soluble pclyvinyl alcohol film. The sachets, when added to a dipping tank, dissolved rapidly and released the 47,7% Deltamethrin dispersible powder which dispersed easily to form a very stable suspension.
- Deltamethrin can be irritant to humans.
- the use of the capsule avoided handling of the insecticide by the user, such as a farmer:
Landscapes
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Agronomy & Crop Science (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ZA81848 | 1981-02-09 | ||
| ZA810848 | 1981-02-09 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP0070852A1 true EP0070852A1 (de) | 1983-02-09 |
Family
ID=25575194
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP82900377A Withdrawn EP0070852A1 (de) | 1981-02-09 | 1982-02-08 | Pestizide formulierungen |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP0070852A1 (de) |
| JP (1) | JPS58500024A (de) |
| AU (1) | AU8083282A (de) |
| BR (1) | BR8206159A (de) |
| WO (1) | WO1982002647A1 (de) |
| ZW (1) | ZW1682A1 (de) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IL90585A (en) * | 1988-06-15 | 1996-05-14 | May & Baker Ltd | Package releasing its contents on contact with water |
| GB2230445B (en) * | 1989-02-17 | 1993-10-27 | May & Baker Ltd | Package releasing its contents on contact with water |
| JPH0248505A (ja) * | 1988-08-10 | 1990-02-19 | Tosa Guriinzu Kk | 紙袋包装の農業用薬剤 |
| FR2644036B1 (fr) * | 1989-03-07 | 1992-01-17 | Rhone Poulenc Agrochimie | Combine herbicide constitue d'un emballage polymere hydrosoluble et d'un herbicide contenant de la n-phosphonomethylglycine |
| MA22490A1 (fr) * | 1991-04-02 | 1992-12-31 | Rhone Poulenc Agrochimie | Composition insecticide et unite insecticide |
| AU655282B2 (en) * | 1991-06-14 | 1994-12-15 | Rhone-Poulenc Agro | New aqueous formulations |
| FR2686320B1 (fr) * | 1991-11-21 | 1996-12-13 | Rhone Poulenc Agrochimie | Composition agrochimique effervescence a l'etat pulverulent dans un sac hydrosoluble ou hydrodispersable . |
| FR2684968B1 (fr) * | 1991-11-21 | 1994-12-23 | Rhone Poulenc Agrochimie | Systemes de conteneurisation pour compositions pour l'agriculture. |
| FR2718610B1 (fr) * | 1994-04-14 | 1996-06-07 | Roussel Uclaf | Nouvelles formulations pesticides et leur procédé de préparation. |
| JP2003506464A (ja) * | 1999-08-12 | 2003-02-18 | イーライ・リリー・アンド・カンパニー | 外部寄生虫殺虫性の水性懸濁製剤 |
| US6927210B1 (en) | 1999-08-12 | 2005-08-09 | Eli Lilly And Company | Ectoparasiticidal aqueous suspension formulations of spinosyns |
| KR20040045440A (ko) | 2001-09-17 | 2004-06-01 | 일라이 릴리 앤드 캄파니 | 농약 배합물 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB191113504A (en) * | 1911-06-06 | 1912-06-06 | Robert Berk | Improvements relating to Manures, Fertilisers, Insecticides and the like. |
| GB922317A (en) * | 1958-05-05 | 1963-03-27 | Associated Fumigators Ltd | Improvements in or relating to means for packaging pesticides |
| FR1263098A (fr) * | 1960-07-25 | 1961-06-05 | Enveloppe soluble à l'eau, pour l'emballage de produits détersifs, insecticides, sels de bain et autres matières à arôme fort | |
| US3556765A (en) * | 1967-08-08 | 1971-01-19 | Encap Products Co | Liquid soluble packet |
| US3877928A (en) * | 1967-08-08 | 1975-04-15 | Walter A Houston | Liquid soluble packet |
-
1982
- 1982-01-25 ZW ZW16/82A patent/ZW1682A1/xx unknown
- 1982-02-08 AU AU80832/82A patent/AU8083282A/en not_active Abandoned
- 1982-02-08 BR BR8206159A patent/BR8206159A/pt unknown
- 1982-02-08 JP JP57500506A patent/JPS58500024A/ja active Pending
- 1982-02-08 EP EP82900377A patent/EP0070852A1/de not_active Withdrawn
- 1982-02-08 WO PCT/GB1982/000031 patent/WO1982002647A1/en not_active Ceased
Non-Patent Citations (1)
| Title |
|---|
| See references of WO8202647A1 * |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS58500024A (ja) | 1983-01-06 |
| WO1982002647A1 (en) | 1982-08-19 |
| ZW1682A1 (en) | 1983-08-31 |
| BR8206159A (pt) | 1983-01-11 |
| AU8083282A (en) | 1982-08-26 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
| 17P | Request for examination filed |
Effective date: 19821007 |
|
| AK | Designated contracting states |
Designated state(s): CH DE FR GB LI |
|
| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN |
|
| 18D | Application deemed to be withdrawn |
Effective date: 19850521 |
|
| RIN1 | Information on inventor provided before grant (corrected) |
Inventor name: GIESELBACH, MARINUS LUKAS MUNNIK Inventor name: HOY, JOHN |