EP0108883A2 - Procédé pour empêcher la corrosion des cylindres pour machines d'impression - Google Patents
Procédé pour empêcher la corrosion des cylindres pour machines d'impression Download PDFInfo
- Publication number
- EP0108883A2 EP0108883A2 EP83108957A EP83108957A EP0108883A2 EP 0108883 A2 EP0108883 A2 EP 0108883A2 EP 83108957 A EP83108957 A EP 83108957A EP 83108957 A EP83108957 A EP 83108957A EP 0108883 A2 EP0108883 A2 EP 0108883A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- printing
- corrosion
- dampening
- benzotriazole
- cylinders
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000007639 printing Methods 0.000 title claims abstract description 22
- 238000000034 method Methods 0.000 title claims abstract description 6
- 238000005260 corrosion Methods 0.000 title abstract description 13
- 230000007797 corrosion Effects 0.000 title abstract description 13
- 230000008569 process Effects 0.000 title abstract description 4
- 230000005764 inhibitory process Effects 0.000 title 1
- 239000000654 additive Substances 0.000 claims abstract description 10
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims abstract description 10
- 230000000996 additive effect Effects 0.000 claims abstract description 5
- 238000007645 offset printing Methods 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 abstract description 2
- 238000005530 etching Methods 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- 239000003112 inhibitor Substances 0.000 description 7
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 230000000845 anti-microbial effect Effects 0.000 description 2
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000009931 harmful effect Effects 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 238000005496 tempering Methods 0.000 description 2
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 1
- 239000004254 Ammonium phosphate Substances 0.000 description 1
- 239000005696 Diammonium phosphate Substances 0.000 description 1
- 229910001030 Iron–nickel alloy Inorganic materials 0.000 description 1
- 229910000990 Ni alloy Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 1
- 235000019289 ammonium phosphates Nutrition 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 239000007853 buffer solution Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910000388 diammonium phosphate Inorganic materials 0.000 description 1
- 235000019838 diammonium phosphate Nutrition 0.000 description 1
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 231100000957 no side effect Toxicity 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41N—PRINTING PLATES OR FOILS; MATERIALS FOR SURFACES USED IN PRINTING MACHINES FOR PRINTING, INKING, DAMPING, OR THE LIKE; PREPARING SUCH SURFACES FOR USE AND CONSERVING THEM
- B41N3/00—Preparing for use and conserving printing surfaces
- B41N3/08—Damping; Neutralising or similar differentiation treatments for lithographic printing formes; Gumming or finishing solutions, fountain solutions, correction or deletion fluids, or on-press development
Definitions
- the invention relates to a compound of formula 1H-benzotriazole.
- the flat printing process is based on the different wetting properties of printing ink and fountain solution. Influencing factors from a wide variety of problem areas, such as different dampening systems, printing plates, substrates and colors affect the printing process.
- a wide variety of fountain solution additives are known. The correct use of the fountain solution additives means an improvement in economy.
- DE-OS 2 914 255 it is known from DE-OS 2 914 255 to coat the surfaces of sheet-guiding cylinders to protect against the harmful effects of the materials used for printing and cleaning.
- Inhibitors to slow the rate of corrosion of metals are known.
- this inhibitor has not proven itself for the present problem.
- the object of the invention is to find a method by which the corrosive phenomena that occur in offset printing machines, especially on the cylinders, are prevented.
- a possibility is to be found to prevent the corrosion of nickel-plated cylinders.
- the solution to the problem is achieved according to the invention in that the compound 1H-benzotriazole is used as an additive for fountain solution in offset printing machines.
- 1H-benzotriazole has proven to be particularly effective for protecting nickel-plated cylinder surfaces. Surprisingly, the corrosion protection is complete at pH 5.5 and above. This is just a pH value that is preferably set for dampening solutions in the practice of offset printing.
- the additive or inhibitor 1H-benzotriazole shows in a particularly advantageous manner no side effects on the properties and function of the printing plate, and on the printability and drying of the printing ink.
- the inhibitor also has no harmful effects on the printing paper.
- 1H-Benzotriazole is colorless and does not change the color of the printing paper.
- the inhibitor does not affect the other components of the dampening solution and their effects.
- Components are e.g. Buffer system, agent for reducing the surface tension, as well as antimicrobial additives.
- Buffer system agent for reducing the surface tension
- antimicrobial additives e.g., antimicrobial additives.
- fountain solution additives must have an antimicrobial effect, i.e. preserve the fountain solution, because fountain solutions are generally good breeding grounds for microorganisms.
- the 1 shows a dampening unit 1 with a water tank 2 in the area of a plate cylinder 3.
- the plate cylinder 3 has a surface 4.1 on which a pressure plate rests.
- the water tank 2 is arranged in the central axis position of the plate cylinder 3. From the water tank 2 lead 8 and return lines 9 to a dosing and tempering 6, which is filled via an inlet valve 13.
- a pump 10 doses the liquid from the reservoir 6 into the water tank 2.
- the liquid is supplied via the inlet valve 13 from a water reservoir 5.
- a water pipe 14 fills the water reservoir 5 as required.
- a surface 4 of the printing cylinder 17 can e.g. be nickel plated.
- the liquid transfer to the pressure cylinder 17 takes place from the dampening unit 1.1. Here the liquid passes through a plate cylinder 3.1. From there, the liquid passes from below via a rubber cylinder 16.1 to the pressure cylinder 17 and thus enables the above-mentioned formation of corrosion.
Landscapes
- Printing Plates And Materials Therefor (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Manufacturing Of Printed Circuit Boards (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT83108957T ATE39336T1 (de) | 1982-11-13 | 1983-09-10 | Verfahren zur vermeidung von korrosion an druckmaschinenzylindern. |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE3242104 | 1982-11-13 | ||
| DE3242104A DE3242104C1 (de) | 1982-11-13 | 1982-11-13 | Verwendung eines Zusatzes zum Korrosionsschutz von Druckzylinderoberflaechen |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| EP0108883A2 true EP0108883A2 (fr) | 1984-05-23 |
| EP0108883A3 EP0108883A3 (en) | 1986-08-20 |
| EP0108883B1 EP0108883B1 (fr) | 1988-12-21 |
Family
ID=6178109
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP83108957A Expired EP0108883B1 (fr) | 1982-11-13 | 1983-09-10 | Procédé pour empêcher la corrosion des cylindres pour machines d'impression |
Country Status (3)
| Country | Link |
|---|---|
| EP (1) | EP0108883B1 (fr) |
| AT (1) | ATE39336T1 (fr) |
| DE (2) | DE3242104C1 (fr) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0358113A3 (en) * | 1988-09-08 | 1990-09-26 | Hoechst Aktiengesellschaft | Fountain solution for offset printing |
| US5523194A (en) * | 1994-09-16 | 1996-06-04 | E. I. Du Pont De Nemours And Company | Fount solutions for planographic printing processes |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE366560A (fr) * | 1929-12-09 | |||
| US3764323A (en) * | 1971-04-15 | 1973-10-09 | Apeco Corp | Method of forming lithographic printing plate |
| US3969237A (en) * | 1973-03-22 | 1976-07-13 | Mobil Oil Corporation | Lubricant compositions containing benzotriazole derivatives as copper passivators |
-
1982
- 1982-11-13 DE DE3242104A patent/DE3242104C1/de not_active Expired
-
1983
- 1983-09-10 AT AT83108957T patent/ATE39336T1/de not_active IP Right Cessation
- 1983-09-10 EP EP83108957A patent/EP0108883B1/fr not_active Expired
- 1983-09-10 DE DE8383108957T patent/DE3378725D1/de not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0358113A3 (en) * | 1988-09-08 | 1990-09-26 | Hoechst Aktiengesellschaft | Fountain solution for offset printing |
| US5523194A (en) * | 1994-09-16 | 1996-06-04 | E. I. Du Pont De Nemours And Company | Fount solutions for planographic printing processes |
Also Published As
| Publication number | Publication date |
|---|---|
| DE3242104C1 (de) | 1985-08-14 |
| DE3378725D1 (en) | 1989-01-26 |
| EP0108883B1 (fr) | 1988-12-21 |
| EP0108883A3 (en) | 1986-08-20 |
| ATE39336T1 (de) | 1989-01-15 |
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