EP0110007B1 - Utilisation de protéines du lait comme produits auxiliaires textiles - Google Patents

Utilisation de protéines du lait comme produits auxiliaires textiles Download PDF

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Publication number
EP0110007B1
EP0110007B1 EP83106984A EP83106984A EP0110007B1 EP 0110007 B1 EP0110007 B1 EP 0110007B1 EP 83106984 A EP83106984 A EP 83106984A EP 83106984 A EP83106984 A EP 83106984A EP 0110007 B1 EP0110007 B1 EP 0110007B1
Authority
EP
European Patent Office
Prior art keywords
milk
proteines
casein
dyeing
agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
EP83106984A
Other languages
German (de)
English (en)
Other versions
EP0110007A2 (fr
EP0110007A3 (en
Inventor
Dénes Pötschke
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to AT83106984T priority Critical patent/ATE33861T1/de
Publication of EP0110007A2 publication Critical patent/EP0110007A2/fr
Publication of EP0110007A3 publication Critical patent/EP0110007A3/de
Application granted granted Critical
Publication of EP0110007B1 publication Critical patent/EP0110007B1/fr
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/02—After-treatment
    • D06P5/04—After-treatment with organic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/384—Animal products
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof

Definitions

  • the invention relates to the use of milk protein as a textile auxiliary.
  • milk protein is used as a textile auxiliary or as an additive therefor, e.g. B. used for washing or cleaning textile products before dyeing, during dyeing and after dyeing.
  • B. used for washing or cleaning textile products before dyeing, during dyeing and after dyeing.
  • the milk protein is particularly valuable in its use when leveling stained goods. It has been shown that stains and other discoloration can be removed in a washing process with the help of the cleaning agent according to the invention even where there are all commercially available chemicals such as.
  • B. Hydrosulfite-type reducing agents with sodium hydroxide solution fail.
  • casein is used as a protective sheath for covering the fibers of wool yarn in order to avoid dyeing the fibers during the subsequent dyeing with block aniline black, i. H. to keep these places white.
  • the casein is used to mask the fiber to protect the fiber from coloring.
  • the casein is an insoluble coating around the fiber.
  • casein is used as a thickener for printing pastes.
  • ammonium caseinate is used as a protective colloid when dyeing polyester fibers, the casein having the task of stabilizing dyeing aids.
  • the protective colloid is destroyed for dyeing by increasing the temperature in order to release the dyeing aid.
  • Milk protein is degradable, so there are no environmental problems. Milk protein is a by-product of milk utilization in large quantities, for which the invention also creates a use.
  • Protein mixtures which can contain albumins and globulins are suitable as milk protein for the use according to the invention.
  • Casein or caseinates are preferred.
  • Milk protein, especially casein is usually commercially available as a powder that is sparingly soluble in water. However, by increasing the pH, casein can be made soluble in a known manner. Solubilization using ammonium hydroxide is preferred. However, other soluble caseinates can also be used.
  • the milk protein can be used in dissolved form, which is preferred if further constituents are usually used in liquid form anyway, as is particularly the case with textile auxiliaries.
  • a preservative is also advantageously used in order to avoid bacterial decomposition of the milk protein.
  • the treatment agent according to the invention is preferably free of polyphosphates. Further features and advantages of the invention result from the following examples in connection with the subclaims.
  • Cellulosic knitwear dyed with reactive and substantive dyes can no longer be improved with all known leveling and peeling (dye removal) textile auxiliaries and chemicals, and stain-free and color-neutral.
  • leveling and peeling (dye removal) textile auxiliaries and chemicals and stain-free and color-neutral.
  • a casein-containing leveling agent of the following composition these false stains are repaired in a boiling process without color spots or color:
  • Dwell time circulate at 98 ° C for 90 min. Then: drain and rinse twice with cold water
  • the goods are about 10% or not lightened at all (color remains). The discolouration has disappeared and the goods are absolutely color-neutral, the goods are not damaged and show a strikingly soft feel.
  • Examples 2 to 6 below show the use of milk proteins in the form of liquid preparations of digested milk protein which contain preservatives. These liquid preparations are preferably used in combination with surfactants or surfactant mixtures. When used as a dyeing aid, the solution of the milk protein can be called an equalizer and the solution of the surfactants can be called a corrector.
  • the leveler can be used on its own in the textile industry, e.g. B. as a leveling agent. In areas of application where increased cleaning is required, however, the leveler (milk protein) is preferably used in combination with the corrector (surfactant mixture).
  • the ratio of leveler to corrector can be in the ratio of 1: 2 to 2: 1, it preferably being 1: 1.
  • the leveler preferably contains 5 to 20 percent by weight soluble milk protein (caseinates) and a sufficient amount of preservative.
  • the corrector usually contains 20 to 60 percent by weight of wetting agent and water-soluble organic solvents.
  • the leveler and corrector are preferably prepared and used in the form of a common liquid mixture.
  • this may contain about 10 to 30 percent by weight of casein or caseinate and about 90 to 70 percent by weight of surfactant mixture. Depending on the intended use, this liquid mixture is then diluted many times over.
  • the corrector is mainly used for stained reactive and direct stains on cellulose goods with the possibility of refinishing in the decoction bath, as well as for lightening too dark reactive stains on cellulose.
  • milk protein is used as a leveling agent for cotton dyeing, especially of knitted cotton fabrics using substantive and reactive dyes after the pull-out process.
  • the leveling agent is added to the dye liquor prophylactically to prevent color irregularity.
  • liquid leveler per liter of liquor 0.05 to 0.35 g casein per liter of liquor
  • Equalizer and corrector which preferably consists of a mixture of non-ionic emulsifiers, detergents and cleaning enhancers, remove color stains and dirt stains from cotton stains that cannot otherwise be cleaned in combination if they have been dyed with substantive and reactive dyes.
  • the coloring remains unimportant.
  • the color tone becomes a maximum of 10% lighter.
  • Color nuance using milk protein and a surfactant mixture in a hot dye bath Color nuance using milk protein and a surfactant mixture in a hot dye bath.
  • the work speed is 30 to 40 m per minute and the bath temperature is 85 - 95 ° C.
  • the soaping is washable and rub-resistant. Other fastness properties such as light fastness etc. are not adversely affected. In the case of rough goods, rough passages and, if necessary, also padding quantity can be reduced.
  • the special leveling and cleaning effect is due to the milk protein, especially casein and caseinate.
  • the other chemicals or the corrector have a supporting effect.
  • the remaining components of the detergent or the corrector can be replaced by equivalent substances.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Zoology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Claims (8)

1. Utilisation de protéines du lait en tant que produit auxiliaire textile pour le lavage ou le nettoyage d'un tissu textile avant sa teinture.
2. Utilisation de protéines du lait en tant que produit auxiliaire textile pendant ou après la teinture d'un tissu en cellulose avec des colorants réactifs ou substantifs.
3. Utilisation de protéines du lait selon la revendication 2 en tant qu'agent d'égalisation pour la teinture d'un tissu en cellulose à l'aide de colorants réactifs ou substantifs.
4. Utilisation d'une protéine du lait selon la revendication 2 en tant qu'agent de surteinture pour réaliser la surteinture de couleur uniforme d'un tissu en cellulose coloré avec des colorants réactifs ou substantifs, en liaison avec un colorant.
5. Utilisation d'une protéine du lait selon la revendication 2 en tant qu'agent d'égalisation et d'éclaircissement de la teinte pour un tissu en cellulose teinté à l'aide d'un colorant réactif ou substantif, notamment en liaison avec un agent tensio-actif.
6. Utilisation d'une protéine du lait en liaison avec un agent tensio-actif utilisé comme agent de savonnage complémentaire pour un tissu en cellulose teinté à l'aide d'un colorant reactif, d'indanthréne, de naphtène et de soufre.
7. Utilisation d'une protéine du lait selon l'une des revendications précedentes, sous la forme d'un produit exempt de polyphosphates.
8. Utilisation d'une protéine du lait selon l'une des revendications précédentes, sous la forme de caséine ou de caséinates.
EP83106984A 1982-07-30 1983-07-16 Utilisation de protéines du lait comme produits auxiliaires textiles Expired EP0110007B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT83106984T ATE33861T1 (de) 1982-07-30 1983-07-16 Verwendung von milchprotein als textilhilfsmittel.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3228479 1982-07-30
DE19823228479 DE3228479A1 (de) 1982-07-30 1982-07-30 Waschmittel fuer textilien

Related Child Applications (1)

Application Number Title Priority Date Filing Date
EP87105029.0 Division-Into 1983-07-16

Publications (3)

Publication Number Publication Date
EP0110007A2 EP0110007A2 (fr) 1984-06-13
EP0110007A3 EP0110007A3 (en) 1984-12-19
EP0110007B1 true EP0110007B1 (fr) 1988-04-27

Family

ID=6169707

Family Applications (2)

Application Number Title Priority Date Filing Date
EP87105029A Expired - Lifetime EP0244647B1 (fr) 1982-07-30 1983-07-16 Utilisation de la caséine comme agent de nettoyage
EP83106984A Expired EP0110007B1 (fr) 1982-07-30 1983-07-16 Utilisation de protéines du lait comme produits auxiliaires textiles

Family Applications Before (1)

Application Number Title Priority Date Filing Date
EP87105029A Expired - Lifetime EP0244647B1 (fr) 1982-07-30 1983-07-16 Utilisation de la caséine comme agent de nettoyage

Country Status (5)

Country Link
US (1) US4761161A (fr)
EP (2) EP0244647B1 (fr)
JP (1) JPS5943099A (fr)
AT (2) ATE33861T1 (fr)
DE (3) DE3228479A1 (fr)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0762157B2 (ja) * 1987-08-14 1995-07-05 文一郎 細田 石けん
DE3903362A1 (de) * 1989-02-04 1990-08-09 Basf Ag Chemisch modifizierte proteine
NZ240224A (en) * 1991-08-26 1993-07-27 Protein Tech Int Laundry detergents including a casein modified material as a soil anti-redeposition agent
US5885306A (en) * 1994-02-01 1999-03-23 Meiji Seika Kaisha, Ltd. Method for preventing redeposition of desorbed dyes to pre-dyed fabrics or its garments and dye antiredeposition agent
US5494744A (en) * 1994-10-12 1996-02-27 Kimberly-Clark Corporation Method of applying a protein coating to a substrate and article thereof
US6194367B1 (en) 1995-03-01 2001-02-27 Charvid Limited Liability Co. Non-caustic cleaning composition comprising peroxygen compound and specific silicate and method of making the same in free-flowing, particulate form
US5898024A (en) * 1995-03-01 1999-04-27 Charvid Limited Liability Non-caustic cleaning composition comprising peroxygen compound and specific silicate, and method of making the same in free-flowing, particulate form
US5663132A (en) * 1995-03-01 1997-09-02 Charvid Limited Liability Company Non-caustic composition comprising peroxygen compound and metasilicate and cleaning methods for using same
JPH11501996A (ja) * 1995-03-14 1999-02-16 キンバリー クラーク ワールドワイド インコーポレイテッド 湿潤可能物品
US5858503A (en) * 1995-10-26 1999-01-12 Kimberly-Clark Worldwide, Inc. Method of applying chemical charge modifiers to a substrate and article thereof
US5855788A (en) * 1996-02-07 1999-01-05 Kimberly-Clark Worldwide, Inc. Chemically charged-modified filter for removing particles from a liquid and method thereof
US5912194A (en) * 1996-08-30 1999-06-15 Kimberly Clark Corp. Permeable liquid flow control material
DE19942538A1 (de) * 1999-09-07 2001-03-08 Cognis Deutschland Gmbh Waschmittel
DE19944222A1 (de) * 1999-09-15 2001-03-29 Cognis Deutschland Gmbh Waschmitteltabletten
DE10061280A1 (de) * 2000-12-08 2002-06-13 Novaprot Gmbh Reinigungswirksame, grenzflächenaktive Kombination aus nachwachsenden Rohstoffen mit hoher Fettlösekraft
DE102005055495A1 (de) * 2005-11-18 2007-05-24 Henkel Kgaa Textilbehandlungsmittel mit einem Milcherzeugnis
JP2009516089A (ja) * 2005-11-18 2009-04-16 ヘンケル・アクチェンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフト・アウフ・アクチェン 乳生成物を含んでなる布処理剤
CN1865559B (zh) * 2006-06-22 2010-09-29 上海题桥纺织染纱有限公司 牛奶蛋白纤维或其长丝或其混纺织物织造和染色的方法
WO2010025452A1 (fr) * 2008-08-29 2010-03-04 Micro Pure Solutions, Llc Procédé de traitement de fluides contenant du sulfate d’hydrogène

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2748800A1 (de) * 1976-11-05 1978-05-11 Unilever Nv Reinigungsmittel
EP0071413A2 (fr) * 1981-07-24 1983-02-09 Unilever Plc Compositions détergentes

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DE516983C (de) * 1927-02-10 1931-01-29 Appreturanstalt Verfahren zur Erzeugung weisser oder gefaerbter Effekte in Stueckware beim Faerben mit Klotzanilinschwarz
US2894801A (en) * 1956-11-29 1959-07-14 United Merchants & Mfg Textile printing emulsions
BE627260A (fr) * 1962-01-29
US3287277A (en) * 1964-02-20 1966-11-22 Barbour John Henderson Liquid detergent
GB1328107A (en) * 1969-12-30 1973-08-30 Ciba Geigy Uk Ltd Dyeing process
JPS4948590A (fr) * 1972-09-14 1974-05-10
FR2264085B1 (fr) * 1974-03-15 1976-12-17 Procter & Gamble Europ
GB1536136A (en) * 1975-03-03 1978-12-20 Unilever Ltd Detergent composition
US4079020A (en) * 1975-11-07 1978-03-14 Lever Brothers Company Cleaning composition
GB1562793A (en) * 1975-11-07 1980-03-19 Unilever Ltd Cleaning composition
DE2838274A1 (de) * 1978-09-01 1980-03-13 Bayer Ag Verfahren zum faerben und bedrucken von cellulosefasern mit reaktivfarbstoffen
NZ192549A (en) * 1979-01-12 1981-11-19 Unilever Ltd Liquid detergent comprising a copolymer of n-vinylpyrrolidone
DE3066352D1 (en) * 1979-05-04 1984-03-08 Ciba Geigy Ag Dyeing composition and processes for dyeing fabrics made of polyester or a polyester blend with cotton or wool
FR2528459B1 (fr) * 1982-06-11 1985-07-26 Sandoz Sa Procede de teinture ou d'impression de textiles encolles

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2748800A1 (de) * 1976-11-05 1978-05-11 Unilever Nv Reinigungsmittel
EP0071413A2 (fr) * 1981-07-24 1983-02-09 Unilever Plc Compositions détergentes

Also Published As

Publication number Publication date
DE3376435D1 (en) 1988-06-01
US4761161A (en) 1988-08-02
DE3382198D1 (de) 1991-04-11
EP0110007A2 (fr) 1984-06-13
ATE33861T1 (de) 1988-05-15
EP0244647A3 (en) 1988-06-08
JPS5943099A (ja) 1984-03-09
EP0244647B1 (fr) 1991-03-06
ATE61396T1 (de) 1991-03-15
DE3228479A1 (de) 1984-02-09
EP0244647A2 (fr) 1987-11-11
EP0110007A3 (en) 1984-12-19

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