EP0071481A1 - Agents de réglage de la mousse et compositions détergentes les contenant - Google Patents

Agents de réglage de la mousse et compositions détergentes les contenant Download PDF

Info

Publication number: EP0071481A1
Authority: EP; European Patent Office
Prior art keywords: suds; gelatinised starch; detergent composition; silicone oil; control agent
Prior art date: 1981-07-31
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Granted

Application number

EP82304013A

Other languages

German (de)

English (en)

Other versions

EP0071481B1 (fr

Inventor

Louis Ho Tan Tai

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Unilever PLC

Unilever NV

Original Assignee

Unilever PLC

Unilever NV

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1981-07-31

Filing date

1982-07-29

Publication date

1983-02-09

1982-07-29 Application filed by Unilever PLC, Unilever NV filed Critical Unilever PLC

1982-07-29 Priority to AT82304013T priority Critical patent/ATE20358T1/de

1983-02-09 Publication of EP0071481A1 publication Critical patent/EP0071481A1/fr

1986-06-11 Application granted granted Critical

1986-06-11 Publication of EP0071481B1 publication Critical patent/EP0071481B1/fr

Status Expired legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims abstract description 31
239000003795 chemical substances by application Substances 0.000 title claims abstract description 29
239000003599 detergent Substances 0.000 title claims abstract description 20
229920002472 Starch Polymers 0.000 claims abstract description 27
235000019698 starch Nutrition 0.000 claims abstract description 27
239000008107 starch Substances 0.000 claims abstract description 25
239000008187 granular material Substances 0.000 claims abstract description 22
229920002545 silicone oil Polymers 0.000 claims abstract description 21
150000001875 compounds Chemical class 0.000 claims abstract description 11
238000000034 method Methods 0.000 claims abstract description 10
239000003960 organic solvent Substances 0.000 claims abstract description 6
238000005507 spraying Methods 0.000 claims abstract description 4
239000002245 particle Substances 0.000 claims description 14
239000003945 anionic surfactant Substances 0.000 claims description 6
238000001704 evaporation Methods 0.000 claims description 2
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 11
238000005469 granulation Methods 0.000 abstract description 5
230000003179 granulation Effects 0.000 abstract description 5
230000002209 hydrophobic effect Effects 0.000 abstract description 5
239000000377 silicon dioxide Substances 0.000 abstract description 5
239000007771 core particle Substances 0.000 abstract 1
238000005406 washing Methods 0.000 description 13
239000001993 wax Substances 0.000 description 11
239000000843 powder Substances 0.000 description 8
239000000344 soap Substances 0.000 description 6
239000011248 coating agent Substances 0.000 description 5
238000000576 coating method Methods 0.000 description 5
229920001296 polysiloxane Polymers 0.000 description 5
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
239000000463 material Substances 0.000 description 4
239000003463 adsorbent Substances 0.000 description 3
230000009849 deactivation Effects 0.000 description 3
230000000694 effects Effects 0.000 description 3
239000004744 fabric Substances 0.000 description 3
238000009472 formulation Methods 0.000 description 3
239000002736 nonionic surfactant Substances 0.000 description 3
239000012188 paraffin wax Substances 0.000 description 3
HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
239000004115 Sodium Silicate Substances 0.000 description 2
238000005054 agglomeration Methods 0.000 description 2
230000002776 aggregation Effects 0.000 description 2
230000001427 coherent effect Effects 0.000 description 2
238000009826 distribution Methods 0.000 description 2
238000002474 experimental method Methods 0.000 description 2
239000007788 liquid Substances 0.000 description 2
-1 polysiloxanes Polymers 0.000 description 2
229910000029 sodium carbonate Inorganic materials 0.000 description 2
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
229910052911 sodium silicate Inorganic materials 0.000 description 2
235000019832 sodium triphosphate Nutrition 0.000 description 2
239000002904 solvent Substances 0.000 description 2
238000003860 storage Methods 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
229920002261 Corn starch Polymers 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
235000019759 Maize starch Nutrition 0.000 description 1
206010067482 No adverse event Diseases 0.000 description 1
229910019142 PO4 Inorganic materials 0.000 description 1
235000019484 Rapeseed oil Nutrition 0.000 description 1
240000008042 Zea mays Species 0.000 description 1
230000002411 adverse Effects 0.000 description 1
238000013019 agitation Methods 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
229910000323 aluminium silicate Inorganic materials 0.000 description 1
125000000129 anionic group Chemical group 0.000 description 1
238000004380 ashing Methods 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
239000007844 bleaching agent Substances 0.000 description 1
239000000969 carrier Substances 0.000 description 1
239000004927 clay Substances 0.000 description 1
238000005260 corrosion Methods 0.000 description 1
230000007797 corrosion Effects 0.000 description 1
BNVZBQVIMPLFNA-UHFFFAOYSA-L disodium;2-(carboxymethoxy)butanedioate Chemical compound [Na+].[Na+].OC(=O)COC(C([O-])=O)CC([O-])=O BNVZBQVIMPLFNA-UHFFFAOYSA-L 0.000 description 1
VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 1
238000001035 drying Methods 0.000 description 1
235000013305 food Nutrition 0.000 description 1
239000003112 inhibitor Substances 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
238000002156 mixing Methods 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
239000010452 phosphate Substances 0.000 description 1
229920000642 polymer Polymers 0.000 description 1
239000002243 precursor Substances 0.000 description 1
150000003138 primary alcohols Chemical class 0.000 description 1
150000003333 secondary alcohols Chemical class 0.000 description 1
239000011734 sodium Substances 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000001509 sodium citrate Substances 0.000 description 1
NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
DZCAZXAJPZCSCU-UHFFFAOYSA-K sodium nitrilotriacetate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CC([O-])=O DZCAZXAJPZCSCU-UHFFFAOYSA-K 0.000 description 1
229960001922 sodium perborate Drugs 0.000 description 1
229940045872 sodium percarbonate Drugs 0.000 description 1
229940048086 sodium pyrophosphate Drugs 0.000 description 1
YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
239000007787 solid Substances 0.000 description 1
241000894007 species Species 0.000 description 1
239000007921 spray Substances 0.000 description 1
238000001694 spray drying Methods 0.000 description 1
239000000126 substance Substances 0.000 description 1
125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
239000004094 surface-active agent Substances 0.000 description 1
239000000725 suspension Substances 0.000 description 1
FRPJTGXMTIIFIT-UHFFFAOYSA-N tetraacetylethylenediamine Chemical compound CC(=O)C(N)(C(C)=O)C(N)(C(C)=O)C(C)=O FRPJTGXMTIIFIT-UHFFFAOYSA-N 0.000 description 1
235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0026—Low foaming or foam regulating compositions
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones

Definitions

This invention relates to detergent compositions containing suds control agents and to a process for their manufacture.
Detergent compositions particularly fabric washing detergent powders, which produce only a relatively small amount of suds in washing machines are gaining an increasing share of the European market as automatic (drum- type) washing machines become more widespread.
existing products generally use a mixture of soaps for controlling suds produced by anionic surfactants, or by mixtures of anionic and nonionic surfactants, it is now generally accepted in the industry that such products are not ideal, since the soap tends to have adverse effects, for example, on powder-properties. Consequently, there are now a large number of proposals in the literature for alternative suds-control agents which do not contain soap.
gelatinised starch is a useful material for forming the basis of a silicone-based suds control agent in that it has an optimum combination of sorbency and solubility characteristics.
the present invention provides a detergent composition comprising an anionic surfactant and a suds-control agent, characterised in that the suds-control agent comprises a core of gelatinised starch having a mixture of a silicone oil and hydrophobic silica adsorbed thereon.
a silicone oil compound This mixture of silicone oil and hydrophobic silica will now be referred to as a silicone oil compound.
the suds-control agent is coated with a layer of wax, preferably paraffin wax, since we have discovered that the storage characteristics of such coated agents are superior to those of uncoated ones.
the invention provides a process for making a detergent composition characterised by the steps of
gelatinised starch for the adsorbent core of the suds-control agent.
Gelatinised starch is essentially a partially hydrolysed starch which can be obtained by suspending granules of starch, such as maize starch, in water and drying the suspension in steam heated drums.
gelatinised starches sold under the registered Trade Mark "Amijel” by Society des Produits du Mais of Clamart, France, but we believe that other gelatinised starches will be just as effective.
the suds-control effect of silicone oil compounds is quite easily deactivated and two factors in the characteristics of the gelatinised starch which have been found to be important are its ionic character.and its pH. We prefer, for the stability reason referred to, that the gelatinised starch should be nonionic in character and also that the pH should be in the range 5.5 to 9.
the gelatinised starch Further important characteristics of the gelatinised starch are its particle size and its particle size distribution. Small particle size, that is to say a weight average particle size of from 50 to 500 microns is important from the viewpoint of maximising the surface area of the gelatinised starch, so that it can adsorb as much silicone oil compound as possible.
the particle size distribution is preferred to be narrow so that if it is decided to granulate the gelatinised starch, then the resultant granules are relatively uniform in size and shape.
the subsequent coating with a layer of wax is then more likely to be of uniform thickness and to be coherent than if particles of a widely different particle size are used to form the granule.
silicone oils used in the silicone oil compounds of the invention are generally from the chemical class of alkyl polysiloxanes. These materials are well known to industrial chemists and are available in a wide range of molecular weights, the higher molecular weight materials, as is usually the case with polymers, tending to be more viscous. Silicone oils are available from various suppliers, and Dow Corning Corporation of Illinois, USA, and Rhone-Poulenc Chemie, supply mixtures of silicone oils and silicas of various types, including hydrophobic silicas, which we have found very satisfactory for use as silicone oil compounds in this invention.
the process of this invention involves a granulation or agglomeration step.
Granulation and agglomeration are well-known techniques in which liquid is added to particles of a solid, with agitation, and in which large particles are formed.
the "Eirich" pan (registered Trade Mark) is an apparatus which is well-known in the food and detergents industry which was developed especially for granulation processes.
fluidised bed apparatus such as the "Anhydro" fluidised bed (registered Trade Mark) for granulation or, more preferably a Schugi (registered Trade Mark) mixer.
This type of mixer consists essentially of a closed cylinder provided with a set of mixer blades rotatable about its major axis. The blades are of variable pitch and are arranged so that they can impart a spiral mixing motion to particles in the mixer.
the side-walls of the cylinder are provided with spray nozzles for the introduction of liquid.
the process also involves a coating step and this can be a spraying step in which a solution of a wax in an organic solvent is sprayed onto the granules produced in the previous step. The solvent is then evaporated to leave a coherent coating of the wax on the granules.
a molten wax can be used in the coating step.
the type of wax used is not critical since, as it is _present in only a relatively thin layer, it will dissolve off the granules or agglomerates in the warm, detergent-rich environment of the-wash. liquor.
the softening point of the wax should be below the temperature at which washing generally takes place, that is to say below about 80°C.
wash temperatures it is becoming increasingly common for wash temperatures to be specified at as low as 60° or even 40°C. We prefer to use paraffin wax of these softening points, but there is no reason why other waxes, should not be used.
the relative proportions of the essential components in the preferred suds-control agents of the invention can vary quite widely, although since the gelatinised starch is intended to be present as an adsorbent it will normally be present in an amount greater than the silicone oil which it is intended to adsorb. Preferred relative proportions are: the percentages being based on the total weight of the suds-control agent.
the suds-control agent will normally be present in detergent compositions in accordance with the invention in amounts of from 0.1 to 2%, preferably 0.1 to 1%.
this invention is concerned with a suds-control agent and consequently no attempt has been made in this specification to describe all possible detergent compositions to which the component could be added. It is self-evident that the usual detergent composition components are appropriate provided that they . have no adverse reaction with the components of the suds-control agent.
anionic surfactants such as alkylbenzene sulphonates, primary and secondary alkyl sulphates, secondary alkane sulphonates, soaps and olefine sulphonates can be used.
Nonionic surfactants either alone or in combination with anionic surfactants can also be used, the preferred nonionic surfactants being C 7 to c24 primary or secondary alcohols ethoxylated with from 1 to 25 moles of ethylene oxide per mole of alcohol. Typical amounts of surfactant are from 3 to 25% by weight when only one species is present, and from 1 to 16% by weight when more than one is present.
Builders may be present in amounts of from 5 to 50% by weight.
Typical of the inorganic builders are sodium tripolyphosphate, sodium pyrophosphate and sodium orthophosphate, sodium carbonate and the crystalline and amorphous forms of aluminosilicates.
Organic builders such as sodium nitrilotriacetate, sodium citrate, sodium carboxymethyloxysuccinate, and the host of other materials have been been suggested as phosphate replacers are also appropriate.
sodium silicate as a corrosion inhibitor and powder structurant
oxygen bleaches such as sodium perborate and sodium percarbonate
bleach precursors such as tetraacetylethylene diamine, fluorescers, antiredeposition agents and anti- ashing agents, suds-suppressing agents other than the silicone granules of the invention, and moisture.
a fabric washing powder having the following formulation was prepared by conventional spray-drying and dry-dosing techniques:
the suds assessment test is performed by washing a standard load of clean washing in a Brandt 433 (registered trade mark) washing machine.
the washing machine was specially modified to provide a window and the window had an arbitrary scale on it from which suds height could be read.
the reservoir holding the wash liquor is fitted with a thermometer.
Example 2 A similar experiment to that in Example 1 was performed, but in this example the suds-control granules were prepared from 46 parts of the gelatinised starch and 46 parts of the silicone oil compound.
the granules were combined with the remaining components of the fabric washing powder, and the suds control performance of the powder was assessed as described above except that the powder formulation contained 1% of sodium hardened rape seed oil soap and a correspondly reduced amount of water.
the results of the suds control -assessment are shown in Table 2.

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Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Health & Medical Sciences (AREA)
Molecular Biology (AREA)
Emergency Medicine (AREA)
Detergent Compositions (AREA)

EP82304013A 1981-07-31 1982-07-29 Agents de réglage de la mousse et compositions détergentes les contenant Expired EP0071481B1 (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
AT82304013T ATE20358T1 (de)	1981-07-31	1982-07-29	Schaumregulierungsmittel und diese enthaltende detergenszusammensetzungen.

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
GB8123492		1981-07-31
GB8123492		1981-07-31

Publications (2)

Publication Number	Publication Date
EP0071481A1 true EP0071481A1 (fr)	1983-02-09
EP0071481B1 EP0071481B1 (fr)	1986-06-11

Family

ID=10523604

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
EP82304013A Expired EP0071481B1 (fr)	1981-07-31	1982-07-29	Agents de réglage de la mousse et compositions détergentes les contenant

Country Status (4)

Country	Link
EP (1)	EP0071481B1 (fr)
AT (1)	ATE20358T1 (fr)
DE (1)	DE3271649D1 (fr)
ES (1)	ES8308354A1 (fr)

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP0094250A1 (fr) *	1982-05-11	1983-11-16	Unilever Plc	Procédé pour la préparation de granules contenant un agent antimousse à base de silicone
EP0109247A3 (en) *	1982-11-10	1985-04-03	Unilever Plc	Hydrocarbon anti-foam granules
GB2178444A (en) *	1985-07-30	1987-02-11	Procter & Gamble	Suds-controlled, granular, detergent compositions
EP0206522A3 (en) *	1985-05-23	1987-05-27	Unilever Plc	Antifoam ingredient for detergent compositions
EP0213953A3 (en) *	1985-09-04	1988-01-13	Unilever Plc	Antifoam ingredient for detergent compositions
EP0684303A2 (fr)	1994-05-27	1995-11-29	Unilever Plc	Compositions détergents
US6521587B1 (en)	1999-08-13	2003-02-18	Dow Corning S.A.	Silicone foam control agent
US6521586B1 (en)	1999-08-13	2003-02-18	Dow Corning S.A.	Silicone foam control agent
US7279453B2 (en) *	2001-02-22	2007-10-09	Henkel Kommanditgesellschaft Auf Aktien	Foam regulating granulate
WO2010028898A1 (fr) *	2008-09-12	2010-03-18	Unilever Plc	Améliorations se rapportant à des assouplisseurs de tissu
CN114786739A (zh) *	2019-12-16	2022-07-22	库珀轮胎和橡胶公司	二氧化硅涂覆的淀粉

Citations (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR2462184A1 (fr) *	1979-07-31	1981-02-13	Eurand France	Nouvelles compositions antimousses sous forme de granules utilisables notamment dans les lessives en poudre
EP0040091A1 (fr) *	1980-05-12	1981-11-18	Unilever Plc	Granulés supprimant la mousse à utiliser dans des compositions détergentes

1982
- 1982-07-29 AT AT82304013T patent/ATE20358T1/de not_active IP Right Cessation
- 1982-07-29 EP EP82304013A patent/EP0071481B1/fr not_active Expired
- 1982-07-29 DE DE8282304013T patent/DE3271649D1/de not_active Expired
- 1982-07-30 ES ES514599A patent/ES8308354A1/es not_active Expired

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR2462184A1 (fr) *	1979-07-31	1981-02-13	Eurand France	Nouvelles compositions antimousses sous forme de granules utilisables notamment dans les lessives en poudre
EP0040091A1 (fr) *	1980-05-12	1981-11-18	Unilever Plc	Granulés supprimant la mousse à utiliser dans des compositions détergentes

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP0094250A1 (fr) *	1982-05-11	1983-11-16	Unilever Plc	Procédé pour la préparation de granules contenant un agent antimousse à base de silicone
EP0109247A3 (en) *	1982-11-10	1985-04-03	Unilever Plc	Hydrocarbon anti-foam granules
EP0206522A3 (en) *	1985-05-23	1987-05-27	Unilever Plc	Antifoam ingredient for detergent compositions
GB2178444B (en) *	1985-07-30	1989-12-28	Procter & Gamble	Detergent compositions.
GB2178444A (en) *	1985-07-30	1987-02-11	Procter & Gamble	Suds-controlled, granular, detergent compositions
EP0213953A3 (en) *	1985-09-04	1988-01-13	Unilever Plc	Antifoam ingredient for detergent compositions
US4818292A (en) *	1985-09-04	1989-04-04	Lever Brothers Company	Antifoam ingredient for detergent compositions
EP0684303A2 (fr)	1994-05-27	1995-11-29	Unilever Plc	Compositions détergents
EP0684303A3 (fr) *	1994-05-27	1996-07-10	Unilever Plc	Compositions détergents.
US6521587B1 (en)	1999-08-13	2003-02-18	Dow Corning S.A.	Silicone foam control agent
US6521586B1 (en)	1999-08-13	2003-02-18	Dow Corning S.A.	Silicone foam control agent
US7279453B2 (en) *	2001-02-22	2007-10-09	Henkel Kommanditgesellschaft Auf Aktien	Foam regulating granulate
WO2010028898A1 (fr) *	2008-09-12	2010-03-18	Unilever Plc	Améliorations se rapportant à des assouplisseurs de tissu
CN114786739A (zh) *	2019-12-16	2022-07-22	库珀轮胎和橡胶公司	二氧化硅涂覆的淀粉
CN114786739B (zh) *	2019-12-16	2023-10-31	固特异轮胎和橡胶公司	二氧化硅涂覆的淀粉

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ES514599A0 (es)	1983-08-16
ATE20358T1 (de)	1986-06-15
DE3271649D1 (en)	1986-07-17
EP0071481B1 (fr)	1986-06-11
ES8308354A1 (es)	1983-08-16

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Publication	Publication Date	Title
US4451387A (en)	1984-05-29	Suds control agents and detergent compositions containing them
EP0040091B1 (fr)	1983-09-14	Granulés supprimant la mousse à utiliser dans des compositions détergentes
CA1290640C (fr)	1991-10-15	Ingredient antimeulsifiant
US4818292A (en)	1989-04-04	Antifoam ingredient for detergent compositions
US4726908A (en)	1988-02-23	Agglomeration process including a heating step for making a free-flowing granulate
US3933672A (en)	1976-01-20	Controlled sudsing detergent compositions
CA1231206A (fr)	1988-01-12	Agents de lessive et d'assouplissement de tissus
EP0210721B1 (fr)	1990-03-21	Agents contrôlant la mousse pour détergents
EP0210731B1 (fr)	1990-03-14	Agents pour contrôler la mousse dans les détergents
CA1117394A (fr)	1982-02-02	Detergents
US4419250A (en)	1983-12-06	Agglomerated bentonite particles for incorporation in heavy duty particulate laundry softening detergent compositions.
GB2178444A (en)	1987-02-11	Suds-controlled, granular, detergent compositions
EP0071481B1 (fr)	1986-06-11	Agents de réglage de la mousse et compositions détergentes les contenant
NO166654B (no)	1991-05-13	Partikkelformig hjelpestoff for anvendelse i partikkelformige vaskemiddelblandinger; partikkelformig vaskemiddelblanding som inneholder slikt hjelpestoff.
CA1039142A (fr)	1978-09-26	Detersif a mousse controlee
JPS61271007A (ja)	1986-12-01	消泡成分
EP0094250B1 (fr)	1986-07-30	Procédé pour la préparation de granules contenant un agent antimousse à base de silicone
SE459658B (sv)	1989-07-24	Partikelformig hoegverkande textilmjukgoerande detergentkomposition avsedd foer maskintvaett, agglomererade bentonitpartiklar, laempliga att infoerliva i en partikelformig hoegverkande detergentkomposition samt foerfarande av bentonitpartiklarna
EP0337523B1 (fr)	1993-06-09	Compositions détergentes en poudre et leur procédé de préparation
US4482477A (en)	1984-11-13	Particulate detergent containing siliconate, composition and method for manufacture thereof
EP0403084B1 (fr)	1995-07-19	Procédé et produit d'agglomération de zéolites
JPH0445560B2 (fr)	1992-07-27
EP0520582B1 (fr)	1998-02-04	Procédé de préparation de compositions détergentes séchées par pulvérisation à base de zéolithe
EP0119746B1 (fr)	1986-06-25	Procédé pour la manufacture de poudre détergente
EP0723795A2 (fr)	1996-07-31	Agents anti-mousse sous forme de particules et leur utilisation