Classifications

• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
  • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
  • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
  • D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
  • D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
  • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
  • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
  • D06M13/144—Alcohols; Metal alcoholates
  • D06M13/148—Polyalcohols, e.g. glycerol or glucose
• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
  • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
  • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
  • D06M13/165—Ethers
• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
  • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
  • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
  • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
  • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
  • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
  • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
  • D06M13/2243—Mono-, di-, or triglycerides
• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
  • D06M7/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made of other substances with subsequent freeing of the treated goods from the treating medium, e.g. swelling, e.g. polyolefins
• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
  • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
  • D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions

Definitions

• the present invention relates to a yarn finish composition, a process for treating yarn therewith and yarn so treated. More particularly, the present invention relates to an oil-in-water finish composition for application to polyester, preferably polyethylene terephthalate, yarn as a spin finish and/or overfinish. When used as a spin finish, the composition is essentially non-fuming.
• yarn is used herein to include a variety of filamentary forms, for example filaments, fiber, thread, yarn in the form of cord, or other similar forms. Preferred use is in the construction of pneumatic tires or other reinforced rubber goods.
• the present invention provides an oil-in-water yarn finish composition, a process for treating yarn therewith and yarn so treated.
• the present invention also provides a method for improving the emulsion stability of an oil-in-water yarn finish composition.
• composition be an emulsion of water and about 15 to 40, most preferably 30, percent by weight of a nonaqueous portion which comprises:
• the emulsion stabilizer may contain small quantities of water (discussed below) and thus, the nonaqueous portion may not be completely nonaqueous; however, the amount of water is deemed insignificant.
• a "high" lauric oil is meant one which contains at least about 40 percent lauric groups
• a “high” oleic oil is meant one which includes at least about 60 percent oleic groups.
• Transesterification of the high lauric oil and the high oleic oil may be accomplished by any known manner. The method of manufacture is well known in the industry, such as is disclosed in "Bailey's Industrial Oil and Fat Products” Third Edition, pages 958-964 (1964), hereby incorporated by reference.
• a transesterified high lauric oil and high oleic oil is intended both the product of a transesterification of the high lauric oil and the high oleic oil and also the same or a similar product produced by means other than transesterification.
• a lubricant may include from about 10 to about 90 percent high lauric oil and from about 10 to about 90 percent high oleic oil.
• high oleic oils would include glycerol trioleate, olive oil, peanut oil, selectively hydrogenated soybean oil and combinations thereof.
• high lauric oils would include coconut oil, palm kernel oil and combinations thereof.
• the lubricant preferably comprises transesterified coconut oil and glycerol trioleate, the product comprising approximately 50 percent glycerol trioleate and approximately 50 percent coconut oil.
• the polyoxyalkylene castor oil is preferably polyoxyethylene castor oil wherein there preferably are 16 to 33, more preferably 25 to 30, most preferably 25 or 26, moles of ethylene oxide per mole of castor oil.
• the alkylene oxide used could be propylene oxide or the butylene oxides as well as ethylene oxide.
• the preferred salt of dialkyl sulfosuccinate neat is sodium dioctyl sulfosuccinate.
• the preferred mixture of a salt of dioctyl sulfosuccinate and a salt of an aromatic carboxylic acid is a mixture of sodium dioctyl sulfosuccinate and sodium benzoate; the aromatic carboxylic acid could also be, for example, naphthalic acid.
• the preferred salt of dialkyl sulfosuccinate in solution or mixture is a solution of sodium dinonyl sulfosuccinate, propanol and water.
• the salts useful in this invention are the ammonium and alkali metal salts, particularly sodium and potassium, with the sodium salts being most preferred.
• the balance of the composition forms 40 to 94.75, more preferably 70 to 89.75 weight percent of the composition.
• the emulsion stabilizer is a solution of sodium dinonyl sulfosuccinate
• the silane is gamma-glycidoxypropyltrimethoxysilane
• the balance of the nonaqueous portion of the composition comprises: 57 weight percent transesterified coconut oil and glycerol trioleate; 25 weight percent polyoxyethylene castor oil having 25 or 26 moles of ethylene oxide per mole of castor oil; 5.5 weight percent of a mixture of triglycerol monooleate and triglycerol dioleate; 9.5 weight percent of decaglycerol tetraoleate; and 3 weight percent of 4,4'-butylidene-bis(6-tert-butyl-m-cresol).
• the finish composition is readily prepared in one of two ways.
• the lubricant, emulsifiers and antioxidant i.e., the balance of the nonaqueous portion, may be mixed together and the blend cleared with a small amount of water.
• the emulsion stabilizer can then be added to the resultant composition, and the remaining water is added subsequent thereto.
• the emulsion stabilizer can be added with the balance of the nonaqueous portion, preferably last, prior to the addition of any water (other than the small amount which may be present in the emulsion stabilizer).
• the lubricant and emulsifiers may suitably be heated to dissolve the antioxidant, but this is not necessary.
• the preferred method of preparing the composition of the present invention is as follows: the lubricant is heated to from about 98 to 122 0 C (210 to 250°F), and the antioxidant (SANTOWHITE® Powder) is added slowly under agitation; the emulsifiers are then added as the blend cools to about 48.9°C (120°F), and a low amount of water is added (if necessary) to obtain a crystal clear blend at room temperature.
• the amount of water necessary to clear the blend is from about 5.0 to about 12.5, preferably about 10, weight percent.
• the emulsion stabilizer is preferably added at room temperature to the blend.
• the blend including the emulsion stabilizer, and the necessary amount of water be added to one another at room temperature.
• the water is agitated, and the necessary amount of blend is quickly added.
• the agitation should be such that aeration does not occur.
• the mass should be stirred for at least 15 minutes to ensure adequate dispersion of the blend.
• Biocides or other additives may be added immediately after the blend is introduced.
• the silane and any other adhesion promoter utilized is added subsequent to the biocide (if a biocide is included in the emulsion).
• Dyes used as tinting agents for identification purposes should be added to the water and stirred until complete dispersion or dissolution of the dye is obtained prior to the introduction of the blend.
• the pH of the emulsion can be adjusted to the required degree dependent upon the p H of subsequent treatment systems, e.g., a subsequent latex dip system, to be used.
• a less preferred way of preparing the aqueous emulsion for use is to warm the blend to 37.8°C (l00°F), thoroughly mix the blend, heat the necessary amount of water to 48.9°C (120°F), and continue in the manner described above.
• the improvement in a process for the production of synthetic polymer yarn comprises treating the yarn with a sufficient amount of the oil-in-water yarn finish composition described above to achieve a total oil on yarn of 0.1 to 2.0 weight percent.
• the finish composition may be used as a spin finish during spinning of the yarn and/or as an overfinish subsequent to drawing.
• the spinning and drawing processes may be either coupled or uncoupled, preferably the former.
• the treating amount of finish composition is sufficient to achieve a total oil on yarn of 0.05 to 0.8 weight percent.
• the treating amount of finish composition is sufficient to achieve a total oil on yarn of 0.05 to 1.2 weight percent.
• the method for improving the emulsion stability of an oil-in-water yarn finish composition is to add 0.25 to 10 percent, based on the weight of the final nonaqueous portion of the composition, of an emulsion stabilizer as previously described.
• Emulsion stability is determined by measuring the percent light transmittance of a particular oil-in-water finish composition as compared to water (100 percent light transmittance) - the smaller the oil particle size, the greater the light transmittance, which results in better emulsion stability.
• the instrument utilized is the Beckman DK-2A (Beckman Instruments), a U V -visible spectrophotometer read at 735 nanometers.
• the yarns of this invention can be processed by any spin-draw process or spinning and separately drawing process available to the art and the patent and technical literature, using any suitable polyamide or polyester.
• the preferred polyesters are the linear terephthalate polyesters, i.e., polyesters of a glycol containing from 2 to 20 carbon atoms and a dicarboxylic acid component containing at least about 75 percent terephthalic acid.
• the remainder, if any, of the dicarboxylic acid component may be any suitable dicarboxylic acid such as sebacic acid, adipic acid, isophthalic acid, sulfonyl-4,4'-dibenzoic acid, or 2,8-di-benzofuran-dicarboxylic acid.
• the glycols may contain more than two carbon atoms in the chain, e.g., diethylene glycol, butylene glycol, decamethylene glycol, and bis-l,4-(hydroxymethyl)cyclohexane.
• linear terephthalate polyesters which may be employed include poly(ethylene terephthalate), poly(butylene terephthalate), poly(ethylene terephthalate/5-chloro- isophthalate) (85/15), poly(ethylene terephthalate/5-[sodium sulfo]isophthalate) (97/3), poly(cyclohexane-1,4-dimethylene terephthalate), and poly(cyclohexane-I,4-dimethylene terephthalate/hexahydroterephthalate) (75/25).
• a melt of polyethylene terephthalate was supplied at a rate of 70 pounds (31.8 kg) per hour per end and at a temperature of about 290°C to the apparatus shown in Figures 1 and 2 of U.S. Patent 4 251 481 to Hamlyn, hereby incorporated by reference.
• the molten polymer was fed by extruder 11 to spin pump 12 which fed spin block 13 containing a conventional spin pot as shown in Figure 1 of U.S. Patent No. 4 072 457 to Cooksey et al., hereby incorporated by reference.
• a split spinnerette designed for the simultaneous extrusion of two multifilament ends of 192 filaments each was utilized.
• the two ends 14 and 15 of multifilament, continuous filament yarn passed downwardly from the spinnerette into a substantially stationary column of air contained in a heated sleeve 16, about 15 inches (38.1 cms) in height, the temperature of the sleeve itself being maintained at about 400°C.
• Yarn leaving heated sleeve 16 was passed directly into the top of the quench chamber of quenching apparatus 17.
• Quenching apparatus 17 was as shown in Figure 1C of U.S. Patent No. 3 999 910 to P endlebury et al., hereby incorporated by reference. Quenching air at about 18.3°C (65°F) and 60 percent relative humidity was supplied to cross flow quench the filaments as they descended through the quench chamber.
• the ends 14 and 15 of yarn were lubricated by finish applicator 18 and then separated and converged by guides 19.
• the spin finish comprised 40 parts mineral oil having a viscosity of 38-40 SUS and a boiling range between 266 and 327°C; 15 parts refined coconut oil; 15 parts isohexadecyl stearate; 5 parts polyoxyethylene (20) tallow amine; 13 parts polyoxyethylene (4) lauryl ether; 10 parts sodium salt of alkylarylsulfonate; and 2 parts NEKAL WS-25 (see Table 1, footnote 13).
• a sufficient amount (approximately 0.45 percent wet pickup) of the finish composition was applied to the yarn to achieve about 0. 2 percent, based on the weight of the yarn, on the yarn.
• the overfinish was applied in an amount sufficient to achieve a total oil on yarn of about 1.0 to 1.2 percent and about 0.1 percent of silane on the yarn.
• Application of the overfinish (via contact with a roll rotating in a trough of overfinish) was even and smooth.
• the yarn was subsequently twisted to make a 3-ply cord in known manner, and the cords were treated with a conventional, non-ammoniated resorcinol-formaldehyde-latex dip comprising vinyl pyrridine latex, resorcinol, formaldehyde, sodium hydroxide and water. Subsequent thereto, the cords were dried [e.g., in a first oven at 148°C (300°F) for 80 seconds, followed by a second oven at 241°C (465°F) for 60 seconds, at +1% stretch] and introduced to a rubber compound. This green rubber was cured in a mold, and strips thereof tested in accordance with the strip adhesion test defined in U.S. Patent 3 940 544 to Marshall et al., hereby incorporated by reference, and modified to make strips having 40 ends per inch (15.7 ends per cm) rather than 20 ends per inch (7.8 ends per cm). There were no adverse affects on adhesion.
• Example 1 The procedure of Example 1 was repeated utilizing the overfinish composition as the spin finish to achieve a final oil on yarn of about 0.79 percent. There was no application of an overfinish. There were no adverse affects on adhesion.
• Example 1 The procedure of Example 1 was repeated with the following changes.
• the overfinish did not include an adhesion promoter, i.e., the gamma-glycidoxypropyltrimethoxysilane was omitted.
• the cord was treated with a conventional, blocked diisocyanate dip comprising Hylene M P [E. I.
• the resorcinol-formaldehyde-latex dip was ammoniated, and subsequent to treatment therewith, the cords were dried in a first oven at 148°C (300°F) for 80 seconds, followed by a second oven at 216°C (420°F) for 60 seconds, at -1 % stretch.
• the yarn processed well and had acceptable product qualities, e.g. adhesion.
• Example 3 The procedure of Example 3 is repeated utilizing the overfinish composition as the spin finish to achieve a final oil on yarn of about 0.8 percent. There is no application of an overfinish. The yarn processes well and has acceptable product quantities.

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• Engineering & Computer Science (AREA)
• Textile Engineering (AREA)
• Health & Medical Sciences (AREA)
• Emergency Medicine (AREA)
• Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Applications Claiming Priority (4)

Publications (3)

Family

ID=26980491

Family Applications (1)

Country Status (3)

Cited By (1)

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• 1982
  • 1982-09-13 CA CA000411307A patent/CA1179105A/fr not_active Expired
  • 1982-09-16 EP EP19820108548 patent/EP0079443B1/fr not_active Expired
  • 1982-09-16 DE DE8282108548T patent/DE3276244D1/de not_active Expired

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